Technique Suitability Research Articles

An advanced fabrication method for Yb3+-Doped optical fibers featuring AlPO4 core glass

Ytterbium (Yb)-doped fibers using aluminophosphosilicate (Yb-APS) host glass offer significant advantages over conventional aluminosilicate (Yb-AS) fibers, such as strong photodarkening resistance, higher RE-ion solubility and lower Numerical Aperture (NA), making them ideal for high-power laser applications. However, achieving optimal performance in Yb-APS fiber fabrication poses various challenges, including maintaining a precise Al3+/P5+ ratio (1:1), minimizing the central dip in the refractive index profile (RIP), ensuring proper dopant distribution, and reducing background loss. We introduce a new fabrication method for Yb-APS fiber to address these challenges. This approach entails first synthesizing amorphous Yb³⁺: AlPO4 particles, then incorporating them into the fiber core using a hybrid technique that merges Vapor Phase Delivery (VPD) with solution doping (SD). We extensively utilized various materials and optical characterizations, including XRD, FTIR, Raman spectroscopy, FESEM, and XPS, to fine-tune the composition of Yb³⁺: AlPO4. The optical characterization of the developed preform sample, including absorption, emission, and luminescent lifetime measurements, was conducted to assess the fabrication technique's suitability. The results confirmed the successful incorporation of Yb-ions into the preform core, with peaks consistent with reported values. The fiber's attenuation loss was measured, showing approximately 10 dB/km at 1200 nm. This indicates that the particles dissolved smoothly during preform and fiber processing, resulting in minimal scattering loss in the fiber core. The developed fiber demonstrated NA of 0.1, uniform RIP along the preform length with significant reduction of the central dip formation and improved spectral performance (∼1.7X broader bandwidth) compared with an equivalent Yb-AS fiber. These findings suggest the Yb-APS fiber's overall effectiveness and structural robustness, highlighting the potential of the proposed fabrication method for high-power fiber laser applications.

Interstellar Polarization Survey. IV. Characterizing the Magnetic Field Strength and Turbulent Dispersion Using Optical Starlight Polarization in the Diffuse Interstellar Medium

Angular dispersion functions are typically used to estimate the fluctuations in polarization angle around the mean magnetic field orientation in dense regions, such as molecular clouds. The technique provides accurate turbulent-to-regular magnetic field ratios, 〈Bt2〉1/2/Bpos , which are often underestimated by the classic Davis–Chandrasekhar–Fermi method. We assess the technique's suitability to characterize the turbulent and regular plane-of-sky magnetic field in low-density structures of the nearby interstellar medium (ISM), particularly when the turbulence outer scale, δ, is smaller than the smallest scale observed, ℓ min. We use optical polarization maps of three intermediate-latitude fields (∣b∣ ≳ 7.°5) with dimensions of 0.°3 × 0.°3, sourced from the Interstellar Polarization Survey–General ISM catalog. We decomposed the H i emission detected by the Galactic All-Sky Survey within our fields to estimate the multiphase ISM properties associated with the structure coupled to the magnetic field. We produced maps of the plane-of-sky magnetic field strength (B pos), mass density (ρ), and turbulent velocity dispersion (σ v,turb). In the regions with well-defined structures at d < 400 pc, the average B – ranges from ∼3 μG to ∼9 μ G, depending on the method and physical properties. In the region where structures extend up to 1000 pc, B pos varies from ∼1 to ∼3 μ G. The results agree with previous estimations in the local, diffuse ISM. Finally, optical starlight polarization and thermal dust polarization at 353 GHz consistently reveal a highly regular plane-of-sky magnetic field orientation unfazed by diffuse dust structures observed at 12 μm.

Isodose mapping of terrestrial gamma radiation in Sarawak-Borneo: Insights from surface-weathered soil analysis

Presentation of baseline data on terrestrial gamma radiation (TGR) levels is crucial for assessing the annual effective dose received by the public due to natural radiation exposure. Cumulative doses from various sources can become significant, warranting a spatial understanding of TGR distribution. Few countries have comprehensively mapped TGR on a national scale, often facing challenges due to remote or inaccessible regions. This study investigated the influence of weathered soil groups on TGR dose rates in Sarawak-Borneo, Malaysia, to facilitate insights for TGR projection and isodose mapping. A total of 1044 TGR dose rate measurements were collected using NaI (Tl) scintillation detector survey meters, with a mean of 100 nGy h−1 and a range of 8–375 nGy h−1. Non-parametric statistical analyses of variance using Welch's ANOVA, Brown-Forsythe, and Kruskal-Wallis validated (P-sig.=.000) notable dissimilarities among six categories of superficial-weathered soil. Graphical analysis using Sinclair's cumulative plot revealed deviations at intervals of 50, 80, 100, 120, 175, and 205 nGy h−1. These deviations indicate distinct lithological influences. Skeletal soil (entisols) and podzolic soils had high mean dose rates (148 and 113 nGy h−1, respectively) due to limited development, thus preserving abundant uranium (U) and thorium (Th). Meanwhile, gleysols and thionic soils exhibited compatible means (90 and 82 nGy h−1, respectively), while alluvial (or transported soils) and organic soils displayed lower dose rate ranges (mean of 76 and 47 nGy h−1, respectively), reflecting rapid hydrolysis weathering processes. Simple linear regression analysis revealed a strong relationship between TGR dose rate and mean value of weathered soil groups (y = 0.851x + 0.141 nGy h−1), signifying the significance and magnitude of weathered soil groups' impact on TGR dose rates. The obtained R-value is 0.704, indicating a strong linear correlation among soil group variables, and a Durbin-Watson statistic of 1.41, suggesting positive autocorrelation among residuals, thus positive relationships. An isodose map was successfully developed using the Kriging technique, aligning with lithological features of the study area. Semivariogram analysis reveals spatial dependence within a range of 1.47°, supporting the Kriging technique's suitability for spatial inference. In conclusion, this study has successfully revealed the relationship between TGR dose rates and superficial-weathered soil in Sarawak-Borneo. While the linear relationship is applicable to the Sundaland-Borneo tectonic block, it has potential to be used as a valuable tool for spatial inference of TGR dose rates in isodose development with similar lithologial characteristics, aiding in radiation exposure assessment and environmental monitoring.

Water mediated electrochemical conversion of PMMA and other organic residues into graphene and carbon materials

This paper proposes a new thermal, electrical, and water assisted reaction (TEAWAR) technique to convert PMMA and organic residues into graphene and carbonaceous materials. Graphene and other carbon based materials have attracted considerable research interest due to their unique and enhanced properties. Graphene is a particularly promising material for electronic and sensing applications, although preparation is cumbersome requiring high vacuum and other sophisticated facilities to produce quality graphene layers. Graphene and other carbon based materials are commonly prepared from organic and polymer precursors under high thermal conditions. This paper proposes a facile method to prepare graphene and other carbonaceous materials from poly(methyl methacrylate) (PMMA) polymer. PMMA is converted into graphene using a PMMA coated conducting substrate as one electrode in a two electrode electrochemical cell with water electrolyte, where conversion success depends on applied potential, time, temperature, and PMMA layer thickness. We converted PMMA coated on conducting substrates into graphene using 200 V potential for more than 1 h at 50 °C. This technique's suitability for organic residues conversion into carbon was also tested and found to be feasible to convert onion peel and other waste materials into carbon. Converted graphene was applied for photosensing and hydrogen evolution reaction (HER) applications. The formed graphene exhibited good catalytic property comparable to various graphene related materials.

Possible Extraction of Drugs from Lung Tissue During Broncho-alveolar Lavage Suggest Uncertainty in the Procedure's Utility for Quantitative Assessment of Airway Drug Exposure

Following inhaled dosing, broncho-alveolar lavage (BAL) is often used for sampling epithelial lining fluid (ELF) to determine drug concentration in the lungs. This study aimed to explore the technique's suitability. Urea is typically used to estimate the dilution factor between the BAL fluid and physiological ELF, since it readily permeates through all fluids in the body. As representatives of permeable small molecule drugs with high, medium and low tissue distribution properties, propranolol, diazepam, indomethacin and AZD4721 were infused intravenously to steady state to ensure equal unbound drug concentrations throughout the body. The results showed that propranolol had higher unbound concentrations in the ELF compared to the plasma whilst this was not the case for the other compounds. Experiments with different BAL volumes and repeated lavaging indicated that the amount of drug extracted is very sensitive to experimental procedure. In addition, the results show that the unbound concentrations in ELF compared to plasma differs dependent on molecule class and tissue distribution properties. Overall data suggests that lavaging can remove drug from lung tissue in addition to ELF and highlights significant uncertainty in the robustness of the procedure for determining ELF drug concentrations.

Space-Resolved Tissue Analysis by Solid-Phase Microextraction Coupled to High-Resolution Mass Spectrometry via Desorption Electrospray Ionization.

It is hard to overstate the tremendous utility of desorption electrospray ionization (DESI) and its various configurations for rapid and high-throughput analyses or spatially resolved imaging of heterogeneous systems. However, there have been few attempts to employ this technique in spatially resolved mode with solid substrates featuring extractive and analyte-enrichment properties. This study documents the development of a platform that combines solid-phase microextraction (SPME) with desorption electrospray ionization mass spectrometry (DESI-MS) for unidimensional investigation of the heterogeneous distribution of compounds in semisolid systems (i.e., depth profiling across the fiber axis), with the ultimate end of employing it for brain tissue analysis. To this end, a DESI interface and a custom holder accommodating SPME probes were built in house, with the latter contributing to reduction of mechanical sources of signal instability. The system was evaluated through the quantitative reconstruction of the laminar and radial concentration gradients of xenobiotics introduced in multilayer gel arrangements and surrogate brain tissue models. Good quantitative capability was achieved by employing a strategy that combined signal correction via preloading internal standard onto SPME fibers and signal integration in scan-by-scan mode. The proposed technique's suitability for characterizing more complex systems, such as rat brains ex vivo, was also evaluated. The proposed approach allows for fast and noninvasive probing of three-dimensional objects without the need for their slicing, and the space-resolved mode reduces the number of required probe insertions, allowing in vivo applications. We foresee suitability of this setup for examining the spatial patterns of local drug release in the brain and the extent of the resultant physiological responses.

Experimentation with Newton's extension to solve nonlinear algebraic equations

Iteration formula for this method is derived by including the second order term in the Taylor expansion. Experimentation shows that the method is suitable in some cases where standard Newton's formula fails. Also, the technique's suitability for finding more than one (possibly all) roots from a single starting value, is explored.

The Spectroscopic Age of 47 Tucanae

High signal-to-noise ratio integrated spectra of the metal-rich globular cluster 47 Tuc, spanning the HγHR and Fe 4668 line indices, have been obtained. Jones & Worthey have suggested that the combination of these indices is the best available mechanism for cleanly separating the age-metallicity degeneracy that hampers the dating of distant, unresolved, elliptical galaxies. For the first time, we apply this technique to a nearby spheroidal system, 47 Tuc, for which independent ages, based upon more established methods, exist. Such an independent test of the technique's suitability has not been attempted before but is essential before the technique's application to more distant, unresolved, stellar populations can be considered valid. Because of its weak series of Balmer lines relative to model spectra, our results imply a spectroscopic age of 47 Tuc well in excess of 20 Gyr, which is at odds with the color-magnitude diagram age of 14 ± 1 Gyr. The derived metal abundance, however, is consistent with the known value. Although the observational constraints are restrictive, existing data cannot entirely exclude emission fill-in of the Hγ line as the source of the discrepancy.

Investigating k distribution methods for parameterizing gaseous absorption in the Hadley Centre Climate Model

A technique for generating the coefficients of the k distribution method has been developed which uses very few exponential terms to represent absorption in a spectral region. This new technique, using k distributions derived from HITRAN 1992 spectroscopic data, predicts vertical profiles of irradiances and heating rates due to the major radiatively active gases with a better balance between speed of computation and accuracy than previous methods. Absorption coefficients were specified in a manner similar to that of the correlated k distribution method, whereas the weights of each term were determined using a fitting procedure similar in principle to the exponential‐sum fitting of transmissions method. Errors in irradiances and heating rates for various atmospheric profiles and the reference profile (with which fitting of weights was performed) were of a similar magnitude, thereby indicating the technique's suitability for use in global model studies. This parameterization is now used by the Hadley Centre climate model.