Broken Symmetry States Research Articles

Nonequilibrium quantum phase transition in a spinor quantum gas in a lattice coupled to a membrane

Recently, a novel kind of hybrid atom-optomechanical system, consisting of atoms in a lattice coupled to a membrane, has been experimentally realized [Vochezer {\it et al.,} Phys. Rev. Lett. \textbf{120}, 073602 (2018)], which promises a viable contender in the competitive field of simulating non-equilibrium many-body physics. Here we are motivated to investigate a spinor Bose gas coupled to a vibrational mode of a nano-membrane, focusing on analyzing the role of the spinor degrees of freedom therein. Through an adiabatic elimination of the degrees of freedom of the quantum oscillator, we derive an effective Hamiltonian which reveals a competition between the force localizing the atoms and the membrane displacement. We analyze the dynamical stability of the steady state using Bogoliubov-de Gennes approach and derive the stationary phase diagram in the parameter space. We investigate the non-equilibrium quantum phase transition from a localized symmetric state of the atom cloud to a shifted symmetry-broken state, where we present a detailed analysis of the effects of the spin degree of freedom. Our work presents a simple way to study the effects of the spinor degree of freedom on the non-equilibrium nonlinear phenomena that is complementary to ongoing experiments on the hybrid atom-optomechanical system.

Symmetry broken states in an ensemble of globally coupled pendulums

We consider the rotational dynamics in an ensemble of globally coupled identical pendulums. This model is essentially a generalization of the standard Kuramoto model, which takes into account the inertia and the intrinsic nonlinearity of the community elements. There exists the wide variety of in-phase and out-of-phase regimes. Many of these states appear due to broken symmetry. In the case of small dissipation our theoretical analysis allows one to find the boundaries of the instability domain of in-phase rotational mode for ensembles with arbitrary number of pendulums, describe all arising out-of-phase rotation modes and study in detail their stability. For the system of three elements parameter sets corresponding to the unstable in-phase rotations we find a number of out-of-phase regimes and investigate their stability and bifurcations both analytically and numerically. As a result, we obtain a sufficiently detailed picture of the symmetry breaking and existence of various regular and chaotic states.

Charge regulation radically modifies electrostatics in membrane stacks.

Motivated by biological membrane-containing organelles in plants and photosynthetic bacteria, we study charge regulation in a model membrane stack. Considering (de)protonation as the simplest mechanism of charge equilibration between the membranes and with the bathing environment, we uncover a symmetry-broken charge state in the stack with a quasiperiodic effective charge sequence. In the case of a monovalent bathing salt solution our model predicts complex, inhomogeneous charge equilibria depending on the strength of the (de)protonation reaction, salt concentration, and membrane size. Our results shed light on the basic reorganization mechanism of thylakoid membrane stacks.

The optical control of phase locking of polariton condensates

The phase and the frequency of an exciton polariton condensate excited by a nonresonant pump can be efficiently manipulated by an external coherent light. Being tuned close to the resonance with the condensate eigenfrequency, the external laser light imposes its frequency to the condensate and locks its phase, thereby manifesting a synchronization effect. The conditions of formation of the phase synchronized regime are determined. The synchronization of a couple of closely spaced polariton condensates by a spatially uniform coherent light is examined. At the moderate strength of the coherent driving the synchronization is accompanied by the appearance of symmetry-breaking states of the polariton dyad, while these states are superseded by the symmetric state at the high-intensity driving. By employing a zero-dimensional model of coupled dissipative oscillators with both dissipative and conservative coupling, we study the bifurcation scenario of the symmetry-breaking state formation.

Superconductors, orbital magnets and correlated states in magic-angle bilayer graphene.

Superconductivity can occur under conditions approaching broken-symmetry parent states1. In bilayer graphene, the twisting of one layer with respect to the other at 'magic' twist angles of around 1 degree leads to the emergence of ultra-flatmoiré superlattice minibands. Such bands are a rich and highly tunable source of strong-correlation physics2-5, notably superconductivity, which emerges close to interaction-induced insulating states6,7. Here we report the fabrication of magic-angle twisted bilayer graphene devices with highly uniform twist angles. The reduction in twist-angle disorder reveals the presence of insulating states at all integer occupancies of the fourfold spin-valley degenerate flat conduction and valence bands-that is, at moiré band filling factors ν=0,±1,±2,±3. At ν≈-2, superconductivity is observed below critical temperatures of up to 3 kelvin. We also observe three new superconducting domes at much lower temperatures, close to the ν=0 and ν=±1 insulating states. Notably, at ν=±1 we find states with non-zero Chern numbers. For ν=-1 the insulating state exhibits a sharp hysteretic resistance enhancement when a perpendicular magnetic field greater than 3.6 tesla is applied, which is consistent with a field-driven phase transition. Our study shows that broken-symmetry states, interaction-driven insulators, orbital magnets, states with non-zero Chern numbers and superconducting domes occur frequently across a wide range of moiré flat band fillings, including close to charge neutrality. This study provides a more detailed view of the phenomenology of magic-angle twisted bilayer graphene, adding to our evolving understanding of its emergent properties.

Coupling Constants, High Spin, and Broken Symmetry States of Organic Radicals: an Assessment of the Molecules-in-Molecules Fragmentation-Based Method.

We extend the application of our multilayer molecules-in-molecules (MIM) fragmentation-based method to the study of open-shell systems, particularly organic radicals. A test set of organic mono-, di- and polyradicals with a wide range in size, containing up to 360 atoms, was investigated. Total energies computed with MIM using density functional theory (DFT) were compared with full, unfragmented energies to assess the performance of MIM and to develop a systematic protocol for the treatment of large radical systems. More specifically, a two-layer (MIM2) model with a fragmentation scheme along the backbone involving covalently bonded dimers, trimers, or tetramers was considered, with DFT at a smaller basis set serving as the low level of theory. The MIM method was evaluated on the high-spin state and several possible broken-symmetry (BS) states for di- and polyradicals. When relevant spin-spin interactions were considered, the errors in total energies were less than 1 kcal mol-1. In addition, the applicability of MIM2 was extended to predict the intersite magnetic exchange coupling constants (J), which were compared with reference values. Further, since the energy levels derived from Hamiltonian diagonalization are physically more meaningful, the calculated J values estimated from the BS-DFT methodology were used to obtain the lower spin state energies of the polyradicals. The difference in calculated total energies of the lower spin state between full and MIM2 lie within 1 kcal mol-1 in the majority of these cases. Our rigorous, quantum chemical study demonstrates that MIM can be successfully applied to the study of large organic radicals reliably and accurately within the framework of BS-DFT.

Novel excitations near quantum criticality in geometrically frustrated antiferromagnet CsFeCl3.

The investigation of materials that exhibit quantum phase transition provides valuable insights into fundamental problems in physics. We present neutron scattering under pressure in a triangular-lattice antiferromagnet that has a quantum disorder in the low-pressure phase and a noncollinear structure in the high-pressure phase. The neutron spectrum continuously evolves through critical pressure; a single mode in the disordered state becomes soft with the pressure and it splits into gapless and gapped modes in the ordered phase. Extended spin-wave theory reveals that the longitudinal and transverse fluctuations of spins are hybridized in the modes because of noncollinearity, and previously unidentified magnetic excitations are formed. We report a new hybridization of the phase and amplitude fluctuations of the order parameter near a quantum critical point in a spontaneously symmetry-broken state.

Visualizing the charge order and topological defects in an overdoped (Bi,Pb)2Sr2CuO6+x superconductor

Electronic charge order is a symmetry breaking state in high-$T_\mathrm{c}$ cuprate superconductors. In scanning tunneling microscopy, the detected charge-order-induced modulation is an electronic response of the charge order. For an overdoped (Bi,Pb)$_2$Sr$_2$CuO$_{6+x}$ sample, we apply scanning tunneling microscopy to explore local properties of the charge order. The ordering wavevector is non-dispersive with energy, which can be confirmed and determined. By extracting its order-parameter field, we identify dislocations in the stripe structure of the electronic modulation, which correspond to topological defects with an integer winding number of $\pm 1$. Through differential conductance maps over a series of reduced energies, the development of different response of the charge order is observed and a spatial evolution of topological defects is detected. The intensity of charge-order-induced modulation increases with energy and reaches its maximum when approaching the pseudogap energy. In this evolution, the topological defects decrease in density and migrate in space. Furthermore, we observe appearance and disappearance of closely spaced pairs of defects as energy changes. Our experimental results could inspire further studies of the charge order in both high-$T_\mathrm{c}$ cuprate superconductors and other charge density wave materials.

Propagation of dark soliton interacting with domain wall in two immiscible Bose–Einstein condensates**Project supported by the National Natural Science Foundation of China (Grant Nos. 61565007, 11875149, 11747079, and 11874127), the Science Fund from the Department of Science and Technology of Jiangxi Province, China (Grant Nos. 20162BCB23049 and 20171ACB21045), the Youth Jinggang Scholars Program in Jiangxi Province, China, and the Program

Reflection and transmission are two behaviors of wave propagating to an interface. The immiscible binary mixtures of Bose–Einstein condensates can form the symmetry-breaking state, in which the domain wall on the center can serve as the interface. In this study, we explore in detail the propagation of a dark soliton interacting with the domain wall in the harmonic trap. We find that the low-energy dark soliton is easy to form the transmission and the high-energy dark soliton trends to reflect from the domain wall. Both reflection and transmission of dark soliton on the domain wall induce the sound radiation. But the sound radiation in the reflection derives from the collective oscillation of condensates, and it in the transmission comes not only from the collective oscillation, but also from the condensate filling in the dark soliton.

Probing Quantum Criticality and Symmetry Breaking at the Microscopic Level

We report on an experimental study of the Lipkin-Meshkov-Glick model of quantum spins interacting at infinite range in a transverse magnetic field, which exhibits a ferromagnetic phase transition in the thermodynamic limit. We use dysprosium atoms of electronic spin J=8, subjected to a quadratic Zeeman light shift, to simulate 2J=16 interacting spins 1/2. We probe the system microscopically using single magnetic sublevel resolution, giving access to the spin projection parity, which is the collective observable characterizing the underlying Z_{2} symmetry. We measure the thermodynamic properties and dynamical response of the system, and we study the quantum critical behavior around the transition point. In the ferromagnetic phase, we achieve coherent tunneling between symmetry-broken states, and we test the link between symmetry breaking and the appearance of a finite order parameter.

Dissipative Bose-Josephson junction coupled to bosonic baths.

We investigate the effect of dissipation in a Bose-Josephson junction (BJJ) coupled to baths of bosons at its two sites. Apart from the dynamical transition due to repulsive interactions, the BJJ undergoes a quantum phase transition by increasing the coupling strength with the bath modes. We analyze this system by mapping to an equivalent spin model coupled to the bosonic modes. The excitation energies and fluctuation of number imbalance are obtained within a Holstein-Primakoff approximation, which exhibits vanishing of the energy gap and enhanced quantum fluctuations at the critical point. We study the dynamics of BJJ using a time-dependent variational method and analyze stability of different types of steady states. As a special case we study in detail the phase space dynamics of BJJ coupled to a single mode, which reveals diffusive and incoherent behavior with increasing coupling to the bath mode. The dynamical steady states corresponding to the π oscillation and self-trapped state become unstable when their oscillation frequencies are in resonance with the bath modes. We study the Josephson dynamics in the presence of an Ohmic bath with Gaussian noise to incorporate the thermal fluctuations and obtain the Josephson oscillation frequency and damping analytically. We also observe the transition to the symmetry-broken state for strong coupling as well as decay of π oscillation and a self-trapped state to the ground state due to dissipation. Variation of the phase fluctuation with temperature of the bath shows similar behavior as observed in experiment. Finally we discuss the experimental setup to study the observable effects of dissipation in BJJ.

Electrically Tunable Flat Bands and Magnetism in Twisted Bilayer Graphene.

Twisted graphene bilayers provide a versatile platform to engineer metamaterials with novel emergent properties by exploiting the resulting geometric moiré superlattice. Such superlattices are known to host bulk valley currents at tiny angles (α≈0.3°) and flat bands at magic angles (α≈1°). We show that tuning the twist angle to α^{*}≈0.8° generates flat bands away from charge neutrality with a triangular superlattice periodicity. When doped with ±6 electrons per moiré cell, these bands are half-filled and electronic interactions produce a symmetry-broken ground state (Stoner instability) with spin-polarized regions that order ferromagnetically. Application of an interlayer electric field breaks inversion symmetry and introduces valley-dependent dispersion that quenches the magnetic order. With these results, we propose a solid-state platform that realizes electrically tunable strong correlations.

Scanning tunneling microscope study of quantum Hall isospin ferromagnetic states in the zero Landau level in a graphene monolayer

A number of quantum Hall isospin ferromagnetic (QHIFM) states have been predicted in the relativistic zero Landau level (LL) of graphene monolayer. These states, especially the states at LL filling factor v = 0 of charge-neutral graphene, have been extensively explored in experiment. To date, identification of these high-field broken-symmetry states has mostly relied on macroscopic transport techniques. Here, we study splitting of the zero LL of graphene at partial filling and demonstrate a direct approach by imaging the QHIFM states at atomic scale with a scanning tunneling microscope. At half filling of the zero LL (v = 0), the system is in a spin unpolarized state and we observe a linear magnetic-field-scaling of valley splitting. Simultaneously, the spin degeneracy in the two valleys is also lifted by the magnetic fields. When the Fermi level lies inside the spin-polarized states (at v = 1 or -1), the spin splitting is dramatically enhanced because of the strong many-body effects. At v = 0, we direct image the wavefunctions of the QHIFM states at atomic scale and observe an interaction-driven density wave featuring a Kekule distortion, which is responsible for the large gap at charge neutrality point in high magnetic fields.

Topological Ising pairing states in monolayer and trilayer TaS2

We study the possibility of topological superconductivity in the noncentrosymmetric monolayer and trilayer ${\mathrm{TaS}}_{2}$ with out-of-plane mirror symmetry. A time-reversal-invariant nodal $(s+f)$-wave pairing state with even mirror parity is found to be a promising candidate. This mixed state holds 12 (36) nodes at the Fermi pockets around $\mathrm{\ensuremath{\Gamma}}$ for the monolayer (trilayer) case and its unconventional superconductivity is consistent with the scanning tunneling microscopy experiments observed in $2H\text{\ensuremath{-}}{\mathrm{TaS}}_{2}$ thin flakes. Furthermore, with doping or under uniaxial pressure for trilayer $2H\text{\ensuremath{-}}{\mathrm{TaS}}_{2}$, large-Chern-number time-reversal symmetry-breaking mixed states between $(d+id)$- and $(p\ensuremath{-}ip)$-wave pairings can be realized in the phase diagram.

Magnetic profile of proximity-coupled (Dy,Bi)2Te3/(Cr,Sb)2Te3 topological insulator heterostructures

Magnetic topological insulators (TIs) are an ideal playground for the study of novel quantum phenomena building on time-reversal symmetry-broken topological surface states. By combining different magnetic TIs in a heterostructure, their magnetic and electronic properties can be precisely tuned. Recently, we have combined high-moment $\mathrm{Dy}:{\mathrm{Bi}}_{2}{\mathrm{Te}}_{3}$ with high transition temperature $\mathrm{Cr}:{\mathrm{Sb}}_{2}{\mathrm{Te}}_{3}$ in a superlattice, and we found, using x-ray magnetic circular dichroism (XMCD), that long-range magnetic order can be introduced in the $\mathrm{Dy}:{\mathrm{Bi}}_{2}{\mathrm{Te}}_{3}$ layers. Accompanying first-principles calculations indicated that the origin of the long-range magnetic order is a strong antiferromagnetic coupling between Dy and Cr magnetic moments at the interface extending over several layers. However, based on XMCD alone, which is either averaging over the entire thin-film stack or is surface-sensitive, this coupling scenario could not be fully confirmed. Here we use polarized neutron reflectometry, which is ideally suited for the detailed study of superlattices, to retrieve the magnetization in a layer- and interface-resolved way. We find that the magnetization is, in contrast to similar recent studies, homogeneous throughout the individual layers, with no apparent interfacial effects. This finding demonstrates that heterostructure engineering is a powerful way of controlling the magnetic properties of entire layers, with the effects of coupling reaching beyond the interface region.

Common-injection-induced isolated desynchronization in delay-coupled VCSELs networks with variable-polarization optical feedback.

We have investigated the cluster isolated desynchronization, a symmetry-breaking state, in the delay-coupled vertical-cavity surface-emitting lasers (VCSELs) networks subject to variable-polarization optical feedback (VPOF). It is shown that, in the VPOF-VCSELs networks, the elusive isolated desynchronization phenomenon could emerge out of the cluster synchronization by the common-signal injection approach from an additional auxiliary VCSEL. The influences of parameters in VPOF-VCSELs networks on the existence and stability of isolated desynchronization are systematically investigated. Moreover, the generality of the proposed scheme is validated in the VPOF-VCSELs network with real-world network topology (Nepal power grid network). Our results offer a new insight to manage the synchronization patterns of a VCSELs network.

Invariant theory and orientational phase transitions.

The Landau theory of phase transitions has been productively applied to phase transitions that involve rotational symmetry breaking, such as the transition from an isotropic fluid to a nematic liquid crystal. It even can be applied to the orientational symmetry breaking of simple atomic or molecular clusters that are not true phase transitions. In this paper, we address fundamental problems that arise with the Landau theory when it is applied to rotational symmetry breaking transitions of more complex particle clusters that involve order parameters characterized by larger values of the l index of the dominant spherical harmonic that describes the broken symmetry state. The problems are twofold. First, one may encounter a thermodynamic instability of the expected ground state with respect to states with lower symmetry. A second problem concerns the proliferation of quartic invariants that may or may not be physical. We show that the combination of a geometrical method based on the analysis of the space of invariants, developed by Kim to study symmetry breaking of the Higgs potential, with modern visualization tools provides a resolution to these problems. The approach is applied to the outcome of numerical simulations of particle ordering on a spherical surface and to the ordering of protein shells.

Dynamical aspects of spontaneous symmetry breaking in driven flow with exclusion.

We present a numerical study of a two-lane version of the stochastic nonequilibrium model known as the totally asymmetric simple exclusion process. For such a system with open boundaries, and suitably chosen values of externally imposed particle injection (α) and ejection (β) rates, spontaneous symmetry breaking can occur. We investigate the statistics and internal structure of the stochastically induced transitions or "flips," which occur between opposite broken-symmetry states as the system evolves in time. From the distribution of time intervals separating successive flips, we show that the evolution of the associated characteristic times against externally imposed rates yields information regarding the proximity to a critical point in parameter space. On short timescales, we probe for the possible existence of precursor events to a flip between opposite broken-symmetry states. We study an adaptation of domain-wall theory to mimic the density reversal process associated with a flip.

Charge Density Wave Melting in One-Dimensional Wires with Femtosecond Subgap Excitation

Charge density waves (CDWs) are symmetry-broken ground states that commonly occur in low-dimensional metals due to strong electron-electron and/or electron-phonon coupling. The nonequilibrium carrier distribution established via photodoping with femtosecond laser pulses readily quenches these ground states and induces an ultrafast insulator-to-metal phase transition. To date, CDW melting has been mainly investigated in the single-photon regime with pump photon energies bigger than the gap size. The recent development of strong-field midinfrared sources now enables the investigation of CDW dynamics following subgap excitation. Here we excite prototypical one-dimensional indium wires with a CDW gap of ∼300 meV with midinfrared pulses at ℏω=190 meV with MV/cm field strength and probe the transient electronic structure with time- and angle-resolved photoemission spectroscopy. We find that the CDW gap is filled on a timescale short compared to our temporal resolution of 300fs and that the band structure changes are completed within ∼1 ps. Supported by a minimal theoretical model we attribute our findings to multiphoton absorption across the CDW gap.

Geometry and Electronic Structure of the P-Cluster in Nitrogenase Studied by Combined Quantum Mechanical and Molecular Mechanical Calculations and Quantum Refinement.

We have studied the geometry and electronic structure of the P-cluster in nitrogenase in four oxidation states: PN, P1+, P2+, and P3+. We have employed combined quantum mechanical and molecular mechanical (QM/MM) calculations, using two different density-functional theory methods, TPSS and B3LYP. The calculations confirm that the side chain of Ser-188 is most likely deprotonated in the partly oxidized P1+ state, thereby forming a bond to Fe6. Likewise, the backbone amide group of Cys-88 is deprotonated in the doubly oxidized P2+ state, forming a bond to Fe5. The calculations also confirm the two conformations of the P-cluster in the atomic-resolution crystal structure of the enzyme, representing the PN and P2+ states, but show that the finer differences between the two structures are not fully reflected in the crystal structure, because the coordinates of only two atoms differ between the two conformations. However, the recent crystal structure of the P1+ state seems to be of lower quality with many dubious Fe-Fe and Fe-S distances. Quantum refinement of this structure indicates that it is a mixture of the P1+ and P2+ states but confirms that the side chain of Ser-188 is most likely deprotonated in both states. TPSS gives structures that are appreciably closer to the crystal structures than does B3LYP. In addition, we have studied all 16-48 possible broken-symmetry states of the four oxidation states of the P-cluster with DFT in the one or two observed spin states. For the reduced PN state, we can settle the most likely state from the calculated energies and geometries. However, for the more oxidized states there are large differences in the predictions obtained with the two DFT methods.