Superfluid Clusters Research Articles

Supersolidity of α cluster structure in Ca40

$\alpha$ cluster structure in nuclei has been long understood based on the geometrical configuration picture. By using the spatially localized Brink $\alpha$ cluster model in the generator coordinate method, it is shown that the $\alpha$ cluster structure has the apparently opposing duality of crystallinity and condensation, a property of supersolids. To study the condensation aspects of the $\alpha$ cluster structure a field theoretical superfluid cluster model (SCM) is introduced, in which the order parameter of condensation is incorporated by treating rigorously the Nambu-Goldstone mode due to spontaneous symmetry breaking of the global phase. The $\alpha$ cluster structure of $^{40}$Ca, which has been understood in the crystallinity picture, is studied by the SCM with ten $\alpha$ clusters. It is found that the $\alpha$ cluster structure of $^{40}$Ca is reproduced by the SCM in addition to $^{12}$C reported in a previous paper, which gives support to the duality of the $\alpha$ cluster structure. The emergence of the mysterious $0^+$ state at the lowest excitation energy near the $\alpha$ threshold energy is understood to be a manifestation of the Nambu-Goldstone zero mode, a soft mode, due to the condensation aspect of the duality similar to the Hoyle state in $^{12}$C. The duality of $\alpha$ cluster structure with incompatible crystallinity and coherent wave nature due to condensation is the consequence of the Pauli principle, which causes clustering.

High-resolution two-dimensional electronic spectroscopy reveals the homogeneous line profile of chromophores solvated in nanoclusters

Doped clusters in the gas phase provide nanoconfined model systems for the study of system-bath interactions. To gain insight into interaction mechanisms between chromophores and their environment, the ensemble inhomogeneity has to be lifted and the homogeneous line profile must be accessed. However, such measurements are very challenging at the low particle densities and low signal levels in cluster beam experiments. Here, we dope cryogenic rare-gas clusters with phthalocyanine molecules and apply action-detected two-dimensional electronic spectroscopy to gain insight into the local molecule-cluster environment for solid and superfluid cluster species. The high-resolution homogeneous linewidth analysis provides a benchmark for the theoretical modelling of binding configurations and shows a promising route for high-resolution molecular two-dimensional spectroscopy.

Bose–Einstein condensation of dilute alpha clusters above the four-α threshold in 16O in the field theoretical superfluid cluster model

Abstract Observed well-developed $\alpha$ cluster states in $^{16}$O located above the four-$\alpha$ threshold are investigated from the viewpoint of Bose–Einstein condensation of $\alpha$ clusters by using a field-theoretical superfluid cluster model in which the order parameter is defined. The experimental energy levels are reproduced well for the first time by calculation. In particular, the observed 16.7 MeV $0_7^+$ and 18.8 MeV $0_8^+$ states with low-excitation energies from the threshold are found to be understood as a manifestation of the states of the Nambu–Goldstone zero-mode operators, associated with the spontaneous symmetry-breaking of the global phase, which is caused by the Bose–Einstein condensation of the vacuum 15.1 MeV $0^+_6$ state with a dilute well-developed $\alpha$ cluster structure just above the threshold. This gives evidence of the existence of the Bose–Einstein condensate of $\alpha$ clusters in $^{16}$O. It is found that the emergence of the energy level structure with a well-developed $\alpha$ cluster structure above the threshold is robust, almost independently of the condensation rate of $\alpha$ clusters under significant condensation rate. The finding of the mechanism that causes the level structure that is similar to $^{12}$C to emerge above the four-$\alpha$ threshold in $^{16}$O reinforces the concept of Bose–Einstein condensation of $\alpha$ clusters in addition to $^{12}$C.

Local density of the Bose-glass phase

We study the Bose-Hubbard model in the presence of on-site disorder in the canonical ensemble and conclude that the local density of the Bose glass phase behaves differently at incommensurate filling than it does at commensurate one. Scaling of the superfluid density at incommensurate filling of $\rho=1.1$ and on-site interaction $U=80t$ predicts a superfluid-Bose glass transition at disorder strength of $\Delta_c \approx 30t$. At this filling the local density distribution shows skew behavior with increasing disorder strength. Multifractal analysis also suggests a multifractal behavior resembling that of the Anderson localization. Percolation analysis points to a phase transition of percolating non-integer filled sites around the same value of disorder. Our findings support the scenario of percolating superfluid clusters enhancing Anderson localization near the superfluid-Bose glass transition. On the other hand, the behavior of the commensurate filled system is rather different. Close to the tip of the Mott lobe ($\rho=1, U=22t$) we find a Mott insulator-Bose glass transition at disorder strength of $\Delta_c \approx 16t$. An analysis of the local density distribution shows Gaussian like behavior for a wide range of disorders above and below the transition.

Bose-Einstein condensation of α clusters and new soft mode in C12 – Fe52 4N nuclei in a field-theoretical superfluid cluster model

Bose-Einstein condensation of alpha clusters in light and medium-heavy nuclei is studied in the frame of the field theoretical superfluid cluster model. The order parameter of the phase transition from the Wigner phase to the Nambu-Goldstone phase is a superfluid amplitude, square of the moduli of which is the superfluid density distribution. The zero mode operators due to the spontaneous symmetry breaking of the global phase in the finite number of alpha clusters are rigorously treated. The theory is systematically applied to N alpha nuclei from12C-52Fe at various condensation rates. In 12C it is found that the energy levels of the gas-like well-developed alpha cluster states above the Hoyle state are reproduced well in agreement with experiment for realistic condensation rates of alpha clusters. The electric E2 and E0 transitions are calculated and found to be sensitive to the condensation rates. The profound raison d'etre of the alpha cluster gas-like states above the Hoyle state, whose structure has been interpreted geometrically in the nuclear models without the order parameter such as the cluster models or ab initio calculations, is revealed. It is found that in addition to the Bogoliubov-de Gennes vibrational mode states collective states of the zero mode operators appear systematically at low excitation energies from the N alpha threshold energy. These collective states, new-type soft modes in nuclei due to the Bose-Einstein condensation of the alpha clusters, emerge systematically in light and medium-heavy mass regions and are also located at high excitation energies from the ground state in contrast to the traditional concept of soft mode in the low excitation energy region.

Ultracold bosons with cavity-mediated long-range interactions: A local mean-field analysis of the phase diagram

Ultracold bosonic atoms in optical lattices self-organize into a variety of structural and quantum phases when placed into a single-mode cavity and pumped by a laser. Cavity optomechanical effects induce an atom density modulation at the cavity-mode wavelength that competes with the optical lattice arrangement. Simultaneously short-range interactions via particle hopping promote superfluid order such that a variety of structural and quantum coherent phases can occur. We analyze the emerging phase diagram in two dimensions by means of an extended Bose-Hubbard model using a local mean-field approach combined with a superfluid cluster analysis. For commensurate ratios of the cavity and external lattice wavelengths, the Mott insulator-superfluid transition is modified by the appearance of charge density wave and supersolid phases, at which the atomic density supports the buildup of a cavity field. For incommensurate ratios, the optomechanical forces induce the formation of Bose-glass and superglass phases, namely, nonsuperfluid and superfluid phases, respectively, displaying quasiperiodic density modulations, which in addition can exhibit structural and superfluid stripe formation. The onset of such structures is constrained by the on-site interaction and is favorable at fractional densities. Experimental observables are identified and discussed.

Probing the Superfluid Response of para-Hydrogen with a Sulfur Dioxide Dopant.

We recently presented the first attempt at using an asymmetric top molecule (para-water) to probe the superfluidity of nanoclusters (of para-hydrogen) [ Zeng , T. ; Li , H. ; Roy , P.-N. J. Phys. Chem. Lett. 2013 , 4 , 18 - 22 ]. Unfortunately, para-water could not be used to probe the para-hydrogen superfluid response. We now report a theoretical simulation of sulfur dioxide rotating in para-hydrogen clusters and show that this asymmetric top can serve as a genuine probe of superfluidity. With this probe, we predict that as few as four para-hydrogen molecules are enough to form a superfluid cluster, the smallest superfluid system to date. We also propose the concept of "exchange superfluid fraction" as a more precise measurement. New superfluid scenarios brought about by an asymmetric top dopant and potential experimental measurements are discussed.

Superfluid clusters, percolation and phase transitions in the disordered, two-dimensional Bose–Hubbard model

The Bose glass (BG) phase is the Griffiths region of the disordered Bose–Hubbard model (BHM), characterized by finite, quasi-superfluid clusters within a Mott insulating background. We propose to utilize this characterization to identify the complete zero-temperature phase diagram of the disordered BHM in d ⩾ 2 dimensions by analysing the geometric properties of what we call superfluid (SF) clusters, which are defined to be clusters of sites with non-integer expectation values for the local boson occupation number. The Mott insulator phase then is the region in the phase diagram where no SF clusters exist, and the SF phase the region where SF clusters percolate—the BG phase is inbetween: SF clusters exist, but do not percolate. This definition is particularly useful in the context of local mean field (LMF) or Gutzwiller–Ansatz calculations, where we show that an identification of the phases on the basis of global quantities such as the averaged SF order parameter and the compressibility is misleading. We apply the SF cluster analysis to the LMF ground states of the two-dimensional disordered BHM to produce its phase diagram and find (a) an excellent agreement with the phase diagram predicted on the basis of quantum Monte Carlo simulations for the commensurate density n = 1 and (b) large differences to stochastic mean field and other mean field predictions for fixed disorder strength. The relation of the percolation transition of the SF clusters with the onset of non-vanishing SF stiffness indicating the BG to SF transition is discussed.

Rotational fluctuation of molecules in quantum clusters. I. Path integral hybrid Monte Carlo algorithm

In this paper, we present a path integral hybrid Monte Carlo (PIHMC) method for rotating molecules in quantum fluids. This is an extension of our PIHMC for correlated Bose fluids [S. Miura and J. Tanaka, J. Chem. Phys. 120, 2160 (2004)] to handle the molecular rotation quantum mechanically. A novel technique referred to be an effective potential of quantum rotation is introduced to incorporate the rotational degree of freedom in the path integral molecular dynamics or hybrid Monte Carlo algorithm. For a permutation move to satisfy Bose statistics, we devise a multilevel Metropolis method combined with a configurational-bias technique for efficiently sampling the permutation and the associated atomic coordinates. Then, we have applied the PIHMC to a helium-4 cluster doped with a carbonyl sulfide molecule. The effects of the quantum rotation on the solvation structure and energetics were examined. Translational and rotational fluctuations of the dopant in the superfluid cluster were also analyzed.

Electron bubbles in helium clusters. II. Probing superfluidity

In this paper we present calculations of electron tunneling times from the ground electronic state of excess electron bubbles in ((4)He)(N) clusters (N=6500-10(7), cluster radius R=41.5-478 A), where the equilibrium bubble radius varies in the range R(b)=13.5-17.0 A. For the bubble center located at a radial distance d from the cluster surface, the tunneling transition probability was expressed as A(0)phi(d,R)exp(-betad), where beta approximately 1 A(-1) is the exponential parameter, A(0) is the preexponential factor for the bubble located at the cluster center, and phi(d,R) is a correction factor which accounts for cluster curvature effects. Electron tunneling dynamics is grossly affected by the distinct mode of motion of the electron bubble in the image potential within the cluster, which is dissipative (i.e., tau(D)<tau(0)) in normal fluid ((4)He)(N) and ((3)He)(N) clusters, while it is undamped (i.e., tau(D)>>tau(0)) in superfluid ((4)He)(N) clusters, where tau(D) is the bubble motional damping time (tau(D) approximately 4 x 10(-12) s for normal fluid clusters and tau(D) approximately 10 s for superfluid clusters), while tau(0) approximately 10(-9)-10(-10) s is the bubble oscillatory time. Exceedingly long tunneling lifetimes, which cannot be experimentally observed, are manifested from bubbles damped to the center of the normal fluid cluster, while for superfluid clusters electron tunneling occurs from bubbles located in the vicinity of the initial distance d near the cluster boundary. Model calculations of the cluster size dependence of the electron tunneling time (for a fixed value of d=38-39 A), with lifetimes increasing in the range of 10(-3)-0.3 s for N=10(4)-10(7), account well for the experimental data [M. Farnik and J. P. Toennies, J. Chem. Phys. 118, 4176 (2003)], manifesting cluster curvature effects on electron tunneling dynamics. The minimal cluster size for the dynamic stability of the bubble was estimated to be N=3800, which represents the threshold cluster size for which the excess electron bubble in ((4)He)(N) (-) clusters is amenable to experimental observation.

Third sound detection of superfluid transitions in 3He-4He films

Experiments in 3 He 4 He films using the torsional oscillator method suggest the existence of two superfluid transitions. We only detect the low temperature superfluid transition T A by third sound velocity measurement, which raises the question of the existence of percolation between superfluid clusters at T > T A .