Sheet Surface Research Articles

The Phase Structure of Wave Disturbances Excited by a Pulsating Source at the Interface of a Liquid Flow of Finite Depth and an Ice Sheet

The floating ice sheet determines the dynamic interaction between the ocean and the atmosphere, affects the dynamics of the sea surface and subsurface waters, since the ice sheet and the entire mass of liquid under it participate in the general vertical movement. The paper investigates the phase structure of wave fields arising at the interface between ice and a flow of homogeneous liquid of finite thickness when flowing around a localized pulsating source of disturbances. The ice sheet is modeled by a thin elastic plate, the deformations of which are small, and the plate is physically linear. An integral representation of the solution is obtained, and the results of calculations of dispersion dependencies and phase patterns for various parameters of wave generation are presented. It is shown that the main parameters determining the characteristics of the amplitude-phase structure of wave disturbances of the ice sheet surface are ice thickness, flow velocity, and pulsation frequency. Numerical calculations demonstrate that when the flow velocities, ice thickness, and frequency change, there is a noticeable qualitative restructuring of the phase patterns of the excited long-range wave fields at the ice-liquid interface.

Comparison of Multiple Methods for Supraglacial Melt-Lake Volume Estimation in Western Greenland During the 2021 Summer Melt Season

Supraglacial melt-lakes form and evolve along the western edge of the Greenland Ice Sheet and have proven to play a significant role in ice sheet surface hydrology and mass balance. Prior methods to quantify melt-lake volume have relied upon Landsat-8 optical imagery, available at 30 m spatial resolution but with temporal resolution limited by satellite overpass times and cloud cover. We propose two novel methods to quantify the volume of meltwater stored in these lakes, including a high-resolution surface DEM (ArcticDEM) and an ablation model using daily averaged automated weather station data. We compare our methods to the depth-reflectance method for five supraglacial melt-lakes during the 2021 summer melt season. We find agreement between the depth-reflectance and DEM lake infilling methods, within +/−15% for most cases, but our ablation model underproduces by 0.5–2 orders of magnitude the volumetric melt needed to match our other methods, and with a significant lag in meltwater onset for routing into the lake basin. Further information regarding energy balance parameters, including insolation and liquid precipitation amounts, is needed for adequate ablation modelling. Despite the differences in melt-lake volume estimates, our approach in combining remote sensing and meteorological methods provides a framework for analysis of seasonal melt-lake evolution at significantly higher spatial and temporal scales, to understand the drivers of meltwater production and its influence on the spatial distribution and extent of meltwater volume stored on the ice sheet surface.

How does a change in climate variability impact the Greenland ice sheet surface mass balance?

Abstract. Given the long response time of ice sheets, simulations of the Greenland ice sheet typically exceed the availability of input climate data to reliably simulate the fast processes underlying surface mass balance. Strong feedback processes are known to make the mass balance sensitive to inter- and intra-annual variability. Even simulations with climate models do not always cover the full period of interest, motivating bridging these gaps using relatively coarsely resolved climate reconstructions or temporal interpolation methods. However, both of these approaches usually only provide information about the climatological average but not variability. We investigate how this simplification impacts the surface mass balance using the BErgen Snow SImulator. The model was run for up to 500 years using the same atmospheric climatology but different synthetic variabilities. While changing inter-annual variations has an impact of less than 5 % on the surface mass balance of the Greenland ice sheet, neglecting intra-annual variability by using a daily climatology causes a 40 % change in mass balance. Decomposing the total effect into contributions from different input variables, the biggest contributor is precipitation followed by temperature. Using a daily climatology, a small amount of snowfall every day overestimates the albedo and thus surface mass balance (SMB). We propose a correction that re-captures the effect of intermittent precipitation, reducing the SMB overestimation to 15 %–25 %. We conclude that simulations of the Greenland surface mass and energy balance should be forced with a transient climate, in particular for models that are calibrated with transient data.

Effect of polydimethylsiloxane content on the electrothermal performance and tensile strength of laser induced graphene films: Experimental and theoretical

BackgroundSince its discovery in 2014, laser induced graphene (LIG) has gained a lot of interest from research institutions and the industry as a result of its single-step fabrication process and tailorable properties. Nonetheless, LIG's brittle nature makes it susceptible to any mechanical disturbances thus shearing off from the polyimide (PI) sheet surface. This limits its applicability in electrothermal heating and other applications requiring high flexibility. Therefore, there is a need to enhance LIG's robustness on the precursor surface. MethodsTo overcome this, LIG films were fabricated from PI using a 10.6 µm CO2 laser machine and polydimethylsiloxane (PDMS) contents were infused into the LIG structure by spin coating to form LIG/PDMS films. Furthermore, the adhesion strength of LIG/PDMS films was further improved by making micro scratches on the substrate surface by pressing the PI sheets in between the jaws of a Universal Testing Machine (UTM). The joule heating of LIG and LIG/PDMS heaters was evaluated before, during, and after mechanical testing. Theoretical models (heat balance and Ansys Finite Element, FE) were also performed to validate experimental results. Significant findingsAt an input DC voltage of 8 V, the LIG/PDMS with 50 μL PDMS and LIG heaters generated saturation temperatures of 250 and 308.86 °C, respectively. Much as the saturation temperatures were lower for LIG/PDMS heaters, their mechanical strength was enhanced in comparison with the LIG heaters. LIG/PDMS films could undergo more bending cycles (4800) than LIG films (2400). Additionally, LIG/PDMS film accommodated more stress (⁓ 0.16 Mpa) than LIG film (⁓ 0.04 Mpa) after tensile tests. Interestingly, the LIG/PDMS heater's electrothermal performance was better than that of LIG heater after tension. The heat balance equation and simulation results showed a tight match with experimental generated temperatures, verifying the approach's trustworthiness. Hence, the demonstrated effectiveness and efficiency of LIG-based heaters with high flexibility under various mechanical stresses open new possibilities for diverse electronic applications.

Synthesis of tin selenide nanoparticles using Polygonum avicular extract decorated on graphitic carbon nitride for enhancing photodegradation of amoxicillin trihydrate and photoproduction of hydrogen peroxide

In this research, tin selenide nanoparticles (SnSe-NPs) were synthesized using Polygonum avicular extract via the hydrothermal method and decorated on graphitic carbon nitride (g-C3N4) by the simple sonicated method to produce SnSe/g-C3N4 composites. The characterization and properties of the SnSe/g-C3N4 composites, as compared to pristine SnSe and g-C3N4, were determined by Fourier-transform infrared spectroscopy, X-ray powder diffraction, scanning electron microscope, transmission electron microscopy, field emission scanning electron microscopy, X-ray photoelectron spectroscopy, ultraviolet–visible diffuse reflectance spectroscopy, Mott-Schottky, and electrochemical impedance spectroscopy. As a result, the SnSe-NPs possessed the rod-like shape and after the decoration onto the g-C3N4 sheet surface, it reduced the bandgap energy of the g-C3N4 from 2.58 downward 1.43 eV. Besides, the photoactivities of the 10-SnSe/g-C3N4 catalyst were investigated via both sides of amoxicillin trihydrate (AMXT) photodegradation and hydrogen peroxide (H2O2) photoproduction, in which the results were achieved 87.84 % AMXT and 85.48 μM H2O2, respectively, under visible light. Furthermore, the photodegradation was consistent with the pseudo-first-order kinetics and it performed the highest photodegradation at pH ∼5, while the importance of isopropyl alcohol as a trapping agent and •O2− radicals was affirmed in the H2O2 photoproduction. Moreover, the photoproduction of H2O2 was remained after 4 cycles achieved at 62.70 % in the final cycle, which demonstrated the stability and reusability of the 10-SnSe/g-C3N4. These aforementioned results demonstrate that the SnSe/g-C3N4 material is a promising candidate for addressing environmental pollution and energy scarcity issues.

Validation and Analysis of the ICESat-2 ATL11 Product: A Case Study of Lake Vostok

Elevation changes are crucial input data for mass balance assessment based on satellite altimetry. However, due to the accuracy limitations of altimetry data and mass conversion models, a significant uncertainty remains in estimating the mass balance of the Antarctic ice sheet, especially in East Antarctica. The ICESat-2 photon altimetry satellite enhances the precision of ice sheet surface elevation measurements to an accuracy of 2–4 cm. This improvement is particularly beneficial for detecting subtle elevation changes in East Antarctica. The ATL11 product from ICESat-2 offers a time series of ice surface elevations across Antarctica, enabling direct calculation of elevation change rates. To evaluate the capability of the ATL11 product in accurately depicting detailed elevation changes within the local terrain, we selected the Vostok Subglacial Lake as the validation region. Our research involves comparing fitted surface elevation change rates with in-situ data, while also considering surface mass balance, wind, and surface elevation to analyze the factors contributing to small differences in elevation changes within the local lake area. This analysis aims to identify the factors contributing to the minor variations in elevation changes within the local lake area. According to our analysis, the Vostok Lake surface elevation change rate is 2.00 ± 0.77 cm yr−1 from April 2019 to June 2023, with an average period of 356 ± 81 days. The results demonstrate that the ATL11 elevation product sequence has the potential to accurately characterize subtle elevation changes and seasonal variations in the Antarctic ice sheet.

Formability Characterization Using Curvature and Strain-Rate-Based Limit Strain Detection Methods Applied to Marciniak, Nakazima, and Stretch-Bend Tests

Despite advancements in the characterization of forming limit curves (FLCs) with the development of stereoscopic digital image correlation (DIC), there is still uncertainty in the accuracy of the limit strains, especially in forming operations with out-of-plane bending. The ISO12004-2:2008 standard offers a standardized approach to FLC determination but is not without limitations and is not always applicable to new materials and forming processes (e.g., warm forming, hot stamping). In the present work, a physically based limit strain detection technique is developed, termed the Enhanced Curvature Method (ECM), based on the sheet surface curvature evolution at the onset of necking in sheet formability testing. The ECM is applied to the characterization of 1.1 mm AA5182-O sheet using Marciniak, Nakazima, and stretch–bend characterization tests, and its limit strains are compared with those from the linear best-fit (LBF) local strain-rate approach and the ISO-12004 standard. The ECM considers the physical nature of necking in sheet forming with the aid of thresholds defined in terms of an imperfection metric analogous to the well-known Marciniak–Kuczynski (MK) imperfection factor. By quantifying the evolution of necking, FLCs of different safety margins can be readily generated, enabling a more intuitive selection for the factor of safety. For lower and upper ECM thresholds, the Marciniak plane strain limiting strain was determined to lie between 0.173 and 0.198, respectively, which is comparable to the analytical prediction of 0.194 and in general agreement with the published literature for AA5182-O. Similar plane strain limits were obtained using the ISO and LBF methods with values of 0.188 and 0.208, respectively. The same rankings in limit strain values between methods were observed for plane strain loading in Nakazima and stretch–bend tests.

An extreme precipitation event over Dronning Maud Land, East Antarctica - A case study of an atmospheric river event using the Polar WRF Model

Extreme precipitation events (EPEs) are crucial in Antarctica, impacting the Antarctic ice sheet's surface mass balance and stability. Comprehensive case studies are essential for better understanding these events and the underlying processes driving them. Here, we investigate an extreme snowfall event in Dronning Maud Land (DML), East Antarctica on November 8 and 9, 2015. This event contributed approximately 22 % of the annual accumulation in less than two days and exhibited high spatial variability in precipitation distribution. We employed a high-resolution atmospheric model specifically optimized for the polar regions (Polar WRF) and ERA5 reanalysis data to analyze the event in detail. Our findings highlight the importance of a blocking high-pressure ridge of record strength that effectively blocked and diverted a strong extratropical cyclone into DML, ultimately leading to the heavy snowfall event. The sudden deepening of the cyclone was initiated by a ‘jet streak’ in the upper atmosphere that steered the system southeastwards towards the Antarctic coast. Notably, we observed an anomalously high poleward moisture transport in the form of a strong atmospheric river on November 7, 2015. This atmospheric river originated in the South Atlantic Ocean and tracked poleward from the 30°S-40°S latitude band. Vertical cross-sections of the model outputs indicate that most of the precipitation was concentrated in regions with steep orography along the path of the atmospheric river. This interaction between the atmospheric river and the steep terrain led to the uplift of maritime air, resulting in heavy snowfall. This study highlights the significance of extreme upper and lower atmospheric conditions in driving intense moisture transport towards coastal DML. The interaction between the atmospheric river and the steep orography contributed to heavy snowfall, underscoring the importance of considering orographic influences in understanding EPEs in Antarctica.

Improved preservation of the color and bioactive compounds in strawberry pulp dried under UV-Blue blocked solar radiation

Strawberry (Fragaria ananassa spp.) is a highly preferred fruit because of its health benefits, flavor, fragrance, and color appeal. The drying process for strawberries extends their shelf life but also changes their color and alters their nutritional contents. The anthocyanins are responsible for the color, which are susceptible to degradation during thermal processing, reducing the customer appeal of these food products. The benefit of solar drying of strawberry pulp using UV-Blue blocking optical filters compared with d irect solar drying is presented in this work. Total anthocyanins, antioxidant activity, and the color of the strawberry pulp were monitored as the drying progressed. The UV-Blue blocking optical filter consisted of a copper sulfide/copper selenide thin film of 160 nm in thickness applied on the outer surface of cellular polycarbonate sheets of 8 mm cell-size, 0.1 mm wall thickness (1 kg/m2) cut from sheets measuring 122 cm x 122 cm in area, and protected by a food-safe adhesive polyethylene foil. Total anthocyanins and antioxidant activity were measured using the differential pH and the DPPH (2,2-diphenyl-1-picrilhydrazil) methods. The filter preserves a higher total anthocyanin content and antioxidant activity in the dried product than in the pulp dried under sunlight conditions. A reduced total color change was observed in the product dried under the UV-Blue blocking solar filter. This study highlights a general need to evaluate the bioactive merits of solar dried farm produce to assess the advantage they hold for their commercialization.

A magnetohydrodynamic flow of a water-based hybrid nanofluid past a convectively heated rotating disk surface: A passive control of nanoparticles

Abstract One of the basic fluid mechanics problems of fluid flows over a revolving disk has both theoretical and real-world applications. The flow over a rotating disk has been the subject of numerous theoretical studies because it has many real-world applications in areas like rotating machinery, medical equipment, electronic devices, and computer storage. It is also crucial for engineering processes. Therefore, this article deals with a time-independent water-based hybrid nanofluid flow containing copper oxide and silver nanoparticles past a spinning disk. The Newtonian flow is taken into consideration in this analysis. The influence of magnetic field, thermophoresis, nonlinear thermal radiation, Brownian motion, and activation energy has been considered. The present analysis is modeled in a partial differential equation form and is then converted to ordinary differential equations using appropriate variables. A numerical solution using the bvp4c technique is accomplished using MATLAB software. The current results are matched with the previous literature and established a close relationship with previous studies. The purpose of this investigation is to numerically investigate the time-independent hybrid nanofluid flow comprising copper oxide and silver nanoparticles over a rotating disk surface. The results show that the increased magnetic parameters increase the friction force at the surface, which decreases the radial and azimuthal velocity distribution. At the sheet surface, the radial velocity of the hybrid nanofluid shows dominant performance compared to the nanofluid. On the other hand, the magnetic factor has dominant behavior on the azimuthal velocity component of the nanofluid flow compared to the hybrid nanofluid flow. The higher volume fraction and magnetic factor enhance the skin friction at the disk surface. Furthermore, greater surface drag is found for the hybrid nanofluid flow. The higher solid volume fraction, temperature ratio, and Biot number enhance the rate of heat transmission. Also, a higher rate of heat transmission is observed for the hybrid nanofluid flow.

Fast preparing bioelectrode with conductive bioink for nitrite detection in high sensitivity and stability

Electrochemically active biofilms (EABs) for nitrite detection have high specificity, rapid response, operational simplicity, and extended lifespan advantages. However, their scale production remains challenging due to time-consuming and uniform preparation. In this study, a novel approach was proposed to fast fabricate an EAB biosensor with a synthetic biofilm electrode for nitrite detection. The biofilm electrode was prepared by coating bioinks with varying conductive materials onto the surface of the graphite sheets, showing short incubation time and good reproducibility. Incorporating conductive materials into the bioinks remarkably enhanced the maximum voltage of the first cycle of bioelectrode incubation, with an increase of up to 633% for carbon nanofibers. The nitrite reduction current was amplified by a factor of 2.97, due to the enhancement of extracellular electron transfer (EET). The developed nitrite biosensor exhibited a detection range of 0.1–15 mg NO2--N L−1, with a high sensitivity of 610.8 μA mM−1 cm−2, and a stabilization operation time of at least 280 cycles. This study not only provided valuable insights into conductive materials for synthetic biofilms but also presented a practical approach for the rapid preparation, scale production, and optimization of highly sensitive and stable EAB sensors.

A one-pot strategy for modifying the surface of Ti3C2Tx MXene

Surface modification of MXenes significantly expands their potential for a wide range of applications. Here, we demonstrate a one-pot spontaneous polymerization of acrylic acid onto MXene sheet surfaces using an aryl diazonium coupling agent (nitrobenzene diazonium salt) as an approach to tune MXene interfacial properties. We use this formation of polymer coatings as a coagulation strategy for spinning fibers from liquid crystal MXene dispersions, obtaining densified free-standing fibers with tensile strength and breaking energy of ~155 MPa and ~4.5 MJ m−3. This simple method potentially offers a scalable approach for fabricating functional MXene macroarchitectures.

Numerical investigation of surface and volume thermal imaging of nickel-graphene foam sheets by finite element method

The detailed theoretical analysis of heat equations is applied to Nickel foam specimens with various pore-size coated graphene thin film of 200 nm thickness under laser excitation. 2D and 3D thermal numerical models were proposed by applying the finite element method. To explain the proposed numerical model, the influence of discretization parameters and the heat diffusion length were studied. The proposed model accurately predicts the thermal spreading in the specimens. The numerical model showed the sensitivity of the model for the structure variation to achieve an accurate thermal imaging when the used laser is of radius value is within of specimen pore size and modulated at low frequency.

Novel Gas Sensing Approach: ReS2/Ti3C2Tx Heterostructures for NH3 Detection in Humid Environments.

Continuous monitoring of ammonia (NH3) in humid environments poses a notable challenge for gas sensing applications because of its effect on sensor sensitivity. The present work investigates the detection of NH3 in a natural humid environment utilizing ReS2/Ti3C2Tx heterostructures as a sensing platform. ReS2 nanosheets were vertically grown on the surface of Ti3C2Tx sheets through a hydrothermal synthetic approach, resulting in the formation of ReS2/Ti3C2Tx heterostructures. The structural, morphological, and optical properties of ReS2/Ti3C2Tx were investigated using various state-of-the-art techniques, including scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, zeta potential, Brunauer-Emmett-Teller technique, and Raman spectroscopy. The heterostructures exhibited 1.3- and 8-fold increases in specific surface area compared with ReS2 and Ti3C2Tx, respectively, potentially enhancing the active gas adsorption sites. The electrical investigations of the ReS2/Ti3C2Tx-based sensor demonstrated enhanced selectivity and superior sensing response ranging from 7.8 to 12.4% toward 10 ppm of NH3 within a relative humidity range of 15-85% at room temperature. These findings highlight the synergistic effect of ReS2 and Ti3C2Tx, offering valuable insights for NH3 sensing in environments with high humidity, and are explained in the gas sensing mechanism.

A semiconductor SERS sensor of corrosion-resistant PPy/GO composite film by electrochemical growth for detecting crystal violet residues in fresh fish tissue

Crystal violet (CV) residues in Marine food have produced a severe health threat in human life. In this study, we proposed a semiconductor surface-enhanced Raman scattering (SERS) sensor of corrosion-resistant Polyaniline/Graphene oxide (PPy/GO) film by electrochemical growth method to detect CV residues in fresh fish tissue. A PPy/GO dispersion solution was one-step deposited on a stainless steel sheet surface by electrochemical polymerization process to form a PPy/GO composite film acting as a semiconductor SERS substrate. Since the substrate of PPy/GO film was mainly composed of GO sheet without other metals, it had a good corrosion resistance. The SERS enhancement factor and charge transfer intensity PCT of PPy/Go SERS substrate for CV molecules were up to 1.18 × 106 and 0.903, respectively. Furthermore, the limit of detection (LOD) of PPy/GO SERS substrate could reach 1.58 nM. In addition, SERS sensor of PPy/GO film could identify CV residues in fresh fish tissues, and its recovery rate was 91.8 %–107 %. This preparing method and detecting method we proposed PPy/GO SERS substrate provide a new pathway for detecting CV residues in Marine food.

Improved photocatalytic performance of cobalt doped ZnS decorated with graphene nanostructures under ultraviolet and visible light for efficient hydrogen production

Highly dispersed Cobalt doped ZnS nanostructures were successfully fabricated on the surfaces of graphene sheets via a simple hydrothermal method. X-ray diffraction (XRD), X-ray photocurrent spectroscopy (XPS), Raman spectroscopy (RS), Fourier transform infrared spectroscopy (FTIR) and Scanning electron microscopy (SEM) were utilized to analyze the structural characteristics of the cobalt doped ZnS decorated with graphene CoxZn1-xS\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\rm Co}_x{\\rm Zn}_{1-x}{\\rm S}$$\\end{document} rGO nanostructures (NSs). UV-visible optical absorption (UV-vis) studies were conducted to investigate their optical properties. In laboratory studies utilizing water and visible light, the photocatalytic activity of CoxZn1-xS\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\rm Co}_x{\\rm Zn}_{1-x}S$$\\end{document}rGO NSs at (x = 0, 1, 2, 4 and 6 atm.%) were evaluated. Graphite Oxide (GO) was successfully transformed into sheets of graphene and CoxZn1-xSrGO\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\rm Co}_x{\\rm Zn}_{1-x}{\\rm S \\, rGO}$$\\end{document} NSs possessed a crystalline structure according to the findings of XRD, RS and FTIR analysis. SEM investigation showed graphene sheets enhanced with ZnS NSs possessed cuboidal, spheroidal form of structure and displayed a paper like appearance. UV-vis confirmed a noticeable rapid increase in transmittance along the UV wavelength area and confirmed a highly transparent NSs in the wavelength range of (180-800 nm). Calculations using density functional theory (DFT) revealed that the Co NSs have more negative conduction bands than ZnS, allowing for effective electron transfer from cobalt to ZnS and exhibiting a band gap decrease as Co content increased. The Co0.04Zn0.96S\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\rm Co}_{0.04}{\\rm Zn}_{0.96}S$$\\end{document} rGO NSs sample had the highest photocatalytic activity, measured at 7648.9μmolh-1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$7648.9 \\, \\upmu {\\rm mol} \\, {\\rm h}^{-1}$$\\end{document}. A combination of improved dispersion properties, greater surface area, increased absorption and enhanced transfer of photogenerated electrons, CoxZn1-xS\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${\\rm Co}_x{\\rm Zn}_{1-x}S$$\\end{document} rGO NSs increased the photocatalytic hydrogen generation activity.

Manually directional splitting of in-situ intact igneous rocks into large sheets

This paper presents a directional large-area rock fracturing method. The method had distinctive features compared with other common fracturing methods. The area of the fracturing surface could reach 10–500 m2. The fractured rock was sheet-like in shape, with a thickness of 6–8 cm. The main fracturing tools and procedures used were described in the paper. This paper analysed the reason for controllable and directional (also mode-I) rupturing in rock from the view of fracture mechanics. Counter-intuitively, the fracturing surface of the rock sheet had an angle (approximately 25°) to the loading direction (i.e., the orientation of the maximum principal compressive stress). The rupture behavior was controlled by the relationship between the load and the geometric boundary of the rock. It is found that the fracturing surface can suddenly and rapidly propagate after a certain strike by calculating the energies of the rock sheet. The striking energy could be converted into elastic strain energy, which accumulates in a very-slightly bent rock sheet step by step until exceeds the bearing limit of rock sheet. Most of the stored elastic strain energy was subsequently released in the form of splitting energy, leading to rock fracturing. This study provides insights into the occurrence of tectonic earthquakes.

Hole Polaron-Mediated Suppression of Electron-Hole Recombination Triggers Efficient Photocatalytic Nitrogen Fixation.

In the pursuit of successful photocatalytic transformations, challenges persist due to limitations in charge carrier utilization and transfer efficiency, which stemming from rapid recombination. Overcoming these limitations necessitates the exploration of novel mechanisms that enhance the effective separation of photogenerated electron-hole pairs. Herein, deviating from the conventional approach of enhancing carrier migration to separate photogenerated charges and extend their lifetime, the proposal is to directly prevent the recombination of photogenerated electrons and holes by forming hole polarons. Specifically, disordered pores are introduced on the surface of KTaO3 ultrathin sheets, and the clear-cut evidences in electron paramagnetic resonance, photoluminescence, and ultrafast spectroscopy unambiguously confirm the enhanced carrier-phonon coupling, which results in the formation of hole polarons to impede the recombination of photogenerated electron-hole pairs. Taking the challenging nitrogen oxidation reaction as an example, it is found that the hole polarons in atomic-disordered pore KTaO3 ultrathin nanosheets trigger outstanding photo-oxidation performance of nitrogen (N2)to nitrate, with a nitrate-producing rate of 2.1 mg g-1 h-1. This scenario is undoubtedly applicable to a wide variety of photocatalytic reactions due to the common challenge of charge carrier recombination in all photocatalytic processes, manifesting broad implications for promoting photocatalysis performance.

Corrosion shielding effect of polyaluminium sulphate on metallic aluminium during the solidification of radioactive incineration bottom ash by low alkalinity cement

Radioactive incineration bottom ash containing metallic Al is difficult to be directly solidified in the cement matrix due to the generation of hydrogen gas during the reaction of aluminium with alkali pore solution of cement paste. In this study, the simulated incineration bottom ash (SIBA) containing metallic Al was successfully and directly solidified by polyaluminium sulphate (PAS)-modified low alkalinity cement (LAC), and the mechanism of the corrosion shielding effect of PAS on metallic Al was characterized by a range of analytical techniques. The results indicate that the cement waste form containing 29.56 wt% SIBA achieved a compressive strength of 16.6 MPa at 28 days of hydration, which increased by 13.3 % and 36.1 % after freeze-thawing test and immersion test, respectively. The 42d cumulative fraction leached of Nd3+ and Ce3+ were 1.74×10−7 cm and 3.40×10−7 cm, respectively. The corrosion degree and corrosion rate of Al sheets in LAC with PAS addition was much lower than that without PAS at early and late age hydration, by transforming thick porous corrosion layer to thin dense one. The mineral phase of corrosion product remained as bayerite (Al(OH)3), regardless of whether PAS was added. The addition of PAS reduced the hydrogen gas generation and prevented the dissolution of Al(OH)4- from metallic Al sheet. The hydrolysis of PAS produced a large amount of Al(OH)4- in pore solution, which extended the pH range for Al(OH)3 passivation by preventing the transformation of Al(OH)3 protection layer on the Al sheet surface to Al(OH)4- in the pore solution, and accelerated the formation of ettringite to decrease the pH of pore solution. This study cast the light on the direct solidification of metallic-aluminium-containing incineration bottom ash or Al bulks by cement-based materials without the need for complex pretreatment processes.

The Effects of Botulinum Toxin Type A on the Biological Behavior of Fibroblasts on Silicone Implants.

Capsular contracture is one of the most severe complications following breast augmentation surgery. It has been reported that botulinum toxin Type A (BTX-A) can inhibit capsular contracture, but the exact mechanisms remain unclear. Therefore, this study aims to explore the potential mechanisms behind BTX-A's inhibition of capsular contracture by observing its effects on the biological behavior of fibroblasts and its impact on the TGF-β/Smad signaling pathway. In vitro experiments involved culturing fibroblasts on PDMS surfaces, subsequently treating them with various concentrations of BTX-A. Fibroblast proliferation activity was assessed using the CCK-8 assay, while the migration and cytoskeletal morphology of the fibroblasts were meticulously examined. ELISA was utilized to quantify the expression of fibrosis-related cytokines. Gene and protein expressions related to the TGF-β/Smad pathway were analyzed through real-time PCR and Western blotting techniques. BTX-A moderately enhanced the early proliferation and migration of fibroblasts on the surface of PDMS silicone sheets and reduced the synthesis of collagen types I and III. Furthermore, under the influence of BTX-A, the expression of TGF-βR2 and α-SMA in the TGF-β/Smad pathway was significantly inhibited. This study demonstrates that BTX-A can inhibit fibroblast differentiation by downregulating the expression of TGF-βR2, thereby suppressing the TGF-β/Smad pathway. This suggests a possible mechanism through which BTX-A mitigates capsular contracture. This journal requires that authors assign a level of evidence to each submission to which Evidence-Based Medicine rankings are applicable. This excludes Review Articles, Book Reviews, and manuscripts that concern Basic Science, Animal Studies, Cadaver Studies, and Experimental Studies. For a full description of these Evidence-Based Medicine ratings, please refer to the Table of Contents or the online Instructions to Authors www.springer.com/00266 .