Declining urban air quality affects socioeconomic stability, public health, and ecosystems and is demanding attention of the administration to address environmental sustainability goals. Given the effects of ozone, a greenhouse gas, on local climate and health, this study introduces a Unified Spectro-Spatial Graph Neural Network (USS-GNN) designed for simultaneous 24-hour forecasting of ozone and its precursor, nitrogen-dioxide, while addressing their chemical interactions and spatiotemporal dynamics. This model exploits the graph structure of atmospheric dynamics and mines high-level spatial, spectral, and physical features from atmospheric data through a Dot Product Edge Attention mechanism and a location-aware graph feature rewiring technique. The proposed model is developed for Indian capital city New Delhi, utilizes hourly observations for the years 2021 and 2022 and achieved R2 values of 0.650 and 0.618, RMSE of 13.950 and 16.120 μg/m3, MAE of 10.730 and 12.930 μg/m3 for ozone and nitrogen-dioxide respectively, outperforming state-of-the-art models. The model’s forecast analysis identified error-prone areas, effects of local meteorology, and pollutant interdependencies. An ablation study further detailed the impacts of graph operations on forecasts. Moreover, this study promotes the utility of bivariate modeling frameworks in improving urban pollution monitoring and supporting sustainable city management through data-driven policy implementations.
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