Surface Pressure Research Articles

Passive Ventilation of Residential Buildings Using the Trombe Wall

The article explores passive systems for regulating microclimates in residential settings, with a focus on modular constructions. It investigates the use of the trombe wall system for passive ventilation to ensure comfort and hygiene. The study examines building designs that enable effective air circulation without using mechanical systems. Furthermore, the effectiveness of the passive system of using solar energy with the trombe wall as a ventilation device in modular houses has been experimentally confirmed. Although the research confirms the effectiveness of this solar system in modular homes, there is limited documentation regarding its overall efficiency, particularly concerning the impact of the surface pressure coefficient on ventilation. The study establishes the correlations governing the thermosiphon collector’s effectiveness at varying air layer thicknesses. Optimal parameters, such as maximum air consumption (L = 120 m3h−1), are identified at an air layer thickness (δ) of 100 mm and outlet openings area (F) of 0.056 m2. These findings pave the way for improving passive systems aimed at maintaining optimal thermal and air conditions in modern homes. The findings suggest the potential for more efficient and sustainable housing solutions. Further research is essential to understand how factors like building design and wind speed affect ventilation system efficacy.

Measurement report: In situ vertical profiles of below-cloud aerosol over the central Greenland Ice Sheet

Abstract. Surface radiative cooling in polar regions can generate persistent stability in the atmospheric boundary layer. Stable layers below clouds can decouple the cloud layer from the near-surface environment. Under these conditions, surface aerosol measurements are not necessarily representative of the near-cloud or intra-cloud aerosol populations. To better understand the variability in the vertical structure of aerosol properties over the central Greenland Ice Sheet, in situ measurements of aerosol particle size distributions up to cloud base were made at Summit Station in July and August 2023. These measurements identified distinct vertical aerosol layers between the surface- and cloud-base-associated thermodynamic decoupling layers. Such decoupling layers occur 49 % of the time during the summer in central Greenland, suggesting that surface aerosol measurements are insufficient for describing the cloud-relevant aerosol population half of the time. Experience during this first measurement season demonstrated the ability of a tethered-balloon platform to operate effectively under icing conditions and at low surface pressure (< 680 hPa). The results presented here illustrate the value of vertically resolved in situ measurements of aerosol properties in developing a nuanced understanding of the aerosol effects on cloud properties in polar regions.

Real-Time Aerodynamic Load Estimation for Hypersonics via Strain-Based Inverse Maps

This work develops an efficient real-time inverse formulation for inferring the aerodynamic surface pressures on a hypersonic vehicle from sparse measurements of the structural strain. The approach aims to provide real-time estimates of the aerodynamic loads acting on the vehicle for ground and flight testing, as well as guidance, navigation, and control applications. Specifically, the approach targets hypersonic flight conditions where direct measurement of the surface pressures is challenging due to the harsh aerothermal environment. For problems employing a linear elastic structural model, the inference problem can be posed as a least-squares problem with a linear constraint arising from a finite element discretization of the governing elasticity partial differential equation. Due to the linearity of the problem, an explicit solution is given by the normal equations. Precomputation of the resulting inverse map enables rapid evaluation of the surface pressure and corresponding integrated quantities, such as the force and moment coefficients. The inverse approach additionally allows for uncertainty quantification, providing insights for theoretical recoverability and robustness to sensor noise. Numerical studies demonstrate the estimator performance for reconstructing the surface pressure field, as well as the force and moment coefficients, for the Initial Concept 3.X (IC3X) conceptual hypersonic vehicle.

The Feasibility of Asynchronous Rotation via Thermal Tides for Diverse Atmospheric Compositions

The equilibrium rotation rate of a planet is determined by the sum of torques acting on its solid body. For planets with atmospheres, the dominant torques are usually the gravitational tide, which acts to slow the planet’s rotation rate, and the atmospheric thermal tide, which acts to spin up the planet. Previous work demonstrated that rocky planets with thick atmospheres may produce strong enough thermal tides to avoid tidal locking, but a study of how the strength of the thermal tide depends on atmospheric properties has not been done. In this work, we use a combination of simulations from a global climate model and analytic theory to explore how the thermal tide depends on the shortwave and longwave optical depth of the atmosphere, the surface pressure, and the absorbed stellar radiation. We find that for planets in the habitable zones of M stars only high-pressure but low-opacity atmospheres permit asynchronous rotation owing to the weakening of the thermal tide at high longwave and shortwave optical depths. We conclude that asynchronous rotation may be very unlikely around low-mass stars, which may limit the potential habitability of planets around M stars.

Quantifying the influence of dominant factors on the long-term sandstorm weather - A case study in the Yellow River Basin during 2000–2021

Sandstorm is a disastrous weather phenomenon that often occurs in arid and semi-arid areas, endangering the ecological environment and affecting people's lives and property safety seriously. Since the 21st century, the sandstorm weather in the Yellow River Basin has ameliorated obviously. However, the causes of the long-term trends in sandstorms during 21st century were still unknown. In this study, fifteen influencing factors from five aspects: ecology, meteorology, hydrology, geography and man-made were selected to comprehensively analyze the driving mechanism of sandstorm activities in the Yellow River Basin since the 21st century, and the effect of each influencing factor on sandstorm weather was quantified. The results indicated that ecological, meteorological and geographical factors had dominant impacts on the spatio-temporal variation of sandstorms during 2000–2021, while hydrological and human factors played little role in the long-term variation of sandstorms. Sandstorms frequently occurred in semi-desert or grassland or non-high vegetation covered areas in spring. Vegetation coverage, precipitation, surface pressure, surface roughness, and soil moisture content were negatively correlated with sandstorms, while wind speed, friction velocity, evaporation, and soil temperature were positively correlated with sandstorms. Precipitation, runoff, evaporation, soil moisture content, soil temperature, and surface temperature indirectly acted on normalized brightness temperature dust index (NBTDI) and sandstorms by changing soil texture. Normalized Vegetation Index (NDVI) had direct negative effects on NBTDI, while wind speed 10 m (WS10m), slope of sub-gridscale orography (SOSGO), and forecast surface roughness (FSR) had direct positive effects on NBTDI. This study comprehensively revealed the dominant factors and their driving mechanism of sandstorm weather in the Yellow River Basin since the 21st century, which had practical application value for the prevention of sandstorms.

Cu gradient design to attain high efficient solution-processed CuIn(S,Se)2 solar cells

Solution-processed chalcopyrite solar cells are widely regarded as a promising alternative method in reducing the cost compared with vacuum-based techniques. It is noted that the absorber layer usually needs to be prepared under a high insert pressure (∼1.6 atm) to suppress element loss or under a mild pressure but additional surface etching is needed for fabricating high efficient solar cell. Herein, a copper gradient structured precursor is proposed to prepare CuIn(S,Se)2 (CISSe) film under a mild pressure (1.1 atm). The designed gradient Cu not only promotes crystal grain growth and tailors the defects, but also avoids the surface etching of the formed CISSe film for the fabrication of high efficient solar cells. Further, Cu gradient design decreases the conduction band offset of heterojunction, boosting the carriers transport across the p-n heterojunction. Accordingly, a 13.35% efficient CISSe solar cell, comparable to the high efficient CISSe solar cell prepared by this method under high pressure or with film surface etching, is fabricated. This work provides a facile pathway to fabricate high efficient solution-processed chalcopyrite solar cell, avoiding high selenization pressure and film etching, and shows huge potential for solution-processed copper-based solar cells.

Underexpanded jet impingement in near vacuum environment

Understanding the dynamics of rocket plume impingement on flat surfaces is critical for designing effective and sustainable landing pads. The current near vacuum study measures the surface pressures and temperature profiles arising on a flat surface due to highly underexpanded, axisymmetric plume impingement. The experiments were conducted in a dedicated, large-volume plume-regolith facility situated at the University of Glasgow. A total of eight tests were conducted, comprising of both constant and pulsed firing modes. The impingement plate is located at stand-off distances equal to 4 and 16 times the nozzle exit diameters and plate inclinations of 0° and 30°. Reduced stand-off distance increases impingement pressure, with a transient peak in the early stages of impingement indicating the presence of a primary shock wave. Higher stand-off distance resulted in decreased impingement pressure without an initial peak, but with a spike at the end of impingement once the nozzle had stopped firing. For inclined plates, the centerline impingement pressure magnitude decreased by around 40% compared with the 0° inclination. The measured pressures at lower stand-off height are then compared with the results of both a two-way coupled direct simulation Monte Carlo/Navier–Stokes–Fourier solver and an analytical theory. The results from all methods are in good agreement with each other, with the simulation and experimental centerline pressures being within 1% of each other. As the optical thickness of the gas is very low in the experimental case, the numerical method is used to generate a Schlieren image to analyze the shock structure.

Impact of WindBorne Observation Assimilation on Prediction of a TPV Merger Case From THINICE

AbstractThe impact of assimilating in situ temperature, moisture and wind observations from a WindBorne Systems balloon, with long duration and adjustable ballast, is evaluated using a case study from the 2022 THINICE field campaign. A case is selected wherein the WindBorne balloon directly sampled a jet streak associated with a tropopause polar vortex (TPV). The observed TPV merged with another TPV at the same time as a downstream Arctic cyclone (AC) redeveloped eastward. The case is used to better understand the role of the observed TPV in the evolution of the downstream AC. The assimilation of the WindBorne observations improves the forecast track and amplitude of the TPV during the ∼1 day forecast period that the TPV can be tracked as a distinct feature. The root mean square error of temperature at 350 hPa is improved by the WindBorne assimilation throughout the 2.5 day forecast period. The surface cyclone track forecast is improved by the WindBorne assimilation during the period of eastward redevelopment of the surface cyclone, and the sea level pressure RMSE in the surrounding region is reduced during the first ∼1.5 days of forecast lead time. Results demonstrate the capability of the long‐duration controllable WindBorne balloons to improve the analysis of the TPV associated with the jet streak, leading to improved forecast of both tropopause‐level and surface pressure features. Additionally, the importance of observing the upstream TPV amplitude for improving forecasts of the process of TPV merging and its impact on the evolution and longevity of the mature AC is confirmed.

Investigation of smoothed particle hydrodynamics (SPH) method for modeling of two-phase flow through porous medium: application for drainage and imbibition processes

The drainage and imbibition processes are critical mechanisms in petroleum engineering. These processes in a porous medium are controlled by surface forces and pressure gradients. The study of these processes in the pore scale by common simulators always has limitations in multiphase flow modeling. Also, obtaining relative permeability curves through laboratory analysis requires expensive equipment. Additionally, these laboratory experiments are quite expensive and may introduce significant uncertainties. For this purpose, this study investigated the creation of relative permeability curves and their effect on oil production. Initially, single-phase fluid and two-phase droplet flow within a fracture with both soft and rough surfaces were utilized to validate the formulation of the Smoothed Particle Hydrodynamics (SPH) method. Then, by using three randomly constructed porous medium models, the imbibition and drainage processes have been studied. Finally, sensitivity study has been carried out on critical parameters related to fluid flow dynamics in the porous environment, including pressure changes, wettability, and heterogeneity in drainage and imbibition processes. The simulation results were consistent with current theories; therefore, it is reasonable to consider SPH to characterize the fluid flow dynamic during the drainage and imbibition processes. According to sensitivity studies, pressure gradient (residual saturation of displaced fluid is about 5.65% and 8.44%) and heterogeneity (the residual saturation of the displaced fluid was 4.04% and 2.98%) have the largest impact on flow modeling in both drainage and imbibition processes and wettability (the residual saturation became 36.62% and 5.12%) has significant effect on the drainage process through porous medium. In general, fluid flow dynamic studies can be performed using the SPH method to model fluid flow in simple and complex porous medium under various flow conditions. The SPH method can also be used as an applicable tool to investigate the hydrocarbon fluids flow within larger geometries in the future.

Residual stress induced granular bright facets around inclusions in high-strength steels under high-cycle fatigue

Granular bright facets (GBFs) are frequently observed adjacent to inclusions and within fish-eye areas in the fatigue fractures of high-strength steels under very-high-cycle fatigue (VHCF), considered as a characteristic fracture feature of VHCF. Previous understanding on GBF formation emphasizes the occurrence of nanocystallization in microstructure. In this study, however, the same morphology can also be observed under high-cycle fatigue (HCF). GBF, although closer to fatigue crack initiator and experiencing more stress cycles than the peripheral part of fish-eye (PPFE), exhibits rougher surface morphology in the absence of accumulated plastic strain in microstructure, manifesting relieved crack surface wear. This indicates that the traditional theories on GBF formation for VHCF becomes invalid for HCF. The root cause for GBF formation under HCF is analyzed to be the presence of residual stress around inclusions, which reduces the contact pressure of fatigue crack surfaces inducing wear relief. Accordingly, an analytical model capable of predicting GBF thickness with the effects of HCF conditions and steel properties taken into consideration is established. The model yields accurate predictions of GBF thickness with various loading stresses and inclusion diameters, validated by experimental observations. This study provides theoretical guidance for HCF fracture analysis and fatigue life prediction.

Irrotational Flow over Ogee Spillway Crest: New Solution Method and Flow Geometry Analysis

A spillway is a hydraulic structure of major importance in dam safety, and its current analysis usually involves a hybrid approach combining CFD modeling with experimental research, either using well-known WES design charts or conducting new model experiments in the laboratory. Flow over spillway crests involves fluid accelerations, making irrotationality an adequate simplification of the Navier–Stokes (NS) equations. However, an efficient tool using this method is currently lacking for spillway flow, particularly for ogee spillway flow. This work focuses on this aspect of the problem, and a new method for computing irrotational flow solutions over ogee spillways is proposed by developing flow net computational solutions. The proposed method entails a new iterative procedure in the complex potential plane where free surface pressures are exactly set to zero, contrary to other methods, and an automatic determination of the critical point, the unknown energy head, and the free surface profile. The model generates solutions efficiently in only a few seconds on a personal workstation, permitting a fast estimate of spillway flow operation, and is thus an effective complement to experimental and NS-CFD modeling. The solutions produced are compared with observations of a high operational head equal to five times the design head of the ogee crest, resulting in reasonable agreement. The application of the new model to investigate the limitations of analytical equations used in spillway flow, like Jaeger’s theory, establishes limits for its use by relating its curvature parameter to the spillway chute slope.

Comprehensive Spatial-Temporal and Risk Factor Insights for Optimizing Livestock Anthrax Vaccination Strategies in Karnataka, India.

Anthrax, a zoonotic disease affecting both livestock and humans globally, is caused by Bacillus anthracis. The objectives of this study were the following: (1) to identify environmental risk factors for anthrax and use this information to develop an improved predictive risk map, and (2) to estimate spatial variation in basic reproduction number (Ro) and herd immunity threshold at the village level, which can be used to optimize vaccination policies within high-risk regions. Based on the anthrax incidences from 2000-2023 and vaccine administration figures between 2008 and 2022 in Karnataka, this study depicted spatiotemporal pattern analysis to derive a risk map employing machine learning algorithms and estimate Ro and herd immunity threshold for better vaccination coverage. Risk factors considered were key meteorological, remote sensing, soil, and geographical parameters. Spatial autocorrelation and SaTScan analysis revealed the presence of hotspots and clusters predominantly in the southern, central, and uppermost northern districts of Karnataka and temporal cluster distribution between June and September. Factors significantly associated with anthrax were air temperature, surface pressure, land surface temperature (LST), enhanced vegetation index (EVI), potential evapotranspiration (PET), soil temperature, soil moisture, pH, available potassium, sulphur, and boron, elevation, and proximity to waterbodies and waterways. Ensemble technique with random forest and classification tree models were used to improve the prediction accuracy of anthrax. High-risk areas are expected in villages in the southern, central, and extreme northern districts of Karnataka. The estimated Ro revealed 11 high-risk districts with Ro > 1.50 and respective herd immunity thresholds ranging from 11.24% to 55.47%, and the assessment of vaccination coverage at the 70%, 80%, and 90% vaccine efficacy levels, all serving for need-based strategic vaccine allocation. A comparison analysis of vaccinations administered and vaccination coverage estimated in this study is used to illustrate difference in the supply and vaccine force. The findings from the present study may support in planning preventive interventions, resource allocation, especially of vaccines, and other control strategies against anthrax across Karnataka, specifically focusing on predicted high-risk regions.

Influence of surface curvature on the impact force of water droplet

Although the global market for wind energy is growing rapidly, leading-edge erosion is a critical issue hindering the development of wind power. The impact force of a droplet colliding with flat surfaces has been investigated in previous studies. However, the impact force exerted on curved surfaces, such as that experienced by eroded wind turbine blades, is not well understood. This study discusses the relationship between the impact force generated on a solid surface by a water droplet and the radius of curvature of the impacting surface. The impact force by a droplet was measured using a force sensor mounted on semi-cylindrical caps with different radii of curvature. The measurement results showed that the impact force decreased as the radius of curvature decreased. A computational fluid dynamics model solving incompressible flows showed that, unlike the case of a curved surface, the initial momentum of the droplet was mostly transferred to the flat surface. This resulted in a high impulse for an impact with a flat surface. The falling droplet was blocked by the surface, and the lateral jet was accelerated sideward. This acceleration was moderate for curved surfaces. When colliding with a flat surface, a higher impact force was generated owing to the wider area of the excited surface pressure compared with that of the curved surface. Finally, the relationship between the peak of the impact force and the surface curvature was derived, suggesting that the force peak is inversely proportional to the curvature.

Stable carbon isotope evolution of formaldehyde on early Mars

Organic matter in the Martian sediments may provide a key to understanding the prebiotic chemistry and habitability of early Mars. The Curiosity rover has measured highly variable and 13C-depleted carbon isotopic values in early Martian organic matter whose origin is uncertain. One hypothesis suggests the deposition of simple organic molecules generated from 13C-depleted CO derived from CO2 photochemical reduction in the atmosphere. Here, we present a coupled photochemistry-climate evolution model incorporating carbon isotope fractionation processes induced by CO2 photolysis, carbon escape, and volcanic outgassing in an early Martian atmosphere of 0.5–2 bar, composed mainly of CO2, CO, and H2 to track the evolution of the carbon isotopic composition of C-bearing species. The calculated carbon isotopic ratio in formaldehyde (H2CO) can be highly depleted in 13C due to CO2-photolysis-induced fractionation and is variable with changes in atmospheric CO/CO2 ratio, surface pressure, albedo, and H2 outgassing rate. Conversely, CO2 becomes enriched in 13C, as estimated from the carbonates preserved in ALH84001 meteorite. Complex organic matter formed by the polymerization of such H2CO could explain the strong depletion in 13C observed in the Martian organic matter. Mixing with other sources of organic matter would account for its unique variable carbon isotopic values.

Experimental Investigation on Shear Strength at the Permeable Concrete–Fine-Grained Soil Interface for Slope Stabilization Using Deep Socket Counterfort Drains

In slopes where high pore water pressure exists, deep counterfort drains (also called drainage trenches or trench drains) represent one of the most effective methods for improving stability or mitigating landslide risks. In the cases of deep or very deep slip surfaces, this method represents the only possible intervention. Trench drains can be realized by using panels or secant piles filled with coarse granular material or permeable concrete. If the trenches are adequately “socket” into the stable ground (for example sufficiently below the sliding surface of a landslide or below the critical slip surface of marginally stable slopes) and the filling material has sufficient shear strength and stiffness, like porous concrete, there is a further increase in shear strength due to the “shear keys” effect. The increase in shear strength is due both to the intrinsic resistance of the concrete on the sliding surface and the resistance at the concrete–soil interface (on the lateral surface of the trench). The latter can be very significant in relation to the thickness of the sliding mass, the “socket depth”, and the spacing between the trenches. The increase in shear strength linked to the “shear keys effect” depends on the state of the porous concrete–soil interface. For silty–clayey base soils, it is very significant and is of the same order of magnitude as the increase in shear resistance linked to the permanent reduction on the slip surface in pore water pressure (draining effect). This paper presents the results of an experimental investigation on the shear strength at the porous interface of concrete and fine-grained soils and demonstrates the high significance and effectiveness of the “shear keys” effect.

Surface pressure reconstruction from LPT data with boundary conforming grids

Abstract The coupling between fluid-structure interactions is governed by the pressure distribution over the interaction surface between the fluid and solid domains. The capabilities of non-intrusive optical techniques, such as particle image velocimetry and Lagrangian particle tracking (LPT), have been proven to provide accurate velocity and acceleration information within the flow field while simultaneously tracking the corresponding structural deformations. However, scattered data from LPT measurements are typically mapped onto Cartesian grids, independently of the shape of the solid objects in the measurement domain. The use of Cartesian grids poses challenges for the determination of the surface pressure because the velocity gradients close to the object’s surface are not captured accurately. Therefore, an alternative surface pressure reconstruction scheme utilizing LPT data based on the arbitrary Lagrangian–Eulerian approach is proposed to mitigate the error propagation associated with the use of uniform grids. The introduced method provides an exact surface conformation utilizing boundary fitted coordinate systems and radial basis function based mesh deformations, which eliminates the need to use extrapolations to obtain surface pressure distributions. The introduced approach is assessed by means of a synthetic hill surface probing a three-dimensional analytical flow field; its practical applicability is demonstrated through an experimental characterization of turbulent boundary layer interactions with a steadily and unsteadily deforming elastic membrane.

Numerical Analysis of 3D Unilateral Quasi-static Contact: Effect of Coating Thickness and Mechanical Properties

In this study, a numerical model for unilateral quasi-static contact between a rigid sphere and an elastic coating has been developed. The contact problem was solved using a numerical procedure based on the FFT technique, considering various coatings with different thicknesses and mechanical properties, implemented through a Matlab code. The model calculates the contact surface deformation and pressure field through a double iteration process. The first iteration solves the contact problem for a given indenter penetration, while the second iteration refines this penetration by minimizing the difference between the fixed and calculated loads. To achieve this, influence coefficients are derived from the elasto-static equations using the Papkovich-Neuber potentials. The study discusses the influence of coating thickness and friction coefficient value on the tribological behavior of the coating. The results indicate that contact pressure increases (ranging from 1.9 to 2.5) as the coating becomes thicker or more rigid (0.02 mm to 0.2 mm). Additionally, the tribological behavior of the coated surface is affected by the coating's thickness, hardness, and friction coefficient value. Importantly, this model demonstrates versatility by being applicable to both smooth and rough surfaces.

Changes of Intense Extratropical Cyclone Deepening Mechanisms in a Warmer Climate in Idealized Simulations

Abstract To understand how extratropical cyclones (ETCs) may change in a warmer climate, we conduct idealized baroclinic life cycle simulations using the Icosahedral Nonhydrostatic (ICON)–NWP model with varied initial conditions. With respect to a present-day climate, two experiments are highlighted: a 4-K uniform warming and a more realistic late twenty-first-century warming pattern projected by a Coupled Model Intercomparison Project, version 6 (CMIP6), model. Different ETC deepening mechanisms, especially by diabatic processes, are quantified via the pressure tendency equation analysis, and the horizontal model resolution dependency is examined by contrasting coarse-grid (80 km) and convection-permitting (2.5 km) simulations. While our simulated ETCs are primarily baroclinically driven, dominated by the horizontal warm-air advection in the air column above the surface low, such an effect only strengthens by 10% in both warming experiments. However, the direct contribution of diabatic heating to surface pressure drop almost doubles, which likely feeds back positively to horizontal warm-air advection. Although their combined response to warming is pronounced, it is largely offset by the strengthened adiabatic cooling (17%) due to enhanced upward motions in warmer and moister ETCs, leading to a marginal ETC deepening at maturity (lowers by ∼1.5–4 hPa). Nevertheless, the near-surface impacts strongly increase, particularly the local extreme precipitation (up to 56%). The convection-permitting and the coarse-grid simulations show qualitatively consistent ETC responses to global warming. We suggest that the systematically weaker ETCs (with higher central pressure) in 2.5-km compared to 80-km simulations might be primarily caused by model uncertainty in representing the convective-diabatic heating over the warm front near the cyclone core.

Dilatational rheological studies on the surface micelles of Poly(styrene)-[formula omitted]-Poly(4-vinyl pyridine) block copolymer at the air-water interface

A thin film of an amphiphilic block copolymer, poly(styrene)-b-poly(4-vinyl pyridine), is investigated at the air–water interface. The surface pressure - area per molecule isotherm and the static compressional modulus provide evidence of two phases, assigned as L1 and L2, respectively. The surface topography and the phase images of these phases obtained using atomic force microscope reveal the presence of surface micelles of different sizes and densities. The dilatational rheology of these phases was investigated using the oscillatory barrier method for different strain amplitudes (1−5%) and qualitatively assessed using Lissajous–Bowditch curves. It points out the emergence of nonlinearity (asymmetric shape and distorted ellipse) with an increase in strain amplitude. Using a fast Fourier transform, the amplitudes and the phases of different harmonics of the stress–strain curves were extracted, and the total harmonic distortion was determined. In contrast to L1 phase, the total harmonic distortion for the L2 phase increases monotonically with strain amplitude. Fixing the strain amplitude at 1% (small amplitude regime), the temperature as well as frequency dependence studies of the dilatational moduli were carried out. The dynamic storage moduli of the L1 phase is found to be insensitive to temperature while it decreases for the L2 phase suggesting softening. Further, evidence for solid-like viscoelastic response emerges (explained using the Kelvin–Voigt model) for the L1 phase, whereas the L2 phase show a cross-over behaviour.

Study on the Adsorption Law of n-Pentane in Silica Slit Nanopores.

As the main components of shale, inorganic minerals are important carriers for oil and gas adsorption, whose pore structures and surface properties have significant effects on the fluid adsorption capacity. In this study, slit nanopores (SNPs) were constructed by silica. To investigate the microscopic adsorption law of n-pentane in silica, the grand canonical Monte Carlo (GCMC) method was used to simulate the adsorption behaviors of n-pentane in silica nanoparticles. The effects of different surface wettability, pore size, temperature, and pressure values on the adsorption behavior of pentane were discussed, revealing the micro adsorption mechanism of pentane in silica with different pore sizes and wettability and evaluating the degree of oil and gas utilization. The research results indicate that the adsorption capacity of pentane is greatly affected by the temperature under low-pressure conditions. With the increase of the pore size, the adsorption capacity of pentane increases linearly, and the number of adsorbed pentane molecules gradually decreases. The availability of oil and gas increases, and the oil and gas are more easily extracted. As the surface hydrophobicity of minerals increases, the van der Waals force between minerals and pentane also increases, leading to an increase in the number of adsorbed states of pentane. The stronger the hydrophilicity of the wall, the fewer the pentane molecules adsorbed on the surface, which would improve the efficiency of oil and gas extraction. This study provides potential for the development of novel surfactants based on adsorption selectivity.