Altimetry missions designed for ocean monitoring can also evaluate the Antarctic ice sheet’s mass balance by measuring surface height. However, the returned radar echoes (waveforms) have complex shapes influenced by various snow and ice surface properties at multiple scales. Radar altimeters, operating in different modes and frequencies, interact with these surface properties in diverse ways. In this study, we developed a method to assess Antarctic surface properties using data from SARAL/AltiKa and Sentinel-3A & 3B altimeters for June 2021 and January 2023, respectively. We normalized and averaged the observed waveforms in 5 × 5 km2 grid cells. These were then used to create false-color images, with each grid cell’s average power and time gate represented as different ‘bands’. False-color images were analyzed using Principal Component Analysis (PCA) and ISODATA unsupervised classification to identify regions of Antarctica with similar surface properties. We achieved a percent variance of 73% and 84% for the first three Principal Components (PCs), and 96% and 98% for the first ten PCs with the Sentinel-3 and SARAL/AltiKa datasets, respectively. Finally, we analyzed the Ka and Ku band altimeter waveform shapes for each identified class to better understand snow and ice sensitivity to waveforms.