Sustainable Materials Research Articles

Advancing Residential Construction with Papercrete Concrete: A Comprehensive Review

Abstract: The construction industry is witnessing a shift towards sustainable materials, with innovative solutions like Papercrete offering eco-friendly alternatives to traditional concrete. This study explores the utilization of Papercrete in construction, highlighting its environmental benefits, cost-effectiveness, and applications. Through a comprehensive review of existing literature, including studies on similar materials like Wood-Crete and Aggregates of Wastepaper and Lime (AWPL), this research identifies gaps and opportunities in sustainable building material development. Additionally, experimental studies on Ultra-High-Performance Concretes (UHPCs) with Supplementary Cementitious Materials (SCMs) and Papercrete bricks provide insights into their compressive strength and suitability for construction. The technical specifications and cost analysis section delineates guidelines for excavation and backfilling activities, crucial for efficient project execution. Utilizing AutoCAD and Microsoft Excel for drafting and estimation, respectively, ensures accuracy and efficiency in project planning. The detailed estimate for a proposed 2BHK residential building demonstrates the practical application of these tools and methods, with results indicating the viability of Papercrete in construction. Overall, this study emphasizes the importance of sustainable building materials in mitigating environmental impact, enhancing occupant health, and promoting economic sustainability in the construction industry.

Lightweight, Strong, and Transparent Wood Films Produced by Capillary Driven Self-Densification.

Wood delignification and densification enable the production of high strength and/or transparent wood materials with exceptional properties. However, processing needs to be more sustainable and besides the chemical delignification treatments, energy intense hot-pressing calls for alternative approaches. Here, this study shows that additional softening of delignified wood via a mild swelling process using an ionic liquid-water mixture enables the densification of tube-line wood cells into layer-by-layer sheet structures without hot-pressing. The natural capillary force induces self-densification in a simple drying process resulting in a transparent wood film. The as-prepared films with ≈150µm thickness possess an optical transmittance ≈70%, while maintaining optical haze >95%. Due to the densely packed sheet structure with a large interfacial area, the reassembled wood film is fivefold stronger and stiffer than the delignified wood in fiber direction. Owing to a low density, the specific tensile strength and elastic modulus are as high as 282MPacm3g-1 and 31GPacm3g-1. A facile and highly energy efficient wood nanotechnology approach are demonstrated toward more sustainable materials and processes by directly converting delignified wood into transparent wood omitting polymeric matrix infiltration or mechanical pressing.

Advances in Materials with Self-Healing Properties: A Brief Review

The development of materials with self-healing capabilities has garnered considerable attention due to their potential to enhance the durability and longevity of various engineering and structural applications. In this review, we provide an overview of recent advances in materials with self-healing properties, encompassing polymers, ceramics, metals, and composites. We outline future research directions and potential applications of self-healing materials (SHMs) in diverse fields. This review aims to provide insights into the current state-of-the-art in SHM research and guide future efforts towards the development of innovative and sustainable materials with enhanced self-repair capabilities. Each material type showcases unique self-repair mechanisms tailored to address specific challenges. Furthermore, this review investigates crack healing processes, shedding light on the latest developments in this critical aspect of self-healing materials. Through an extensive exploration of these topics, this review aims to provide a comprehensive understanding of the current landscape and future directions in self-healing materials research.

Micrometer‐Thin Nanocellulose Foils for 3D Organic Electronics

AbstractCellulose is a natural polymer with great properties such as high optical transparency and mechanical strength, flexibility, and biodegradability. Hence, cellulose‐based foils are suitable for the replacement of synthetic polymers as substrate materials in organic electronics. This article reports the fabrication of ultrathin, free‐standing cellulose foils by spraying aqueous 2,2,6,6‐tetramethylpiperidine‐1‐oxyl‐nanocellulose (TEMPO) fibrils ink layer‐by‐layer on a hot substrate using a movable spray nozzle. The resulting foils are only 2 ± 1 µm in thickness with an average basis weight of 1.9 g m−2, which ranges in the same scale as the world's thinnest paper. The suitability of these ultra‐thin nanocellulose foils as a sustainable substrate material for organic electronic applications is demonstrated by testing the foils resistance against organic solvents. Furthermore, silver nanowires (AgNWs) and the blend poly(3,4‐ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) are integrated into the foils, and the foils are molded into 3D paper structures in order to create conductive, paper‐based building blocks for organic electronics.

A Review on the Effects of Waste Textile Polymer Fiber on Concrete Strength: Exploring the Key Parameters

The construction industry is one of the largest users of natural resources and can, thus, lead to significant environmental issues. Therefore, there is elevated interest worldwide in developing sustainable construction materials and techniques that can reduce these associated environmental impacts. In this context, one substantial area of focus is the incorporation of textile waste in construction materials, such as concrete. Textile waste is generated in large quantities from the production stage through to the consumption and end-of-life disposal periods. Hence, it is prudent to devise effective ways of recycling this waste, which can, in turn, reduce the environmental implications of textile production and cut down the quantity of waste sent to landfills. Furthermore, fibers obtained from recycled textile waste can be used to reinforce concrete, thus replacing the need for synthetic fibers. This review focuses on the use and effects of incorporating polymer fibers from recycled textile waste in concrete and the use of textile polymer fiber in the construction of various structures, and challenges in the use of recycled fibers in concrete and the parameters affecting the resultant strength of concrete structures, such as stress transfer, crack control, bond strength, and spalling, etc., are discussed.

Biomass-Derived Carbon Materials for Advanced Metal-Ion Hybrid Supercapacitors: A Step Towards More Sustainable Energy

Modern research has made the search for high-performance, sustainable, and efficient energy storage technologies a main focus, especially in light of the growing environmental and energy-demanding issues. This review paper focuses on the pivotal role of biomass-derived carbon (BDC) materials in the development of high-performance metal-ion hybrid supercapacitors (MIHSCs), specifically targeting sodium (Na)-, potassium (K)-, aluminium (Al)-, and zinc (Zn)-ion-based systems. Due to their widespread availability, renewable nature, and exceptional physicochemical properties, BDC materials are ideal for supercapacitor electrodes, which perfectly balance environmental sustainability and technological advancement. This paper delves into the synthesis, functionalization, and structural engineering of advanced biomass-based carbon materials, highlighting the strategies to enhance their electrochemical performance. It elaborates on the unique characteristics of these carbons, such as high specific surface area, tuneable porosity, and heteroatom doping, which are pivotal in achieving superior capacitance, energy density, and cycling stability in Na-, K-, Al-, and Zn-ion hybrid supercapacitors. Furthermore, the compatibility of BDCs with metal-ion electrolytes and their role in facilitating ion transport and charge storage mechanisms are critically analysed. Novelty arises from a comprehensive comparison of these carbon materials across metal-ion systems, unveiling the synergistic effects of BDCs’ structural attributes on the performance of each supercapacitor type. This review also casts light on the current challenges, such as scalability, cost-effectiveness, and performance consistency, offering insightful perspectives for future research. This review underscores the transformative potential of BDC materials in MIHSCs and paves the way for next-generation energy storage technologies that are both high-performing and ecologically friendly. It calls for continued innovation and interdisciplinary collaboration to explore these sustainable materials, thereby contributing to advancing green energy technologies.

Smart textiles: Paving the way to sustainability

As an emerging technology, smart textiles can bring solutions to many problems, but also create new ones, especially related to their disposal and their impact on the environment. That is why it is important to address this problem at this stage of technological development when smart textiles have not yet pervaded the mass markets. In this article, first, an attempt is made to understand the chronological development of smart textiles: the reasons for a weak breakthrough in the commercial markets throughout the decades, starting from the 1990s until today, but also the emergence of new driving forces that should inevitably lead to a bright future for smart textiles. In addition, we explore the contemporary possibilities for sustainable materials, manufacturing techniques, and end-of-life solutions for developing sustainable smart textiles based on a broad literature review, online sources, and a questionnaire survey among textile experts. Finally, an overview of the latest developments related to the standardization of smart textiles is given. This research was spurred by participation in CONTEXT COST Action (CA17107 - European Network to connect research and innovation efforts on advanced Smart Textiles).

A Research Article on Sustainable Construction Material

The construction industry is facing increasing pressure to adopt sustainable practices to mitigate environmental impacts and address resource scarcity. Sustainable construction materials play a pivotal role in achieving these goals by reducing carbon emissions, minimizing waste generation, and promoting circular economy principles. This research article provides a comprehensive review of advancements in sustainable construction materials, encompassing various categories such as recycled materials, bio-based materials, and low-carbon alternatives. It explores a wide array of materials such as Human Hair fiber, bamboo, coconut fiber, and more. Each material's sustainable attributes, including recyclability, durability, energy efficiency, and reduced environmental impact, are thoroughly examined. Furthermore, the review investigates the manufacturing processes, life cycle assessment, and environmental performance of these materials. It discusses the challenges and barriers to the widespread adoption of sustainable construction materials, including cost considerations, regulatory hurdles, and technological limitations.

First‐Principles Investigations of Structural, Electronic, and Elastic Properties of ZrSiO3 Perovskite: Layer Dependence, Surface Termination, and Pressure Effects

Zirconium silicate (ZrSiO3) perovskite is a promising material for various technological applications. The structural, electronic, and thermodynamic properties of ZrSiO3 perovskite are studied under different conditions, including pressure and layer configuration variations using density functional theory. The present investigation includes a thorough analysis of 2D perovskite derivatives derived from its basic 3D structure. The bulk and surface‐terminated silicon‐dominant SiO2 and zirconium‐dominant ZrO compounds are found to be mechanically stable with an anisotropy factor above 1. The calculated indirect‐bandgap values for the ZrO termination and SiO2 termination are found to be 2.585 and 1.639 eV, respectively. Moreover, the pore size of the SiO2‐terminated slab model of ZrSiO3 is calculated to be 105.39 μm and that for ZrO‐termination to be 129.30 μm. Thus, the material considered for the study can have potential applications in bone regeneration and tissue engineering. Further, the possibilities for modifying ZrSiO3 for uses in electrical devices, sensors, sustainable energy materials, and even biomedical applications like tissue engineering are intriguingly expanded by the present findings.

Unveiling ductile, rare-earth-free structural materials: A DFT exploration of MnTi and MnZr

This paper presents a theoretical exploration of the electronic, structural, and mechanical attributes inherent in three rare-earth-free intermetallic compounds, namely, MnTi, MnZr, and MnHf. Employing density functional theory (DFT) calculations with the Implementation of projector augmented wave (PAW); our investigation adopts the supercell approach to meticulously determine the structural and mechanical properties of these materials. The findings reveal that MnTi and MnZr exhibit intrinsic ductility, positioning them as viable contenders for applications demanding high-strength structures. In contrast, MnHf demonstrates mechanical instability. This study provides promising insights into the mechanical characteristics of MnTi and MnZr, underscoring their potential as sustainable structural materials, given the abundance and non-toxic nature of their constituents. The research findings presented herein contribute to the understanding of rare-earth-free intermetallics, offering valuable information for applications in materials science and engineering.

Starch‐based nanoparticles as a replacement for synthetic latex: A comprehensive assessment of printability and colorimetric characteristics

AbstractThe papermaking, packaging, and printing industry are actively seeking sustainable material alternatives to address growing concerns about environmental consciousness and finite resources. Synthetic latex, a frequently utilized binder in paper coating formulations, present difficulties due to their dependence on fossil fuel resources and their reduced recyclability in comparison to eco‐friendly sustainable products. In this study, synthetic latex was replaced with a starch‐based nanoparticle (starch NP) binder at a 1:1 ratio in a coating formulation. Printing trials to assess colorimetric characteristics was made using electrophotography (EP) printing, given the current upward trajectory and expansion of EP technology into the label, packaging, and folding carton sectors. The in‐depth investigations reveal that incorporating starch NP binder result in improved optical, color, and dot characteristics. Moreover, it maintains consistent and comparable coefficients of friction. Partial replacement of synthetic latex with the starch NP binder yields significant enhancements in surface roughness and text quality. Importantly, the starch NP binder not only improves the dielectric relaxation properties of the paper and enhances toner transfer but also accelerates the distribution of the electrical field compared to synthetic latex, optimizing toner transfer and thereby enhancing color gamut volume. The study demonstrates that employing the starch NP binder leads to substantial improvements in colorimetric performance without any drawbacks in EP printing, making it highly advantageous to replace 50% of the synthetic binder.

Conversion of Post-Refining Waste MONG to Gaseous Fuel in a Rotary Gasifier

Biodiesel manufacturing frequently employs sustainable materials like soybeans, microorganisms, palm extract, jatropha plant, and recycled frying oils. The expansion of biodiesel manufacturing has escalated the volume of waste byproducts, encompassing glycerin and non-glycerin organic matter (MONG), jointly known as raw glycerin. MONG is characterized by a low calorific value, a high autoignition temperature, and significant viscosity at room temperature. As a waste product, it negatively affects the natural environment due to the lack of viable disposal methods. Hence, there is a need for its conversion into high-calorific gaseous fuel with significantly less environmental impact. One of the methods for converting MONG into gaseous fuel is the pyrolysis process. This study describes the pyrolytic conversion of MONG conducted on a test stand consisting of a rotating chamber with a shell filled with liquid lead as a heating medium. Based on the measurements and balance calculations, the amount of heat required to preserve the autothermal process was determined. The calorific value and composition of the pyrolytic gas were measured, revealing that 70% of the gas involves compounds characterized by a high calorific value. As a result, the calorific value of dry, purified gas equals 35.07 MJ/kg. A life cycle assessment has been conducted, in order to determine if the produced gaseous fuel matches sustainable development criteria. MONG-based gas is a sustainable replacement of, e.g., natural gas, lignite, or hard coal; however, it allows us to avoid 233–416 kg/h CO2 emissions per 1 MWt of heat.

Driving towards sustainability: A review of natural fiber reinforced polymer composites for eco-friendly automotive light-weighting

The automotive industry stands at a critical juncture, compelled by the imperative of sustainability to seek innovative materials for eco-friendly light-weighting. Natural fiber reinforced polymer composites (NFRPCs) have gained popularity due to their environmentally friendly nature and excellent engineering capabilities. This review paper comprehensively examines the landscape of NFRPCs in the context of automotive applications. Beginning with an overview of the ecological urgency and regulatory framework driving sustainable automotive materials, the review navigates through key advancements in NFRPC technology. The paper delineates the diverse array of natural fibers employed as reinforcements, elucidating their intrinsic properties, sources, and processing considerations. Concurrently, an in-depth analysis of various polymer matrices showcases their compatibility with different fiber types, emphasizing the critical interplay between fiber and matrix for optimal composite performance. A pivotal facet of this review manuscript lies in the rigorous evaluation of NFRPC performance across an array of metrics, including mechanical, thermal, and environmental considerations. Studies examining the interfacial interactions between natural fibers and polymers, as well as enhancements through additives and treatments, are critically assessed. Environmental and economic considerations are paramount in the quest for sustainable automotive materials. While economic evaluations delve into the viability and cost-effectiveness of widespread adoption, life cycle assessments and environmental impact analyses are evaluated to estimate the ecological footprint of NFRPCs. The paper also surveys current trends and prospects, offering insights into forthcoming innovations and directions for research. Therefore, this review article consolidates a comprehensive body of knowledge on NFRPCs for eco-friendly automotive light-weighting. By synthesizing findings from diverse studies, it provides a holistic perspective on the potential, challenges, and future trajectory of NFRPCs in the automotive sector.

Influence of Sustainable Grout Material on the Moisture Damage of Semi-flexible Pavement

Semi-flexible pavement (SFP), also known as grouted pavement, is a type of pavement structure consisting of a porous asphalt skeleton with air voids between 25 and 35% injected with cementitious grout materials. The special skeleton of SFP provided enhanced durability and resilience, making it a promising option for the construction of road surfaces in high-traffic areas and severe conditions. The main aim of the current research is to investigate the rutting behavior and moisture resilience of SFP-containing sustainable grout using ceramic waste powder (CWP). This research introduced the use of CWP as a replacement for conventional grout (cement) in SFP for the first time. CWP partially replaced cement at ratios of 15, 20, 30, 40, and 50% of the cement weight. Indirect Tensile Strength (ITS) and Hamburg Wheel Tracking Tests (HWTT) were used to evaluate the performance of SFP to reduce the detrimental effect of moisture. The grout modified with CWP shows excellent results in the ITS and Tensile Strength Ratio (TSR), and all modified SFP mixtures give higher values in these tests compared with Control Mix (CM). In the HWTT, the minimum rut depth of the modified SFP was 2.8 mm and 3.10 mm. Compared to CM, rutting decreased by 73%–76% for CWP mixes with 20% and 30% replacement. This indicates the high fluidity of CWP, which enabled it to penetrate all voids in the porous pavement (PA) and form a dense microstructure due to its excellent pozzolanic interaction, making it a strong structure capable of bearing rutting.

Flexural Behavior of Cross-Laminated Timber Panels with Environmentally Friendly Timber Edge Connections

As a sustainable construction material, timber is more promoted than steel, concrete, and aluminum nowadays. The building industry benefits from using timber based on several perspectives, including decarbonization, improved energy efficiency, and easier recycling and disposal processes. The cross-laminated timber (CLT) panel is one of the widely utilized engineered wood products in construction for floors, which is an ideal alternative option for replacing reinforced concrete. One single CLT panel has an outstanding flexural behavior. However, CLT cannot be extended independently without external connections, which are normally made of steel. This article proposes two innovative adhesive-free edge connections made of timber, the double surface (DS) and half-lapped (HL) connections. These connections were designed to connect two CLT panels along their weak direction. Parametric studies consisting of twenty models were conducted on the proposed edge connections to investigate the effects of different factors and the flexural behavior of CLT panels with these edge connections under a four-point bending test. Numerical simulations of all the models were done in the current study by using ABAQUS 2022. Furthermore, the employed material properties and other relevant inputs (VUSDFLD subroutines, time steps, meshes, etc.) of the numerical models were validated through existing experiments. The results demonstrated that the maximum and minimum load capacities among the studied models were 6.23 kN and 0.35 kN, respectively. The load–displacement responses, strain, stress, and defection distributions were collected and analyzed, as well as their failure modes. It was revealed that the CLT panels’ load capacity was distinctly improved due to the increment of the connectors’ number (55.05%) and horizontal length (80.81%), which also reinforced the stability. Based on the findings, it was indicated that adhesive-free timber connections could be used for CLT panels in buildings and replace traditional construction materials, having profound potential for improving buildings’ sustainability and energy efficiency.

Experimental Analysis of Mechanical Tests on a Plate Composed of Banana Fibre

Due to their attractive characteristics, natural and synthetic fibre - reinforced hybrid composite materials are playing a prominent role in science. Innovators are now being drawn to the poor world to create new sustainable and environment products and materials focused on environmental objectives. Natural fibre has a number of advantageous qualities, including low density, non-toxicity, and minimal comparability in strengths, minimal waste disposal issues, and inexpensive cost. This study presents the experimental analysis of mechanical tests performed on a plate composed of banana fiber. The mechanical properties, including tensile strength, flexural strength, and compression strength, were evaluated to assess the performance and potential applications of the banana fibre plate. The experimental tests were conducted following standard testing procedures specified by ASTM. The results obtained provide valuable insights into the mechanical behavior of the banana fibre plate and contribute to the understanding of its suitability for various engineering applications.

A nano-imprinted graphene oxide-cellulose composite as a SERS active substrate.

Cellulose is a sustainable material capable of forming optically active nanoarrays on its surface. We created a composite of cellulose acetate (CA) and graphene oxide (GO), by mixing GO (0.1 mg mL-1) into CA. This was then imprinted with nanoscale surface features that form Bragg-like modes in resonance with the excitation laser when a thin layer of silver is vapor deposited onto the surface of the substrate. The addition of GO leads to improved surface-enhanced Raman scattering (SERS) signal strengths, obtaining an average SERS signal increase of 1.4-fold following the inclusion of GO. The combination of photonic and electromagnetic effects with charge transfer-based processes that support the SERS chemical mechanism and the possible presence of electromagnetic hot spots from the roughened surface results in an enhanced SERS signal strength when GO is added. This work shows the potential for nanoimprinted graphene oxide/cellulose acetate composites as flexible sensor platforms to detect target molecules.

Bio-based protic salts as precursors for sustainable free-standing film electrodes

Transforming amines with low boiling points and high volatilities into protic salts is a versatile strategy to utilize low molecular weight compounds as precursors for N-doped carbon structures in a straightforward carbonization procedure. Herein, conventional mineral acids commonly used for the synthesis of protic salts were replaced by bio-derived phytic acid, which, combined with various amines and amino acids, yielded partially or fully bio-derived protic salts. The biomass-based salts showed higher char-forming ability than their mineral acid-based analogs (up to 55.9% at 800°), simultaneously providing carbon materials with significant porosity (up to 1177 m2g−1) and a considerable level of N,P,O-doping. Here, we present the first comprehensive study on the correlation between the structure of the bio-derived protic precursors and the properties of derived carbon materials to guide future designs of biomass-derived precursors for the one-step synthesis of sustainable carbon materials. Additionally, we demonstrate how to improve the textural properties of the protic-salt-derived carbons (which suffer from high brittleness) by simply upgrading them into highly flexible nanocomposites using high-quality single-walled carbon nanotubes. Consequently, self-standing electrodes for the oxygen reduction reaction were created.

Characterization of holocellulose extracted from agricultural and food processing byproducts via ecofriendly delignification pulping process

AbstractThis study investigated an ecofriendly peracetic acid delignification process to extract holocellulose from various fiber rich plant‐based byproducts (coconut palm spathe/leaf, apple pulp, wine grape pomace, hazelnut shell, and hemp fiber/hurd), and evaluated their physicochemical, morphological, and thermophysical properties in comparison with commercial cellulose nanofibers produced from wood. Holocellulose from coconut palm spathe has long fiber (~846.7 μm), whereas that from wine grape pomace and hazelnut shell exhibits a cylinder shape of particles with short fiber length (~123.8 and ~ 71.1 μm, respectively). Biofilms cast from apple pulp and hemp fiber holocellulose have higher degradation temperature (361 and 358°C, respectively) than biofilms from other materials, thus more thermally stable. All biofilms demonstrate high UV absorbance, and the biofilm cast from apple pulp holocellulose is transparent with smooth surface. Fourier‐transform infrared spectroscopy analysis confirms the presence of cellulose and hemicellulose as the main components in the biofilms, along with traces of residual lignin that remained after the extraction process. This study demonstrates that holocellulose with varied cellulose morphology and polymeric characteristics could be extracted depending on the type of byproducts and be employed to produce sustainable packaging materials.

Extraction of cellulose from halophytic plants for the synthesis of a novel biocomposite.

Cellulose nanofibers, a sustainable and promising material with widespread applications, exhibit appreciable strength and excellent mechanical and physicochemical properties. The preparation of cellulosic nanofibers from food or agricultural residue is not sustainable. Therefore, this study was designed to use three halophytic plants (Cressa cretica, Phragmites karka, and Suaeda fruticosa) to extract cellulose for the subsequent conversion to cellulosic nanofibers composites. The other extracted biomass components including lignin, hemicellulose, and pectin were also utilized to obtain industrially valuable enzymes. The maximum pectinase (31.56 IU mL-1), xylanase (35.21 IU mL-1), and laccase (15.89 IU mL-1) were produced after the fermentation of extracted pectin, hemicellulose, and lignin from S. fruticosa, P. karka, and C. cretica, respectively. Cellulose was methylated (with a degree of substitution of 2.4) and subsequently converted into a composite using polyvinyl alcohol. Scanning electron microscopy and Fourier-transform infrared spectroscopy confirmed the successful synthesis of the composites. The composites made up of cellulose from C. cretica and S. fruticosa had a high tensile strength (21.5 and 15.2 MPa) and low biodegradability (47.58% and 44.56%, respectively) after dumping for 3 months in soil, as compared with the composite from P. karka (98.79% biodegradability and 4.9 MPa tensile strength). Moreover, all the composites exhibited antibacterial activity against gram-negative bacteria (Escherichia coli and Klebsiella pneumoniae) and gram-positive bacteria (Staphylococcus aureus). Hence, this study emphasizes the possibility for various industrial applications of biomass from halophytic plants.