Sustainable Dyeing Research Articles

Tuning the morphology and surface structure of MnOx@GF through Ce for high-efficiency degradation of Rhodamine B by electro-Fenton

Widespread and ineffective dye treatment in aquatic environment leads to serious pollution problems, threatening ecology and human health. Herein, manganese cerium bimetallic oxide cathode material (MnCeOx@GF) was prepared by hydrothermal method combined with calcination, and the electrochemical Fenton degradation performance of a typical dye Rhodamine B (Rh B) was investigated. The results show that the degradation of Rh B by MnCeOx@GF can reach 96.5 % within 2 h in acidic environment and continue to perform effectively after 4 repeated experiments. Combined with SEM and electrochemical test results, it can be seen that the bimetallic composite oxides formed by manganese and cerium on the surface of the support can effectively enhance the catalytic activity of the material, the addition of cerium changes the morphology of manganese oxides and promotes the generation of multiple valence composite oxides of transition metals, and improves the degradation of Rh B. Based on the free radical masking experiments, hydroxyl radical (·OH) is the main active substance in the electro-Fenton degradation process. This work not only provides a way to design and manufacture cathode materials for in situ electrosynthesis of H2O2, but also provides an important reference for improving the reusability of cathodes for sustainable dye wastewater treatment.

Self-Assembled Ultra-Long Hybrid Nanowire Formed by Simple Mixing: An Untapped Feature of Peroxydisulfate.

Peroxydisulfate (PDS), a popular molecule that is able to oxidize organic compounds, is garnering attention across various disciplines of chemistry, materials, pharmaceuticals, environmental remediation, and sustainability. Methylene blue (MB) is a model pollutant that can be readily oxidized by PDS-derived radicals. Unlike the conventional degradation process, here a reversible "dissolution-precipitation" phenomenon is discovered, triggered by a simple mixing of PDS and MB, revealing a novel application of PDS in fabricating self-assembled ultra-long nanowires with MB. This phenomenon is unique to PDS and MB, different from the traditional salting out or self-aggregation of dyes. Formation of nanowires facilitated by electrostatic interaction between S+ and O- moieties and π-π stacking is reversible, controlled by temperature and the solvent polarity. MB1-PDS-MB2 configuration (MB: PDS = 2:1) is theoretically predicted by density functional theory (DFT) calculations and further validated by stoichiometric ratios of carbon, sulfur, and nitrogen in the obtained precipitates (MBO). This untapped feature of PDS enables the development of colorimetric quantitative detection of PDS and sustainable dye recycling. Far more than those demonstrated cases, the potentialities of MBO as a nanomaterial merit further exploration.

Investigation on novel chitin and chitosan from dung beetle Heteronitis castelnaui (Harold, 1865) and its potential application for organic dyes removal from aqueous solution

Chitosan, a natural polysaccharide, has attracted considerable attention as an environmentally friendly and highly efficient adsorbent for dye removal. It is usually produced by deacetylation or partial deacetylation of chitin. However, conventional sources of chitin and chitosan are limited, prompting the need for alternative sources with improved adsorption capabilities. Herein, this study focuses on exploring a novel chitin and chitosan source derived from the dung beetle and evaluates its potential for organic dye removal from aqueous solutions. The research involves the extraction and characterization of chitin and chitosan from dung beetle Heteronitis castelnaui (Harold, 1865) using various analytical techniques, including SEM, FT-IR, TGA, XRD, NMR, deacetylation degree and elemental analysis. The chitosan obtained was used for the formation of hydrogels with sodium alginate via cross-linking with calcium chloride. And then the prepared hydrogels were evaluated for its adsorption capacity through batch adsorption experiments using methylene blue as a model pollutant. The adsorption capacity for methylene blue was 1294.3 mg/g at room temperature with solution pH = 12, MB concentration of 1800 mg/L. Furthermore, the kinetics of the adsorption process were analyzed using pseudo-first-order and pseudo-second-order models to understand the rate of adsorption. The maximum adsorption capacities were determined using Langmuir and Freundlich isotherm models. This study provides valuable insights for the development of sustainable dye adsorption technologies, specifically investigating a novel chitosan source derived from the dung beetle.

Eco-friendly Sustainable Dyeing of Tencel Textiles with Plant-Based Bio-Mordant Using Dewberry Fruit Extract as a Source of Natural Dye

Eco-friendly Sustainable Dyeing of Tencel Textiles with Plant-Based Bio-Mordant Using Dewberry Fruit Extract as a Source of Natural Dye

Efficient adsorption of acid orange 7 from wastewater using novel bio-natural granular bentonite-sawdust-corncob (GBSC): Mixture optimization, adsorption kinetic and regeneration

The removal of dyes from industrial wastewater is one of the most environmental challenges that should be addressed through sustainable technologies. In this study, a novel green and cost-effective granular from bentonite and bio-wastes of sawdust and corncob (GBSC) was prepared for sustainable treatment of acid orange 7 (AO7) dye wastewater. The d-optimal mixture method was employed to determine the optimum combination of the GBSC in terms of dye adsorption and structure stability. Characterizations of the GBSC were investigated using SEM, XRD, FTIR and BET analyses and compared with bentonite powder (BP), modified bentonite powder (MBP), and granular modified bentonite (GMB). According to the results, a mixture of bentonite 60 wt%, sawdust 20 wt% and corncob 20 wt% at 550 °C yielded the optimal combination of the GBSC which resulted to the highest adsorption capacity 135.22 mg/g, the lowest mass loss 3.1% and maximum crushing strength 12.275 N. The kinetic and isotherm of the adsorption data were fitted well by the pseudo-second-order model and Langmuir isotherm. Our finding suggested a green circular economy model by utilizing agriculture wastes (sawdust and corncob) to synthesize GBSC for sustainable dye wastewater treatment, which offers a cost-effective adsorbent (0.907 $/g) with high regeneration (4 times reusability with 40.5% removal rate) to keep them in circulation for as long as possible.

Reactive Dye Wash-Off Processing of Cotton Fabrics Using Polymer Dye Transfer Inhibitors for Sustainable Dyeing

Reactive Dye Wash-Off Processing of Cotton Fabrics Using Polymer Dye Transfer Inhibitors for Sustainable Dyeing

Using gardenia pigment for ultrasonic natural dyeing of hemp fiber: A step towards sustainable dyeing

In recent years, with the country advocating the establishment of a resource-saving and environmentally friendly society, people have been pursuing a green and healthy quality of life. The non-toxic, harmless, and biodegradable characteristics of grass and wood dyeing have brought this method back to people's lives. Despite the presence of antibacterial substances such as tetrahydrocannabinol in cannabis fibers, they are still susceptible to microbial attacks. In recent years, scholars have conducted more research on the separation and purification of gardenia flower pigments, but there has been less analysis on the dyeing fibers and performance testing of gardenia flowers. The renewable characteristics, fewer side effects, and low cost increase the use of natural drugs as antibacterial agents in plant extracts or their active ingredients. This experiment used gardenia flowers as the raw material for dyeing experiments, and the dyeing percentage was used as the inspection index. Ultrasonic dyeing was carried out on hemp fibers after degumming treatment. It also aims to endow these dyed fabrics with natural antibacterial properties. During the sorting process, a liquid bath ratio of 1:20 was selected and experiments were conducted under different parameter variations. During the dyeing process, potassium aluminum sulfate (alum) is used as a mordant, and ultrasound is used as an auxiliary dyeing method. After dyeing, evaluate the fibers based on the percentage of exhaustion of obtained fiber and antibacterial activity against Staphylococcus aureus and Escherichia coli. At the same time, the FT-IR analysis, strength, and color fastness of the sorted samples were also checked. Single factor experiments were conducted by controlling the ultrasonic frequency, dyeing temperature, time, and mordant concentration to analyze the effect of gardenia pigment on the dyeing percentage. Response surface design experiments were used to optimize the dyeing process parameters. The research results indicate that the optimal process conditions for dyeing gardenia flowers are ultrasonic power of 85 %, dyeing temperature of 77 ℃, dyeing time of 60 min, and mordant concentration of 15 g/L. The main and secondary order of factors affecting the dyeing effect of hemp fibers is: mordant concentration>ultrasonic power>dyeing temperature. After optimal dyeing process, the hemp fiber shows a bright yellow color with a dyeing percentage of 57.32 %. The single fiber strength is not affected, and the color fastness to water washing and sun exposure meets the requirements for consumption. The infrared spectrum shows good dyeing effect. It has a certain antibacterial effect on Staphylococcus aureus, but the antibacterial effect on Escherichia coli is not significant. Due to these processes, it has been determined that hemp fiber can obtain antibacterial activity through the use of gardenia flowers and can be effectively colored.

Cellulose-Based Aerogels for Sustainable Dye Removal: Advances and Prospects

Cellulose-Based Aerogels for Sustainable Dye Removal: Advances and Prospects

Dyeing of Cotton Woven Fabric Using Sustainable Natural Dye (Date Leaves) and Bio-Mordants

This study on natural dyes has been chosen for a sustainable dyeing method on textile through the using of 99% cotton 1% spandex woven fabric. The dye was produced from the Date Palm Leaf (Phoenix dactylifera L) using Soxhlet machine through continuous extraction method and dyed using natural bio-mordant eucalyptus, guava leaf. Fourier transform infrared spectroscopy (FTIR) test was carried for nanoparticle characterization along with color measurements with specular and UV include mode. The dyed fabrics were also assessed for wash fastness, fastness against perspiration, dry rubbing and wet rubbing property. In most of the cases the fastness property of sample without mordant is better than with mordant. Cotton fabric is used for dyeing to make it sustainable and to reduce the dependency on synthetic dyes; the natural material can also reduce the pressure on synthetic material.

Stabilized surface charge by optimizing the carbonization temperature of bamboo for sustainable dye degradation at varying pH

Stabilized surface charge by optimizing the carbonization temperature of bamboo for sustainable dye degradation at varying pH

A comprehensive analysis and exploration of the recent developments in the utilization of genetically modified microorganisms for the remediation of hazardous dye pollutants

Innovative and effective remediation techniques are required with regard to growing environmental concerns on hazardous dye pollutants emitted by the textile industries. The review explores on the recent developments in utilization of genetically modified organisms (GMO) for the dye removal. Through improved capacities and specificities towards dye pollutants, genetically modified organisms present a potential strategy towards achieving Sustainable Development Goal (SDG) No. 6 of the UN, focused on clean water and sanitation. The key findings show that genetic engineering methods, including recombinant DNA (rDNA) and CRISPR-Cas9 technologies, can increase the capacity of bacteria to degrade, metabolize, or immobilize dye pollutants, improving degradation efficiency from around 7%–65%. The enzymatic processes are identified as the primary mechanisms involved in dye compound degradation by genetically engineered microbes. The review emphasizes the use of genetic approaches for dye degradation, co-cultivation with native microbial communities, optimizing operational parameters like pH, temperature, and nutrient availability, and omics technologies for a deeper understanding of metabolic networks and regulatory mechanisms with the aim of leading future genetic advancements in dye remediation. The review discusses the practical feasibility and environmental safety challenges of using genetically engineered microbes in sustainable dye remediation, highlighting limitations and future insights.

Three-step kinetic model for fisetin dye diffusion into fibroin fibre

BackgroundThe study’s relevance is determined by the current desire to reduce the negative environmental impact of the textile industry. The study aims to develop and optimise dyeing processes using natural dyes in the textile industry.ResultsThe process of dye transfer from solution to Bombyx mori natural silk fibre can be divided into three successive kinetic stages. The first stage involves the adsorption of dye molecules on the active surface of the fibre, the second, their diffusion deep into the fibre towards its centre, and the third, the uniform distribution of dye molecules along the fibre starting from its centre. It is noticed that diffusion at the third stage slows down significantly, and the third stage lasts much longer than the first and second stages. The analysis of experimental data on dye concentration over time on dyed materials and their comparison with hypothetical data will make it possible to establish time intervals for each stage of the process and diffusion coefficients for each of them.ConclusionThis study has practical implications as it may contribute to more efficient and sustainable dyeing of textile materials using natural dyes, helping to reduce the negative environmental impact of the textile industry, and contributing to our knowledge of diffusion and dyeing processes.

Role of surfactants in the degradation and sustainable dyeing for reactive dyeing wastewater

To enhance the decolorization rate of thermally activated sodium persulfate in dye wastewater, C.I. Reactive Black 5 (RB5) was investigated in this study, which was evaluated by the decolorization of the dye solution. The effect of surfactant concentration (including anionic surfactant sodium dodecyl sulfate (SDS), nonionic surfactant Tween 80 (TW-80) and amphoteric surfactant (BS-12)), SPS concentration, and reaction temperature on the degradation of RB5 was studied. Furthermore, the relationship between free radicals and RB5 degradation was investigated. The results showed that the addition of SDS and TW-80 would inhibit the decolorization of RB5. Correspondingly, the effect would enlarge as the surfactant concentration increased. Nevertheless, the addition of BS-12 wouldn’t affect the final decolorization of RB5 dye solution, despite it could increase the decolorization rate in the initial stage. After 10 min of decolorization, compared to the dye liquor without BS-12, the decolorization could increase by 9.07 % and 0.69 %, respectively, after adding 0.5 and 1.0 CMC of BS-12. Besides, when reactive dyes were degraded by thermally activated sodium persulfate, the SO4-· and ·OH would work together, and SO4-· played a major role while ·OH played an auxiliary part. When the treated wastewater was used for dyeing, the addition of BS-12 could effectively regulate the dyeing rate. The fixation and K/S value were increased by 1.1 % and 0.20, respectively. Furthermore, the dyed fabrics also exhibited improved uniformity, with negligible differences in color fastness. The effects of adding SDS were similar to BS-12, while it decreased the exhaustion and fixation rate of RB5. In addition, non-ionic TW-80 was unfavorable to dyeing. This work provides a new way for efficient treatment of dyeing wastewater as well as reuse, opening an environmentally friendly treatment concept.

Removal of malachite green from an aqueous environment using chitosan-xanthan gum coagulation system: A response surface methodology approach

Natural coagulants provide a safe and sustainable alternative for water treatment. Our study used shrimp shell-derived chitosan combined with xanthan gum to remove malachite green dye from water. Using a Box-Behnken design, we optimized parameters, achieving up to 99.7 % dye removal under optimal conditions: chitosan (1.75 mg/L), xanthan gum (1.73 %–3.0 %), dye (5–27.5 mg/L), pH 6.0, stirring period (5–7.5 min), and stirring rate (105 rpm). Key factors affecting sedimentation included xanthan gum dosage and its interactions with pH and stirring rate. SEM and FT-IR analyses characterized dye-polymer interactions. Pilot-scale tests on aquaculture wastewater showed significant turbidity reduction and enhanced dye removal in 15 L volumes. Toxicity assessments post remediation was performed on Artemia salina as a model organism and hatching efficiency and survival were essential parameters studied. Our findings highlight the potential for sustainable dye recovery and reuse in wastewater treatment.

Multifunctional bacterial cellulose-bentonite@polyethylenimine composite membranes for enhanced water treatment: Sustainable dyes and metal ions adsorption and antibacterial properties

Developing multifunctional materials for water treatment remains a significant challenge. Bacterial cellulose (BC) holds immense potential as an adsorbent with high pollutant-binding capacity, hydrophilicity, and biosafety. In this study, N-acetylglucosamine was used as a carbon source to ferment BC, incorporating amide bonds in situ. Bentonite, renowned for its adsorption properties, was added to the culture medium, resulting in BC-bentonite composite membranes via a one-step fermentation process. Polyethyleneimine (PEI) was crosslinked with amide bonds on the membrane via glutaraldehyde through Schiff base reactions to enhance the performance of the composite membrane. The obtained membrane exhibited increased hydrophilicity, enhanced active adsorption sites, and enlarged specific surface area. It not only physically adsorbed contaminants through its unique structure but also effectively captured dye molecules (Congo red, Methylene blue, Malachite green) via electrostatic interactions. Additionally, it formed stable complexes with metal ions (Cd²⁺, Pb²⁺, Cu²⁺) through coordination and effectively adsorbed their mixtures. Moreover, the composite membrane demonstrated the broad-spectrum antibacterial activity, effectively inhibiting the growth of tested bacteria. This study introduces an innovative method for fabricating composite membranes as adsorbents for complex water pollutants, showing significant potential for long-term wastewater treatment of organic dyes, heavy metal ions, and pathogens.

Traditional Fish Leather Dyeing Methods with Indigenous Arctic Plants

Along the Arctic and sub-Arctic coasts of Alaska, Siberia, north-eastern China, Hokkaido, Scandinavia and Iceland, people have dressed in clothes or worn shoes made of fish skin for millennia. (Within this article, the terms fish skin and fish leather are used to indicate different processes of the same material. Fish skin: Skin indicates the superficial dermis of an animal. Fish skin is referred to as the historical raw material that is tanned following traditional methods such as mechanical, oiling and smoking tanning, using materials such as bark, brain, urine, fish eggs and corn flour. Fish leather is used to refer that the fish skin has passed one or more stages of industrial vegetable or chrome tanning production and is ready to be used to produce leather goods). These items are often decorated with a rich colour palette of natural dyes provided by nature. In this study, minerals and raw materials of plant origin were collected from riverbanks and processed by Arctic seamstresses who operated as designers, biochemists, zoologists, and climatologists simultaneously. During our research, an international team of fashion, tanning and education specialists used local Arctic and sub-Arctic flora from Sweden, Iceland, and Japan to dye fish leather. Several plants were gathered and sampled on a small scale to test the process and determine the colours they generated based on the historical literature and verbal advice from local experts. This paper describes the process and illustrates the historical use of natural dyes by the Arctic groups originally involved in this craft, building on the traditional cultural heritage that has enabled us to develop sustainable dyeing processes. The results are promising and confirm the applicability of these local plants for dyeing fish skins, providing a basis for a range of natural dye colours from local Arctic flora. The aim is to develop a moderate-sized industrial production of fish leather in this colour palette to replace current unsustainable chemical dyeing processes. This project represents an innovation in material design driven by traditional technologies, addressing changes in interactions between humans and with our environment. The results indicate that new materials, processes, and techniques are often the fruitful marriage of fashion and historical research of traditional methods, helping the industry move towards a more sustainable future.

An Environmentally Sustainable Dyeing Approach for the Production of Ecofriendly Colored Wool Yarns via the Application of Millettia laurentii Natural Dye in Conjunction with Metal Salts and Biomordants

An Environmentally Sustainable Dyeing Approach for the Production of Ecofriendly Colored Wool Yarns via the Application of Millettia laurentii Natural Dye in Conjunction with Metal Salts and Biomordants

Modeling and optimization of dyeing process of polyamide 6 and woolen fabrics with plum-tree leaves using artificial intelligence

The dyeing process of textile materials is inherently intricate, influenced by a myriad of factors, including dye concentration, dyeing time, pH level, temperature, type of dye, fiber composition, mechanical agitation, salt concentration, mordants, fixatives, water quality, dyeing method, and pre-treatment processes. The intricacy of achieving optimal settings during dyeing poses a significant challenge. In response, this study introduces a novel algorithmic approach that integrates response surface methodology (RSM), artificial neural network (ANN), and genetic algorithm (GA) techniques for the precise fine-tuning of concentration, time, pH, and temperature. The primary focus is on quantifying color strength, represented as K/S, as the response variable in the dyeing process of polyamide 6 and woolen fabric, utilizing plum-tree leaves as a sustainable dye source. Results indicate that ANN (R2 ~ 1) performs much better than RSM (R2 > 0.92). The optimization results, employing ANN-GA integration, indicate that a concentration of 100 wt.%, time of 86.06 min, pH level of 8.28, and a temperature of 100 °C yield a K/S value of 10.21 for polyamide 6 fabric. Similarly, a concentration of 55.85 wt.%, time of 120 min, pH level of 5, and temperature of 100 °C yield a K/S value of 7.65 for woolen fabric. This proposed methodology not only paves the way for sustainable textile dyeing but also facilitates the optimization of diverse dyeing processes for textile materials.

Dyeability and hydrolytic degradation of polylactic acid fibers under different environments

Polylactic acid (PLA), a biodegradable material derived from industrial crops such as corn and straw, is increasingly recognized in various sectors, including textiles, food, and medicine. However, the dyeability and biodegradability of PLA a key factor contributing to its growing popularity. Herein, we report a sustainable dyeing method for the coloration of PLA fibers with excellent fastness using dispersed dyes. The results showed that the dyed PLA fabric exhibited a K/S value of 8.4, along with impressive grade 4 fastness to both dry and wet rubbing. Additionally, the dyed PLA fabric exhibited increased hydrophilicity and enhanced surface roughness. Most importantly, during the hydrolytic degradation experiment, the dyed polylactic acid fabric experienced a notable 36 % decrease in quality when exposed to a water environment characterized by a pH of 11, a temperature of 40 °C, and a duration of 60 days, whereas the control PLA fabric is only 8 %. The hydrolytic degradation of PLA occurs at its fastest rate when the color of the dye is at its optimal intensity, the environmental temperature is elevated, and the pH level is in an alkaline state. The degradation rate of PLA fabric initially tends to be rapid, followed by a gradual slowdown. This research may provide a useful guideline for the proper storage of dyed PLA fabrics and their use in the textile industry.

Dyeing of Jamdani Saree by Sustainable Dye

Jamdani saree is one of the most important national heritage of Bangladesh. Its weaving technique is one of thefirst inheritances of Bangladesh. From the very beginning of jamdani saree weaving cotton yarn was used as the raw material. The weavers had unique skills to weave the saree. Different natural dyes were used to produce jamdani saree along with finely spun 100% cotton yarn. At present the tradition of using natural dyesand100%cotton yarn has become an option for the weavers and the jamdanitraders for economic and weaving comfort. In this study a jamdani saree was produced with sustainable vegetable dye and 100% cotton yarn 80Ne. It was observed that the weaving lead time and other properties like colorfastness was acceptable compared to the jamdani sarees that are made with synthetic dyes and filament yarn based saree.