The rapid advancement of technology and the demands of our consumer-driven society significantly contribute to the growing volume of e-waste generated annually. This category includes all discarded components and products from electronic and electrical equipment that are not intended for reuse. Among these, Printed Circuit Boards (PCBs) are essential elements in all electrical and electronic devices and are difficult to reuse or recycle considering the complex structure of PCB. This study focuses on analyzing PCBs for their elemental content and the recovery of precious metal, silver. Elemental concentration was analysed using Neutron Activation Analysis (NAA), nano-colorimetry, potentiometry and Atomic Absorption Spectrometry(AAS) techniques .The findings reveal that Non -metallic part in analysed PCBs is about 80-84 % while among metallic concentrations, copper concentration was found to be highest (42.88-90.80 mg/g) and that of lead lowest (0.26-0.75mg/g).The total amount of silver in three PCB samples is approximately 2 mg/g, with a recovery rate was about 66%. However, the fourth sample contains a lower total amount of silver, with a recovery rate of 52.79%