Surface Water In Beijing Research Articles

Micropollutants but high risks: Human multiple stressors increase risks of freshwater ecosystems at the megacity-scale

Micropollutants in water environments have attracted widespread attention, but how human and natural stressors influence the risks of micropollutants has not been comprehensively revealed. A megacity-scale study of the ecological risks of micropollutants in the surface water of Beijing, China is presented to illustrate the magnitudes of the influences of multiple anthropogenic and natural stressors. A total of 133 micropollutants representing typical land use patterns in Beijing, were quantified with the mean concentration range of ND (not detected) to 272 ng·L−1. The micropollutant concentrations in the south were obviously higher than those detected in the northern areas, and neonicotinoid pesticides showed the highest mean concentration of 311 ng·L−1. The chronic and acute risks of micropollutants to algae, invertebrates, and fishes were determined, and herbicides, organophosphorus esters, and insecticides account for the primary risks to algae, invertebrates, and fishes, respectively. The cropland and impervious cover cause the differences in the pollution and risks of micropollutants. The land use in riparian zones greater than 2 km shows a great influence on the chronic chemical risks (CCRs) for the three groups of species, indicating that too local scale does not explain the local pollution status. Climate conditions and human land use are important drivers explaining the CCRs to which various trophic levels of species are exposed. Results demonstrate that multiple categories of micropollutants pose adverse risks to freshwater in the megacity of Beijing, while climate conditions, pollution discharge, and human land use induce the chemical risk of micropollutants to aquatic organisms, and the land use in different riparian zones show different effects on the risks.

Less pressure contributes to gravity-driven membrane ultrafiltration with greater performance: Enhanced driving efficiency and reduced disinfection by-products formation potential

Gravity-driven membrane (GDM) systems have been well developed previously; however, impacts of driving (i.e., transmembrane) pressure on their performance received little attention, which may influence GDM performance. In this study, we evaluated 4 GDM systems via altering the transmembrane pressure from 50 mbar to 150 mbar with 2 groups, treating surface water in Beijing, China. Results showed that less driving pressure was more favorable. Specifically, compared to groups (150 mbar), groups under a pressure of 50 mbar were found to have greater normalized permeability and lower total resistance. During the whole operation period, the quality of effluents was gradually improved. For example, the removal efficiency of UV254 was significantly improved; particularly, under low driving pressure, the removal efficiency of UV254 in PES GDM system increased by 11.91%, as compared to the corresponding system under high driving pressure. This observation was consistent with the reduction on disinfection by-products (DBPs) formation potential; groups under 50 mbar achieved better DBPs potential control, indicating the advantages of lower driving pressure. Biofilms were analyzed and responsible for these differences, and distinct distributions of bacteria communities of two GDM systems under 50 and 150 mbar may be responsible for various humic-like substances removal efficiency. Overall, GDM systems under less pressure should be considered and expected to provide suggestions on the design of GDM systems in real applications.

Characteristics of pharmaceutically active compounds in surface water in Beijing, China: Occurrence, spatial distribution and biennial variation from 2013 to 2017

Pharmaceutically active compounds (PhACs) are widely found in the environment due to vast human consumption. Lots of work has been devoted to investigating the occurrence and seasonal variations globally. To fully understand characteristics and cross-year variation of PhACs in Beijing, 35 PhACs were analyzed in 46 sites across Beijing from both urban and suburban areas. Concentrations of target PhACs were ranged from levels of ng L−1 to μg L−1. Metoprolol (524 ng L−1), caffeine (390 ng L−1) and acetaminophen (156 ng L−1) were the three most abundant non-antibiotics with the highest median concentration, and nalidixic acid (135 ng L−1), erythromycin (64 ng L−1) and sulfamethoxazole (77 ng L−1) were the most abundant antibiotics. Urban and suburban areas are distinguished by PhAC composition in cluster analysis due to different wastewater collection rate. The ratio of easily removable compound group and hardly removable group was then proposed to reflect the wastewater collection rate. The compositional comparison of PhACs in WWTPs’ effluents and their receiving rivers further illustrates the impact of WWTPs in urban area. Higher proportion of antibiotics (>30%) in suburban area reflected the impact of presence of livestock farms, which should be concerned. Further statistical analyses show an improving trend of wastewater collection rate, and excluding metoprolol, an anti-hypertension medicine, the total concentration of 13 target PhACs was reduced by 72% during 2013–2017.

Widespread monitoring of chiral pharmaceuticals in urban rivers reveals stereospecific occurrence and transformation

The present work aimed to discuss the enantiomeric occurrence of chiral pharmaceuticals including 5 parent compounds (PCs) metoprolol, propranolol, atenolol, venlafaxine and fluoxetine as well as 6 of their transformation products (TPs) in surface water in Beijing. Among which, 9 out of 11 were detected during the two sampling campaigns with N-O-Didesmethylvenlafaxine (NODDV) and α-hydroxymetoprolol confirmed in the catchment for the first time. Metoprolol acid (MTPA) was the most abundant up to 1508 ng L−1, followed by metoprolol and O-desmethylvenlafaxine (ODV). Most compounds showed 100% detection frequency or nearly, while norfluoxetine (the main metabolite of fluoxetine) and 4-hydroxypropranololone (one TP of propranolol) were not detected. Metoprolol (MTP) and venlafaxine (VFX) did not vary significantly between two sampling periods with mean concentrations of 280.7 and 22.9 ng L−1, respectively. Enantiomeric enrichment was observed for venlafaxine, metoprolol and NODDV, where R-venlafaxine was preferentially biotransformed than the S-form through O-desmethylation. Risk assessment indicated that fluoxetine and atenolol could pose harmful effects to aquatic organisms. This work provides enantiospecific profiles of pharmaceutically active compounds (PhACs), and extended the concept of applying the ratio of TPs vs. parent compound plus their enantiomeric traits for quantitative assessment of in situ biodegradation. Due to the considerable contribution by TPs (64% in present study) as well as the unexpected impacts from enantiomeric existence, the stereoselectivity of chiral pollutants during environmental process should be taken into account in future study. To the best of the authors’ knowledge, it is the first comprehensive evaluation of chiral pharmaceuticals and transformation products at enantiomeric level in aquatic environment in China, which would facilitate better understanding of their environmental fate.

Efficient multiresidue determination method for 168 pharmaceuticals and metabolites: Optimization and application to raw wastewater, wastewater effluent, and surface water in Beijing, China

New analytical methods are needed to efficiently measure the growing list of priority pharmaceuticals in environmental samples. In this regard, a rapid, sensitive, and robust method was developed for quantitation of 168 pharmaceuticals and pharmaceutical metabolites using solid-phase extraction (SPE) and liquid chromatography with tandem mass spectrometry. The extraction protocol and instrumental efficiency were specifically addressed to increase analytical workload and throughput. The optimized protocols, which are five times more efficient than US EPA Method 1694, enabled analyte recoveries that ranged from 77% to 117% for 162 analytes with method quantitation limits (MQLs) as low as 0.1 ng L−1. To verify the suitability of the improved analytical method for environmental samples, 24-h composite samples of raw wastewater and wastewater effluent, along with downstream surface water, were analyzed. Overall, 143/168 target compounds were identified in at least one of the samples, and 130/168 analytes were present at concentrations above their MQLs. The total mass concentration of the measured analytes decreased by 93% during wastewater treatment. The analyte concentrations in the wastewater effluent were comparable to those measured in surface water 1 km downstream of the wastewater discharge point. Ultimately, the comprehensive method will serve as an important tool to inform the occurrence, fate, transport, and toxicity of a large suite of priority pharmaceuticals and pharmaceutical metabolites in natural and engineered systems.

Spatial distribution, seasonal variation and risks of legacy and emerging per- and polyfluoroalkyl substances in urban surface water in Beijing, China

In the current study, we investigated the occurrence, spatial distribution and seasonal variation of per- and polyfluoroalkyl substances (PFASs), including one group of emerging PFASs, the chlorinated polyfluoroalkyl ether sulfonic acids (Cl-PFESAs), in urban surface water (river and lake) samples from October 2013 to September 2014 (except during the frozen period) in Beijing, China. Perfluorobutanoic acid (PFBA) and perfluoropentanoic acid (PFPeA) were the dominant compounds, with average concentrations of 12.79 and 9.90 ng/L, respectively. For Cl-PFESAs, only C8 Cl-PFESA could be detected, and its concentration ranged from <MLQ to 6.93 ng/L. Higher concentrations of ∑PFASs were observed in the northern and eastern regions of Beijing. The highest and lowest levels of ∑PFASs were found in summer and winter, respectively. For C8 Cl-PFESA, there were no significant differences in the concentrations among different sampling sites. Additionally, risk assessments indicated that the studied PFASs at present levels might pose a low risk to aquatic organisms (green algae, Daphnia sp. and fish). However, further studies should be conducted on the combined risk from PFASs or the risk to other sensitive species in aquatic environments.

Simultaneous enantiomeric analysis of non-steroidal anti-inflammatory drugs in environment by chiral LC-MS/MS: A pilot study in Beijing, China

A simple, sensitive and quick method for direct simultaneous chiral analysis of frequently used non-steroidal anti-inflammatory drugs (NSAIDs) (ibuprofen, naproxen and flurbiprofen) in river water by HPLC-MS/MS was established and validated. Chromatographic parameters including the mobile phase composition, pH values, temperature and flow rates were optimized to obtain both satisfactory sensitivity and enantiomeric resolution (Rs≥ 1.0), which suggested the composition and pH values of mobile phase played crucial influence on enantioseparations. The method demonstrated its superiority compared with previous studies regarding to the low MQLs (1.1–37.1 ng/L) and short runtime (< 20 min), enabling quantitative enantiomeric determination of trace level of emerging contaminants in water. The environmental monitoring of receiving water (34 sites along rivers) in Beijing revealed ibuprofen was the most abundant, with mean concentration of 114.9 ng/L and detection frequency of 91%, naproxen was also detectable at all sites from < MQL-43.2 ng/L, both presenting an excess of the S-(+)-enantiomer. Therefore to better understand the ecological risk posed from the trace organic contaminants on the aquatic organisms, chiral pollutants need analyzed at the enantiomeric levels. This is the first to profile the enantiospecific occurrence of NSAIDs in surface water in Beijing, China. It could provide useful information on environmental behaviors of chiral pollutants and facilitate more accurate environmental risk assessment.

Characterization of pharmaceutically active compounds in Beijing, China: Occurrence pattern, spatiotemporal distribution and its environmental implication

Pharmaceutically active compounds (PhACs) as an important group of “emerging contaminants” (ECs), have been highlighted and received global attentions in last decade. China has tremendous consumption of PhACs and the most pharmaceutical manufacturers worldwide. In this study, 33 PhACs (19 antibiotics included) were monitored in the Beiyun River basin in Beijing, China. The seasonal occurrence, temporal-spatial distribution and potential source were investigated. The total levels were about 2μgL−1. Non-antibiotics were more frequently detected. The highest median concentrations were observed for caffeine (558ngL−1) and erythromycin (319ngL−1). Acetaminophen, erythromycin, diclofenac and N,N-diethyl-meta-toluamide showed highly significant seasonal variation, while caffeine, carbamazepine, metoprolol and most sulfonamides were more stable. The burden was most heavy in Qing River in both seasons (up to 4μgL−1). Antibiotics from veterinary use accounted for minor contribution in this region. The characteristics and trends were overviewed by comparing with our previous survey. The total level of 15 PhACs dropped significantly by 37% on average from 2013 to 2015. The proportion of caffeine, once a major component in 2013, reduced from 77% to 47%. The burden of these ECs in surface water of Beijing is remarkably reduced, suggesting the overall situation has been improving.

Occurrence, distribution and seasonal variation of organophosphate flame retardants and plasticizers in urban surface water in Beijing, China

The occurrence, spatial distribution and seasonal variation of 14 organophosphate esters (OPEs) were investigated in urban surface water (river and lake water) from July 2013 to June 2014 in Beijing, China. Sewage influent and effluent samples, as well as rainwater and road runoff samples were also analyzed as the potential sources of OPEs in surface water. Tris(2-chloro-1-methylethyl) phosphate (TCPP) and tris(2-chloroethyl) phosphate (TCEP) were the most abundant OPEs with the average concentrations of 291 ng L−1 and 219 ng L−1, respectively. Relatively high concentrations of OPEs were detected in rivers located at southern and eastern urban of Beijing, which was probably attributed to the treated and untreated sewage discharge. Besides, higher levels of OPEs were observed in urban surface water in the summer, and the wet deposition (rainfall) was confirmed to be an important factor for this observation. Risk assessment showed low or medium risk of OPEs for the organisms (algae, crustacean and fish).

Spatial distribution, temporal variation and risks of parabens and their chlorinated derivatives in urban surface water in Beijing, China

The occurrence and distribution of 13 target compounds, including eight parabens, four chlorinated parabens and p-hydroxybenzoic acid (PHBA), were detected in surface water samples at 35 sampling sites in the Beijing River system, China. The surface water samples were collected from the main rivers and lakes in the urban area monthly from July 2013 to June 2014 (except the frozen period). Laboratory analyses revealed that parabens were ubiquitous in the surface water of Beijing. PHBA was the predominant compound in the surface water samples, with the average concentration of 239ngL−1, followed by the total amount of chlorinated parabens (average 50.1ng/L) and parabens (average 44.3ng/L). It is noteworthy that octylparaben with longer chain was firstly detected in the surface water. Significant difference was observed for paraben concentrations from different sampling sites, and the highest level of parabens was found in the Xiaotaihou River, which was mainly due to the untreated sewage discharge. Seasonal variation of target compounds in the urban surface water was also studied, and parabens exhibited a different temporal variation from chlorinated derivatives. A combination of factors including high residual chlorine level and water temperature as well as intense ultraviolet radiation might enhance the persistence of chlorinated parabens in chlorinated water during the wet season. Risk assessment showed that parabens and their chlorinated derivatives are not likely to produce biological effects on aquatic ecosystems at current levels in the surface water of Beijing.

Occurrence, distribution and risks of antibiotics in urban surface water in Beijing, China.

The occurrence and distribution of 22 antibiotics, including eight fluoroquinolones, nine sulfonamides and five macrolides, were investigated in the urban surface waters in Beijing, China. A total of 360 surface water samples were collected from the main rivers and lakes in the urban area of Beijing monthly from July 2013 to June 2014 (except the frozen period). Laboratory analyses revealed that antibiotics were widely used and extensively distributed in the surface water of Beijing, and sulfonamides and fluoroquinolones were the predominant antibiotics with the average concentrations of 136 and 132 ng L(-1), respectively. A significant difference of antibiotic concentrations from different sampling sites was observed, and the southern and eastern regions of Beijing showed higher concentrations of antibiotics. Seasonal variation of the antibiotics in the urban surface water was also studied, and the highest level of antibiotics was found in November, which may be due to the low temperature and flow of the rivers during the period of cold weather. Risk assessment showed that several antibiotics might pose high ecological risks to aquatic organisms (algae and plants) in surface water, and more attention should be paid to the risk of antibiotics to the aquatic environment in Beijing.

Occurrence and source apportionment of pharmaceuticals and personal care products in the Beiyun River of Beijing, China

This work investigates, for the first time, the occurrence and sources of 15 pharmaceuticals and personal care products (PPCPs) in surface water of Beijing, one of most densely populated cities in the world, in three sampling events representing different seasonal flow conditions. The detection frequencies of most PPCPs were in the range of 50–100%. The median concentrations of the selected PPCPs ranged from not detected to 4200ngL−1 (caffeine). Generally, higher PPCP levels were observed in early spring, indicating both low flow condition and cold-water temperature might enhance their persistence. Source apportionment showed freshly discharged untreated sewage (67%) significantly contributed to the PPCP burden in the Beiyun River, which provides important information for environmental management.

Nitrogen pollution and source identification of urban ecosystem surface water in Beijing

Nitrogen contamination of surface water is a worldwide environmental problem with intensive agriculture and high population densities. We assessed the spatial and seasonal variation in concentrations of total nitrogen and different nitrogen species present in surface-water in Beijing, China. Also, chemical (NO 3 − −N=C1−) and isotopic (δ 15 N nitrate ) indicators were used to identify nitrate sources. The results showed that, during 2009 and 2010, nitrate nitrogen concentrations ranged from 0.7 to 7.6 mg ·L−1, ammonium nitrogen from 0.1 to 3.4 mg·L−1, and total nitrogen from 2.4 to 17.0 mg·L−1. Inorganic nitrogen accounted for between 60 and 100% of total nitrogen at the ten monitoring sites. Nitrate nitrogen, ammonium nitrogen, and total nitrogen concentrations at the 2 downstream monitoring sites in south-eastern Beijing were significantly higher than those at the other eight upstream monitoring sites (P<0.01). Examination of seasonal variation showed that there was a significant inverse relationship between nitrate nitrogen concentrations and precipitation, and that nitrate nitrogen concentrations peaked in the dry seasons. The information given by the δ 15 N nitrate values and nitrate nitrogen concentrations, combined with the NO 3 − -N=C1− ratio distribution, showed that domestic sewage was the major source of nitrate in Beijing. Methods to control and reduce sewage pollution are urgently needed to help manage surface water quality in Beijing.