Surface Suspended Particulate Matter Research Articles

Suspended particulate matter in the Gulf of Oman: Spatial variations in concentration, bulk composition, and particulate metals controlled by physical and biogeochemical processes

The present work aims to assess the biogeochemical and physical sources of variation in the spatial distribution of suspended particulate matter (SPM), its major biotic and abiotic components, particulate metals, and the Redfield (N:P) stoichiometry of particles in a poorly understood basin of the Gulf of Oman. Particulate samples were collected in February 2022 from the Gulf of Oman aboard the R/V Persian Gulf Explorer, revealing surface SPM concentrations ranging from 140 to 1145 μg/l. The elemental composition of crustal-type elements in the surface offshore region confirmed the input of lithogenic components by aeolian dust from the surrounding deserts. The highest mid-depth SPM levels, with remarkable contribution from CaCO3, were observed at the western shelf edge at 100–300 m depth, supported by the Persian Gulf outflow. Conversely, mid-depth maxima with elevated concentrations of terrigenous elements were observed in the eastern edge, emanating from sediment resuspension and lateral transport under eddy-topography interaction. Organic matter is the most important phase, followed by biogenic silica from the basin-wide winter bloom of diatoms. While signs of CaCO3 dissolution are evident at depths >500 m, the oxidative precipitation of Mn (II) in the upper boundary of the oxygen minimum zone leads to the appearance of perceptible maxima in the vertical profile of particulate MnO2. Seasonal variations in the organic N:P ratio, from summer to winter, at the western station were linked to shifts in phytoplankton assemblage structure, transitioning from cyanobacteria dominance in summer to chain-forming diatoms in winter. The particulate pool of biologically important trace metals was dominated by a non-crustal fraction with enrichment factor followed a descending order: Cd > Mo > Pb > Zn > Ni in surface offshore samples. Metal/P ratios comparison with some previous data from the open ocean SPM and lab cultures of phytoplankton reveals that the Zn/P ratio is significantly exceeded in cultured communities, whereas the Cd/P ratio reflected the consistent demand in the Gulf of Oman compared to reported lab culture requirements.

Suspended particulate matter dynamics at the interface between an estuary and its adjacent coastal sea: Unravelling the impact of tides, waves and river discharge from 2015 to 2022 in situ high-frequency observations

Suspended particulate matter (SPM) dynamics and exchange fluxes at the interface between a macrotidal estuary and its adjacent coastal sea were investigated from long-term high-frequency in situ observations. Optical and acoustic measurements were coupled to calculate SPM concentration over the whole water column using an existing acoustic inversion algorithm. A method was developed to distribute over the water column the surface and bottom calibrated equivalent particle diameters based on complementary ship-based surveys. Surface and bottom SPM show similar patterns in response to main forcings (tide, river discharge and waves), but present significantly higher concentrations near the bed. Increasing tidal ranges were responsible for higher tidal-median SPM concentrations, with spring/neap SPMC ratio varying from 2 to 3. This increase is driven by local resuspension during flood phase at the bottom, and low salinity turbid water flushed out from the estuary from mid-ebb to low tide at the surface. Increasing river discharge implies a downward shift of the estuarine turbidity maximum from the inner estuary to the mouth, and yields a 2-fold increase in both surface and bottom tidal-median concentration. Waves generated strong resuspension, with the highest SPM concentration recorded both at the surface and near the bed. Analysing SPM residual fluxes highlighted large up-estuary fluxes from low to moderate tidal ranges (below 6 m), and exporting seaward fluxes for higher tidal ranges, due to stronger mixing during spring tides. High river discharge enhanced stratification at the mouth and strengthened density circulation and up-estuary residual bottom circulation, resulting in larger up-estuary fluxes for all tidal ranges. Larger SPM concentrations along the tidal cycle during wave events yield high exporting fluxes.

Suspended particulate matter affects the distribution and migration of heavy metals in the Yellow River

Suspended particulate matter (SPM) is an important heavy metal transporter in water. As a well-known high-SPM river, its impact on the distribution and migration of heavy metals in the Yellow River (YR) deserves special attention. In this study, the spatial distributions of heavy metals in surface water and SPM of the YR were investigated. The results indicate that the concentrations (dissolved and particulate phases) and bioavailability (particulate phase) of most heavy metals were higher during the rainy season than during the dry season. A considerable proportion of heavy metals (>70 %) was transported by SPM and fine particles (clay) controlled the pollution status of heavy metals in the YR. This could lead to higher heavy metal concentrations in the SPM midstream and downstream during the rainy season and higher heavy metal concentrations in upstream during the dry season. Heavy metal adsorption experiments showed that specific combination methods (such as binding with carbonate) between Cd and SPM may cause SPM to act as a source of Cd midstream and downstream. This study provides a new perspective on the effects of SPM on heavy metal distribution and migration in the YR.

Hydrodynamically-driven distribution and remobilization of heavy metals in surface sediments around the coastal area of Shandong Peninsula, China.

Heavy metals (HMs) are considered a major pollutant of the surface sediments of the continental shelf. However, there remains little in-depth research on their fate in the ocean, and particularly on their abundance in sediments and the water column and the underlying drivers. This study examined the concentrations of HMs (Cu, Zn, Cr, Pb, Cd, and As) in surface sediments and suspended particulate matter (SPM) around the coastal area of Shandong Peninsula, China. The division of the sedimentary environment and influencing factors were also analyzed using multivariate statistical analysis Fuzzy c-means (FCM) cluster and Non-Linear Mapping (NLM). The study attempted to understand the distribution and remobilization of HMs in the shallow marginal sea using multi-disciplinary approaches, including satellite remote sensing and numerical simulation. The results showed higher HMs in the surface sediments in Weihai Bay (Zone I) than in the junction of the Chengshantou Cap (Zone III) and north of Wei Bay (Zone II). In addition, the results suggested that Cu, Zn, Cr and Pb originated from natural weathering, with their spatial distributions in the three zones highly regulated by sediment grain size, total nitrogen (TN), and total carbon (TC). In contrast, Cd and As originated from anthropogenic contamination (e.g., industrial discharges and aquaculture) in Zone I. HMs (except As) were influenced by terrigenous total organic carbon (TOC) in Zone III. The results of this study suggest that the difference in sediment re-suspension intensity has an important influence on the distribution of HM concentrations in the north Yellow Sea. This study can act as a reference for understanding the fates and source-sink processes of HMs in offshore sediments. The coupling behaviors and microscopic suspension properties of HMs in surface sediments and SPM require further investigation.

The River–Sea Interaction off the Amazon Estuary

The Amazon River has the highest discharge in the world. Nevertheless, there is still a lack of the research on the interaction between river-diluted water and the ocean. This study used the remote sensing data (2008–2017) of the Moderate Resolution Imaging Spectroradiometer (MODIS) aboard the Aqua satellite, and data of the currents, wind fields, sea surface temperature, and water depth. The river–sea interaction off the Amazon estuary was studied by analyzing the diffusion of river-diluted water and the distribution of surface suspended particulate matter (SPM). The results revealed that the Amazon estuary has a “filter effect,” whereby the distribution of the surface SPM exhibited significant spatial characteristics of being high in the nearshore area and low in the offshore area. Most of the SPM accumulated within the estuary in a fan shape, although some was distributed in the shallow water region of the continental shelf along the coasts on both sides of the estuary. The currents were found to limit the diffusion range of SPM. The flow direction and velocity of the North Brazil Current and the North Equatorial Countercurrent, which are largely driven by the magnitude of the trade wind stress, are the main forces controlling the long-distance diffusion of diluted water, thus forming unique river–sea interaction patterns in the Amazon estuary. This research provides a supplement and reference for the study of the diffusion process of SPM and river-diluted water, and on the estuarine river–sea interactions of other large rivers worldwide.

Levels and Distribution of Organophosphate Esters (OPEs) in Typical Megacity Wetland Park Landscape Water Bodies in Southwest China.

Human activities have led to the release of organophosphate esters (OPEs) into the environment. This study aims to investigate the levels and partitioning of OPEs in surface water, suspended particulate matter (SPM) and sediments of landscape waters across eleven parks in the city of Chengdu, a megacity in Southwest China. The average concentration of Σ6OPEs in the SPM samples (median: 2.94 × 103ng/L, 6.88 × 104ng/g dry weight) was 1-3 orders of magnitude higher than that in the surface water (median: 359ng/L) and sediment (median: 82.8ng/g) samples. Tri-n-butyl phosphate (TnBP), tris-(2-chloroethyl)-phosphate (TCEP) and trichloropropyl phosphate (TCIPP) were the primary OPE pollutants in the surface water and SPM samples, while TnBP, tris-(2-butoxyethyl) phosphate (TBEP) and tris-(2-ethylhexyl) phosphate (TEHP) predominated the sediment samples. The higher log Koc values of OPEs in park landscape water bodies estimated in the present study relative to previous studies could be explained by the environmental conditions, such as the sources of the inputs and the hydraulic retention times in these surface waters.

St Helena Marine Water Quality: Background Conditions and Development of Assessment Levels for Coastal Pollutants

St Helena is an isolated oceanic island located in the tropical South Atlantic, and knowledge of broadscale oceanography and productivity in its surrounding waters is limited. This study used model outputs (2007-2017), remote sensing data (1998-2017) and survey measurements (April 2018 and 2019) to determine background conditions for nutrients, chlorophyll and suspended particulate matter (SPM) in offshore waters and propose standards (thresholds) for assessing inshore water quality based on 50% deviation from seasonal (usually June to November) or annual averages. Seasonal thresholds were proposed for surface nitrate (average 0.18 μM), phosphate (average 0.26 μM), silicate (average 2.60 μM), chlorophyll (average 0.45 μg chl l–1), and SPM (average 0.96 mg l–1). Associated background values for most surface parameters (phosphate 0.17 μM, silicate 1.57 μM, chlorophyll 0.30 μg chl l–1; from model outputs and remote sensing) were slightly higher than offshore observations (April 2019). For nitrate, the average background value (0.12 μM) was lower than the observed average (0.24 μM). At depth (150-500 m), annual background values from model outputs were high (nitrate 26.8 μM, phosphate 1.8 μM, silicate 17.3 μM). Observed water masses at depths >150 m, identified to be of Antarctic and Atlantic origin, were nutrient-rich (e.g., 16 μM for nitrate, April 2019) and oxygen deficient (<4-6 mg l–1). A thermocline layer (betweenca.10 and 230 m), characterized by a sub-surface chlorophyll maximum (average 0.3-0.5 μg chl l–1) near the bottom of the euphotic zone (ca.100 m), is likely to sustain primary and secondary production at St Helena. For assessing inshore levels of chemical contaminants and fecal bacteria estimated from survey measurements, standards were derived from the literature. A preliminary assessment of inshore observations using proposed thresholds from surface offshore waters and relevant literature standards indicated concerns regarding levels of nutrients and fecal bacteria at some locations. More detailed modeling and/or field-based studies are required to investigate seasonal trends and nutrient availability to inshore primary producers and to establish accurate levels of any contaminants of interest or risk to the marine environment.

Organophosphate esters in water, suspended particulate matter (SPM) and sediments of the Minjiang River, China

As organic pollutants of emerging concern, organophosphate esters (OPEs) have shown toxicity to organisms after entering the water environment. However, research on OPEs in freshwater in Southwest China is very limited. The levels, distribution and partitioning behavior of OPEs in the Minjiang River and their influencing factors is still unknown. In this study, six OPEs, tri-n-butyl phosphate (TnBP), tri(2-chloroethyl)-phosphate (TCEP), trichloropropyl phosphate (TCPP), triphenyl phosphate (TPhP), tributoxyethyl phosphate (TBEP), and tris(2-ethylhexyl)-phosphate (TEHP), were determined in surface water, suspended particle matter (SPM) and sediments of the Minjiang River. The results showed that the average concentrations of Σ6OPEs in surface water, SPM and sediments of the Minjiang River were 199.32 ± 124.95 ng/L, 38463.79 ± 45641.89 ng/g dry weight (dw) and 76.45 ± 28.00 ng/g dw, respectively. High concentrations of OPEs were detected in SPM samples, indicating that more attention should be paid to pollution in SPM. It is worth noting that the variation trend of OPEs in SPM was almost opposite to that in water but basically similar to that in sediment. The proportions of alkyl OPEs in Σ6OPEs increased from surface water to SPM and sediments. Alkyl OPEs were the main pollutants in SPM (10.44%–80.88% of Σ6OPEs, mean of 54.52%) and sediments (59.08%–81.30% of Σ6OPEs, mean of 68.91%), whereas chlorinated OPEs were the most abundant components in surface water (43.16%–75.99% of Σ6OPEs, mean of 55.50%). The water-sediment partition coefficient (logKOC) of OPEs was 4.97–7.58, while the water-SPM partition coefficient was 6.71–10.00. No significant correlations were found between logKOW and logKOC. KOW was not the main factor affecting the distribution of OPEs in the Minjiang River, China.

Distribution of C/N/P stoichiometry in suspended particulate matter and surface sediment in a bay under serious anthropogenic influence: Daya Bay, China.

The C/N/P stoichiometry of organic matter can provide useful information for better understanding of the effects of human activities on aquatic ecosystems. The Daya Bay is a semi-closed bay under serious anthropogenic influences in the southeastern China. This study investigated the contents and ratios of C, N, and P in suspended particulate matter (SPM) and surface sediment in Daya Bay during the spring of 2017. Average C/N/P ratios were 139/17/1 in the surface SPM, 129/16/1 in the bottom SPM, and 61/8/1 in the surface sediment. The C/N ratio of SPM was significantly lower in the western inner bay, suggesting that eutrophication can reduce this ratio. The N/P ratio of SPM was slightly higher in the inner bay, while no clearly distribution pattern was found in the C/P ratio of SPM. Compared with SPM, surface sediment showed significantly lower N/P and C/P ratios. The C/N, N/P, and C/P ratios and contents of total organic C, N, and P were higher in the surface sediment in the inner bay. Our results suggested that the distribution of C/N/P stoichiometry was uncoupled between SPM and surface sediment. The C/N/P stoichiometry of surface sediment can effectively reflect the regional variation of terrigenous input and the influence of nuclear power plant thermal effluent.

Spatial Variation and Risk Assessment of Arsenic and Heavy Metals in Surface Water and Suspended Particulate Matter in Tail Reaches of the Yellow River, China

To determine the pollution levels and potential toxic risks of arsenic (As) and heavy metals (Cr, Ni, Cu, Zn, Pb and Cd) in water and suspended particulate matter (SPM) in tail reaches (including freshwater reach and low-salinity reach) of the Yellow River as the Flow-Sediment Regulation Project (FSRP) has been carried out for approximately 15 yr, the surface water and SPM were sampled at pre-flood (April) and post-flood seasons (October). Results showed that similar changes of As and metal levels in water and SPM were observed along the tail reaches at pre-flood or post-flood season. Compared to pre-flood season, the levels of As, Cu, Cr and Ni in freshwater reach and the concentrations of Cr and Ni in low-salinity reach rose greatly at post-flood season. The levels of As and metals in SPM of freshwater reach or low-salinity reach at pre-flood season were significantly higher than those at post-flood season (P < 0.01). The pollutions of As and metals in surface water of tail reaches at pre-flood or post-flood season were not serious. The SPM in freshwater reach at pre-flood season were polluted by Cd, As, Cr, Cu and Ni while those in low-salinity reach were polluted by Cd and Cr. The SPM in freshwater reach at post-flood season were polluted by Cd and Pb while those in low-salinity reach were polluted by Cd and Cr. Cd was identified as heavy metal of primary concern at both pre-flood and post-flood seasons. Combined with the existed data reported in present research, this study found that the toxic risk of As and metals in SPM of tail reaches at pre-flood season was higher than that at post-flood season, implying that the implementation of FSRP during flooding season, to a great extent, reduced the toxic risk of these elements. With the long-term implementation of FSRP, the pollution levels of As and metals (particularly for Cd) in SPM of tail reaches might be elevated and the potential toxic risk primarily produced by Cr, Ni and As might be increased if effective measures were not taken in future.

Dynamics of the Estuarine Turbidity Maximum Zone from Landsat-8 Data: The Case of the Maroni River Estuary, French Guiana

The estuarine turbidity maximum (ETM) zone occurs in river estuaries due to the effects of tidal dynamics, density-driven residual circulation and deposition/erosion of fine sediments. Even though tropical river estuaries contribute proportionally more to the sediment supply of coastal areas, the ETM in them has been hardly studied. In this study, surface suspended particulate matter (SPM) determined from OLI (Operational Land Imager)-Landsat 8images was used to gain a better understanding of the spatio-temporal dynamics of the ETM of the tropical Maroni estuary (located on the Guianas coast, South America). A method to estimate the remotely-sensed ETM location and its spatiotemporal evolution between 2013 and 2019 was developed. Each ETM was defined from an envelope of normalized SPM values &gt; 0.6 calculated from images of the estuary. The results show the influence of the well-marked seasonal river discharge and of tides, especially during the dry season. The ETM is located in the middle estuary during low river-flow conditions, whereas it shifts towards the mouth during high river flow. Neap–spring tidal cycles result in a push of the ETM closer to the mouth under spring-tide conditions or even outside the mouth during the rainy season. An increase in SPM, especially since 2017, coincident with an extension of the ETM, is shown to reflect the periodic influence of mud banks originating from the mouth of the Amazon and migrating along the coast towards the Orinoco (Venezuela). These results demonstrate the advantages of ocean color data in an exploratory study of the spatio-temporal dynamics of the ETM of a tropical estuary, such as that of the Maroni.

An Algorithm to Estimate Suspended Particulate Matter Concentrations and Associated Uncertainties from Remote Sensing Reflectance in Coastal Environments

Suspended Particulate Matter (SPM) is a major constituent in coastal waters, involved in processes such as light attenuation, pollutant propagation, and waterways blockage. The spatial distribution of SPM is an indicator of deposition and erosion patterns in estuaries and coastal zones and a necessary input to estimate the material fluxes from the land through rivers to the sea. In-situ methods to estimate SPM provide limited spatial data in comparison to the coverage that can be obtained remotely. Ocean color remote sensing complements field measurements by providing estimates of the spatial distributions of surface SPM concentration in natural waters, with high spatial and temporal resolution. Existing methods to obtain SPM from remote sensing vary between purely empirical ones to those that are based on radiative transfer theory together with empirical inputs regarding the optical properties of SPM. Most algorithms use a single satellite band that is switched to other bands for different ranges of turbidity. The necessity to switch bands is due to the saturation of reflectance as SPM concentration increases. Here we propose a multi-band approach for SPM retrievals that also provides an estimate of uncertainty, where the latter is based on both uncertainties in reflectance and in the assumed optical properties of SPM. The approach proposed is general and can be applied to any ocean color sensor or in-situ radiometer system with red and near-infra-red bands. We apply it to six globally distributed in-situ datasets of spectral water reflectance and SPM measurements over a wide range of SPM concentrations collected in estuaries and coastal environments (the focus regions of our study). Results show good performance for SPM retrieval at all ranges of concentration. As with all algorithms, better performance may be achieved by constraining empirical assumptions to specific environments. To demonstrate the flexibility of the algorithm we apply it to a remote sensing scene from an environment with highly variable sediment concentrations.

Coupling remote sensing data with in-situ optical measurements to estimate suspended particulate matter under the Evros river influence (North-East Aegean sea, Greece)

ABSTRACTMonitoring the riverine output of Suspended Particulate Matter (SPM) distribution in marine embayment is a crucial factor for the water quality of neighbouring coastal regions. This study presents satellite-derived SPM calculations against in-situ measurements in the continental shelf of North-East Aegean surrounding the transboundary Evros river mouth. Surface SPM, Inherent Optical Properties (IOPs) and remote sensing reflectance (Rrs) data were collected in a field campaign during low river discharge period (June 2016). The relationship between the optical backscattering coefficient (bbp) and the in-situ SPM concentrations was investigated. Subsequently, an empirical single band model was applied for estimating SPM concentrations by using the Landsat-8 Operational Land Imager (L8/OLI) red band and the model was then locally tuned within the study area. Furthermore, a multi-band SPM-retrieval algorithm was developed using the in-situ surface reflectance Rrs for calibration and it was validated using the Leave-One-Out Cross Validation technique (LOOCV). The relationship between in-situ SPM and backscattering coefficient values showed good proportionality, thus, nominating the predominance of terrestrial mineral particles. Validation against field measurements indicated that the SPM concentrations derived from the newly-developed multi-band algorithm had an improved significance correlation (96%), compared to both the single band model (not-tuned) (coefficient of determination, R2 = 0.82) and its locally tuned version (R2 = 0.83). Most importantly, the generated multi-band model apart from exhibiting the best performance (R2 = 0.93), it revealed high SPM spots which were not detected by the locally tuned single band model, indicating additional processes originating from river outflows, coastal erosion and subaqueous thermal springs in the area. In contrast, the locally tuned single band model overestimated SPM values in offshore waters, where low concentrations are encountered under the influence of the clear Black Sea Water (BSW).

Analysis of Suspended Sediment Variability in a Large Highly Turbid Estuary Using a 5‐Year‐Long Remotely Sensed Data Archive at High Resolution

AbstractSpatial variability of surface suspended particulate matter (SPM) concentration in the Gironde estuary and their relationships with environmental forcing are investigated through high spatial resolution multispectral data collected from July 2013 to August 2018 by the Operational Land Imager (Landsat‐8/OLI) and MultiSpectral Instrument (Sentinel‐2/MSI). A principal component analysis using the T‐mode orientation is applied to the discontinuous multiannual time series composed of 41 remotely sensed images. The three first principal components (PC1, PC2, and PC3) explain 65.7% of the total variance. The SPM distribution associated with PC1 and PC2 exhibits a privileged along‐estuary direction of the oscillation modes, while the spatial patterns of PC3 are clearly dominated by lateral oscillations opposing channels and shoals. The main environmental factors affecting the SPM distribution are identified by the analysis of their temporal patterns. The tidal range and the daily river discharge control the spatial patterns of PC1 and PC2, while the tidal cycles and the wind speed are significantly correlated with PC3. Furthermore, the analysis in the along‐estuary and lateral directions shows marked longitudinal and transverse SPM gradients and a strong control of bathymetry on the SPM spatial distribution. For the first time, we highlight that the maxima of surface residual turbidity are located on the shoals regardless of the environmental (tidal and hydrological) conditions. Compared to previous studies, usually based on single‐point in‐water column measurements, these results provide a novel and complementary description of the spatial variability of SPM. They are useful to validate sediment transport numerical models, but also may improve our understanding of suspended sediment dynamics in estuarine systems governed by an estuarine turbidity maximum.

Critical transitions in suspended sediment dynamics in a temperate meso-tidal estuary

There is growing consensus that human interventions can fundamentally change fine sediment transport in estuaries. Critical transitions in response to human interventions have been hypothesized based on indirect observational evidence and theoretical understanding. So far direct evidence has been lacking. Based on a 20 year data-set of surface suspended particulate matter (SPM) concentrations, we present empirical evidence of critical transitions in a temperate meso-tidal estuary. In 2008–2009 the SPM dynamics of the Scheldt estuary (Belgium/The Netherlands) changed dramatically. Not only did the total amount of sediment in suspension increase, a new maximum turbidity zone (MTZ) at typical winter discharges appeared. At intermediate and low summer discharges the longitudinal distribution of SPM now flickers between two markedly different states. Our data suggest that a range of human interventions (fairway widening and deepening, dredging and dumping activities) set the scene leading to the observed transitions. Moreover the freshwater MTZ in the Scheldt and in its major tributary exhibit an increasing sensitivity towards freshwater discharge, coinciding with water quality improvements. This suggests large scale impacts of changes in eutrophication status on estuarine sediment dynamics. This has largely been a blind spot in morphodynamic research.

Occurrence, spatial-temporal distribution and ecological risks of pharmaceuticals and personal care products response to water diversion across the rivers in Nanjing, China

Water diversion projects have been continuously used to alleviate water quality issues that arise during urbanization. However, studies about whether it has possible effects on the status of pharmaceutical and personal care products (PPCPs) are limited. In this study, the occurrence trends and spatial-temporal distribution characteristics of 50 PPCPs were investigated in surface water, suspended particulate matter (SPM) and sediments in Nanjing urban rivers under the background of the water diversion project from the Yangtze River to the Qinhuai River. In the four field campaigns that were embarked on April to July 2018, a total of 40, 38 and 24 PPCPs were detected in surface water, SPM and sediments, respectively, with overall concentrations of 138–1990 ng/L, 3214–33,701 ng/g and 12.1–109 ng/g dry weight (dw) among nine sampling sites. The excessive concentration of caffeine (20.6–905 ng/L) may be evidence of the direct discharge of untreated sewage and an obvious indicator of the overall concentrations of PPCPs. The PPCPs contamination levels in surface water were increased along with the direction of the water diversion in urban runoff, and decreased by 8–31% due to the increase in volume attributable to the water diversion. The distribution coefficients (Kd) of pollutants in the SPM-water phases (3.0–5.6 L/kg) were two orders of magnitude higher than those in the sediment-water phases (0.3–3.3 L/kg). And the positive correlations between their log Kow and SPM-water log Kd values indicated SPM was the important carrier determining the fate of organic UV filters. Furthermore, the results of ecological risk assessment demonstrated that although the increase in the volume of water caused by the water diversion reduced the overall ecological risks of PPCPs in urban rivers, the current contamination level still represents high risks to algae and fish.

Distribution, partitioning behavior and positive matrix factorization-based source analysis of legacy and emerging polyfluorinated alkyl substances in the dissolved phase, surface sediment and suspended particulate matter around coastal areas of Bohai Bay, China

The concentrations and spatial occurrences of 17 legacy per- and polyfluoroalkyl substances (PFAS) and 4 emerging PFAS in the coastal water-dissolved phase, surface sediment phase and suspended particulate matter (SPM) in the coastal areas of Bohai Bay were investigated. In addition, the partition behaviors of PFAS in the water-SPM system and water-sediment system and the potential sources of PFAS in the marine environment were revealed. The total concentrations of PFAS (∑PFAS) in the water-dissolved phase, surface sediment and SPM were 20.5–684 ng/L, 2.69–25.0 ng/g dry weight (dw) and 4.39–527 ng/g dw, respectively. The level of PFAS contamination in the coastal areas of Shandong Province was higher than that in other areas. The average partition coefficients (log Kd) of PFAS in the water-SPM system and water-sediment system were 1.56–3.57 and 0.72–2.95, respectively. Long-chain PFAS and PFECHS (perfluoroethylcyclohexane sulfonate) have a higher log Kd than that of short-chain PFAS. PFAS with short carbon chains were mainly detected in the water-dissolved phase, but long-chain PFAS mainly occurred in the surface sediment and SPM phases. Source analysis based on the positive matrix factorization (PMF) model found that erosion inhibitor factories, aqueous film-forming foam factories, metal plating plants, fluoropolymer chemical manufacture and food contact materials were the main sources of PFAS in Bohai Bay. These results improved our understanding of the partitioning behavior and sources of PFAS in aquatic environments.

Fast and Feasible Ultrasound-Assisted Pretreatment for the Determination of Organotin Compounds in Environmental Samples.

The goal of this study was to improve an already established reference method, such as the one devoted to organotin compounds determination (Reference Method for Marine Pollution Studies, No. 59, UNEP). The proposed upgrade consists of replacing the mechanical shaking by ultrasound energy and applying low temperature throughout the whole procedure. The optimization of the new operational conditions was performed by using a factorial design. Quality control was performed using a certified sediment reference material (PACS-2) for sediments (82.5-97% of recovery) and recoveries on spiked samples for suspended particulate matter (SPM) and mussels (94-100%). The proposed procedure was applied to surface sediment samples, SPM, and native bivalve mollusks (Brachidontes rodriguezii) collected in Bahia Blanca estuary, a very industrialized zone. The relative standard deviation (RSD%) of the environmental samples were less than 7.9%. It is important to note that the proposed procedure reduced the sample pretreatment time about seven times.

Spatial and temporal distribution of metals in suspended particulate matter of the Kali estuary, India

Major (Al, Fe, Mn, Ti, Mg) and trace (Cu, Zn, Pb, Cr, Ni, Co, Zr, Rb, Sr, Ba, Li, Be, Sc, V, Ga, Nb, Mo, Sn, Sb, Cs, Hf, Ta, Bi, Th, U) elements and particulate organic carbon (POC) concentrations in surface suspended particulate matter (SPM) of the Kali estuary, (central west coast of India) were studied during the pre-monsoon, monsoon and post monsoon seasons to infer estuarine processes, source of SPM and Geoaccumulation Index (Igeo) assigned pollutionIgeo levels. Distribution of SPM indicates the presence of the estuarine turbidity maximum (ETM) during all three seasons near the river mouth and a second ETM during the post monsoon time in the upstream associated with salinities gradient. The SPM during the monsoon is finer grained (avg. 53 μm), characterized by uniformly low normalized elemental concentration, whereas the post and pre monsoon are characterized by high normalized elemental concentration with coarser grain size (avg. 202 μm and 173 μm respectively) with highest ratios in the upstream estuary. The elemental composition and principal component analysis for the upstream estuary SPM support more contribution from the upstream catchment area rocks during the monsoon season; there is additional contribution from the downstream catchment area during the pre and post monsoon period due to the tidal effect. The Kali estuarine SPM has higher Al, Fe, Mn, Ti, Mg, Ni, Co, Ba, Li and V with respect to Average World River SPM (WRSPM). Igeo values for the SPM indicate Kali Estuary to be severely enriched with Mn and moderately enriched with Cu, Zn, Ni, Co, U and Mo in the upstream estuary during pre and post monsoon seasons. Seasonal changes in salinity gradient (reduced freshwater flow due to closing of the dam gates), reduced velocity at meandering region of the estuary and POC of 1.6–2.3% resulted in co-precipitation of trace elements that were further fortified by flocculation and coagulation throughout the water column resulting in metal trapping in the upstream region.

The dynamics of suspended particulate matter (SPM) and chlorophyll-a from intratidal to annual time scales in a coastal turbidity maximum

The analysis of 1.8years of data gives an understanding of the response to varying forcing of suspended particulate matter (SPM) and chlorophyll-a (CHL-a) in a coastal turbidity maximum zone (TMZ). Both temporal and vertical concentration variations in the near-bed layer (0–2m) in the shallow (11m deep) coastal zone at 1km off the Dutch coast are shown. Temporal variations in the concentration of both parameters are found on tidal and seasonal scales, and a marked response to episodic events (e.g. storms). The seasonal cycle in the near-bed CHL-a concentration is determined by the spring bloom. The role of the wave climate as the primary forcing in the SPM seasonal cycle is discussed. The tidal current provides a background signal, generated predominantly by local resuspension and settling and a minor role is for advection in the cross-shore and the alongshore direction. We tested the logarithmic Rouse profile to the vertical profiles of both the SPM and the CHL-a data, with respectively 84% and only 2% success. The resulting large percentage of low Rouse numbers for the SPM profiles suggest a mixed suspension is dominant in the TMZ, i.e. surface SPM concentrations are in the same order of magnitude as near-bed concentrations.