Tank Emissions Research Articles

Enhancing Residential Sustainability: Multi-objective optimization of hydrogen-based multi-energy system

To enhance residential sustainability by providing decarbonized and locally produced energy to a residential district, the relevance of a grid-connected multi-energy system, including PV panels, a battery, an electrolyzer, a hydrogen tank, and a fuel cell, is studied. A model is developed that creates high-resolution, continuous yearly profiles. The model is then utilized in a metaheuristic multi-objective optimization based on total cost and life cycle greenhouse gas emissions to highlight sizing trends. In the results, the most cost-efficient solutions rely mostly on PV power with minimal battery storage capacity, whereas hydrogen systems are necessary to achieve the best emission reductions. The analysis does not identify a promising prospect for seasonal energy storage with the current tank and battery lifetime emissions. Producing more than 65 % of the energy demand locally is not deemed beneficial.

Comparative analysis of alternative powertrain technologies in freight trains: A numerical examination towards sustainable rail transport

This study assesses the energy efficiency and environmental implications of six powertrain technologies in the U.S. freight rail network: diesel, biodiesel, diesel-hybrid, biodiesel-hybrid, hydrogen fuel cell, and electric. Utilizing a simulation model, energy consumption at the tank across different demand scenarios and geographical regions is conducted. The study revealed electric powertrains as the standout, slashing energy consumption at the tank by 56% compared to traditional diesel, with the potential for zero CO2 emissions when powered by green energy sources. Biodiesel and biodiesel-hybrid also outperformed conventional diesel, cutting CO2 tank emissions by 6% and 21%, respectively. Diesel-hybrid registered a 16% reduction in both tank energy and diesel consumption, while hydrogen fuel cells demonstrated a 15% energy consumption drop at the tank and zero emissions. Implementing these advanced technologies requires considerable infrastructure investment and adaptation, which is beyond the scope of our analysis. While centered on the U.S. rail network, our findings offer valuable insights for global freight rail systems, underpinning the push for sustainable powertrain transitions.

Quantification of natural gas and other hydrocarbons from production sites in northern West Virginia using tracer flux ratio methodology.

Tracer flux ratio (TFR) methodology performed downwind of 15 active oil and natural gas production sites in Ohio County, West Virginia sought to quantify air pollutant emissions over two weeks in April 2018. In coordination with a production company, sites were randomly selected depending on wind forecasts and nearby road access. Methane (CH4), ethane (C2H6), and tracer gas compounds (acetylene and nitrous oxide) were measured via tunable infrared direct absorption spectroscopy. Ion signals attributed to benzene (C6H6) and other volatile gases (e.g., C7 - C9 aromatics) were measured via proton-transfer reaction time-of-flight mass spectrometry. Short-term whole facility emission rates for 12 sites are reported. Results from TFR were systematically higher than the sum of concurrent on-site full flow sampler measurements, though not all sources were assessed on-site in most cases. In downwind plumes, the mode of the C2H6:CH4 molar ratio distribution for all sites was 0.2, which agreed with spot sample analysis from the site operator. Distribution of C6H6:CH4 ratios was skew but values between 1 and 5 pptv ppbv-1 were common. Additionally, the aromatic profile has been attributed to condensate storage tank emissions. Average ratios of C7 - C9 to C6H6 were similar to other literature values reported for natural gas wells.

Abnormal tank emissions in the Permian Basin identified using ethane to methane ratios

There has been increasing interest in quantifying methane (CH4) emissions from a view toward mitigation. Accordingly, ground-based sampling of oil and gas production sites in the Permian Basin was carried out in January and October 2020. Molar ethane to methane ratios (EMRs) were quantified, which may be used to distinguish emissions from particular sources, such as produced gas and oil tank flashing. The geometric mean EMR for 100 observations was 18 (±2)%, while source specific EMRs showed that sites where emissions were attributed to a tank produced much higher EMRs averaging 47%. Sites with other noticeable sources such as compressors, pneumatics, and separators had lower and less variable EMRs. Tanks displayed distinct behavior with EMRs between 10% and 21% producing CH4 emissions >30× higher than tanks with EMRs >21%. This observation supports the hypothesis that high emission rate tank sources are often caused by separator malfunctions that leak produced gas through liquids storage tanks.

Methane emissions from oil and gas production sites and their storage tanks in West Virginia.

A measurement campaign characterized methane and other emissions from 15 natural gas production sites. Sites were surveyed using optical gas imaging (OGI) cameras to identify fugitive and vented emissions, with the methane mass emission rate quantified using a full flow sampler. We present storage tank emissions in context of all site emissions, followed by a detailed account of the former. In total, 224 well pad emission sources at 15 sites were quantified yielding a total emission rate of 57.5 ± 2.89 kg/hr for all sites. Site specific emissions ranged from 0.4 to 10.5 kg/hr with arithmetic and geometric means of 3.8 and 2.2 kg/hr, respectively. The two largest categories of emissions by mass were pneumatic devices (35 kg/hr or ~61% of total) and tanks (14.3 kg/hr or ~25% of total). Produced water and condensate tanks at all sites employed emissions control devices. Nevertheless, tanks may still lose gas via component leaks as observed in this study. The total number of tanks at all sites was 153. One site experienced a major malfunction and direct tank measurements were not conducted due to safety concerns and may have represented a super-emitter as found in other studies. The remaining sites had 143 tanks, which accounted for 42 emissions sources. Leaks on controlled tanks were associated with ERVs, PRVs, and thief hatches. Since measurements represented snapshots-in-time and could only be compared with modeled tank emission data, it was difficult to assess real capture efficiencies accurately. Our estimates suggest that capture efficiency ranged from 63 to 92% for controlled tanks.

저장시설 배출량 산정기법 비교와 대기오염 방지시설 운용에 대한 LCA 분석

This study, to check the validity of storage tank emission regulation for the mandatory installation of air pollution prevention facilities for internal floating roof tanks and total hydrocarbon emission regulation, a reasonable emission calculation method is reviewed by comparing the engineering emission calculation methods in Korea and the United States. So when calculating storage tank emissions, it is recommended to calculate emissions by referring to the US AP-42, than life cycle assesment was conducted by composing four emission scenarios using the calculated emission information. From the side view, it was confirmed that it is more beneficial to improve the facility from a fixed roof storage tank to an internal floating roof storage tank than to operate an air pollution prevention facility for a storage tank filled with nitrogen.

Uncertainty consideration in CFD-models via response surface modeling: Application on realistic dense and light gas dispersion simulations

Major accidents in the process industry often lead to the release of light or dense gases, which can mean a thread to employees, local residents or to the environment. Possible scenarios are therefore analyzed and evaluated in advance for approval issues. There is a trend, where simple empirical models are being replaced with more complex numerical models. Gaussian dispersion models or models based on dimensional analysis approaches are for example, increasingly replaced by CFD simulations. The main reason for this is the potentially higher accuracy. However, usually scenarios using sharp parameter values are calculated, since comprehensive consideration of parameter distributions via Monte Carlo or Latin Hypercube Sampling fails due to the numerical effort. This includes the risk that the influence of uncertainties on the simulation results is not taken into account. Response surface methods offer an alternative, with which the CFD problem can be mapped onto an algebraic surrogate model. If this is sufficiently precise, parameter sampling can also be carried out with the surrogate as well, as shown in some publications. Previous investigations only demonstrated the basic principle using trivial dispersion models. In this paper two realistic CFD simulations from the plant safety area are considered: VOC emissions from a storage tank and near-ground dense gas emissions. The entire procedure of response surface determination and parameter studies was automated and parallelized for high-performance-computing, and is carried out on the underlying CFD grids. For the CFD simulations as well as for all visualizations, the commercial software ANSYS CFX and the open source software OpenFOAM were used. The aim of this paper is to demonstrate the method using industry-relevant applications as well as to show how this can be used in practical engineering applications. The quality of surrogate modeling, the numerical effort and advantages that can result from the procedure are discussed as well as advantages which may result from taking parameter uncertainties into account in safety studies.

ONLINE FIXED TANK VOLATILE ORGANIC CONTENT QUANTIFICATION USING MACHINE LEARNING

Tank emission calculation is typically performed offline, and manual data gathering from various tanks could be a timely and inefficient task. This paper presents iCON’s first principal process simulation software to perform tank emission quantification by leveraging its extensive database of all process simulation models and chemical components’ physical properties. Hence, a lot of operation cost is saved by eliminating the need for inventory sampling activity for each tank. This paper also will discuss online tank emission work processes to make them sustainable. iCON Tank Emission complies with the United States Environmental Protection Agency (USEPA) Compilation of Air Pollutant Emission Factors (AP-42) Fifth Edition Chapter 7 Liquid Storage Tanks that covers fixed roof tanks (vertical and horizontal) and floating roof tanks (internal, external, and domed) with a respective combination of the roof, shell, rim seal, fittings and breather vent settings. It is also linked to the monthly Malaysian Climate Condition covering domestic municipals’ temperature (minimum and maximum), Solar Irradiance Factor, and wind speed that improve the tank emission calculation accuracy. iCON Tank Emission lets users calculate thousands of tank emissions simultaneously by using iCON Machine Learning feature and displays the monthly and yearly summary reports for report standardisation among multiple business units. The simulation convergence time is instantaneous, making it time efficient for HSE engineers to perform strict monthly calculations and reporting online. Case studies and whatif scenarios could also be run to reduce tank emission via the introduction of vapour recovery and optimising tank mechanical parameters, i.e., type of rim seal, colour, and fittings selection. iCON Online Tank Emission links the iCON model with real-time plant information data for real-time tank emission calculation, transparent to management and regulators. The findings from this compositional first principle thermodynamic base tank emission simulation study are considered more efficient, faster, and cheaper than the conventional method.

Accurate Identification of Ambient VOCs Emission Sources in an Industrial Park Using On-Line Monitoring Data

To accurately identify and locate ambient volatile organic compounds(VOCs)emission sources in industrial parks, a continuous online GC-FID method was used to monitor 43 kinds of VOCs on an hourly basis during January 2017 at five sites in an industrial park. A statistical analysis and a PMF model were used to analyze the sources of VOCs, and by combining with CPF and enterprise emission information, the location of each pollution source was accurately identified. The average VOCs concentration was 56.40×10-9 and the highest concentration of alkanes was observed at four sites, with the exception of one site. Ethane, propane, ethylene, toluene, isobutane, n-butane, and acetylene were the main contributors. Ambient VOCs in the park mainly derives from five sources:urban transmission, butane leakage, process emissions, storage tank emissions, and ethylene synthesis. The enterprises in the zone B1, A1-A3, C1-C2, F4, E4-E6, F4-F6, and the canal loading and unloading area are the main emission areas of the pollution sources. Using online monitoring data, the research combined a PMF model, meteorological conditions, and corporate emissions information to achieve precise positioning of the pollution sources of VOCs in the industrial park, thus providing a basis for the supervision and management of corporate emissions in industrial parks.

Emissions from Air Vents of Coke-Plant Tanks

In view of the unsteady venting of tanks at coke plants over time, measurements of air-vent emissions are difficult. Accordingly, calculation is more expedient. Methods are reviewed for calculation the main types of tank emissions: minor breathing losses, major breathing losses, air admission, convection, and evaporation from a free surface.

Life cycle assessment of petroleum refining process: A case study in China

Climate change mainly caused by transportation fuel consumption has attracted global concern. In life cycle environmental burdens generated from transportation fuel production, petroleum refining stage is the hotspot. However, the in-depth environmental analysis of petroleum refining is very limited. China is the second largest petroleum refining country, so it is very essential to break petroleum refining stage into specific unit to analyze how Chinese refinery can be improved in environment performance. To achieve this goal, a systematic life cycle analysis of the environmental burden generated from petroleum refining process was conducted to identify the control emphasis and seek potential improvement measures. Sensitive analysis and volatile organic compounds (VOCs) emission characteristics were additional discussed to improve the accuracy of results. The significant burdens generated from petroleum refining process were freshwater ecotoxicity and climate change. Crude oil extraction and transport dominated most environmental categories, which indicated that the environmental problem exist in upstream supply chain. Catalytic cracking, feedstock and product handling, catalytic reforming, crude oil distillation, cooling water system and diesel hydrotreating were the major control units due to their direct emissions and electricity consumption. VOCs (e.g., acrolein and chlorofluorocarbons) produced from refinery fugitive emissions were the main substances for refinery to reduce human toxicity, ozone depletion and photochemical oxidant formation influences. 14% of Climate change were derived from organic chemicals emission in this study, which suggested that VOCs-related carbon emission should be involved in current carbon accounting work or greenhouse gases (GHGs) studies on the petroleum refining industry. The identified control emphasis included equipment leaks from core refining units, storage tank emissions control, energy structure optimization and catalysts consumption intensity reduction. Some feasible and useful reduction measures targeted the control emphasis were proposed for policy makers and refinery managers to formulate reduction strategies and improve the sustainability of the petrochemical industry.

Ammonia emissions from an in-ground finisher hog manure tank

A large fraction of emitted and ultimately deposited ammonia (NH3) originates from swine waste storage. Understanding the factors that influence these emissions is important in determining how to mitigate NH3 loading of the atmosphere. Hog manure is stored in slurry pits, tanks, or lagoons. Ammonia emissions from a ground-level mid-western hog finisher manure tank collecting manure from a mean of 3508 animals was measured for 8–20 d each quarter of the year for two years. Forty of the 164 measurement days had sufficient measurements to represent entire days. These daily emissions averaged 0.44 g NH3 m−2h−1 (53.1 g d−1 AU−1, 7.2 g d−1 hd−1: AU = 500 kg animal mass, hd = 1 animal) with maximum emissions of 1.62 g NH3 m−2h−1 (194.2 g d−1 AU−1, 26.4 g d−1 hd−1). Emissions from the tank were greater on an area basis but comparable on an animal basis relative to emissions from much larger anaerobic lagoons. Emissions were correlated with air temperature and manure composition, but not wind speed or friction velocity- probably due to the turbulence created by the tank structure under all winds. Crusting of the manure surface in the tank corresponded with a non-significant 10% increase in NH3 emissions. A model of the tank emissions, based on nominal nitrogen loading rates from the literature and taking into account the configuration of the circular tank, had a mean bias error of 0.01 g NH3 m−2h−1 (0.9 g d−1 AU−1, 0.1 g d−1 hd−1) and a root mean square error of 0.26 g NH3m−2h−1 (31.6 d−1 AU−1, 4.3 g d−1 hd−1). Additional emissions measurements from such ground-level manure storage tanks with greater documentation of the manure liquid composition are needed to verify the modeling approach.

Quantifying alkane emissions in the Eagle Ford Shale using boundary layer enhancement

Abstract. The Eagle Ford Shale in southern Texas is home to a booming unconventional oil and gas industry, the climate and air quality impacts of which remain poorly quantified due to uncertain emission estimates. We used the atmospheric enhancement of alkanes from Texas Commission on Environmental Quality volatile organic compound monitors across the shale, in combination with back trajectory and dispersion modeling, to quantify C2–C4 alkane emissions for a region in southern Texas, including the core of the Eagle Ford, for a set of 68 days from July 2013 to December 2015. Emissions were partitioned into raw natural gas and liquid storage tank sources using gas and headspace composition data, respectively, and observed enhancement ratios. We also estimate methane emissions based on typical ethane-to-methane ratios in gaseous emissions. The median emission rate from raw natural gas sources in the shale, calculated as a percentage of the total produced natural gas in the upwind region, was 0.7 % with an interquartile range (IQR) of 0.5–1.3 %, below the US Environmental Protection Agency's (EPA) current estimates. However, storage tanks contributed 17 % of methane emissions, 55 % of ethane, 82 % percent of propane, 90 % of n-butane, and 83 % of isobutane emissions. The inclusion of liquid storage tank emissions results in a median emission rate of 1.0 % (IQR of 0.7–1.6 %) relative to produced natural gas, overlapping the current EPA estimate of roughly 1.6 %. We conclude that emissions from liquid storage tanks are likely a major source for the observed non-methane hydrocarbon enhancements in the Northern Hemisphere.

Aerial Surveys of Elevated Hydrocarbon Emissions from Oil and Gas Production Sites.

Oil and gas (O&G) well pads with high hydrocarbon emission rates may disproportionally contribute to total methane and volatile organic compound (VOC) emissions from the production sector. In turn, these emissions may be missing from most bottom-up emission inventories. We performed helicopter-based infrared camera surveys of more than 8000 O&G well pads in seven U.S. basins to assess the prevalence and distribution of high-emitting hydrocarbon sources (detection threshold ∼ 1-3 g s(-1)). The proportion of sites with such high-emitting sources was 4% nationally but ranged from 1% in the Powder River (Wyoming) to 14% in the Bakken (North Dakota). Emissions were observed three times more frequently at sites in the oil-producing Bakken and oil-producing regions of mixed basins (p < 0.0001, χ(2) test). However, statistical models using basin and well pad characteristics explained 14% or less of the variance in observed emission patterns, indicating that stochastic processes dominate the occurrence of high emissions at individual sites. Over 90% of almost 500 detected sources were from tank vents and hatches. Although tank emissions may be partially attributable to flash gas, observed frequencies in most basins exceed those expected if emissions were effectively captured and controlled, demonstrating that tank emission control systems commonly underperform. Tanks represent a key mitigation opportunity for reducing methane and VOC emissions.

Impact of Crude Oil Storage Tank Emissions and Gas Flaring on Air/Rainwater Quality and Weather Conditions in Bonny Industrial Island, Nigeria

This study investigated the effects of gaseous emissions from crude storage tank and gas flaring on air and rainwater quality in Bonny Industrial Island. Ambient air quality parameters, rainwater and weather parameters were collected at 60 m, 80 m, 100 m, 200 m and control plot for 4 weeks at the Bonny. Rainwater parameters were investigated using standard laboratory tests. Data analyses were done using Analysis of variance, pairwise t-test and Pearson’s correlation statistical tools. Results show that emission rates, volatile organic compound (VOC) noise and flare temperature decreased with increasing distance from flare points and crude oil storage tanks. Findings further revealed the emission rates varied significantly with distance away from the gas flaring point (F = 6.196; p = 0.004). The mean concentration of pollutants between gas flare site and crude oil storage tank showed that CO (0.02 ± 0.001 - 0.002 ±0.001), SPM (0.011 ± 0.001 - 0.01 ± 0.001), VOC (0.005 ± 0.001 - 0.01 ± 0.001) and NO2 (0.04 ± 0.001 - 0.005 ± 0.000) had significant variations (p > 0.05) with CO, O3 and NO2 having higher concentrations at the gas flare site while SPM, and VOC were higher around the crude oil storage tank site. Wind turbulence was higher around the gas flaring point (4.93 TKE) than the crude oil storage tank (4.55 TKE). Similarly, there was significant variation in the sun radiation, precipitation, and wind speed caused by gas flaring (1582.25 w/m2, 436.25 mm, 0.53 m/s) and crude oil storage tank (1536.25 w/m2, 3.91.41 mm, 0.51 m/s). There were also significant variations in flared temperature (F = 22.144; p = 0.001); NO2 (F = 8.250; p = 0.001), CO (F = 6.000; p = 0.004) and VOC (F = 5.574; p = 0.006) with distance from the gas flaring point. The variation in the rainwater parameters with distance from the gas flaring indicated significant variations in pH (F = 5.594; p = 0.006). The study showed that the concentration of VOC and particulates were high in the supposedly control area which is perceived to be safe for human habitation. Significant variations exist in emission rate (p = 0.015), flare temperature (p = 0.001), NO2 (p = 0.003), VOC (p = 0.001), noise (p = 0.041), hydrogen carbonate (p = 0.037) and chromium (p = 0.032) between the gas flaring and crude oil storage tank. Regular monitoring is advocated to mitigate the harmful effects of the pollutants.

Assessment of volatile organic compound and hazardous air pollutant emissions from oil and natural gas well pads using mobile remote and on-site direct measurements

Emissions of volatile organic compounds (VOCs) and hazardous air pollutants (HAPs) from oil and natural gas production were investigated using direct measurements of component-level emissions on pads in the Denver-Julesburg (DJ) Basin and remote measurements of production pad-level emissions in the Barnett, DJ, and Pinedale basins. Results from the 2011 DJ on-site study indicate that emissions from condensate storage tanks are highly variable and can be an important source of VOCs and HAPs, even when control measures are present. Comparison of the measured condensate tank emissions with potentially emitted concentrations modeled using E&P TANKS (American Petroleum Institute [API] Publication 4697) suggested that some of the tanks were likely effectively controlled (emissions less than 95% of potential), whereas others were not. Results also indicate that the use of a commercial high-volume sampler (HVS) without corresponding canister measurements may result in severe underestimates of emissions from condensate tanks. Instantaneous VOC and HAP emissions measured on-site on controlled systems in the DJ Basin were significantly higher than VOC and HAP emission results from the study conducted by Eastern Research Group (ERG) for the City of Fort Worth (2011) using the same method in the Barnett on pads with low or no condensate production. The measured VOC emissions were either lower or not significantly different from the results of studies of uncontrolled emissions from condensate tanks measured by routing all emissions through a single port monitored by a flow measurement device for 24 hr. VOC and HAP concentrations measured remotely using the U.S. Environmental Protection Agency (EPA) Other Test Method (OTM) 33A in the DJ Basin were not significantly different from the on-site measurements, although significant differences between basins were observed.Implications: VOC and HAP emissions from upstream production operations are important due to their potential impact on regional ozone levels and proximate populations. This study provides information on the sources and variability of VOC and HAP emissions from production pads as well as a comparison between different measurement techniques and laboratory analysis protocols. On-site and remote measurements of VOC and HAP emissions from oil and gas production pads indicate that measurable emissions can occur despite the presence of control measures, often as a result of leaking thief hatch seals on condensate tanks. Furthermore, results from the remote measurement method OTM 33A indicate that it can be used effectively as an inspection technique for identifying oil and gas well pads with large fugitive emissions.

Impact assessment of odours emitted by a wastewater treatment plant

Complaints from the Domingos Martins population about sewage odours in the city made the district attorney order an impact assessment of the odours emitted by the city wastewater treatment plant (WWTP). This study comprised various techniques, models and population surveys. In 2007, an odour emission model proved that the main hydrogen sulphide emitter was the aeration tank of the WWTP (13.5 g h(-1)) and such emissions, according to CALPUFF model, should be perceived in the whole Domingos Martins city centre area. In this area, 58% of those interviewed were annoyed by the WWTP odours. However, in 2009, the odour monitoring panel recorded few odour occurrences. A second population survey showed that hereafter only 20% of those interviewed were annoyed by the WWTP emissions. Odour emission and dispersion models run with 2010 data proved a drastic reduction of the WWTP aeration tank emissions and consequently the city centre was not bothered by WWTP emissions anymore. The odour emission reduction was due to the modification of the WWTP aeration tank system. Despite the odour emission reduction, houses located southeast of the WWTP were still annoyed by sewage odours. However, in this part of the town, other sources of sewage odours have been found.

The best-kept secret for minimizing your energy costs: Exhaust systems integrated with process covers save heatingand cooling losses, reduce exposure to harmful fumes

Summary The importance of protecting the worker from hazardous chemical exposure outweighs all other factors when designing an industrial ventilation system. A complete understanding of airflow and controlling tank emissions is required. Incoraprating a properly designed exhaust system, with automatic covers and volume dampers operating in tandem, can create tremendous pollution prevention and energy savings, especially today, where energy costs alone could make the difference between profit and peril.

Monitoring of Hydrocarbon Emissions in a Petroleum Refinery

In a petroleum refinery the hydrocarbon emissions which are mostly fugitive in nature are emitted from process, offsites and periodic accidental releases such as: materials storage & handling, process, equipment leaks, solvent evaporation, combustion sources, waste treatment etc. In India, the monitoring of such emissions in a refinery are limited as also the standards are not set for its limit in ambient air. Hence there is an urgent need for generating a database for such emissions. Recently in India, MoEF/CPCB has set some guidelines under CREP rules for monitoring such emissions in a refinery. A detailed monitoring of the hydrocarbon emissions from different sources in a typical 10.5 MMTPA Indian refinery is undertaken during 1999-2001 and the results are presented. It is observed that the storage tank emissions alongwith process leaks form the major contributor towards fugitive hydrocarbon emissions.

Computational fluid dynamics study of flow around floating-roof oil storage tanks

Volatile organic compounds (VOCs) emitted from petrochemical plants and storage facilities play a key role in forming ground-level ozone, which causes breathing problems for humans and damages plants. External floating-roof oil storage tanks are a major source of VOC emissions. Wind passing over the fittings that penetrate the tank roof cause product to evaporate from the surface of the tank. This paper presents the results of a detailed CFD study of the wind speeds and flow structures observed above and around the tanks. The model was developed using AEA Technology's CFX4, and validated from a series of known 2-d cases and then from extensive field measurements, on small- and full-scale tanks. Two distinct flow regimes have been observed above the roof: at large roof depressions (empty tank), the flow recirculates within the tank cavity; at small roof depression (full tank), the flow reattaches within the cavity. Implications for tank design and emissions measurement are presented.