Temperature-dependent Physical Properties Research Articles

Microstructure and Physico-Mechanical Properties of Biocompatible Titanium Alloy Ti-39Nb-7Zr after Rotary Forging

The evolution of microstructure, phase composition and physico-mechanical properties of the biocompatible Ti-39Nb-7Zr alloy (wt.%) after severe plastic deformation by rotary forging (RF) was studied using various methods including light optical microscopy, scanning and transmission electron microscopies, X-ray diffraction, microindentation, tensile testing and investigation of thermophysical properties during continuous heating. The hot-rolled Ti-39Nb-7Zr with initial single β-phase structure is subjected to multi-pass RF at 450 °C with an accumulated degree of true deformation of 1.2, resulting in the formation of a fibrous β-grain structure with imperfect 500 nm subgrains characterized by an increased dislocation density. Additionally, nano-sized α-precipitates formed in the body and along the β-grain boundaries. These structural changes resulted in an increase in microhardness from 215 HV to 280 HV and contact modulus of elasticity from 70 GPa to 76 GPa. The combination of strength and ductility of Ti-39Nb-7Zr after RF approaches that of the widely used Ti-6Al-4V ELI alloy in medicine, however, Ti-39Nb-7Zr does not contain elements with limited biocompatibility and has a modulus of elasticity 1.5 times lower than Ti-6Al-4V ELI. The temperature dependences of physical properties (elastic modulus, heat capacity, thermal diffusivity) of the Ti-39Nb-7Zr alloy after RF are considered and sufficient thermal stability of the alloy up to 450 °C is demonstrated.

Progress of Polymer Electrolytes Worked in Solid-State Lithium Batteries for Wide-Temperature Application.

Solid-state Li-ion batteries have emerged as the most promising next-generation energy storage systems, offering theoretical advantages such as superior safety and higher energy density. However, polymer-based solid-state Li-ion batteries face challenges across wide temperature ranges. The primary issue lies in the fact that most polymer electrolytes exhibit relatively low ionic conductivity at or below room temperature. This sensitivity to temperature variations poses challenges in operating solid-state lithium batteries at sub-zero temperatures. Moreover, elevated working temperatures lead to polymer shrinkage and deformation, ultimately resulting in battery failure. To address this challenge of polymer-based solid-state batteries, this review presents an overview of various promising polymer electrolyte systems. The review provides insights into the temperature-dependent physical and electrochemical properties of polymers, aiming to expand the temperature range of operation. The review also further summarizes modification strategies for polymer electrolytes suited to diverse temperatures. The final section summarizes the performance of various polymer-based solid-state batteries at different temperatures. Valuable insights and potential future research directions for designing wide-temperature polymer electrolytes are presented based on the differences in battery performance. This information is intended to inspire practical applications of wide-temperature polymer-based solid-state batteries.

A study of the effect of cerium ion doping concentration on the structural, electrical, and thermoelectric properties of CaMnO3 nanoparticles

Abstract Universally, energy loss in the form of heat is predominant and this heat is irrecoverable waste heat that leads to global warming. Clean, green, eco-friendly, cost-effective, and renewable energy sources are the possible solutions for this energy crisis and global warming issues. Thermoelectric power generation is a promising technology by converting this irrecoverable waste heat directly into electricity without any greenhouse gas emission. Nanostructured CaMnO3 at various cerium concentrations have been successfully prepared by sol–gel hydrothermal method followed by annealing and sintering. Pure and doped samples were systematically characterized by DSC, powder XRD, RAMAN, SEM with EDAX and FTIR spectroscopy. Electrical and thermoelectrical measurements were carried out on the sintered pellets. The XRD analyses confirmed the formation of orthorhombic perovskite structure for all the samples and the average particle size lies in the range of 50–60 nm. FTIR analysis shows the presence of CaMnO3 nanoparticles without any impurities. The temperature dependence of physical properties was performed and analyzed between room temperature and 600 °C. Electrical resistivity strongly depends on the nature of substituent ions and negative values indicate that the electrons are major charge carriers. Large Seebeck coefficient value and high-power factor make Ca1−x Ce x MnO3 an efficient thermoelectric material for energy storage applications.

Electro-thermal modeling of an induction heating process of 42CrMo4 steel probe

This paper describes the procedure of electromagnetic and thermal modeling of an induction hardening load of 42CrMo4 steel. In addition to the temperature and field level dependent physical properties of the material, the magnetic behavior of the load is captured by means of some kind of non-linear impedance boundary condition which simplifies the computational cost of the simulation. The numerical results show the critical behavior around Curie temperature. Finally, a comparison between several simulation results and experimental measurements are provided to assess the usefulness of the proposed electro-thermal simulation.

Investigation of some thermal properties of iron and chromium-based core-shell nanowires

Fe and Cr based core–shell nanowires (CSNWs) are modeled as cylindrical structures in which the atoms are arranged in a bcc crystal structure. Two different sizes with diameters of 2.5 nm and 4.5 nm for nanowires (NWs) are created and their lengths are set as four times their diameters. Their structural and thermodynamic properties are investigated through the molecular dynamics (MD) simulation technique in the canonical (NVT) statistical ensemble implemented in the open-source Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) software package. Atomic interactions between the atoms are described by using the many-body potentials based on the Embedded Atom Model (EAM). The melting temperatures of the NWs have been determined by investigating the behavior of the potential energy, specific heat capacity, radial distribution function, Lindemann melting criterion, the mean square displacement, and diffusion coefficients as a variation of temperature. The same melting temperatures are acquired from all these temperature-dependent physical properties for all NWs considered in this study. To the best of our knowledge, our simulation results are presented for the first time in this work and have the potential to guide experimental studies.

Numerical simulation of heat transfer during meat ball cooking and microbial food safety enhancement.

This study was conducted to apply the finite volume method (FVM) to solve the partial differential equation (PDE) governing the heat transfer process during meat cooking with convective surface conditions. For a one-dimensional, round-shaped food, such as meat balls, the domain may be divided into shells of equal thickness, with energy balance established for each adjacent shell using in the finite difference scheme (FDS) to construct a set of finite difference equations, which were then solved simultaneously using the FORTRAN language and the IVPAG subroutine of the International Mathematics and Statistics Library. The FDS is flexible for temperature-dependent physical properties of foods, such as thermal conductivity (k), specific heat (Cp ), thermal diffusivity (α), and boundary conditions, for example, surface heat transfer coefficient (h), to predict the dynamic temperature profiles in beef and chicken meat balls cooked in an oven. Once the FVM model was established and validated, it was used to simulate the dynamic temperature profiles during cooking, which were then used in combination with the general method to evaluate the thermal lethality of Shiga toxin-producing Escherichia coli and Salmonella spp. using D and z values in ground meats during cooking. The method can be applied to design cooking processes that effectively inactivate foodborne pathogens while maintaining the quality of cooked meats and evaluate the adequacy of a cooking process. PRACTICAL APPLICATION: The temperature dependences of thermal conductivity (k) and thermal diffusivity (α) of raw ground beef and ground chicken meats were measured. These thermal properties were then used in numerical simulation to predict the dynamic heating temperature profile and thermal lethality of ground beef and chicken meat balls. The numerical simulation method may be used to optimize and evaluate thermal processes and ensure the inactivation of pathogens in meat products during cooking.

First and second laws analysis of viscoelastic fluid with temperature dependent properties for Couette-Poiseuille flow

The entropy analysis of viscoelastic fluid obeying the simplified Phan-Thien-Tanner (SPTT) model with variable thermophysical properties are obtained for laminar, steady state and fully developed Couette-Poiseuille flow. The homotopy perturbation method (HPM) allows us to solve nonlinear momentum and energy differential equations. The Reynold's model is used to describe the temperature dependency of thermophysical properties. Results indicate that the increase of the group parameter (Br/Ω) and the Brinkman number (Br) which show the power of viscous dissipation effect; increases the entropy generation while increasing fluid elasticity (εDe2) decreases the generated entropy. Increasing the Reynolds variational parameter (α) which control the level of temperature dependence of physical properties attenuate entropy generation when moving plate and applied pressure gradient have the opposite direction and decreases entropy generation when moving plate and applied pressure gradient have the same direction or both plates are at rest. Also, increasing elasticity reduces the difference between variable and constant thermophysical properties cases. These results may give guidelines for cost optimization in industrial processes.

A novel model for viscoelastic fluid flow and heat near a stretchable plate using variable fluid properties: A computational study

This article is concerned with the boundary layer formations over a deforming plane heated surface in a viscoelastic fluid having temperature-dependent physical properties. Viscoelastic fluid obeys a well-accepted Jeffrey fluid model that characterizes both relaxation and retardation times phenomena. Mathematical modeling is performed by considering exponential variations in viscosity, thermal conductivity, relaxation time, and retardation time with temperature. Transport equations are formulated under the aforesaid assumption and are solved for self-similar solutions using a numerical scheme. Solutions are utilized to generate streamlines and isotherms in both Newtonian and viscoelastic fluids. The momentum and thermal layers are specifically scrutinized for various controlling parameters. Illustrative results are included reflecting the consequences of variable physical properties on the induced viscoelastic fluid motion and accompanying heat transfer. In addition, skin friction factor for Jeffrey fluid with variable properties is evaluated and described.

A Two-Dimensional Thermoelastic Analysis of a Cylindrical Shell Made of FGM with Temperature-Dependent Physical Properties

A Two-Dimensional Thermoelastic Analysis of a Cylindrical Shell Made of FGM with Temperature-Dependent Physical Properties

Heat transport across multi-layered skin tissue experiencing short-pulse laser irradiation: Case of temperature-dependent thermal physical parameters

Exactly tracing the heat transport within a multi-layered biological tissues exposed to a pulse laser irradiation is the key issue for successful application of modern therapies. The purpose of this paper is to explore the heat transport within an irradiated biological tissue with multi-layered sub-structure and temperature-dependent physical properties. A non-linear model of bio-heat transfer involved variable physical properties with respected to the space and temperature has been firstly proposed on the basis of dual-phase-lag model (DPL) of bio-heat transfer. A numerical procedure constructed on an explicit difference algorithm is then developed to trace the temperature history of each layer with temperature-dependent physical properties and associated thermal damage induced by a pulse laser. The parametric study of laser parameters, structure parameters of tissue and blood vessel, and variable thermal parameters on thermal response has been performed. The results state that the heat transport has been inhibited when considering temperature-dependent physical properties and a lower temperature would be predicted, which also would weaken the underlying thermal damage.

A review of the Kondo insulator materials class of strongly correlated electron systems: Selected systems and anomalous behavior

Studies of strongly correlated electron systems have been at the forefront of research in condensed matter physics ever since the discovery of the co-existence of strong Pauli-paramagnetism and superconductivity in the archetypal heavy-fermion compound CeCu2Si2 in 1979. The construct of correlated electron physics typifies the behavior of thermal and electronic properties of a material when the Coulomb interaction between conduction electrons exceeds the electron kinetic energy at a given thermal energy and redefines in remarkable ways our understanding of the behavior of a metal near its ground state. While correlated electron behavior has by now been demonstrated in a variety of different types of materials, Kondo systems in particular are arguably the most intensively studied among these. The Kondo interaction is used to describe the effect that a spin-magnetic ion has on its environment when immersed in the conduction electron sea of a metal. The localized spin of the Kondo ion polarizes nearby conduction electrons to form a so-called Kondo cloud, which acts to screen and magnetically (partially) neutralize the localized spin. In Kondo systems, the low-temperature behavior is prone to the formation of heavy fermions, which is the term given to quasiparticle excitations that define the emergence of effective electron masses that can be up to three orders of magnitude greater than that of a free electron. The Kondo effect presents itself in three guises: first, the single-ion Kondo state which is found in a metal having only a small amount of magnetic ions dissolved into it; second, the incoherent Kondo state in materials where there is a Kondo ion in every crystallographic unit cell of the material, but the Kondo ions remain incoherent or uncoupled from each other; and third, the coherent Kondo lattice state which manifests itself toward low temperatures where the interaction between Kondo ions becomes comparable to the thermal energy of conduction electrons that mediate magnetic exchange between Kondo ions. In a small number of cases, the outcome of a material condensing into the Kondo state turns out to be the peculiar formation of a very narrow energy band gap at the metallic Fermi energy. Such a band gap has significant consequences in practically all of the physical properties of a material that stem from the behavior of conduction electrons in proximity of the Fermi energy. This is most readily seen in electrical resistivity, heat capacity, and magnetic susceptibility. The band gapping gives cause to the term Kondo insulator (also referred to as Kondo semimetal or heavy-fermion semiconductor) that is used to describe this exceptional variety of Kondo systems. The term Kondo insulator is in general use although most Kondo insulators have a small but finite electrical conduction in the low-temperature limit where Kondo screening may be accomplished to its full extent. While the Kondo lattice ground state is exemplified by a very high density of electronic states at the Fermi energy, Kondo insulators, on the other hand, have, by virtue of narrow band gapping, a low density of electronic states. It remains a counter-intuitive observation, therefore, that despite their low density of states, Kondo insulators have curiously strong spin polarization energy scales and accompanying high values of their Kondo temperature, being the defining quantity which acts as an organizing principle in their temperature-dependent physical properties. In this article, we review the fundamentals of the Kondo insulating state, and we discuss the theoretical principles of what is presently understood about the formation of a Kondo insulator. The experimental results of a selected number of examples that have gained prominence in this class of materials are compared to each other in order to seek out similarities that may help deepen our understanding of the Kondo insulating state.

Enhancement of a quasi-analytical solution for modelling additive manufacturing processes

Numerical modelling methods (e.g. finite element) can provide accurate descriptions of long-range temperature fields in laser or electron-beam melting processes, however the high computational costs at part-scale make them unsuitable for process modelling in additive manufacturing (AM). Alternative methods such as semi-analytical solutions based on a moving heat source reduce the computational expense but at the cost of unrealistic assumptions. Radiation, temperature-dependent physical properties and latent heat are not considered in the semi-analytical approach but can have a significant effect on the thermal history. In this study, the error associated with each of these contributions are assessed against the conduction-only semi-analytical solution for a range of processing parameters for surface melting on solid Ti-6Al-4V. The semi-analytical model is then “enhanced” using results from finite element simulations to better account for the heat transfer in the AM process.

A new general analytical PBEM for solving three-dimensional transient nonlinear heat conduction problems with spatially-varying heat generation

In this paper, a polygonal boundary element method (PBEM) is presented, to solve the transient nonlinear heat conduction problems with spatially variable heat generation and temperature-dependent thermal physical properties. A new general method is developed to analytically compute the domain integrals regarding arbitrary nonlinearly-varying thermal conductivity, specific heat, and density, by which the computations of numerous Gaussian points in the numerical method can be circumvented and the efficiency of the PBEM can be significantly improved. The finite difference scheme is employed to evaluate the transient term, and the Newton iterative method is used to search the exact solution of the nonlinear system equation. Four numerical examples are designed to examine the property of the proposed method. The results indicate that the proposed analytical PBEM can accurately solve the three-dimensional transient nonlinear heat conduction problems with heat generation.

Joule heating and Soret effects on an electro-osmotic viscoelastic fluid flow considering the generalized Phan-Thien–Tanner model

This work analyzes the non-isothermal electro-osmotic fluid flow in a microchannel considering the Soret effect and temperature-dependent properties. The constitutive equation that models the fluid rheology corresponds to the generalized Phan-Thien–Tanner (gPTT) model. Temperature and pressure gradients are induced due to the interaction between an ionized fluid and the electrical field imposed at the microchannel's ends, resulting in Joule heating. The temperature-dependent physical properties of the fluid modify the ionic distribution in the electric double layer and its thickness change along the microchannel walls. The generalized Phan-Thien–Tanner (gPTT) model is used as a constitutive equation that describes the fluid rheology, where the trace-stress tensor is based on the Mittag–Leffler function, which represents the destruction of physical junctions and entanglements in the Lodge–Yamamoto network of viscoelastic fluids, through the inclusion of two fitting parameters: α and β. The gPTT model allows better fitting and flexibility to experimental data and a wider range of variation in the description of rheological responses of complex fluids. The hydrodynamics and thermodiffusion obtained through the gPTT model are compared against that using the linear form of the Phan-Thien–Tanner model (lPTT).

Thermal environment of the Chang’E-5 landing site and its effect on the external temperature of the lander

<p indent="0mm">The thermal environment of the lunar surface is extremely important to the thermal design of the lander, the placement of the detection instruments, and the interpretation of scientific exploration data. Clarifying the source and intensity of radiation on the outer surface of the lander is the key to its thermal management. In this paper, we first reported continuous temperature records over a 47.2 h period from five thermal couple sensors mounted on the auxiliary pillars of the landing gear of Chang’E-5 (CE-5). The recorded temperatures varied from a relatively small range of <sc>245.68–272.52 K</sc> at the beginning to a considerably wider range of <sc>284.86–369.76 K</sc> at the end of the recording period. To analyze the obtained CE-5 temperature records, we first developed a lunar surface thermal environment model with a layered regolith and temperature-dependent thermal physical properties. The model calculated that the ambient temperature of the CE-5 landing site over the sensor recording period increased from 341.40 to <sc>356.15 K.</sc> The calculated temperature was comparable to the estimates based on the <italic>in</italic>-<italic>situ</italic> spectral measurement, whereas it was systematically <sc>6–12 K</sc> higher than Diviner thermal infrared brightness temperature. We further developed a heat conduction model of the sensor-mounted auxiliary pillar and considered the surface temperature and the pillar geometry with respect to the Sun’s and the Earth’s orbital parameters. By introducing an impact factor<italic> F</italic> and via trial and error, we fitted the five CE-5 lunar temperature records with the RMESs of 0.72, 2.14, 0.53, 1.35, and <sc>3.36 K,</sc> respectively. Our analysis showed that the lunar surface thermal environment has a significant effect on the temperatures of both the shaded and sunny sides of the lunar lander. The environmental impact on the shaded side even exceeds that on the sunny side during the CE-5 recording period. The results of this paper are of great significance to both the theoretical research on the mechanism of the lunar thermal environment and the engineering applications in the thermal management design of a lunar lander, site selection of a lunar exploration mission, and temperature-related data interpretations, such as <italic>in</italic>-<italic>situ</italic> spectral data analysis.

Phase transformation and deformation of the high-frequency induction brazed grinding wheel based on multi-field coupling

With the characteristic of the high bonding strength to matrix, good sharpness, and large chip-storage spaces, the brazed super abrasive grinding wheels have superiorities in the machining of difficult-to-machine materials. However, thermal deformation is caused by the high temperature during the brazing process, leading to the accuracy of the brazed grinding wheel being degraded greatly. By means of local heating, high-frequency induction brazing can reduce the thermal deformation of the wheel. Aiming at the thermal deformation mechanism of the induction brazed wheel, a numerical simulation model of thermal-stress-phase multi-field coupling was established considering the temperature-dependent physical properties of the material. The simulation result indicated that the phase transformation occurred near the work surface of the wheel substrate. The depth of phase transformation layer decreased from 6.0 mm to 2.9 mm with the scanning speed increasing from 0.5 mm/s to 2.0 mm/s. The microstructure of the phase transformation layer mainly consisted of ferrite, pearlite, and bainite after brazing. An appropriate scanning speed was more important for the high accuracy of the wheel substrate during the induction brazing, since it had remarkable influence on the stress and deformation than brazing temperature. The experimental results of the microstructure morphology and deformation proved that the numerical simulation model was correct with 10.4% error.

Investigation of thermo-mechanical coupled behavior within irradiated biological tissues with temperature-dependent properties

The thermo-mechanical coupled behavior of biological tissues excited by a transient heating has been studied in this paper, in which the temperature-dependent physical properties are considered. A non-linear bio-thermo-mechanical coupled model with variable physical parameters has been proposed firstly in the context of the generalized theory with the dual-phase relaxation mechanism. An effective procedure constructed on an explicit finite difference scheme is then implemented to solve this non-linear model numerically. On this basis the thermo-mechanical coupled response and relative thermal damage within a skin tissue irradiated by a pulse laser has been explored. The temporal and spatial distributions of each physical field resulting from various cases have been obtained and illustrated. The results stated that the thermo-mechanical interaction induced by a laser heating would be inhibited by temperature-dependent physical parameters and this inhibition is more significant on the tissue displacement and normal stresses than tissue temperature. The thermal damage is also inhibited when the temperature dependence is considered and the time that healthy tissues can be tolerated would be a larger extension for its accumulative effect with tissue temperature.

Temperature-dependent properties of the antiferroelectric model PbZrO3 : An effective Hamiltonian study

A novel atomistic effective Hamiltonian scheme, incorporating an original and simple bilinear energetic coupling, is developed and used to investigate the temperature-dependent physical properties of the prototype antiferroelectric ${\mathrm{PbZrO}}_{3}$ (PZO) system. This scheme reproduces very well the known experimental hallmarks of the complex Pbam orthorhombic phase at low temperatures and the cubic paraelectric state of $\mathrm{Pm}\overline{3}\mathrm{m}$ symmetry at high temperatures. Unexpectedly, it further predicts a novel intermediate state also of Pbam symmetry, but in which antiphase oxygen octahedral tiltings have vanished with respect to the Pbam ground state. Interestingly, such a new state exhibits a large dielectric response and thermal expansion that remarkably agrees with previous experimental observations and the x-ray experiments we performed. We also conducted direct first-principles calculations at 0 K, which further support such a low-energy phase. Within this fresh framework, a reexamination of the properties of PZO is thus called for.

Characterization of Cubic Zirconia as a Lens Material Suitable for Autonomous Driving

As the development of autonomous driving technology is now in full swing, the demand for miniaturized optical modules mounted on various sensors has increased. Particularly, the optical lens used for such autonomous driving must demonstrate stable performance and durability despite rapid changes in the external environment. In this regard, cubic zirconia (CZ) can be used as an optical lens due to its high refractive index, which is above 2.1 in visible and near-infrared wavelengths, along with its chemical and mechanical durability. Thus, in this paper, we investigated the temperature-dependent physical properties of CZ fabricated by the skull melting method. The temperature coefficient of the refractive index (dn/dT) of the fabricated CZ plate in the temperature range of 25–100 °C decreased from 9.76 × 10−5/K to 7.00 × 10−5/K as the wavelength increased from 447.0 nm to 785.0 nm. The estimated Abbe number decreased from 33.98 at 25 °C to 33.12 at 100 °C, while the measured coefficient of thermal expansion (CTE) was 9.91 × 10−6/K, which revealed that the dn/dT value of the CZ plate was more affected by the dispersion than by the CTE. In addition, the CZ samples with a high refractive index, coated with a dielectric multilayer showed a high average transmittance of 98.2% at the investigated wavelengths, making it suitable for miniaturization or wide-angle optical lens modules. To secure the durability required for automobile lenses, the variation in the surface profile of the CZ before and after the external impact was also analyzed, revealing much better performance than TAF glass. Therefore, the observed results demonstrate that the CZ material is suitable for use as an optical lens for autonomous vehicles.

Vertical inhomogeneous magnetic order in FeRh film

FeRh films, known as antiferromagnetic materials at low temperatures, exhibit unexpected ferromagnetic (FM) characteristics, unlike the bulk. The detailed temperature-dependent physical properties of FeRh films were examined to elucidate the causes. Temperature-dependent magnetic and electrical measurements showed that the coexistence of antiferromagnetic and residual FM states induces thermomagnetic irreversibility (e.g., spin-glass-like behavior) and negative magnetoresistance. Polarized neutron reflectometry (PNR) revealed the presence of non-uniform FM states at the interfaces. Additional temperature-dependent PNR profile and room temperature structural and spectroscopic analyses confirmed that the bottom FM region is correlated with structural distortion. In contrast, the top FM region is temperature-dependent and originates from non-stoichiometry.