Synthetic Leachate Research Articles

Selective Lithium separation from Li/Co/Ni mixtures using optimized flow-electrode capacitive deionization

The increasing need for lithium has heightened its significance as a crucial resource in numerous sectors, particularly in realms of portable electronics, electric vehicles (EVs), and large-scale energy storage systems. However, the finite availability of lithium resources and environmental concerns associated with its extraction underscore the significance of developing an efficient recycling method. In this study, we explored the potential of recovering lithium from waste battery leachate using an emerging technology known as flow-electrode capacitive deionization (FCDI). Unlike traditional capacitive deionization (CDI), FCDI offers continuous desalination capabilities, making it particularly suitable for recycling industries. While FCDI exhibits promise in recovering waste battery leachate, its inherent lack of selectivity presents a challenge. To address this issue, we tried to tune its selectivity towards lithium by employing a layer-by-layer deposition method to modify a cation exchange membrane (CEM) with poly(allylamine hydrochloride) (PAH) and poly(styrene sulfonate) (PSS) functional multilayers. This strategic modification of CEM was performed by alternatively depositing positively charged PAH and negatively charged PSS multilayers, which switched an innate divalent cation preference of CEM into a monovalent cation preference based on differences in ion sizes and charge densities. The membrane was used to treat a synthetic leachate mixture from wasted batteries, with a molar ratio of 30 mM:44 mM:4 mM for Li:Co:Ni, demonstrating a Li selectivity of 12.88 over Co and Ni with an exceptionally low energy consumption of 0.57 Wh/molLi. We believe our approach can lead to new technologies that address shortcomings of existing lithium recycling method and expand the application not only to lithium recycling, but also to future lithium production technologies and removal of specific ions such as for toxin removal.

Leaching of per- and polyfluoroalkyl substances (PFAS) from food contact materials with implications for waste disposal

Leaching of per- and polyfluoroalkyl substances (PFAS) during the post-consumer disposal of food contact materials (FCMs) poses a potential environmental threat but has seldom been evaluated. This study characterized the leaching behavior of PFAS and unidentified precursors from six common FCMs and assessed the impact of environmental conditions on PFAS release during disposal. The total concentration of 21 PFAS ranged from 3.2 to 377 ng/g in FCMs, with PFAS leachability into water varying between 1.1–42.8 %. Increasing temperature promoted PFAS leaching, with leached nine primary PFAS (∑9PFAS) reaching 46.3, 70.4, and 102 ng/L at 35, 45, and 55 ℃, respectively. Thermodynamic analysis (∆G>0, ∆H>0, and ∆S<0) indicated hydrophobic interactions control PFAS leaching. The presence of dissolved organic matter in synthetic leachate increased the leached ∑9PFAS from 47.1 to 103 ng/L but decreased PFBS, PFOS, and 6:2 FTS leaching. The total release of seven perfluorocarboxylic acids (∑7PFCAs) from takeaway food packaging waste was estimated to be 0.3–8.2 kg/y to landfill leachate and 0.6–15.4 kg/y to incineration plant leachate, contributing 0.2–4.8 % and 0.1–3.2 % of total ∑7PFCAs in each leachate type. While the study presents a refined methodology for estimating PFAS release during disposal, future research is needed on the indirect contribution from precursors.

A Study of Copper and Lead Removal from Synthetic Leachate by Photocatalysis

A Study of Copper and Lead Removal from Synthetic Leachate by Photocatalysis

Long-term performance of HDPE extrusion welds aged at 85°C in synthetic leachate

The effect of ageing at 85°C of extrusion welds of 1.5 mm-thick high-density polyethylene (HDPE) geomembrane, immersed in synthetic municipal solid waste leachate, is investigated with respect to its standard oxidative induction time (Std-OIT) and stress crack resistance (SCR). Results show that the heat-affected zones (HAZ) adjacent to the squeeze-out bead (flashing) may exhibit faster STD-OIT depletion than the sheet. Generally, individual weld SCR failure times were observed to be between that of the notched and unnotched sheet. Welds with high welding-induced geometric irregularities (WIGI), and overheated fusion and extrusion welds are shown to result in SCR failure times close to that of a notched sheet. The average time to nominal failure (taken to be when tNF = 250 h) of Cool and Good welding parameter combinations ranges between 3% and 15% shorter than the unnotched sheet. Differences in tNF were attributed to accelerated craze formation in welds with high WIGI from stress concentration. No significant difference was observed between the SCR values of fusion and extrusion welds during 40 months of immersion in MSW-L3. This paper shows that overgrind negatively impacts the SCR of welds and accelerates the degradation of SCR.

Continuous multicolumn ion exchange process for spent lithium-ion battery leachate: Recovery and purification of a Li+Ni+Co mixture

A continuously operated ion exchange process scheme for the recovery and purification of valuable metals from acid leachates of spent Lithium-ion battery cathodes was developed. The aim is to provide a versatile and industrially feasible alternative for liquid–liquid extraction and precipitation for recycling of spent Li-ion batteries. A chelating resin with aminomethylphosphonic acid functional group (Lewatit® MDS TP 260) was used in a laboratory-scale multicolumn configuration that combined counter-current and cross-current operations. The process was operated at 60 °C with a synthetic leachate with pH 1.8 as the feed. A two-step desorption procedure (1.0 M sulfuric acid (H2SO4) followed by 0.4 M potassium oxalate (K2C2O4)) was found to prevent accumulation of strongly bound metals in the resin. 1 M H2SO4 was found sufficient for regeneration. Pure raffinate containing Li, Ni, and Co was successfully separated from impurity metals (Mn, Cu, Al, and Fe). In steady state operation, no loss of ion exchange capacity was observed. The process was optimized experimentally with focus on the effect of fresh feed and eluent flow rates to increase the productivity and improve the recovery rates of the target metals while maintaining a raffinate purity of 100 %. Increasing the amount of leachate processed per switch was found to enhance the recovery of Co, Li and Ni due to the displacement effect. Very high recovery yields (96.97 % for Co, 99.15 % for Ni, and 100 % for Li) were achieved. The laboratory scale unit could process 1.64L(L·h)−1 of leachate to yield 34.04 g(L·h)−1 of Li+Ni+Co mixture in the raffinate. Moreover, Cu+Mn and Al+Fe rich extract streams with 84.74 % and 97.46 % purities were obtained as by-products. With respect to the recovery rates, the continuous ion exchange process is superior to batchwise operation of ion exchange columns, conventional solvent extraction and not to mention precipitation processes making it a viable alternative in hydrometallurgical LIB recycling.

Hydraulic conductivity of bentonite-polymer geosynthetic clay liners to aggressive solid waste leachates

Hydraulic conductivity of conventional mock sodium bentonite (Na–B) and bentonite-polymer (B–P) geosynthetic clay liners (GCLs) were evaluated with three synthetic leachates that are chemically representative of aggressive leachates from coal combustion product (CCR) (I = 3179 mM), mining waste (MW) (I = 2127 mM, pH = 2.0), and municipal solid waste incineration ash landfill (MSWI) (I = 2590 mM). The mock B–P GCLs were created by dry mixing bentonite with branched, linear, or crosslinked polymer. The polymer loading of mock B–P GCLs ranged from 3 to 15%. Comparative tests were also conducted with Na–B GCLs. The mock Na–B GCLs cannot maintain low hydraulic conductivity to aggressive CCR, MW, and MSWI leachates. Mock B–P GCLs with 10% branched polymer had low hydraulic conductivity (< 1.0 × 10−10 m/s) to synthetic MW and MSWI leachates at 20 kPa effective confining stress, whereas the hydraulic conductivity of mock B–P GCLs with 10% linear or crosslinked polymer ranged from 1.5 × 10−9 to 1.4 × 10−7 m/s. As the effective stress increased, the B–P GCLs branched polymer showed a faster decreasing trend than that of Na–B and B–P GCLs with linear or crosslinked polymer.

Recovery of metallic lead from End-Of-Life silicon solar modules using salt bridge electrowinning

Toxic lead (Pb) in end-of-life silicon solar modules must be recovered to keep it out of the environment. Present literature on Pb recovery from solar waste is sparse and uses chemicals like nitric or hydrochloric acid. Previously, the authors reported Pb recovery from silicon modules by leaching and electrowinning in acetic acid. However, the Pb recovered from acetic solution contained a small amount of metallic Pb with the rest being lead oxides/acetates. These Pb compounds require further processing to obtain metallic Pb for reuse in solar panel solder, leading to additional cost and chemical waste. This paper reports recovery of metallic Pb using an electrochemical system with two half cells connected through a salt bridge. The salt bridge enables optimized recovery rates of Pb as high as 99.99 % for synthetic leachates. The first experiment to recover Pb from real silicon module waste shows 80 % recovery without optimization. The new method offers a low-cost, closed-loop, direct pathway to metallic Pb recovery from end-of-life silicon solar modules for reuse in new modules.

Natural Moroccan bentonite clay as an adsorbent for nutrient removal from synthetic leachate: Performance and evaluation

To ensure the protection of public health and environmental integrity, while also meeting effluent regulation standards, it is critical to treat leachate due to its composition of hazardous substances before it is introduced into the environment. Pollution from leachate is characterized by several indicators, including COD, BOD5, conductivity, pH, and the presence of various ions such as ammonium, nitrite, nitrate, chloride, and orthophosphate. This research examines the adsorption properties of natural bentonite clay from Nador, located in eastern Morocco, for its efficacy in removing ammonium, nitrate, and nitrite ions from synthetic leachates. We present the outcomes of adsorption experiments utilizing bentonite clay to eradicate these nitrogen-based ions from artificial leachate, using UV adsorption spectroscopy for the measurement of ion concentrations before and after adsorption. Additionally, the study evaluates the efficiency of bentonite clay in adsorption, identifying the optimal amount of clay required for effective pollutant reduction. Our results demonstrate that, following a 24-hour mixing period, the adsorption rates for ammonium, nitrate, and nitrite ions were roughly 48%, 40%, and 85% at 35 °C, and 40%, 15%, and 25% at 25 °C, respectively. These findings suggest that modulation of agitation duration and temperature can significantly improve adsorption efficiency, with elevated temperatures facilitating shorter reaction times and higher adsorption rates for nitrogen ions. Ultimately, the research confirms the potential of bentonite clay as an effective medium for the removal of these contaminants from landfill leachate, offering a promising approach for enhancing environmental sustainability.

Durability of two bituminous geomembranes (BGMs) with different thicknesses in MSW synthetic leachate

The effect of thickness (4.8 and 4.1 mm) on the degradation of two bituminous geomembranes (BGMs), when immersed in a synthetic leachate is investigated over a period of 33 months. Based on the data collected at four different temperatures (20, 40, 55, 70 °C), it is shown that the 4.1 mm has slightly faster degradation than the 4.8 mm thick BGM. Due to the reduced conditions of the examined leachate, the degradation in the chemical and rheological properties of the bitumen coat was relatively lower than in air and water immersion. However, the presence of a surfactant in the leachate increased the degradation of the polymeric back film and the reinforcement layer responsible for the mechanical properties of the BGM. The time to nominal failure of the two BGMs is predicted at a typical range of landfill liner temperatures using Arrhenius modelling. The predictions at temperatures >20 °C suggest that the examined BGMs may not be suitable for the containment of solid wastes containing surfactants due to the fast degradation in their mechanical properties.

Leaching Behaviour of Synthetic Leachate through a Sewage Sludge and Red Gypsum Composite as Intermediate Landfill Cover

This paper examines the environmental impact of the use of compacted sewage sludge:red gypsum (SS:RG) mixture as intermediate landfill cover in terms of yield and quality of leachate as characterised by hydraulic conductivity and leaching behaviour. A series of column tests using the constant head method is carried out by percolating the synthetic leachate through samples that have been compacted at various degrees (60, 70, 75, 80 and 85%). The leachate quality is monitored at pre-determined days for pH, COD, Cu, Fe and Zn. In general, hydraulic conductivity decreases in three stages, in which the first stage is mainly attributed to the particle rearrangement and hydration of calcium silicate hydrate (CSH). The hydration of CSH increases the pH, which causes the heavy metal to precipitate and be entrapped within the matrices of CSH gel, thereby further reducing the porosity and hydraulic conductivity. A minimum of 75% compaction has shown favourable final porosity, hydraulic conductivity, and leachate quality, although a minimum of 80% compaction is recommended in order to achieve a satisfactory compressive strength of greater than 345 kPa for a landfill operation.

Performance and resilience of the PolyCera® Titan membrane for industrial wastewater treatment.

This research aims to evaluate the performance of PolyCera® Titan membrane for different wastewater treatment. Membrane filtration of several cycles was conducted in understanding the fouling mechanism, fouling propensity, and defouling potential of the PolyCera® Titan which had not been studied by any other researcher before. The PolyCera® Titan membrane is effective for the treatment of textile industry wastewater, palm oil mill effluent (POME), leachate, and semiconductor-industry wastewater. Rejection of methylene blue (MB) and Congo red (CR) was in the range of 78.76-86.04% and 88.89-93.71%, respectively; 94.72-96.50% NaCl, 96.07-97.62% kaolin, and 97.26-97.73% glucose were rejected from synthetic leachate indicating the removal of TDS, TSS, and COD from the leachate, respectively. Standard blocking and complete model were the best models used to explain the PolyCera® Titan membrane fouling mechanism in all types of wastewater treatment processes with a high R2 value. Physical cleaning with the use of distilled water was able to recover the permeate flux with the flux recovery ratio (FRR) value in the range of 79.2-95.22% in the first cycle, 81.20-98.16% in the second cycle, and 86.09-95.96% in the third cycle.

Elimination of orthophosphate from synthetic leachate using adsorption on bentonite clay

The composition of leachates is very variable and rich in toxic compounds, which requires treatment before discharge into the natural environment in order to avoid their impact on the environment and/or human health and to comply with the requirements of regulatory discharge standards in the natural environment. Among the parameters indicating pollution by leachates, we have COD, BOD5, conductivity, pH, the presence of ammonium ions, nitrite, nitrate, chloride, orthophosphate, etc. This study presents the results of synthetic leachate orthophosphate adsorption tests on bentonite clays. For the determination of the orthophosphate concentration in the synthetic leachate, before and after adsorption, we applied the method of Ultra-Violet adsorption spectroscopy. The adsorption capacity of bentonite, the amount needed and the removal efficiency were determined. The orthophosphate adsorption yield on bentonite reaches up to 32.6 % for 5 g/L of bentonite stirred for 4 hours and exceeds 39,19 % after 24 hours of stirring.

Development of Microalgae-Bacteria Aerobic Granular Sludge for Landfill Leachate Treatment

Over the past few decades, aerobic granular sludge has become favorable biotechnology in wastewater treatment. Combining the AGS process with microalgae technology is desired to achieve higher treatment efficiency, especially for high-strength wastewater. This study aims to investigate the effectiveness of microalgae-bacteria AGS in treating landfill leachate. The photo-sequencing batch reactor, inoculated with Acutodesmus obliquus, was fed with old synthetic leachate, and run for 30days. The result showed that chemical oxygen demand (COD) removal up to 96%. The initial ammonia concentration was 130mg/L and achieved an efficiency of up to 80.77%. At the same time, the average removal of the phosphorus was 19.5mg/L, equal to 48.68%. The result of microalgae-bacteria AGS can produce the fast-settling properties of the granules throughout the experiment.

Long-term stress crack resistance of HDPE fusion seams aged at 85 °C in synthetic leachate

The stress crack resistance (SCR) and standard oxidative induction time (Std-OIT) reduction of high- density polyethylene (HDPE) geomembrane (GMB) fusion seams is examined for a 12-year old 1.5 mm HDPE GMB when welded using nine welding parameter combinations. The GMB experienced a decrease in Std-OIT from 135 to 87 min between manufacturing and welding. Welding did not significantly decrease the Std-OIT in the heat-affected zone (HAZs). In general, individual seam SCR failure times fell between the notched and unnotched sheet, with adhered squeeze-out bead seams exhibiting individual failure times closer to the notched sheet and an average time until nominal failure ( tNF) ∼21%–35% shorter than the unnotched sheet. Differences in tNF are attributed to residual stresses and (or) accelerated craze formation in seams with adhered squeeze-out beads. Non-adhered squeeze-out seams exhibited a slower tNF similar to that of the unnotched sheet, indicating a seam tNF less than that of the sheet may not be intrinsic to all HDPE fusion seams. High sheet temperatures at the time of welding and higher heat-applied welding parameters are thought to increase the likelihood of squeeze-out bead adherence. This paper shows that squeeze-out adherence can have a deleterious effect on seam SCR.

Field and laboratory investigation of factors affecting GCL performance in the Antarctic environment

Performance indicators of geosynthetic clay liners (GCLs) exposed to the Antarctic environment were assessed using field and laboratory methods. Barrier properties of the GCLs were not impacted by the field conditions and exhumed hydraulic conductivities with respect to tap water ranged from 0.4 × 10−11 to 12 × 10−11 m/s, compared to 5 × 10−11 m/s (virgin) and from 2.1 × 10−11 to 8.8 × 10−11 m/s for a synthetic leachate, compared to 2.5 × 10−11 to 7.6 × 10−11 m/s for virgin specimens. The self-healing ability of bentonite remained intact despite environmental exposure as evidenced by X-ray radiographs. Using a test plot to evaluate GCL hydration with the major determinant of hydration was identified as proximity to meltwater flow. However, a finer subgrade ( D60 = 5–7 mm) increased average and peak GCL moisture contents in areas not inundated with meltwater and resulted in less deformation than a coarse subgrade ( D60 &gt; 16 mm). Additionally, X-ray radiographs showed increased self-healing in monitoring specimens overlying fine subgrades. Environmental exposure (e.g., temperature cycling and dehydration/rehydration) did not affect the hydraulic conductivity of test plot specimens (1.1 × 10−11 to 8.5 × 10−11 m/s) compared to the virgin GCL (6.7 × 10−11 m/s) with respect to tap water, and minimal cation exchange had occurred.

Hydro-mechanical behavior of two clayey soils in presence of household waste leachates

BACKGROUND AND OBJECTIVESIn landfills, containment is provided by natural or artificial clayey materials known for their low permeability and for their pollutant retention capacity. However, the properties of these media are modified by leachates, whose migration they are supposed to limit. This study aims to reconsider the criteria for choosing suitable materials to make a bottom liner through both their long term hydraulic and mechanical performances.METHODSTwo fine materials sampled in Burkina Faso (West Africa) have been characterized in order to compare their hydro-mechanical behavior in the presence of household waste leachates. The first material is classified as an inorganic clay of low to medium plasticity according to Casagrande plasticity diagram, it is mainly kaolinitic with some traces amounts of smectites. The second one is classified clayey sand of low to medium plasticity, the predominant mineral clay being kaolinite. Hydro-mechanical tests were performed on both sampled materials to judge the sealing properties of these materials, as well as the characteristics of deformation and rupture which have an important effect to ensure the durability of a bottom liner. All these tests were performed first with distilled water then with leachates as interstitial fluids in order to understand the modification of the hydro-mechanical properties of the clayey soils.FINDINGSLeachate contamination always alters hydraulic properties of the materials. However, between the two soils, the most clayey and the most impervious (soils from Nouna) undergo the deeper weathering. Indeed, hydraulic conductivity of these soils in contact with a synthetic leachate increases from 1.71x10-10 to 1.51x10-9 m/s. In contrast to soils from Boudry, these soils also undergo very significant settlements over the long term with compressibility indexes varying from 0.164 to 0.225. For both soils, the shear strength increases showing that, from this point view, the leachate work in the sense of of the bottom liner stability. For soils from Nouna, the effective cohesion increases from 3 to 21 kPa with a slight decrease of friction angle; for soils from Boudry a slight increase of cohesion is noticed while friction angle increases from 34 to 37°.CONCLUSIONThis comparative study is of practical use to environmental geotechnics professionals because it shows that the choice in designing a bottom liner must be a compromise between long term hydraulic and mechanical behaviors of soils. It is also important to know the nature of the flows to contain in order to ensure the durability of the structure.

Recovery of Lanthanum from Aqueous Solutions by Crystallization as Lanthanum Sodium Sulfate Double Salt

The recovery of rare earth elements from spent nickel-metal hydride batteries by hydrometallurgical processing has become increasingly important in recent years. The present work investigated the effect of temperature, systems of adding the reactant, the molar ratio of sodium and lanthanum, and the initial concentration of six sulfate impurities (Ni, Co, Al, Mn, Fe, and Zn) on the crystallization of the monohydrate of sodium lanthanum sulfate double salt (NaLa(SO4)2·H2O) crystals from synthetic leachate solutions. The sodium sulfate reactant was added as an acidic solution by pumping or batchwise as a solid anhydrate salt to a pregnant lanthanum sulfate solution. Compared to precipitation with acidic sodium sulfate solution, precipitation with solid sodium sulfate yielded smaller single crystals, a greater tendency to form aggregates, and lower crystal purity. The lowest overall impurity and highest lanthanum quantity in crystals were obtained by semi-batch reactant adding performance of Na2SO4 solution at 70°C with Na/La molar ratio of 3. Real-time monitoring of the count rates of different chord length fractions clearly showed the influence of crystallization temperature on the precipitation kinetics.

Evaluation of electro-assisted phytoremediation (EAPR) system for heavy metal removal from synthetic leachate using Pistia stratiotes

The highest waste generated in Malaysia is composed of municipal solid waste, which is mainly managed by landfilling. Heavy metals in leachate generated from landfill could have caused hazardous effects to human and environment. EAPR has been increasingly applied to treat soil and wastewater. This technique serves as a potential tool for remediation of real leachate. Metals (Mn, Cd, Fe, Ni, Pb, Zn) uptake by Pistia stratiotes were evaluated via flame atomic adsorption spectrophotometer. Pb and Fe could be the elements that were more efficiently removed by P. stratiotes in the EAPR system. The removal efficiency was 59.86 ± 9.98 and 56.56 ± 18.08% for Pb and Fe, respectively. EAPR significantly reduced the BOD (9.37 ± 2.36 mg/L), color (120.00 ± 5.77 PtCo), and turbidity (25.50 ± 11.96 NTU) of synthetic leachate. An obvious accumulation of heavy metals was observed at roots based on BCF and TF values. BCF values of Pb (18,999.06 ± 8,321.76) and Fe (16,090.81 ± 5,844.36) in the EAPR system were more than 103, which indicates that P. stratiotes is a hyperaccumulator. Further study on the upregulated genes is needed to comprehend the molecular basis of heavy metal stress tolerance.

Preparation of artificial MSW leachate for treatment studies: Testing on black soldier fly larvae process.

When approaching the study of new processes for leachate treatment, each influencing variable should be kept under control to better comprehend the treatment process. However, leachate quality is difficult to control as it varies dramatically from one landfill to another, and in line with landfill ageing. To overcome this problem, the present study investigated the option of preparing a reliable artificial leachate in terms of quality consistency and representativeness in simulating the composition of real municipal solid waste (MSW) leachate, in view of further investigate the recent treatment process using black soldier fly (BSF) larvae. Two recipes were used to simulate a real leachate (RL): one including chemical ingredients alone (artificial synthetic leachate-SL), and the other including chemicals mixed with artificial food waste (FW) eluate (artificial mixed leachate-ML). Research data were analysed, elaborated and discussed to assess simulation performance according to a series of parameters, such as Analytical representativeness, Treatment representativeness (in this case specific for the BSF larvae process), Recipe relevance, Repeatability and Flexibility in selectively modifying individual quality parameters. The best leachate simulation performance was achieved by the synthetic leachate, with concentration values generally ranging between 97% and 118% of the RL values. When feeding larvae with both RL and SL, similar mortality values and growth performance were observed.

Integrated Treatment at Laboratory Scale of a Mature Landfill Leachate via Active Filtration and Anaerobic Digestion: Preliminary Results

The management of mature landfill leachate (MLL) represents an increasingly crucial issue to tackle. In this study, the feasibility of an integrated treatment was investigated at the laboratory scale using synthetic leachate with the objective of maximizing the recovery of potentially useful compounds present in leachate (especially ammonia nitrogen). First, in order to remove heavy metals, active filtration of the MLL was carried out using zero-valent iron (ZVI) mixed with either lapillus or granular activated carbon (GAC). The average removal rates for the ZVI/lapillus and the ZVI/GAC filter were 33%, 85%, 66%, and 58% and 56%, 91%, 67%, and 75% for COD, Cu, Ni, and Zn, respectively. Then, pre-treated MLL was added during the anaerobic digestion (AD) of cellulose with the aim of providing bacteria with macro (i.e., ammonia nitrogen) and micro (e.g., residual heavy metals) nutrients. After 38 days, the best performance in terms of cumulative methane production (5.3 NL) and methane yield (0.26 NL/gVSadded on average) was recorded in the reactor fed with the lowest dosage (17.9 mL/d) of MLL pre-treated by the ZVI/lapillus filter. The main issue that emerged during AD was the possible inhibition of the process linked to an excessive presence of humic substances; however, in future experiments, this problem can be solved through an optimization of the management of the whole process. The residual digestate from AD, rich in nitrogen and humic substances, may be safely used for agriculture purposes, closing the cycle of MLL management.