Surface Nitrate Research Articles

Wintertime productivity and carbon export potential across the Agulhas Current system

The Agulhas Current plays a major role in heat and salt exchange between the Indian and Atlantic Oceans, yet little is known of its influence on ocean fertility. To investigate carbon production and export potential in the Agulhas Current system, we measured net primary production (NPP), nitrate and ammonium uptake, N2 fixation, and nitrification along a transect of the current and adjacent subtropical subgyre (33.4°S–35.7°S) in winter when nutrient supply, and thus productivity, should be highest. Phytoplankton biomass was lowest in the current core, increasing into the subgyre as surface nitrate declined, and was dominated by nanoplankton (2.7–10 μm; 62 ± 5.1% of total biomass). NPP and nitrate uptake were generally high across the transect and increased from the current core into the subgyre; the rates were dominated by picoplankton (<2.7 μm; 53–93%) in the current core and nanoplankton elsewhere (63–69%). On average, euphotic zone nitrification supplied 7.6 ± 6.4% of the nitrate consumed by phytoplankton and N2 fixation was also low (2.1 ± 1.3% of new production); we thus consider nitrate uptake a reasonable proxy for new production, at least in winter. Nitrate uptake was highest at the southern edge of the current core, consistent with current-associated (sub)mesoscale mixing enhancing the upward nutrient supply. The fraction of NPP available for export (i.e., the f-ratio) was high across the transect, ranging from 0.44 to 0.69. Our data thus indicate that both total and new production are elevated across the Agulhas Current system in winter and suggest that the (sub)mesoscale dynamics associated with the current system may enhance carbon production and export in the otherwise oligotrophic southwest Indian Ocean.

High Frequency Monitoring and Nitrate Sourcing Reveals Baseflow and Stormflow Controls on Total Dissolved Nitrogen and Carbon Export Along a Rural‐Urban Gradient

AbstractEfforts to reduce nitrogen and carbon loading from developed watersheds typically target specific flows or sources, but across gradients in development intensity there is no consensus on the contribution of different flows to total loading or sources of nitrogen export. This information is vital to optimize management strategies leveraging source reductions, stormwater controls, and restorations. We investigate how solute loading and sources vary across flows and land‐use using high frequency monitoring and stable nitrate isotope analysis from five catchments with different sanitary infrastructure, along a gradient in development intensity. High frequency monitoring allowed estimation of annual loading and attribution to storm versus baseflows. Nitrate loads were 16 kg/km2/yr. from the forested catchment and ranged from 68 to 119 kg/km2/yr., across developed catchments, highest for the septic served site. Across developed catchments, baseflow contributions ranged from 40% of N loading to 75% from the septic served catchment, and the contribution from high stormflows increased with development intensity. Stormflows mobilized and mixed many surface and subsurface nitrate sources while baseflow nitrate was dominated by fewer sources which varied by catchment (soil, wastewater, or fertilizer). To help inform future sampling designs, we demonstrate that grab sampling and targeted storm sampling would likely fail to accurately predict annual loadings within the study period. The dominant baseflow loads and subsurface stormflows are not treated by surface water management practices primarily targeted to surface stormflows. Using a balance of green and gray infrastructure and stream/riparian restoration may target specific flow paths and improve management.

Influence of altered freshwater discharge on the seasonality of nutrient distributions near La Grande River, northeastern James Bay, Québec

In subarctic marine environments, nutrient stocks are replenished through physical and biogeochemical processes in winter, largely setting an upper limit on new primary production for the next growing season. In spring, marine nutrient stocks are modified by freshwater-associated additions, especially in coastal areas. Hydroelectric development of the La Grande River (LGR) in northern Québec has shifted the timing of peak freshwater discharge from spring into winter, producing 10 times the natural winter discharge. Here, we considered salinity, oxygen isotope ratio (δ18O), and nutrient (nitrate, phosphate) data from coastal waters of northeast James Bay in different seasons of 2016 and 2017. We quantified two main freshwater sources, LGR and sea-ice melt, established by freshwater tracers, and their influence on coastal nutrient distributions. Our results show that LGR is the dominant source of freshwater to coastal waters throughout the year, especially during winter, and an important source of nitrate to nitrogen-limited coastal waters (winter concentrations of 4.53 μM versus 3.18 μM in ambient seawater). Despite being a poor phosphate source (0.11 μM versus 0.66 μM in ambient seawater), LGR provides the largest portion of the phosphate stock in surface waters near its mouth. LGR regulation has changed the pattern of natural fluvial nitrate inputs: what was observed in spring (pre-development) is now observed in winter (post-development). Thus, high winter surface nitrate stocks (22.5 mmol m−2) are available to support primary production, but are dispersed to offshore areas prior to the onset of the growing season, which begins only after the return of light. In northeast James Bay, the timing and magnitude of primary production, dependent on nutrients in the water column, is expected to have been impacted by altered freshwater input, reducing overall production in local areas and potentially increasing production further downstream with cascading effects on the marine ecosystem.

Satellite observed oceanographic drivers of Mobulidae fisheries catch in the Southeast Indian Ocean

Indonesian coastal waters include several marine megafauna biodiversity hotspots. Several fish populations of ecological and socio-economic importance, such as elasmobranchs (sharks and rays), have experienced rapid decline due to unsustainable human activities, primarily overfishing. Small-scale fisheries (SSF) are currently exempt from governmental fisheries management measures despite contributing a significant proportion of a total catch. The Generalised Additive Models were used to investigate the effect of variations in oceanographic parameters of the Teluk Penyu fishing ground, south of central Java, on the magnitude of Mobulidae (Mobula spp.) catch based on its landings data over ten years (2009–2018) from one of Indonesia's largest ports, Cilacap, Central Java, Indonesia. Mobulidae catch from Teluk Penyu fishing ground was generally higher from June to November when the water exhibited relatively high sea surface salinity (sal >34.1 ‰), chlorophyll (0.32–0.45 mg/m3), and nitrate (nit >0.0045 mg NO3/m3), water speed (>0.29 m/s) and eddy kinetic energy (>0.04 m3/s2) levels, and relatively low sea surface temperature (<28 °C), oxygen (<0.182 mg O2/m3) and sea surface height (<0.9 m) levels than the other months of the year. This study reveals that satellite Earth Observation (EO) data provided a preliminary relationship between oceanographic conditions and the amount of catch for developing more effective management and conservation measures for endangered species like Mobulidae. Utilizing EO data may also be applied to help inform much-needed ecosystem-based management measures, including habitat protection and bycatch reduction for conserving endangered Mobulidae species in the Southeast Indian Ocean. The in-situ onboard ocean observation and temporal species-specific catch data will greatly complement the current work.

Catalytic Ozonation of Low Concentration Toluene over MnFeOx-USY Catalyst: Effects of Interactions between Catalytic Components and Introduction of Gas Phase NOx.

A series of Mn and Fe metal oxide catalysts loaded onto USY, as well as single metal oxides, were prepared and characterized. The effects of interactions between the catalytic components and the introduction of gas phase NO on the catalytic ozonation of toluene were investigated. Characterization showed that there existed strong interactions between MnOx, FeOx, and USY, which enhanced the content of oxygen vacancies and acid sites of the catalysts and thus boosted the generation of reactive oxygen species and the adsorption of toluene. The MnFeOx-USY catalyst with MnOx and FeOx dimetallic oxides exhibited the most excellent performance of catalytic ozonation of toluene. On the other hand, the presence of NOx in reaction gas mixtures significantly promoted both toluene conversion and mineralization, which was attributed to the formation of nitrate species on the catalysts surface and thus the increase of both acid sites and toluene oxidation sites. Meanwhile, the reaction mechanism between O3 and C7H8 was modified in which the strong interactions between MnOx, FeOx, and USY accelerated the reaction progress based on the L-H route. In addition, the formation of the surface nitrate species not only promoted reaction progress following the L-H route but also resulted in the occurrence of the reaction via the E-R route.

Unveiling seasonal nitrate contamination dynamics in cropland sub-watersheds: A geo-morphological analysis of the bilate agricultural watershed

Cropland sub-watershed surface and groundwater contamination are pressing issues for water management. This study examines the impact of sediment transport indices (STI) on nitrate concentration in downstream water bodies. The research highlights rainfall's significant role in predicting seasonal nitrate levels. Employing GIS-SWPT tools and hydro-geomorphologic analysis, cropland sub-watersheds, particularly sub-watersheds one and three, are prioritized for their high contribution to downstream surface and groundwater nitrate contamination, with prioritization values of 105.58 and 180.63, respectively. Statistical analysis, conducted using Python's scikit-learn library, validated the findings of the study, with the model's F-statistic of 79.63 and a corresponding p-value of 0.0147 underscoring its overall significance. However, while STI alone showed a prioritization parametric correlation coefficient of 0.5077, suggesting other external factors also contribute to nitrate loading, a strong relationship between STI and nitrate concentration was revealed (R² of 0.993). This integrated approach enhances understanding of how geomorphologic parameters of cropland sub-watersheds influence water quality downstream. By clarifying the complex interactions between sediment transport and nitrate concentration, evidence-based strategies can be developed to mitigate surface and groundwater nitrate pollution. This research provides valuable insights into cropland sub-watershed pollution dynamics and informs targeted management interventions.

Phytoplankton biomass responses to a marine heat wave align with altered nitracline depth

AbstractThe 2014–2015 warm anomaly (aka “the Blob”), the largest of periodic and intensifying marine heat wave (MHW) perturbations in the northeast Pacific, may provide some insight about the future warmer ocean. Here, we use mixed‐layer carbon estimates for total phytoplankton, major size classes and functional groups from 45 CalCOFI cruises to: (1) compare 2014–2015 MHW impacts in the southern California Current System to baseline estimates from 2004 to 2013 and (2) to test a space‐for‐time exchange hypothesis that links biomass structure to variability of nitracline depth (NCD). Seasonal and inshore‐offshore analyses from nine stations revealed almost uniform 2°C MHW warming extending 700 km seaward, fourfold to sixfold declines in nitrate concentration and 18‐m deeper NCDs. Phytoplankton C decreased 16–21% compared to 45–65% for Chl a, with the threefold difference due to altered C : Chl a. Among size classes, percent composition of nanoplankton decreased and picophytoplankton increased, driven by higher Prochlorococcus biomass, while Synechococcus and picoeukaryotes generally declined. Diatom and dinoflagellate C decreased in both onshore and offshore waters. Seasonally, the MHW delayed the normal winter refresh of surface nitrate, resulting in depressed stocks of total phytoplankton and nanoplankton, Synechococcus and picoeukaryotes during winter. Consistent with the space‐for‐time hypothesis, biomass variations for baseline and MHW cruises followed similar (not significantly different) slope relationships to NCD. All biomass components, except Prochlorococcus, were negatively related to NCD, and community biomass structure realigned according to regression slopes differences with NCD variability. Empirically derived biomass‐NCD relationships could be useful for calibrating models that explore future food‐web impacts in this coastal upwelling system.

Lateral redox variability in ca. 1.9 Ga marine environments indicated by organic carbon and nitrogen isotope compositions.

The stepwise oxygenation of Earth's surficial environment is thought to have shaped the evolutionary history of life. Microfossil records and molecular clocks suggest eukaryotes appeared during the Paleoproterozoic, perhaps shortly after the Great Oxidation Episode at ca. 2.43 Ga. The mildly oxygenated atmosphere and surface oceans likely contributed to the early evolution of eukaryotes. However, the principal trigger for the eukaryote appearance and a potential factor for their delayed expansion (i.e., intermediate ocean redox conditions until the Neoproterozoic) remain poorly understood, largely owing to a lack of constraints on marine and terrestrial nutrient cycling. Here, we analyzed redox-sensitive element contents and organic carbon and nitrogen isotope compositions of relatively low metamorphic-grade (greenschist facies) black shales preserved in the Flin Flon Belt of central Canada to examine open-marine redox conditions and biological activity around the ca. 1.9 Ga Flin Flon oceanic island arc. The black shale samples were collected from the Reed Lake area in the eastern part of the Flin Flon Belt, and the depositional site was likely distal from the Archean cratons. The black shales have low Al/Ti ratios and are slightly depleted in light rare-earth elements relative to the post-Archean average shale, which is consistent with a limited contribution from felsic igneous rocks in Archean upper continental crust. Redox conditions have likely varied between suboxic and euxinic at the depositional site of the studied section, as suggested by variable U/Al and Mo/Al ratios. Organic carbon and nitrogen isotope compositions of the black shales are approximately -23‰ and +13.7‰, respectively, and these values are systematically higher than those of broadly coeval continental margin deposits (approximately -30‰ for δ13Corg and +5‰ for δ15Nbulk). These elevated values are indicative of high productivity that led to enhanced denitrification (i.e., a high denitrification rate relative to nitrogen influx at the depositional site). Similar geochemical patterns have also been observed in the modern Peruvian oxygen minimum zone where dissolved nitrogen compounds are actively lost from the reservoir via denitrification and anammox, but the large nitrate reservoir of the deep ocean prevents exhaustion of the surface nitrate pool. Nitrogen must have been widely bioavailable in the ca. 1.9 Ga oceans, and its supply to upwelling zones must have supported habitable environments for eukaryotes, even in the middle of oceans around island arcs.

Mechanistic insights and application potentials for CeO2-Al2O3 passive NOx adsorber (PNA) materials

A series of CeO2/Al2O3 with Ce loading from 0.5 to 5.0 wt% were studied as PNA materials for low temperature NOx abatement. Via XRD, TEM imaging and UV–vis spectroscopy studies, it was demonstrated that CeO2 is present as nanoparticles on the Al2O3 support, and the particle size increases with increasing Ce loading. PNA performance of these materials was investigated by NOx trapping followed by TPD. The PNA chemistry was further probed with in situ NO-DRIFT spectroscopy. PNA chemistry involves a rapid direct NO trapping route that leads to surface nitrite formation, and a slower NO2 trapping route that leads to surface nitrate species. Surface nitrite decomposition releases NO at 200–300 °C, suitable for PNA application. Based on NO yields during TPD, the atomic efficiency of surface Ce was calculated, which demonstrates that dispersing CeO2 on high surface area supports is a viable strategy for improving PNA efficiency of CeO2-based materials.

Sedimentary Organic Nitrogen Isotopic Constraints on the Mid‐Holocene Transition in the Nitrogen Dynamics of the Northern South China Sea

AbstractMillennial‐scale nitrogen (N) cycling processes in marginal seas and their response to climate change have not been well understood. Here, we present high‐resolution (ca. 110 years) organic nitrogen isotope (δ15Norg) data since the last deglaciation (16.1 ka) derived from a highly resolved sediment core in the northern South China Sea, aiming to explore millennial‐scale N cycling processes in this area. Unlike most bulk nitrogen isotope (δ15Nbulk) records from the South China Sea, the δ15Norg records show a clear response to well‐defined climatic episodes during the last deglaciation and early Holocene (EH, ∼11.7 to 9 ka), but exhibit a gradually decreasing trend in mid‐to‐late Holocene (since ca. 9 ka). During the last deglaciation and EH, the upper water column N dynamics are controlled by the lateral transport of surface nitrate from eastern tropical Pacific (ETP) presumably via the North Pacific Intermediate Water (NPIW) and to some extent, influenced by the altered input of terrigenous matter driven by sea level change. The significant decrease in δ15Norg since the mid‐Holocene (at ca. 9 ka) can be best explained by the increase in local N2 fixation forced by enhanced El Niño. This mechanism is consistent with modern observations. Overall, our results may reflect the main controlling factors of surface ocean N dynamics have shifted from zonal transport of nitrate from the ETP to El Niño since the mid‐Holocene.

Effect of SO2 and SO3 Exposure to Cu-CHA on Surface Nitrate and N2O Formation for NH3-SCR.

We report effects of SO2 and SO3 exposure on ammonium nitrate (AN) and N2O formation in Cu-CHA used for NH3-SCR. First-principles calculations and several characterizations (ICP, BET, XRD, UV-vis-DRS) were applied to characterize the Cu-CHA material and speciation of sulfur species. The first-principles calculations demonstrate that the SO2 exposure results in both (bi)sulfite and (bi)sulfate whereas the SO3 exposure yields only (bi)sulfate. Furthermore, SOx adsorption on framework-bound dicopper species is shown to be favored with respect to adsorption onto framework-bound monocopper species. Temperature-programmed reduction with H2 shows two clear reduction states and larger sulfur uptake for the SO3-exposed Cu-CHA compared to the SO2-exposed counterpart. Temperature-programmed desorption of formed ammonium nitrate (AN) highlights a significant decrease in nitrate storage due to sulfur species interacting with copper sites in the form of ammonium/copper (bi)bisulfite/sulfate. Especially, highly stable sulfur species from SO3 exposure influence the NO2-SCR chemistry by decreasing the N2O selectivity during NH3-SCR whereas an increased N2O selectivity was observed for the SO2-exposed Cu-CHA sample. This study provides fundamental insights into how SO2 and SO3 affect the N2O formation during ammonium nitrate decomposition in NH3-SCR applications, which is a very important topic for practical applications.

Projected impacts of global warming scenarios on marine ecosystems: Insights from the CMIP6 model

Rising oceanic temperatures and increased heat content have triggered a decline in marine biodiversity and the degradation of ecosystem services. This study employs the Coupled Model Intercomparison Project Phase 6 (CMIP6) to analyze variables within the Nutrient-Phytoplankton-Zooplankton-Detritus (NPZD) framework. Focusing on two contrasting Shared Socioeconomic Pathways (SSPs) - SSP1-2.6 (low-warming scenario) and SSP5-8.5 (high-warming scenario) - we assess future impacts of climate-related factors on marine ecosystems across major oceanic regions. Under the high-warming SSP5-8.5 scenario, global ocean temperature rise, coupled with declining surface pH levels, nitrate concentrations, and plankton biomass/productivity, is evident. Regional reductions in plankton biomass/productivity, especially pronounced at higher latitudes, are observed in both SSP scenarios. Nutrient cycling emerges as a pivotal factor influencing plankton communities, particularly ammonium regulation in the Southern Ocean. This research emphasizes the urgent need to curb greenhouse gas emissions to mitigate global warmings profound effects on marine ecosystems.

Surface snow bromide and nitrate at Eureka, Canada, in early spring and implications for polar boundary layer chemistry

Abstract. This study explores the role of snowpack in polar boundary layer chemistry, especially as a direct source of reactive bromine (BrOx = BrO + Br) and nitrogen (NOx = NO + NO2) in the Arctic springtime. Surface snow samples were collected daily from a Canadian high Arctic location at Eureka, Nunavut (80° N, 86° W) from the end of February to the end of March in 2018 and 2019. The snow was sampled at several sites representing distinct environments: sea ice, inland close to sea level, and a hilltop ∼ 600 m above sea level (a.s.l.). At the inland sites, surface snow salinity has a double-peak distribution with the first and lowest peak at 0.001–0.002 practical salinity unit (psu), which corresponds to the precipitation effect, and the second peak at 0.01–0.04 psu, which is likely related to the salt accumulation effect (due to loss of water vapour by sublimation). Snow salinity on sea ice has a triple-peak distribution; its first and second peaks overlap with the inland peaks, and the third peak at 0.2–0.4 psu is likely due to the sea water effect (a result of upward migration of brine). At all sites, snow sodium and chloride concentrations increase by almost 10-fold from the top 0.2 to ∼ 1.5 cm. Surface snow bromide at sea level is significantly enriched, indicating a net sink of atmospheric bromine. Moreover, surface snow bromide at sea level has an increasing trend over the measurement period, with mean slopes of 0.024 µM d−1 in the 0–0.2 cm layer and 0.016 µM d−1 in the 0.2–0.5 cm layer. Surface snow nitrate at sea level also shows a significant increasing trend, with mean slopes of 0.27, 0.20, and 0.07 µM d−1 in the top 0.2, 0.2–0.5, and 0.5–1.5 cm layers, respectively. Using these trends, an integrated net deposition flux of bromide of (1.01 ± 0.48) × 107 molec.cm-2s-1 and an integrated net deposition flux of nitrate of (2.6 ± 0.37) × 108 molec.cm-2s-1 were derived. In addition, the surface snow nitrate and bromide at inland sites were found to be significantly correlated (R = 0.48–0.76) with the [NO3-]/[Br-] ratio of 4–7 indicating a possible acceleration effect of reactive bromine in atmospheric NOx-to-nitrate conversion. This is the first time such an effect has been seen in snow chemistry data obtained with a sampling frequency as short as 1 d. BrO partial column (0–4 km) data measured by MAX-DOAS show a decreasing trend in early spring, which generally agrees with the derived surface snow bromide deposition flux indicating that bromine in Eureka atmosphere and surface snow did not reach a photochemical equilibrium state. Through mass balance analysis, we conclude that the average release flux of reactive bromine from snow over the campaign period must be smaller than the derived bromide deposition flux of ∼ 1 × 107 molec.cm-2s-1. Note that the net mean fluxes observed do not completely rule out larger bidirectional fluxes over shorter timescales.

The impact of lake discontinuities on nitrogen biogeochemistry in river networks

ABSTRACT River networks connect terrestrial and marine ecosystems through transport of pollutants and nutrients. Lakes represent discontinuities within these river networks and can be important biogeochemical hotspots, introducing substantial changes to the aquatic environment. Nitrogen (N) is a key macronutrient that can potentially limit or colimit primary production, but the processes that determine the fate of N during transport through river–lake networks are poorly understood. We studied 3 river systems and their lake discontinuities, spanning a range of trophic states and average water residence times, to understand the changes introduced to riverine N biogeochemistry by lake discontinuities. In-lake processes noticeably altered the concentration and speciation of N. Annually, lakes reduced up to 44% of nitrate compared to main inflow concentrations while the variability in nitrate dynamics was seasonally large. The drawdown in surface nitrate concentrations resulted at times in phytoplankton colimitation by N in the lake as well as in the downstream river, where altered N patterns could persist for several kilometres. However, lakes occasionally subsidized N to downstream rivers as ammonium or dissolved organic N. Assimilation of nitrate in lake surface waters was one of the dominant processes impacting N availability; however, stable isotope data revealed an unexpected contribution of nitrification to N cycling in the epilimnion throughout the year and across trophic gradients. These changes in N concentration, as well as speciation introduced by lake discontinuities, have potentially important consequences for the composition and metabolism of communities in downstream rivers and contribute to our fundamental understanding of freshwater processes.

Assessing Nitrate Leaching and Runoff Coefficients in the Dynamic Interplay of Seasonal Crop Biomass: A Study of Surface and Groundwater Nitrate Contamination in the Bilate Cropland Watershed

Effective water resource management and sustainable agricultural practices are contingent upon a thorough understanding of nitrate dynamics. This study investigates the utilization of seasonal average cropland runoff observations to improve the prediction accuracy of nitrate runoff loads to surface water originating from cropping zones. By integrating data from various sources, including seasonal rainfall/runoff observations and cropland parameters, the study explores the complex relationship between crop biomass growth, nitrogen fertilizer application, and seasonal rainfall over cropland. Monthly average observations of cropping zone rainfall/runoff in the cropping zone are analyzed to understand the response of seasonal crop biomass to nitrogen fertilizer application and seasonally calibrated rainfall/runoff in the cropland watershed. The study demonstrates the prototypical runoff observation from cultivated areas and statistically estimates seasonal runoff at downstream stream outlets. This shows a strong correlation with an R² of 0.9742 with a p-value less than 0.001 for seasonal rainfall climate parameters. Seasonal cropland runoff observations from EWX lite are presented for model calibration at downstream outlets, based on regional crop calendars, facilitating the estimation of nitrate loading to surface water and nitrate contamination from cropping zones. The findings reveal distinct cropping zones, particularly zones 5, 6, 11, and 13, which significantly contribute, each exceeding 50 mg/l of leaching load to groundwater. Moreover, more than ten zones surpass the threshold of 50mg/l in nitrate loading to surface water. These quantitative insights provide valuable spatial information regarding nitrate runoff relationships within the watershed, enabling the identification of specific zones with heightened nitrate contributions and offering actionable solutions for promoting sustainable agriculture and refining water resource management strategies.

Spatial and temporal variation in surface nitrate and phosphate in the Northern Gulf of Mexico over 35 years

Dissolved inorganic nutrient concentrations in the surface waters (0 to 5 m) of the Northern Gulf of Mexico (NGoM) were analyzed from 1985 to 2019 (> 10,000 observations) to determine spatiotemporal trends and their connection to nutrients supplied from the Mississippi/Atchafalaya River (MAR). In the NGoM, annual mean dissolved inorganic P (DIP) concentrations increased significantly over time, while dissolved inorganic N (DIN) concentrations showed no temporal trend. With greater salinity, mean DIN:DIP decreased from above the Redfield ratio of 16 to below it, reflecting DIN losses and the more conservative behavior of DIP with salinity. Over the same time period, annual mean P (total dissolved P, DIP, dissolved organic P) loading from the MAR to the NGoM significantly increased, annual mean DIN and total dissolved N loading showed no temporal trend, and dissolved organic N loading significantly decreased. Though DIP increased in the MAR, MAR DIP alone was insufficient to explain the surface distribution of DIP with salinity. Therefore, increases in surface DIP in the NGoM are not simply a reflection of increasing MAR DIP, pointing to temporal changes in other DIP sources. The increase in NGoM DIP suggests greater N limitation for phytoplankton, with implications for N fixation and nutrient management.

Modeling canopy water content in the assessment for rainfall induced surface and groundwater nitrate contamination: The Bilate cropland sub watershed

Nitrate contamination in surface and groundwater remains a widespread problem in agricultural watersheds is primarily associated to high levels of percolation or leakage from fertilized soil, which allows easy infiltration from soil into groundwater. This study was aimed to predict canopy water content to determine the nitrate contamination index resulting from nitrogen fertilizer loss in surface and groundwater. The study used Geographically Weighted Regression (GWR) model using MODIS 006 MOD13Q1-EVI Earth observation data, crop information and rainfall data. Satellite data collection was synchronized with regional crop calendars and calibrated to plant biomass. The average plant biomass during observed plant growth stages was between 0.19 kg/m2 at the minimum and 0.57 kg/m2 at the maximum. These values are based on the growth stages of crops and provide a solid basis for monitoring and validating crop water productivity data. The simulation results were validated with a high correlation coefficient (R2 = 0.996, P < 0.0005) for the observed rainfall in the growing zone compared to the predicted canopy water content. The nitrate contamination index assessment was conducted in 2004, 2008, 2009, 2010, 2011, 2013, 2014, 2015, 2018 and 2020. Canopy water content and root zone seasonal water content were measured in (%) per portion as indicators of the NO−3-N-nitrate contamination index in these years (0.391, 0.316, 0.298, 0.389, 0.380, 0.339, 0.242, 0.342 and 0.356).

Remote Estimates of Sea Surface Nitrate and Its Trends From Ocean Color in the Northwest Pacific

AbstractSea surface nitrate (SSN) plays an important role in assessing new production and phytoplankton growth in the ocean, yet it has been challenging to estimate SSN from satellites due to its complex and varying relationship with different environmental proxies. The different SSN trends in the northwest Pacific reported in previous studies call for more detailed research to examine the interannual variabilities in SSN. We addressed this problem by developing a stacking‐random‐forest based algorithm for Moderate Resolution Imaging Spectroradiometer (MODIS). It allows estimating SSN from daily sea surface temperature (SST) and Chlorophyll‐a concentration (Chl) at a spatial resolution of 4 km. For SSN ranging between 0.0005 and 25.88 μmol/kg (N = 3,452), the model had a root mean square difference of 1.34 μmol/kg (5.3%) and coefficient of determination of 0.92. Further independent validation and sensitivity tests demonstrated the validity of the algorithm in retrieving SSN. Using this novel data record, for the first time, we investigated the SSN interannual variabilities and trends from MODIS. Overall, the SSN showed a weak decreasing trend of −0.01 ± 0.007 μmol kg−1 yr−1 (p &lt; 0.05) in the northwest Pacific in 2002–2020, associated with an increasing trend in SST (0.03 ± 0.01˚C yr−1 at p &lt; 0.05) and insignificant trend (0.001 ± 0.001 mg m−3 yr−1 at p &gt; 0.05) in Chl. The interannual variabilities of SSN were significantly correlated with the environmental proxies (SST, Chl) and the climate indices (Pacific Decadal Oscillation and North Pacific Gyre Oscillation). The SSN trends can be further restricted with more data available.

Estimating Surface Nitrate Concentrations in the Coastal Areas of the Around Savu Sea and Southern Sumba Island Based on Remote Sensing Data

Nitrate is an essential nutrient in phytoplankton's photosynthesis process. In addition, phytoplankton uses nitrate for their growth and reproduction. Nitrate abundance on the coast will affect primary productivity and biogeochemical cycles. The availability of nitrate observation data, especially around the Savu Sea coast, is minimal. In this study, the estimation of nitrate in the coastal area of the southern part of Sumba Island and the eastern part of Savu Island by using the generalized additive model (GAM). Seventy-one nitrate observation data were used to build the GAM model, and remote sensing data were used as input data for nitrate estimation. Sea Surface Temperature (SST) and chlorophyll-a data were obtained from Aqua-MODIS. Sea Surface Salinity (SSS) and Sea Surface Windspeed (SSW) data were obtained from a Microwave Imaging Radiometer with Aperture Synthesis (MIRAS) Soil Moisture-Ocean Salinity (SMOS), and Advanced Scatterometer (ASCAT), respectively. This study uses the Generalized Additive Model (GAM) approach to predict the distribution of nitrate concentrations and determine the main driving factors associated with nitrate. Based on the result, temperature is the dominant factor in nitrate estimation, while chlorophyll-a has a relatively small influence. The best model to predict nitrate distribution uses four parameters, namely SST, SSS, SSW, and chlorophyll-a. The validation results of the expected nitrate value obtained from the model with the observed nitrate value obtained results with the same value range of 0 - 0.35; the difference is the value of the distribution. From the comparison results, the R2 value is 0.357.

Including land management in a European carbon model with lateral transfer to the oceans

The use of cover crops (CCs) is a promising cropland management practice with multiple benefits, notably in reducing soil erosion and increasing soil organic carbon (SOC) storage. However, the current ability to represent these factors in land surface models remains limited to small scales or simplified and lumped approaches due to the lack of a sediment-carbon erosion displacement scheme. This precludes a thorough understanding of the consequences of introducing a CC into agricultural systems. In this work, this problem was addressed in two steps with the spatially distributed CE-DYNAM model. First, the historical effect of soil erosion, transport, and deposition on the soil carbon budget at a continental scale in Europe was characterized since the early industrial era, using reconstructed climate and land use forcings. Then, the impact of two distinct policy-oriented scenarios for the introduction of CCs were evaluated, covering the European cropping systems where surface erosion rates or nitrate susceptibility are critical. The evaluation focused on the increase in SOC storage and the export of particulate organic carbon (POC) to the oceans, compiling a continental-scale carbon budget. The results indicated that Europe exported 1.95 TgC/year of POC to the oceans in the last decade, and that CCs can contribute to reducing this amount while increasing SOC storage. Compared to the simulation without CCs, the additional rate of SOC storage induced by CCs peaked after 10 years of their adoption, followed by a decrease, and the cumulative POC export reduction stabilized after around 13 years. The findings indicate that the impacts of CCs on SOC and reduced POC export are persistent regardless of their spatial allocation adopted in the scenarios. Together, the results highlight the importance of taking the temporal aspect of CC adoption into account and indicate that CCs alone are not sufficient to meet the targets of the 4‰ initiative. Despite some known model limitations, which include the lack of feedback of erosion on the net primary productivity and the representation of carbon fluxes with an emulator, the current work constitutes the first approach to successfully couple a distributed routing scheme of eroded carbon to a land carbon model emulator at a reasonably high resolution and continental scale. Short abstractA spatially distributed model coupling erosion, transport, and deposition to the carbon cycle was developed. Then, it was used to simulate the impact of cover crops on both erosion and carbon, to show that cover crops can simultaneously increase organic carbon storage and reduce particulate organic carbon export to the oceans. The results seemed persistent regardless of the spatial distribution of cover crops.