Temperature Dependence Of Dielectric Properties Research Articles

Studies on temperature dependent dielectric properties of some insulators down to liquid helium temperatures

The work discusses on the behavior of dielectric properties of various commercially available insulators with respect to temperature (4.2 K to 300 K) and operating frequency range of 2.52 KHz to 500 KHz. A conventional parallel plate-based capacitor setup was designed and developed considering various conditions. The dielectric constant was found to be very dependent on the pre-breakdown partial discharges at low temperatures. At 4.2 K the discharges move far away from the electrodes and exert high electric stress on the sample under test, which results in the breakdown or the decrease in the dielectric strength. The relative permittivity (ϵr) also decreased rapidly with the increase in frequency in most of the samples, this decrease is due to the reduction of space charge polarization effect. The correlation between the dielectric properties, operating frequencies and temperature have been studied in detailed.

Modulation of dielectric properties of hexagonal/cubic boron nitride composites

In this work, we synthesized mixed-phase hexagonal-boron nitride (h-BN)/cubic-BN (c-BN) composites with varying ratios and investigated their frequency and temperature-dependent dielectric properties. As the ratio of c-BN increased, we observed a corresponding increase in the dielectric constant of the composites. Furthermore, we used spark-plasma sintering (SPS) to treat the mixed-phase composite, which resulted in a phase transformation from mixed phase to pure h-BN phase. Remarkably, the composite exhibited an increase in dielectric constant after the SPS process, which can be attributed to the densification of the composite and the enhancement in grain size. Our approach presents a promising strategy for effectively modulating the dielectric properties of BN, which is crucial for advanced electronics.

Numerical solution-based algorithm assisted development of a continuous flow microwave reactor

Continuous flow microwave heating is a sustainable technology favored in the chemical and food processing sectors due to its short residence time and relatively low environmental footprint. To address the complexity of fluid dynamics and electromagnetic field interactions, nuanced evaluation methods beyond conventional reflection coefficient analysis are necessary to predict its efficiency and uniformity. In this study, a numerical solution-based algorithm is utilized to propose synchrony and cumulative index metrics for performance analysis. Although identical S-parameter systems demonstrate approximate electromagnetic power loss density in the fluid region, significant disparities in heating performance are observed, evidenced by outlet temperatures ranging between 108.10 °C and 147.09 °C, and covariances ranging from 0.07 to 0.46. The power loss density is corrected based on velocity to introduce the synchrony index, which is further calculated into the cumulative index. This approach provides accurate predictions of efficiency and uniformity, informing system designs that align with specific performance objectives. To achieve the best uniformity in simulated two-part systems, a combination of 63 % GIM system and 37 % EBH-2 system in terms of power input was found to be optimal. However, when considering temperature dependent dielectric properties, the optimal combination was adjusted to 60 % GIM system and 40 % EBH-4 system. The numerical solution-based algorithm facilitates optimization of complex continuous flow microwave systems, providing invaluable insights into the time–space electromagnetic response mechanism of fluids.

Predicting dielectric properties of fruit juices at 915 and 2450 MHz using machine learning and physicochemical measurements

Microwave-assisted thermal processing can provide superior quality for fruit-based products when compared to conventional thermal processing. Understanding the temperature-dependent dielectric properties of liquid foods is needed for the analysis and optimization of the microwave applicator chamber since they govern the heating rate and temperature distribution. While literature offers correlations for specific products, there is a scarcity of methods capable of accommodating variability in composition or predicting behavior for broader product groups. In this study, we measured the dielectric properties (dielectric constant and loss factor) of eight fruit juices (passion fruit, melon, pineapple, cashew, orange, lemon, acerola, and guava) using an open-ended coaxial-line technique for temperatures ranging from 5 to 90 °C at commercial frequencies of 915 and 2450 MHz, alongside electrical conductivity. These properties were successfully correlated with the temperature for each individual juice; then, machine learning techniques (random forest, gradient boosting machine, and multilayer perceptron) were used to predict the properties of this diverse group of eight juices based on various physicochemical measurements. These techniques revealed temperature and electrical conductivity as the most critical predictors, while total solids, pH, acidity, ashes, and select color parameters also emerged as significant variables. These findings demonstrate that the integration of physicochemical analyses with machine learning tools offers an objective approach to correlate and predict dielectric properties for a group of food products, facilitating adjustments in product composition without additional measurements, thus enhancing the efficiency and accuracy of microwave-assisted thermal processing simulations and optimizations.

Enhanced dielectrics, ferroelectric and optical properties of lithium niobate for high temperature applications using potassium oxide (K2O) additive

Dielectrics, Ferroelectric and Optical properties of Lithium Niobate has been examined using Potassium Oxide (K2O) as an additive on the samples prepared by solid state reaction method using high energy ball milling. The crystal structure analysis by Rietveld structure refinement confirms that the LiNbO3 (LN) with K2O additive also exhibit the rhombohedral structure with R3c space group. The SEM characterization of the microstructure reveals that the samples sintered at a temperature of 1050 °C, have regular and uniform grain morphology and better density. The average grain size decreases for the K2O added compositions in the beginning and increases later for higher concentration of additive. Thermal study with TGA suggests that as the activation energy is decreases, the polarization is enhanced and the LN composition with 2.72 wt% K2O additive shows the best thermal stability. The frequency and temperature dependent dielectric properties were investigated in a wide range of frequency and a substantial enhancement in the dielectric constant of LN is obtained by K2O addition. A useful enhancement in permittivity is obtained with increase of temperature. The band gap values for direct and indirect band gaps for the various compositions are also determined. The least direct band gap is discovered to be 2.36 eV for the composition with 2.72 wt% K2O additive. The composition-dependent photoluminescence (PL) emission studies reveal that the emission spectra for both the pure LiNbO3 and K2O added LiNbO3 compositions lies in the UV–visible region. All the investigated compositions exhibit distinct green, yellow, and red emission peaks. The LN with 2.72 wt% K2O additive shows the best dielectric, thermal stability and polarization response with maximum polarization Ps ∼1.16 μC/cm2. The present investigations suggest that properties of LN can be significantly improved by using K2O additive for sustainable, low cost, environmental friendly energy storage material for high temperature applications.

Frequency and temperature dependent dielectric properties of CuO nanoparticles

Copper Oxide (CuO) nanoparticles were synthesized by the solution combustion method. The crystallite size of the particles was determined using X-ray diffraction (XRD). The elastic properties of prepared nanomaterial were also studied using ELATE software. The dielectric properties of CuO nanoparticles were carried out at room (30 °C) and elevated temperatures (50–200 °C). The variation of the alternating current (ac) conductivity (σdc), dielectric constant (k), dielectric loss (tanδ), impedance (Z) and electric modulus (M) were studied as a function of frequency and temperature. The results showed that the dielectric properties and ac conductivity of the prepared nanoparticles were dependent on frequency and temperature. The prepared nanoparticles can be used for energy storage applications.

Dielectric, electrical and optical properties of a Ni-substituted double perovskite ceramic

In this report, iron based double perovskite oxide Ca2Fe0.85Ni0.15NbO6 was successfully synthesized adopting the solid state reaction method. The structure and microstructure along with the purity, frequency and temperature dependent dielectric properties, energy storage and band gap modulation properties of the ceramic is also discussed. The ceramic shows a small band gap with a high remnant polarization which aligns it toward ferroelectric photovoltaic device applications. The temperature stable dielectric constant of the material up to a high temperature range is useful for MLCC applications. The energy storage density of the material is calculated from room temperature hysteresis loop. The frequency variation of ac conductivity refers Jonscher’s law. The temperature variation of frequency exponent term n indicates CBH (correlated barrier hopping), model of the conduction mechanism in the sample. The presence of room temperature M-H loop with negligible magnetization and coercive value indicates the soft ferromagnetic behavior of the ceramic.

Investigation of Sn and Zr co-doped Ba0.5 Sr0.5 TiO3 for dielectric, impedance and conductivity behaviour in temperature and frequency region of measurement

In this report, we are presenting the effect of B-site co-doping with Sn and Zr (2% each) on frequency and temperature-dependent dielectric and electrical properties of Ba0.5Sr0.5TiO3 (BST). The desired compound is synthesised following solid-state reaction route and the structural and micro-structural study of the resulting compound is done using X-ray diffractometer (XRD) and scanning electron microscope (SEM) technique. XRD study revealed that the parent structure of BST is mostly retained after co-doping. SEM micrograph analysis presented dense packing of grains of different sizes distributed all over the volume of compound formed. The compound was found to have a moderate value of dielectric constant and low tangent loss along with a near stable response of these dielectric properties over the studied frequency range, suggesting its possible application in tuneable matching networks and frequency agile antennas. Electrical properties study suggested a non-Debye type electrical response with a thermally activated conduction mechanism occurring in the material. The dependence of conductivity with temperature showed negative temperature coefficient of temperature behaviour of the compound and the ac conductivity spectrum followed Johnscher’s power law. The variation of exponent with temperature suggested correlated barrier hopping conduction mechanism in the material.

Sonochemically synthesized black phosphorus nanoparticles: a promising candidate for piezocatalytic antibacterial activity with enhanced dielectric properties.

The drawbacks inherent to traditional antibacterial therapies, coupled with the escalating prevalence of multi-drug resistant (MDR) microorganisms, have prompted the imperative need for novel antibacterial strategies. Accordingly, the emerging field of piezocatalysis in semiconductors harnesses mechanical stress to drive chemical reactions by utilizing piezo-generated free charge carriers, presenting a promising technology. To the best of our knowledge, this study is the first to provide a comprehensive overview of the eradication of pathogenic S. aureus bacteria using few-layer black phosphorus (SCBP) piezo catalyst under mechanical stimuli, along with the exploration of temperature dependent dielectric properties. The synthesis of the piezo catalysts involved a one-step cost-effective sonochemical method, and its structural, morphological, elemental, optical, and overall polarization properties were thoroughly characterized and compared with the traditional method-derived product (TABP). The synthesis-introduced defects, reduced crystalline diameters, modified bandgap (1.76 eV), nanoparticle aggregation, photoluminescence quenching, along with interfacial polarization, synergistically contribute to SCBP's exceptional dielectric response (4.596 × 107 @40 Hz), which in turn enhanced the piezocatalytic activity. When subjected to soft ultrasound stimulation at 15 kHz, the piezo catalyst SCBP demonstrated significant ROS-mediated antibacterial activity, resulting in a ∼94.7% mortality rate within 40 minutes. The impact of this study extends to cost-effective energy storage devices and advances in antibacterial therapy, opening new dimensions in both fields.

Temperature dependent dielectric characteristics of PPY/Y2O3 composite

The Y2O3 doped polypyrrole composites has been synthesized (PPy-Y2O3) through an insitu polymerization route, to get dielectric properties for potential applications. XRD confirmed the formation of the composites. SEM confirms the flakier structure in the PPyY2O3. The impedance of pure Y2O3 ~ 14 Ω, PPy ~12 Ω to PPy-10%Y2O3 ~10 Ω compositesdecreased, signify the increase in AC conductivity of PPy-Y2O3. The temperature-dependent dielectric properties follow the Maxwell-Wagner model. AC conductivity of the PPy/Y2O3, increased with an increase in temperature depending on Jonscher’s power law. Therefore, the present study suggested that PPy-Y2O3 composites can be considered useful for device applications.

Synthesis and characterization of (1-x)Bi0.9Sm0.1FeO3 - (x)BaZr0.15Ti0.85O3 based solid solution: Temperature-dependent dielectric and impedance properties

Lead-free solid solution of (1-x) Bi0.9Sm0.1FeO3 − (x) BaZr0.15Ti0.85O3 (BSFO − BZT) (x = 0.0, 0.10, 0.15, 0.20, 0.25, 0.50) ceramics were prepared using solid-state reaction method. The structural, morphological, temperature-dependent dielectric properties and leakage current were investigated. The structural investigation revealed the formation of perovskite structure coexisting with tetragonal and rhombohedral phases within (BSFO–BZT) ceramics. The dielectric measurements (within 303 K-773 K) confirmed the existence of a morphotropic phase boundary at x = 0.15 for the (BSFO–BZT) system. The frequency and temperature dependent electrical behavior were explained using Ac conductivity and impedance analysis. The leakage current behavior for all these samples was investigated using both space charge-limited conduction (SCLC) for bulk and Schottky emission (SE) for limited interface conduction approach, whereas the pure BSFO sample was found to be dominated by ohmic conduction, while the BZT-doped samples were dominated by grain boundary-limited conduction.The sample (0.80)Bi0.9Sm0.1FeO3-(0.15)BaZr0.15Ti0.85O3 achieved largest dielectric constant 330 at 10 KHz along with a moderate leakage current density value of 3.54 × 10-5A/cm2 (which is quite lower than pure BSFO) proven its candidacy to develop a stable photovoltaic, multilayer actuators, and ferroelectric memory devices.

Adrenal ablation as a treatment for hypertension: analyzing the dielectric properties of adrenal glands for microwave ablation technologies

Abstract Adrenal gland-induced hypertension, also known as secondary hypertension, is a medical condition caused by an underlying adrenal pathology, most typically adrenocortical adenomas. Current clinical practices involve pharmacotherapy or surgical resection to treat adrenal gland diseases that cause hypertension. However, due to the limitations of these treatment options, microwave ablation (MWA) has emerged as a promising minimally invasive alternative. An accurate understanding of the dielectric properties of adrenal glands would support the further development and optimization of MWA technology for treating adrenal tumors. Only a few studies have examined the dielectric properties of both human and animal adrenal glands, and the sample sizes of these studies have been relatively small. Therefore, further dielectric data of human and animal adrenal glands are warranted. This paper presents the ex vivo dielectric properties of the ovine adrenal glands (medulla and cortex) and summarizes the published literature on dielectric data of adrenal glands from porcine, bovine, ovine, and human samples in the microwave frequency range to analyze the consistency and reliability of the reported data. The dielectric properties of the ovine adrenal glands (N = 8) were measured using an open-ended coaxial probe measurement technique at frequencies ranging from 0.5 to 8.5 GHz. This study also investigated the temperature-dependent dielectric properties of the ovine adrenal medulla ranging from 37 to 64°C at frequencies ranging from 0.5 to 8.5 GHz. The dielectric properties of the ovine adrenal medulla measured in this study were found to be consistent with the literature. Moreover, the review suggests that variations exist in the dielectric properties of the adrenal medulla and cortex among species. The study also found that the dielectric properties of the adrenal medulla decrease with increasing temperature, similar to other tissues for which temperature-dependent dielectric data have been reported. This summary of dielectric data of adrenal glands and the temperature-dependent dielectric properties of the ovine adrenal medulla will accelerate the development of MWA technologies for hypertension treatment.

Dielectric behavior and impedance spectroscopy of Niobium substituted Lanthanum based orthovanadates at high temperatures

We present the detailed study of the temperature dependent dielectric properties, impedance spectroscopy and electrical conductivity of LaV1−xNbxO4 (x=0–1) samples prepared by the solid-state reaction method. The dielectric constant (ϵr′) increases (decreases) with increase in the temperature (frequency); while, the magnitude of ϵr′ remains almost invariant (order of 104 at 100 Hz and 600 °C) with x. The single phase x=0 (monoclinic-monazite, P21/n) and x=1 (monoclinic fergusonite, I2/a) samples show the lower values of loss factor [tanδ= (4–8)] as compared to the x=0–0.8 samples [tanδ= (12–18)] having mixed tetragonal and monoclinic phases, which indicates the strong correlation between the crystal structure and the dielectric properties. The real part of impedance (Z′) decreases with both temperature and frequency, and the observed weak relaxation remains almost unaltered with x. The imaginary part of impedance (Z′′) shows strong relaxation peaks shifting towards higher temperatures with frequency, which is attributed to the effect of grains, grain boundaries, and electrodes in the samples. The activation energy of the relaxation process is estimated to be 0.8–1.0 eV for the x=0–0.6 samples, and ≈1.4 eV for the x=0.8; whereas the x=1 sample shows two values (≈0.5 eV and ≈1.0 eV) in the higher and lower temperature range, respectively. Further, the change in total conductivity with the angular frequency, which found to be in the range of 10−3 to 10−5 S/m, is fitted using the Jonsher power law. The analysis suggests the overlapping large polaron tunneling (OLPT) model for all the samples, whereas the x = 1 sample exhibit a transition near 480 °C and at higher temperatures it shows non-overlapping small polaron tunneling (NSPT) and quantum mechanical tunneling (QMT). This transition is corroborated by the tangent loss curves and may be associated with the change in structure.

Analysis of substitution of bismuth cations in CoFe2O4 nanoparticles and their influence on frequency and temperature-dependent dielectric and magnetodielectric properties

Analysis of substitution of bismuth cations in CoFe2O4 nanoparticles and their influence on frequency and temperature-dependent dielectric and magnetodielectric properties

Engineering room temperature multiferroicity and temperature dependent dielectric properties of Cr doped BaTiO3 ceramics

The coexistence of ferroelectricity, ferromagnetism, and piezoelectricity at room temperature in BaTi1-xCrxO3 (0 ≤ x ≤ 0.06) nanostructures is interesting and leads to the multiferroic nature of system. Sol-gel auto-combustion technique has been used for the synthesis of nanostructures. The XRD patterns along with Rietveld refinement analysis, confirm that the samples possess parent tetragonal perovskite structure in the P4mm space group. The oxygen vacancies stoichiometry ratio was estimated through XPS studies. The scanning electron microscopy (SEM) confirms the large grain size in the doped sample. The study of leakage current density reveals an increase in its value with the increase in Cr content due to defects induced in the system. P-E measurements confirm the ferroelectric nature of the samples that diminishes in the doped samples due to the high leakage current. Moreover, the estimated value of energy efficiency (η) was found to be maximum for the undoped sample. The undoped BaTiO3 has a diamagnetic character that is partially altered into weak ferromagnetic under the Cr-doping at the expense of decreasing polarization parameters. The temperature-dependent dielectric constant shows all characteristics of phase transitions in the samples. The doping of Cr enhances the ferroelectric to paraelectric phase transition temperature (Tc). The piezoelectricity remains preserved in the doped samples. Thus, the coexistence of ferroelectricity, ferromagnetism, and piezoelectricity at room temperature finalizes the multiferroic nature of the synthesized samples.

Synchronization of theoretical and experimental studies on the enriched optical and dielectric properties of size modulated CoCr2O4 quantum dots

This work focused on the influence of annealing temperature on CoCr2O4 nanoceramics synthesized through a co-precipitation method without the aid of surfactants or templates. The study for the first time correlated the electrical and optical properties of this nanomaterial and investigated the underlying physical concepts through probable theoretical demonstrations. Structural analysis using X-Ray diffractometry, Rietveld Refinement, and FTIR spectroscopy revealed a cubic crystal structure (space group Fd-3m) and the evolution of spinel-type AB2O4 phase. The crystallite size, determined via the Debye-Scherrer method, exhibited growth from 5.2 nm to 23.7 nm due to an increase in annealing temperature from 400 °C to 600 °C. Moreover, FESEM images exhibited an increase in grain size due to nanoparticle agglomeration at elevated annealing temperatures. The direct bandgap decreased from 2.55 eV to 2.40 eV as the annealing temperature escalated. The semi-conducting nature was also verified from Band structure, DOS, and I–V analysis. Crystallinity-mediated behaviour of various optical properties and emission spectra were carefully scrutinized. Frequency and calcination temperature-dependent dielectric properties and Nyquist plot revealed MWS-type polarization and semiconducting arc-like behaviour. The Coats and Redfern model computed activation energy of the system was 24.69 kJ/mol. These findings supported the suitability of this nanomaterial in optoelectronic applications.

Relative Investigation on Microwave-Assisted Zr-Modified PbTiO3 and BaTiO3 Ferroelectric Ceramics for Energy Storage Application.

The escalating demand for energy-related devices has prompted an intensive study on materials for energy harvesting and storage. Recently, due to the toxicity of lead-based materials, researchers have drawn their attention to lead-free ferroelectrics. However, it is indisputable that commercially lead zirconium titanate (PZT) has gained an irreplaceable position as an actuator. In the present work, we specifically compare microwave-sintered PbZr0.52Ti0.48O3 and BaZr0.20Ti0.80O3 ceramics based on their energy-storage capacity. The structural, optical, electrical, ferroelectric, and energy storage properties of microwave-sintered Zr-modified lead titanate (PbZr0.52Ti0.48O3, PZT) and Zr-modified barium titanate (BaZr0.20Ti0.80O3, BZT) ceramics are investigated and addressed. The temperature-dependent dielectric property analysis suggests high transition temperature and dielectric properties for PZT ceramic, whereas the near-room temperature transition is observed in the case of BZT. Furthermore, the band-gap energy value of BZT and PZT from UV-vis spectroscopy indicates the possible use of these ceramics in optoelectronic devices. The ferroelectric properties of PZT and BZT are discussed, and the maximum energy storage capacities are found to be 30.5 and 21 mJ/cm3 for PZT and BZT, respectively. It is found that microwave-sintered PZT's characteristics make it an attractive option for use in filters, phase shifters, sensors, actuators, and energy-related devices. On the other hand, BZT finds its suitability in biomedical devices and underwater applications.

Temperature-dependent dielectric properties of p-n heterojunction diodes based on hydrothermally synthesized ZnO nanostructures

In this study, the effect of coating p-Si substrates with a pure ZnO layer using the hydrothermal reaction method on the dielectric parameters was reported. The studied dielectric properties of the ZnO/p-Si structure include dielectric constant (ε′), dielectric loss (ε″), ac electrical conductivity (σ AC), and real and imaginary electrical modulus (M′, M″). These properties were investigated using experimental capacitance-frequency (C-f) and conductivity-frequency (G-f) measurements in a frequency range of 20 Hz-1 MHz and a temperature range of 300-420 K. Experimental results show that dielectric parameters are strongly frequency- and temperature-dependent. The dielectric constant showed an increase of about 11 times in the investigated temperature range. At the same time, AC electrical conductivity increased with increasing frequency and temperature. In addition, the electrical modulus was examined, and peaks were observed in M″ values. It was observed that the peaks shifted to the high-frequency region with the increase in temperature. The activation energies were also calculated from the conductivity parameters and a decrease was observed in the activation energies as the frequency increased. Regardless of temperature and frequency, the higher dielectric loss of the fabricated diode compared to its dielectric constant can be advantageous for certain heating or electromagnetic absorption applications.

Computational modeling of microwave ablation with thermal accelerants

Purpose To develop a computational model of microwave ablation (MWA) with a thermal accelerant gel and apply the model toward interpreting experimental observations in ex vivo bovine and in vivo porcine liver. Methods A 3D coupled electromagnetic-heat transfer model was implemented to characterize thermal profiles within ex vivo bovine and in vivo porcine liver tissue during MWA with the HeatSYNC thermal accelerant. Measured temperature dependent dielectric and thermal properties of the HeatSYNC gel were applied within the model. Simulated extents of MWA zones and transient temperature profiles were compared against experimental measurements in ex vivo bovine liver. Model predictions of thermal profiles under in vivo conditions in porcine liver were used to analyze thermal ablations observed in prior experiments in porcine liver in vivo. Results Measured electrical conductivity of the HeatSYNC gel was ∼83% higher compared to liver at room temperature, with positive linear temperature dependency, indicating increased microwave absorption within HeatSYNC gel compared to tissue. In ex vivo bovine liver, model predicted ablation zone extents of (31.5 × 36) mm with the HeatSYNC, compared to (32.9 ± 2.6 × 40.2 ± 2.3) mm in experiments (volume differences 4 ± 4.1 cm3). Computational models under in vivo conditions in porcine liver suggest approximating the HeatSYNC gel spreading within liver tissue during ablations as a plausible explanation for larger ablation zones observed in prior in vivo studies. Conclusion Computational models of MWA with thermal accelerants provide insight into the impact of accelerant on MWA, and with further development, could predict ablations with a variety of gel injection sites.

Synthesis and characterization of biowaste-based porous carbon nanoparticle-polymer dispersed ferroelectric liquid crystal composites

Herein, porous carbon nanoparticles (PCNPs) were synthesized using magnolia champaca seed pods and studied their doping effect on the polymer-dispersed ferroelectric liquid crystal (PDFLC) properties. The effect of PCNPs concentration (≤0.75 wt.%) on the morphology of PDFLC, polarization, and permittivity are investigated in thin sample cells. Field emission scanning electron microscope image results indicate the spherical shape of PCNPs of particle size ∼27 nm diameter. Temperature-dependent electro-optic and dielectric properties are also investigated in the wide SmC* phase and near transition temperature of SmC*-SmA*. Polarising optical microscope textures confirm the non-homogeneity of FLC molecules in the polymer matrix as a function of PCNPs concentration. Thespontaneous polarization and anchoring energy coefficients increase with increasing the doping amount of PCNPs.The phase transition temperature is found unaffected by PCNP doping in all prepared samples. In PDFLC and PCNPs doped PDFLC composites, usualbehaviourof permittivity as a function of temperature is observed. Fluorescence spectra show an enhanced two-fold increase in emission intensity peak at 412 nm wavelength for 0.5 wt.% PCNPs doped PDFLC while concentration-dependent quenching and slight redshift have been observed for the 0.75 wt.% PCNPs doped PDFLC. The enhanced electro-optic and dielectric properties observed in the composites suggest potential applications in displays, sensors, and optical devices. The findings open doors for further exploration and utilization of these functional materials in advanced electronic and photonic technologies.