The ∼AD 1305 Kaharoa eruption episode of Tarawera Volcanic Complex was the largest (∼4 km3 magma) eruption in New Zealand in the last 1000 years. High-silica (∼76% SiO2) rhyolite was erupted from seven vents along an 8-km linear zone to form pumiceous pyroclastic deposits and lava domes. Initial vent-clearing explosions were followed by a series of plinian pumice eruptions that spread tephra downwind, and pyroclastic density current deposits over the volcano slopes. The early pyroclastic eruptions were followed by extrusion of a dome in the summit vent and the migration of further plinian activity to adjacent vents. The episode finished with the extrusion of three summit lava domes, accompanied by block-and-ash flows. Two main types of rhyolite were erupted: (1) a low-Zr, low-Sr, high-Rb type comprising the early plinian pyroclastics and (2) a high-Zr, high-Sr, low-Rb type comprising the late eruptives including the summit domes. Basaltic material (basalt and basaltic andesite) is commonly present as free clasts within the Kaharoa pyroclastic deposits, along with rare clasts of granodiorite, diorite, gabbro and olivine clinopyroxenite. The basaltic clasts are often veneered by Kaharoa rhyolite. Basaltic material is also common as inclusions within rhyolite pumices, along with olivine and augite xenocrysts derived from the basalt. The basaltic clasts and inclusions contain complexly zoned plagioclase and corroded olivine (commonly with a reaction rim) consistent with disequilibrium caused by magma mixing. Some basaltic clasts and inclusions are hornblende-free; others contain groundmass hornblende. ‘Plumes’ of brown glass often extend from hornblende-bearing basaltic inclusions into the surrounding rhyolite. These plumes demonstrate magma mixing, as does the presence of rhyolitic glass and quartz xenocrysts in some basaltic inclusions. Most basaltic inclusions have crenulate boundaries, suggesting they were fluidal when coming into contact with the rhyolite magma. Diorite, gabbro and olivine clinopyroxenite clasts have mineralogy similar to the basalts, commonly contain patches of fine-grained basaltic material, and are considered co-magmatic with the basalts. Intrusion of basalt magma into the base of the rhyolite magma chamber appears to have occurred for some time before the Kaharoa eruptions began, allowing considerable mixing with the rhyolite magma, transfer of water to some basalt inclusions and formation of hornblende in their groundmass. Conversely, the hornblende-free basalt inclusions did not have time to react with the rhyolite magma and must have been intruded shortly before the start of the eruption. Intrusion of this hornblende-free basalt appears to have triggered the Kaharoa eruption, after the magma chamber had been primed by the earlier intrusions.