Syngas Combustion Research Articles

Emission Factors for Biochar Production from Various Biomass Types in Flame Curtain Kilns

Simple and low-cost flame curtain (“Kon-Tiki”) kilns are currently the preferred biochar technology for smallholder farmers in the tropics. While gas and aerosol emissions have been documented for woody feedstocks (twigs and leaves) with varying moisture contents, there is a lack of data on emissions from other types of feedstocks. This study aims to document the gas and aerosol emissions for common non-woody feedstocks and to compare emissions from finely grained, high-lignin feedstock (coffee husk) with those from coarser, low-lignin feedstocks (maize cobs, grass, sesame stems). Throughout each pyrolysis cycle, all carbon-containing gases and NOx were monitored using hand-held sensitive instruments equipped with internal pumps. Carbon balances were used to establish emission factors in grams per kilogram of biochar. The resulting methane emissions were nearly zero (<5.5 g/kg biochar) for the pyrolysis of three dry (~10% moisture) maize cobs, grass, and a 1:1 mixture of grass and woody twigs. For sesame stems, methane was detected in only two distinct spikes during the pyrolysis cycle. Carbon monoxide (CO) and aerosol (Total Suspended Particles, TSP) emissions were recorded at levels similar to earlier data for dry twigs, while nitrogen oxide (NOx) emissions were negligible. In contrast, the pyrolysis of finely grained coffee husks generated significant methane and aerosol emissions, indicating that technologies other than flame curtain kilns are more suitable for finely grained feedstocks. The emission results from this study suggest that certification of biochar made from dry maize, sesame, and grass biomass using low-tech pyrolysis should be encouraged. Meanwhile, more advanced systems with syngas combustion are needed to sufficiently reduce CO, CH4, and aerosol emissions for the pyrolysis of finely grained biomasses such as rice, coffee, and nut husks. The reported data should aid overarching life-cycle analyses of the integration of biochar practice in climate-smart agriculture and facilitate carbon credit certification for tropical smallholders.

Study of peak Laminar Burning Velocity of several syngas compositions at different temperatures

In the context of the current energy transition, the use of biomass-derived syngas (BDS) is often recognized as a fundamental path towards decreasing fossil fuel dependency and greenhouse gas emissions. However, hydrogen-containing BDS are prone to flame instability problems. More efforts are being carried out aiming at efficiently adopting BDS in industrial combustors with CH4 co-firing or inert gas dilutions by exploring accurate knowledge of burning velocity. To do so, a deeper knowledge of the syngas combustion behaviour is strictly necessary. The objective of this study fits in this framework: in particular, a computational study has been carried out to evaluate kinetic models and present fresh insights on the effects of varying syngas mixtures such as CO/H2, CO/H2/CO2 and CO/H2/CH4 on Laminar Burning Velocity (LBV) and peak LBV location (ΦLBV=max). In-detail chemical kinetic simulations of equimolar (CO: H2 = 1:1) forestry waste syngas were systematically carried out taking advantage of the open-source CANTERA solver. Three detailed kinetic models i.e., newly released FFCM-2, USC mech II, and modified GRI mech III were implemented to report accurate flame parameters at 1 bar and different temperature levels (from 300 K up to 450 K). On comparing the results with experiments, FFCM-2 proved to be a good kinetic model for the considered syngas mixtures CO/H2, CO/H2/CO2 and especially for CO/H2/CH4 for mixtures containing a limited share of 30 % methane at normal and moderately elevated temperature at 0.4 ≤ Φ ≤ 2.1. The USC mech II performed very well for CO/H2, and CO/H2/CO2, while the modified GRI mech III model also gave agreeable predictions for CO/H2/CH4 mixture having rich methane content. Additionally, when varying syngas composition analysis was conducted at different temperatures, the progressive CO2 dilution and CH4 addition of up to 30 % reduced the peak LBV and moved the peak LBV locations (ΦLBV=max) towards lean ER conditions with 9 % and 40 % reductions, respectively; however, only the latter effect was enhanced at the elevated initial temperature. Furthermore, sensitivity analysis of respective syngas mixtures is reported at normal and elevated temperatures to explore the most sensitive intermediate reactions relative to LBV. The shift of peak LBV locations and their enhancement at elevated temperatures also open the research path to study the underlying impacts on the flame modes/regimes and structure, especially CO emissions pathways in syngas with 30 % of CH4 and CO2 additions.

Choice of reaction progress variable under preferential diffusion effects in turbulent syngas combustion based on detailed chemistry direct numerical simulations

The combustion of hydrogen and carbon-monoxide mixtures, so-called syngas, plays an increasingly important role in the safety context of non-fossil energy generation, more specifically in the risk management of incidents in process engineering plants for ammonia synthesis and in nuclear power plants. In order to characterize and simulate syngas/air combustion on industrially relevant scales, subgrid modelling is required, which is often based on a reaction progress variable. To understand the influence of different fuel compositions, turbulence intensities and flame topologies on different possible definitions of reaction progress variable, detailed chemistry direct numerical simulations data of premixed, lean hydrogen/air and syngas/air flames has been considered. A reaction progress variable based on normalized molecular oxygen mass fraction has been found not to capture the augmentation of the normalized burning rate per unit flame surface area in comparison to the corresponding 1D unstretched premixed flame due to preferential diffusion effects. By contrast, reaction progress variables based on other individual species, such as hydrogen, can capture the augmentation of the rate of burning well, but exhibit a pronounced sensitivity to preferential diffusion effects, especially in response to flame curvatures. However, a reaction progress variable based on the linear combination of the main products can accurately represent the temperature evolution of the flame for different mixtures, turbulence intensities and varying local flame topology, while effectively capturing the augmentation of burning rate due to preferential diffusion effects. However, its tendency to assume values larger than 1.0 in the regions of super-adiabatic temperatures poses challenges for future modeling approaches, whereas the reaction progress variable based on hydrogen mass fraction remains bound between 0.0 and 1.0 despite showing deviations in comparison to corresponding variations obtained from the unstretched laminar flame depending on flame curvature variations.

Effects of Hydrogen Addition on the Thermal Performance and Emissions of Biomass Syngas Combustion in a Horizontal Boiler

Effects of Hydrogen Addition on the Thermal Performance and Emissions of Biomass Syngas Combustion in a Horizontal Boiler

Combustion Diagnosis in a Spark-Ignition Engine Fueled with Syngas at Different CO/H2 and Diluent Ratios

The gasification of residues into syngas offers a versatile gaseous fuel that can be used to produce heat and power in various applications. However, the application of syngas in engines presents several challenges due to the changes in its composition. Such variations can significantly alter the optimal operational conditions of the engines that are fueled with syngas, resulting in combustion instability, high engine variability, and misfires. In this context, this work presents an experimental investigation conducted on a port-fuel injection spark-ignition optical research engine using three different syngas mixtures, with a particular focus on the effects of CO/H2 and diluent ratios. A comparative analysis is made against methane, considered as the baseline fuel. The in-cylinder pressure and related parameters are examined as indicators of combustion behavior. Additionally, 2D cycle-resolved digital visualization is employed to trace flame front propagation. Custom image processing techniques are applied to estimate flame speed, displacement, and morphological parameters. The engine runs at a constant speed (900 rpm) and with full throttle like stationary engine applications. The excess air–fuel ratios vary from 1.0 to 1.4 by adjusting the injection time and the spark timing according to the maximum brake torque of the baseline fuel. A thermodynamic analysis revealed notable trends in in-cylinder pressure traces, indicative of differences in combustion evolution and peak pressures among the syngas mixtures and methane. Moreover, the study quantified parameters such as the mass fraction burned, combustion stability (COVIMEP), and fuel conversion efficiency. The analysis provided insights into flame morphology, propagation speed, and distortion under varying conditions, shedding light on the influence of fuel composition and air dilution. Overall, the results contribute to advancing the understanding of syngas combustion behavior in SI engines and hold implications for optimizing engine performance and developing numerical models.

Life Cycle Assessment of Wheat Straw Pyrolysis with Volatile Fractions Chemical Looping Combustion

Among the approaches to facilitating negative CO2 emissions is biochar production. Biochar is generated in the pyrolysis of certain biomasses. In the pyrolysis process, carbon in the biomass is turned into a solid, porous, carbon-rich, and stable material that can be captured from the soil after a period of from a few decades to several centuries. In addition to this long-term carbon sequestration role, biochar is also beneficial for soil performance as it helps to restore soil fertility and improves the retention and diffusion of water and nutrients. This work presents a Life Cycle Assessment of different pyrolysis approaches for biochar production. Biomass pyrolysis is performed in a fixed-bed reactor, which operates at a mild temperature (550 °C). Biochar is obtained as solid product of the pyrolysis, but there are also liquid (bio-oil) and gaseous products (syngas). The pyrolysis gas is partly used to fulfil the energy demand of the pyrolysis process, which is highly endothermic. In the conventional approach, CO2 is produced during the combustion of syngas and emitted to the atmosphere. Another approach to facilitate CO2 capture and thus obtain more negative CO2 emissions in the pyrolysis process is burning syngas and bio-oil in a Chemical Looping Combustion unit. Life Cycle Assessment was performed of these approaches toward biomass pyrolysis to evaluate their environmental impact. The Chemical Looping Combustion approach significantly reduced the values of 7 of the 16 environmental impact indicators studied, along with the Global Warming Potential among them, it slightly increased the value of one indicator related to the use of fossil resources, and it maintained the values of the remaining 8 indicators. Environmental impact reduction occurs due to the avoidance of CO2 and NOx emissions with Chemical Looping Combustion. The CO2 balances of the different pyrolysis approaches with Chemical Looping Combustion configurations were compared with a base case, which constituted the direct combustion of wheat straw to obtain thermal energy. Direct biomass combustion for the production of 17.1 MJ of thermal energy had CO2 positive emissions of 0.165 kg. If the gaseous fraction was burned by Chemical Looping Combustion, CO2 was captured and the emissions became increasingly negative, until a value of −3.30 kg/17.1 MJ was generated. If bio-oil was also burned by this technology, the negative trend of CO2 emissions continued, until they reached a value of −3.66 kg.

Mass yields of products and composition of syngas from pyrolysis of Brazilian plastic solid wastes: Combustion simulation and burner design to minimize COx and CxHy emissions

For the first time, the mass yields of products and the composition of synthesis gas (syngas) from pyrolysis of Brazilian plastic solid waste were evaluated for a reactor processing 20 g of plastic at 800 °C. Combustion of the syngas was simulated, evaluating the levels of COx and CxHy emissions, and a burner was designed to minimize emissions during combustion. The main findings highlighted the importance of performing thermogravimetric analyses of waste materials. Higher thermal degradation temperatures (530–900 °C) were obtained for all the plastics, compared to values reported in the literature (300–600 °C). Between 46.7 and 98.0 wt% of syngas was produced, with lower heating values ranging from 10390 to 45684 kJ kg−1, due to differences between the plastics in the fractions of inorganic and hydrocarbon gases produced. The maximum temperatures for syngas combustion, simulated using ANSYS software, were 2000 and 800 °C inside the burner and combustion chamber, respectively. In the burner, higher COx and CxHy levels were related to the syngas composition and incomplete chemical reactions in the flame zone. The CO and CxHy levels decreased towards the combustion chamber, where CO2 was less than 8 wt%, in compliance with the CONAMA 316/2002 regulation.

Reduced chemical kinetics mechanism for modelling of n-Heptane/syngas combustion with NOx formation in a micro-pilot ignited dual fuel engine

A reduced chemical kinetics model was developed to simulate the combined combustion of n-Heptane with syngas, as well as the standalone syngas combustion and NOx formation in a pilot-ignited dual fuel engine. This simplified model comprises 75 different species and 276 reactions. Its accuracy was confirmed by comparing it with experimental data from existing literature and numerical results from established models. The comparison encompassed key factors such as ignition delay, the speed of combustion in a laminar flame, and the concentration profiles of NOx. The reduced model closely aligned with both experimental and simulated outcomes, particularly under conditions relevant to engine combustion.This reduced mechanism was then employed in a comprehensive computational fluid dynamics computations to predict syngas combustion in a dual-fuel engine that employs the injection of reduced amount of liquid n-Heptane fuel with subsequent micro-pilot ignition. The model accurately captured the necessary conditions for n-Heptane injection and the co-oxidation of syngas with n-Heptane. Moreover, it exhibited strong agreement with experimental measurements of the heat release rate (ROHR) and cylinder pressures. The study's results highlight that the reduced mechanism can precisely simulate combustion of syngas-based fuels in engine cylinder containing up to 57% hydrogen (H2) content. As a result, this simplified model is highly suitable for simulating engine conditions involving fuels derived from syngas.

Sulfurization- Desulfurization of Iron-Calcium Oxygen Carriers during Chemical Looping Combustion of Syngas

Sulfurization- Desulfurization of Iron-Calcium Oxygen Carriers during Chemical Looping Combustion of Syngas

Numerical simulation of the aerodynamic flow of air and the results of the study of a burner device for burning synthetic gas

This work contributes to the ecological solution of synthetic gas combustion. The methods and tools that were used to research this topic are briefly described in the article. For the study, two programs were used and stabilizers were considered in terms of angular parameters. The angular stabilizers' dimensions and the optimal aerodynamic cross-section behind the stabilizer were calculated using numerical simulation in the ?COMSOL Multiphysics? program. This article also describes an experimental bench for burning syngas in a burner device. Due to the low-reaction characteristics of synthetic gas, its composition is variable. In this regard, to efficiently burn synthetic gas of various compositions, it is necessary to select the optimal angle of stabilizer inclination. During the experiments, the effect of angular stabilizers on the stabilization process, the efficiency of burning synthetic gas due to stable combustion, and the reduction of harmful emissions were investigated. Three different stabilizer angles (45?, 60?, and a semicircle) were presented on an experimental bench to find the optimal stabilizer angle for stable combustion with reduced nitrogen oxide emissions. As a result of the observation, it can be concluded that the combustion completeness of synthetic gas in burner devices depends not only on the angle of the stabilizer, but also on the coefficient of the incoming air, and this, in turn, affects the temperature level of the gases in the combustion zone.

CO Laser Absorption Measurements During Syngas Combustion at High Pressure

Abstract Syngas is a desirable fuel for combustion in the Allam-Fetvedt cycle, which involves combustion under supercritical-CO2 conditions. While some work has been conducted in collecting ignition delay times (IDT) at the extreme pressures required by these systems, significant model deficiencies remain. Additionally, considerable barriers in terms of nonideal gas dynamic effects have been shown for these experiments in shock tubes. Further investigation into the fundamental combustion kinetics of H2/CO/CO2 mixtures is required. Time-resolved speciation measurements for target species have been shown to better aid in improving the understanding of underlying chemical kinetics than global ignition delay time measurements. Therefore, laser absorption measurements of CO were measured behind reflected shock waves during combustion of syngas at 5 and 10 bar and temperatures between 1080 and 2100 K. The mixtures investigated utilized H2-to-CO ratios of 1:1 and 1:4, respectively, each at stoichiometric conditions, allowing for discussions of the effect of initial fuel composition. A ratio of fuel to CO2 of 1:2 was also utilized to represent commercially available syngas. The mixtures were diluted in helium and argon (20% He, 76.5% Ar) to minimize thermal effects and to expedite CO thermal relaxation during the experiment. The resulting CO time histories were then compared to modern chemical kinetics mechanisms, and disagreement is seen for this system, which is assumed to be fairly well known. This study elucidates particular chemistry that needs improvement in moving toward a better understanding of syngas combustion at elevated pressures.

Comparative study of a combined heat and power plant retrofitted by CO2 capture during the combustion of syngas from sewage sludge gasification versus zero-emission combustion of hydrogen produced using renewables

With ecological requirements aimed at limiting the production of CO2, it is necessary to produce all, or most of the energy from RES. During the transformation process, ecological and highly efficient combustion power plants will be needed. The classic cycle of combined heat and power (CCGT) with green improvements will continue to be one of the most suitable technologies for this task. This article presents the modernization of the CCGT power plant in Zielona Góra in terms of possible solutions to reduce CO2 emissions and cooperation with RES producing hydrogen. Two variants of retrofit were considered: CO2 capture following the combustion of syngas obtained from gasification of sewage sludge, and emission-free hydrogen combustion in a gas turbine. Calculations were made using numerical modelling and the obtained results were validated. Avoided CO2 emissions for both solutions are shown. The proposed upgrades were compared with the basic variant and other gaseous fuels.

Ammonia/syngas MILD combustion by a novel burner

Ammonia has received increasing attention as one of the most attractive energy carriers because of its carbon-free nature and the established reliable and economic infrastructure for its storage and distribution. However, the low burning velocity and nitrogen-containment of pure NH3 can cause some challenges for its combustion control such as flame instability and large NOx emissions. To overcome these issues, strategies of co-burning NH3 with highly reactive fuels such as CH4 or H2 have been developed and applied. Syngas, which can be produced from biomass pyrolysis, is a promising alternative fuel in the transition from carbon-based fuels to carbon-free fuels. Therefore, comparing to co-firing NH3 with CH4, co-firing NH3 with syngas is a better environmentally friendly option to improve the NH3 combustion property. However, co-firing NH3 with syngas faces severer combustion instability, NOx emissions and NH3 leakage due to the low heating value of syngas. To the best of the authors’ knowledge, the NH3/syngas combustion with low NOx emissions and zero NH3 leakage has not been achieved in a lab-scale combustor. In the present study, NH3/syngas MILD combustion was carried out in a novel burner developed in our previous work. In the novel burner, the high-temperature and diluted air produced by the lean premixed syngas combustion is the key to accomplish the MILD combustion of NH3. The impact of the temperature and O2 mole fraction of the HTDA on the emissions of NO, NO2, N2O, NH3, and CO was experimentally investigated with varying equivalence ratios and NH3 flow rates. The chemical reactor network was employed to analyze the experimental observation from the chemical kinetic aspect.

Modeling of a hybrid power system integrating solar radiation and syngas combustion energy

AbstractThis study aims to model a hybrid power system that can continuously generate power by switching between two possible thermal sources: solar radiation and combustion energy from synthesis gases. The system comprised a hybrid energy receiver, solar dish, Stirling generator, fluidized‐bed gasifier, boiler, and water tank. The solar dish was a dual‐reflection solar collector that used two mirrors, namely the main and subordinate concentrators, to concentrate a broad expanse of solar radiation onto a hybrid energy receiver. The fluidized‐bed gasifier was employed for the production of synthesis gases. The synthesis gases were combusted to provide an auxiliary heat source for the Stirling generator when solar radiation was insufficient. Solar radiation or combustion energy was alternatively introduced into the hybrid energy receiver and converted to power by a 1‐kW‐scale beta‐type Stirling engine. In this manner, the Stirling generator could serve as a base‐load power plant regardless of solar conditions. In this study, a complete quantitative model was developed for a demonstration plant by incorporating thermodynamic and dynamic models of the beta‐type Stirling engine, a ray‐tracing model for the dual‐reflection solar dish, an energy model of the hybrid energy receiver, and experimental data for the fluidized‐bed gasifier. The performance response of the system during switching between solar radiation and combustion energy was predicted. The modeling results indicated that switching can result in a continuous power output ranging from 600 to 1200 W. With synthesis gas combustion as the auxiliary heat source, the hybrid Stirling power system can be operated continuously, and the overall power output is increased by 109.82% compared to a conventional concentrated solar power system that only uses solar radiation.

Effect of CO[formula omitted] dilution on structures of premixed syngas/air flames in a gas turbine model combustor

The impact of CO2 dilution on combustion of syngas (a mixture of H2, CO, and CH4) was investigated in a lab-scale gas turbine model combustor at atmospheric pressure conditions. Two mild dilution levels of CO2, corresponding to 15% and 34% of CO2 mole fraction in the syngas/CO2 mixtures, were experimentally investigated to evaluate the effects of CO2 dilution on the flame structures and the emissions of CO and NOx. All experiments were performed at a constant Reynolds number (Re = 10000). High-speed flame luminescence, simultaneous planar laser-induced fluorescence (PLIF) measurements of the OH radicals and particle image velocimetry (PIV) were employed for qualitative and quantitative assessment of the resulting flame and flow structures. The main findings are: (a) the operability range of the syngas flames is significantly affected by the CO2 dilution, with both the lean blowoff (LBO) limit and the flashback limit shifting towards fuel-richer conditions as the CO2 dilution increases; (b) syngas flames exhibit flame-pocket structures with chemical reactions taking place in isolated pockets surrounded by non-reacting fuel/air mixture; (c) the inner recirculation zone tends to move closer to the burner axis at high CO2 dilution, and (d) the NOx emission becomes significantly lower with increasing CO2 dilution while the CO emission exhibits the opposite trend. The flame-pocket structure is more significant with increased CO2 dilution level. The low NOx emissions and high CO emissions are the results of the flame-pocket structures.

Gasification of MDF residue in an updraft fixed bed gasifier to produce heat and power via an ORC turbine

Biomass, which is a renewable resource, is regarded as an essential energy source due to its accessibility and abundance. In this study, the gasification of wood-based biomass wastes from the medium density fiberboard (MDF) facility was carried out and investigated utilizing an updraft fixed bed gasifier. The feeding capacity of the upstream gasifier is 2100 kg/h. MDF wastes are loaded into the system with feeding capacities of 1500, 1750 and 2100 kg/h. As a reference, the system has also been tested with oak wood chips at a maximum rate of 2100 kg/h. Produced syngas production rate to biomass waste is approximately 2.5 Nm3/kg. The measured gas compositions are CO, CO2, CH4, H2, O2 and N2. Test results with 2100 kg/hMDF wastes have similar gas composition compared to the test results with oak wood chips. The quality of the syngas produced by gasification is directly related to the fuel. It has been observed that the efficiency of the gasification process can be directly or indirectly impacted by the properties of the fuel, such as the moisture content, chemical compositions, and size. The temperature of the produced gas is approximately 430 °C, and it isdirectly combusted with tars and soot it contains to ensure that no chemical energy is lost. The thermal gasification system converts approximately 88% by weight of MDF residue to syngas. The calorific value of produced syngas is obtained between 6.0 and 7.0 MJ/Nm3. The hot syngas containing tars produced from the gasifier was directly burned in the thermal oil heater retrofitted to vortex syngas burner to recover thermal energy, which was then utilized in the production of energy via an ORC turbine. The thermal oil heater has a thermal capacity of 7MWh and the power generation capacity of the ORC turbine is 955 kW of electricity.

Fe-based oxygen carrier for the chemical looping combustion of CO, H2, and CH4 syngas in fluidized bed reactor under interruption of H2S

Chemical looping combustion (CLC) reduces the CO2 capturing cost, elevates combustion efficiency, and prevents NOx formation. This study applied Fe2O3/SiO2 and Fe2O3/Al2O3 oxygen carriers to react with H2, CO and CH4 under different operating setup and examined the interference of H2S. Examination was also conducted on the reaction kinetics, cycle test, and characterization of oxygen carriers. Reduction of oxygen carrier from Fe2O3 to between FeO and Fe occurred during the reaction. The higher syngas concentration led to higher diffusion capacity and promoted utilization of oxygen carriers. Carbon deposition was enhanced by excess concentration of CO and CH4. Involvement of H2S led to declining of performance due to the presence of carbonyl sulfide (COS) and FeS. With Fe2O3/SiO2, application of multiple redox cycles reduced the utilization value to 43 % due to formation of Fe2SiO4. Analysis of exhausted gas after reaction was applied in study of proposed reaction mechanism. Study of reaction kinetics using Type I deactivation test indicated a well fitted result with experimental data with R2 in the range of 0.9605–0.9976. Thus, compared to other studies with discussion only on CO, H2, or CH4 in CLC, this study offered a comprehensive research on interruption of H2S, characterization, and reaction kinetics.

Oxygen carrier derived from ferric sludge for chemical looping combustion of MSW syngas: Waste derived material performance and carbon footprint assessment

The utilization of water treatment sludge (i.e., ferric sludge) was explored as the oxygen carrier (OC) for chemical looping combustion (CLC) of municipal solid waste (MSW) syngas. The performance of ferric sludge (FS) in CLC and simultaneous HCl removal was evaluated in a bench-scale fluidized bed, and was compared with iron ore (IO) as a benchmarked OC. The results show that FS (92 %) performed better than IO (82 %) in terms of syngas combustion efficiency and FS was able to remove HCl (77 % removal efficiency) while IO was unable to remove any HCl. Comparison of reaction temperature reveals that FS performed better at lower CLC temperature between 800 °C and 850 °C. Agglomeration was observed when FS was used in extended CLC cycles. Thus, investigation of using inert α-Al2O3 support together with FS for extended CLC cycles was investigated. Agglomeration and sintering were drastically reduced and good combustion efficiency of 88 % for H2 and 74 % for CO was attained. Carbon footprint assessment illustrated that FS was superior as a greener material based on global warming potential of 20 and 100 years. Conversion of FS as an OC were characterized with 104.23 and 108.0 kgCO2/t lower than IO for GWP-20 and GWP-100, exhibiting the competitiveness in the usage of waste-derived material in CLC. Hence, FS can be considered as a novel, cost-effective, and greener OC for CLC. The co-utilization of waste-derived material and waste-derived syngas through CLC would be an integrated solution for improved circularity and sustainability.

Experimental and simulation study of premixed syngas-air deflagration dynamics with elevated temperature and CO2 addition

Experimental and dynamic analyses of the deflagration characteristics of laminar premixed syngas-air at different preheating temperatures and with different CO2 volume fractions were carried out in a rectangular half-open pipe. The effects of CO2 concentration and different initial temperatures on the flame structure evolution, flame structure profile and reaction rate of critical radicals, flame propagation speed, overpressure dynamics and hydrodynamic instability of syngas-air mixture were studied. The FFCM-1 mechanism was used to predict the laminar burning velocity of syngas-air under relevant conditions. The results revealed that the addition of CO2 inhibited the flame propagation and reduced the concentration of H, OH and O, thus reduced the laminar burning velocity. The increase in temperature promotes the chemical effect of CO2, and the interaction between the flame front and the pressure wave is more pronounced, prolonging the duration of the " tulip " flame. Adding CO2 reduces the flame front speed and overpressure, decreases the oscillation amplitude in late flame propagation, and inhibits the explosion intensity. Meanwhile, the temperature increase accelerates the flame propagation in the spherical and finger stages, and the maximum flame propagation speed and peak pressure appear earlier. In addition, as CO2 content and temperature rise, flame hydrodynamic instability is difficult to ignore. However, there is a lack of data from studies of syngas deflagration dynamics at higher temperatures and with higher CO2 additions. This suggests a focus on studies at higher temperatures as well as with higher CO2 additions to enable the development of accurate kinetic models for wide range of syngas combustion. Also, the higher the initial temperature, the longer the time required for heating.

Waste-to-energy technologies as the future of internal combustion engines

Syngas has a promising future as alternative to petroleum products and as a fuel for combustion engines. This study provides an overview on the feasibility of using syngas to power internal combustion engines. It presents technological process solutions for producing syngas toward minimizing the formation of tars as the most undesirable component for engine applications.. The combustion process characteristic of syngas composition has been tackled including critical criteria such as the flammability limit, ignition delay, laminar velocity, turbulent velocity, and the subsequent challenges in determining a numerical methods that best matches the exprimental datas. The syngas usage as alternative resource, while tackling the uncertainty issue of its composition, for Compression Ignition (CI) and Spark Ignition (SI) with the emission and performance effectiveness has been studied as well. The results of the review showed that syngas can be a viable alternative for some stationary applications, such as advanced integrated systems (ICCG), but its application is, however, relatively limited, for example as a secondary fuel in engines (CI) for automotive applications. However, significant discrepancies between numerical (simulation) and experimental results have been noted. This suggests that there are many scientific and experimental challenges in the area of syngas combustion processes in internal combustion engines. However, given the potential of this group of fuels, especially in the face of the energy crisis, this research is highly desirable and has a significant application perspective.