Superelastic Shape Memory Alloy Research Articles

Study on the behavior and mechanism of double transition points in stable fatigue crack growth of superelastic NiTi shape memory alloy

Fatigue crack growth (FCG) tests were conducted on superelastic NiTi alloys, demonstrating that the da/dN-ΔK curve in the stable crack growth stage exhibits two transition points in the double-logarithmic coordinate system, presenting a tri-linear form. Fracture surface SEM analysis indicated that the FCG mechanisms differ across the three stages on either side of the two transition points. This phenomenon is first discovered and studied in NiTi alloys. The study investigated the size and position relationships between the characteristic zones at the crack tip (phase transformation zone and cyclic plasticity zone) and the microstructure during crack growth. Based on this, a critical prediction method for the transition points was established and found to be in close agreement with the experimental results. Finally, the formation mechanism of the double transition points was explained by combining the SEM results of the fracture surfaces with every stage of FCG.

Optimizing superelastic shape-memory alloy fibers for enhancing the pullout performance in engineered cementitious composites

Abstract This study explores the effect of integrated superelastic shape-memory alloy fibers (SMAFs) on the mechanical performance of engineered cementitious composites (ECCs). Various SMAF configurations – linear-shaped SMAFs (LS-SMAFs), hook-shaped SMAFs (HS-SMAFs), and indented-shaped SMAFs (IS-SMAFs) – with diameters of 0.8 and 1.0 mm were incorporated into ECC matrices, and surface texturization was achieved through abrasive paper treatment. Their mechanical properties were assessed through single fiber pullout tests on ECC mixtures containing 1.5 and 2.0% polyvinyl alcohol (PVA), subjected to both monotonic and cyclic loading conditions. Qualitative analysis, employing scanning electron microscopy, demonstrated that the IS-SMAF configuration provided superior mechanical interlocking and fiber–matrix adhesion, with a distinct flag shape observed during tensile testing. Quantitative data indicated that IS-SMAFs significantly improved the tensile strength and pullout resistance, with slip distances of ≥5 mm and average pullout loads ranging from 263 to 403 N. LS-SMAFs demonstrated better performance compared to HS-SMAFs and LS-SMAFs in terms of tensile and pullout characteristics. Additionally, ECCs with increased PVA content exhibited enhanced withdrawal performance. Thermogravimetry analysis and X-ray diffraction provided insights into the high-temperature stability and crystalline structure of the composites. These results underscore the effectiveness of IS-SMAFs in enhancing ECC properties, offering significant implications for the development and optimization of high-performance composite materials in civil engineering applications.

Deformation-fractional change in resistance model of SMA fiber reinforced mortar beams

Superelastic shape memory alloys (SMA) are metallic alloys that can enable components with self-recovery of cracks and deformation when combined with cement-based materials. Meanwhile, the monitoring method based on fractional change in resistance (FCR) can achieve self-monitoring of components throughout the entire loading process. In this study, the relationship between crack recovery characteristics and FCR of SMA fiber reinforced mortar beams subjected to flexural cyclic loading was analyzed. The beams with SMA fiber volume fractions of 0.1 %, 0.3 %, 0.5 %, and 1.0 % were tested under three-point bending loads. During the loading process, the FCR of the specimens were monitored by the four-electrode method. Finally, the deformation-FCR model for the whole process of the specimens was established to realize the real-time monitoring of the loading state of mortar beams. The results show that SMA fibers can enhance the flexural strength of mortar beams by a maximum of about 64 %, reduce residual deformation, and improve deformation self-recovery ability. The mid-span deflection recovery rate and crack size recovery rate generally increase with higher fiber volume fraction, which can maintain a better deformation recovery effect at the early stage of cracking and gradually decrease with the expansion of cracks. There is a close relationship between the FCR and the degree of crack development that the FCR increases with crack expansion and the magnitude of FCR decreases with increasing fiber content. The established first-order logarithmic fitting model can well describe the relationship between the FCR and cracking, which can provide reference for crack monitoring.

An analytical model for the phase transformation front propagation in superelastic SMA under impact tensile loading

An analytical model for the phase transformation front propagation in superelastic SMA under impact tensile loading

Effects of residual stress on the isothermal tensile behavior of nanocrystalline superelastic NiTi shape memory alloy

The residual stress greatly affects the mechanical behavior of a material. In this work, the effect of residual stress on the isothermal tensile behavior of a NiTi shape memory alloy is studied. The focused ion beam and digital image correlation are combined to measure the two-dimensional residual stress in nanocrystalline NiTi plates processed with prestrain laser shock peening. A four-point bending experiment verified the accuracy of this measurement method. The FIB-DIC method is an attractive tool for measuring the two-dimensional residual stress in phase transition nanocrystalline materials. The internal residual stress significantly decreases the phase transition stress, and the mechanism is studied via finite element and theoretical analyses. This work implies that the mechanical behavior of NiTi shape memory alloys can be tailored via residual stress engineering.

Constitutive modeling of functional fatigue with tension–compression asymmetry for superelastic NiTi shape memory alloy

Under cyclic loads, superelastic shape memory alloys (SMAs) exhibit stress–strain responses featured by functional fatigue, i.e., degradation of superelasticity and accumulation of irrecoverable deformation as cycling number increases, together with an asymmetry between tensile and compressive responses. Comprehensive understanding and modeling of these material complexities are crucial for the design and analysis of various superelastic SMA structures in practical applications. This work has developed a novel constitutive model based on irreversible thermodynamics to account for functional fatigue with tension–compression asymmetry. A potential function, defined as a weighted sum of two potentials that are calibrated against the tensile and compressive responses respectively, is employed to generate the asymmetric responses, and functional fatigue is represented by degradation of superelastic properties and growth of plastic strain as martensitic transformation accumulates. The model is adopted in numerical simulations for superelastic SMA tubes under cyclic lateral compression, which is experimentally investigated as a model problem. The agreement between simulations and experiments shows the validity and effectiveness of this constitutive modeling. Through additional finite element simulations incorporating this model, the effects of tension–compression asymmetry under cycling and diameter-to-thickness ratio of the tubular geometry upon mechanical responses of laterally compressed SMA tubes are also unveiled.

Cyclic Tension–Compression Behaviors of Large-Dimensional Superelastic Shape Memory Alloy Buckling-Restrained Plates

Cyclic Tension–Compression Behaviors of Large-Dimensional Superelastic Shape Memory Alloy Buckling-Restrained Plates

Cyclic Behavior and Damage Assessment of Superelastic SMA Dowel Connections for Braced Timber Frame Applications

Cyclic Behavior and Damage Assessment of Superelastic SMA Dowel Connections for Braced Timber Frame Applications

Giant Elastocaloric Effect and Improved Cyclic Stability in a Directionally Solidified (Ni50Mn31Ti19)99B1 Alloy.

Superelastic shape memory alloys with an integration of large elastocaloric response and good cyclability are crucially demanded for the advancement of solid-state elastocaloric cooling technology. In this study, we demonstrate a giant elastocaloric effect with improved cyclic stability in a <001>A textured polycrystalline (Ni50Mn31Ti19)99B1 alloy developed through directional solidification. It is shown that large adiabatic temperature variation (|ΔTad|) values more than 15 K are obtained across the temperature range from 283 K to 373 K. In particular, a giant ΔTad up to -27.2 K is achieved by unloading from a relatively low compressive stress of 412 MPa at 303 K. Moreover, persistent |ΔTad| values exceeding 8.5 K are sustained for over 12,000 cycles, exhibiting a very low attenuation behavior with a rate of 7.5 × 10-5 K per cycle. The enhanced elastocaloric properties observed in the present alloy are ascribed to the microstructure texturing as well as the introduction of a secondary phase due to boron alloying.

Experimental evaluation of an artificial anal sphincter based on biomechanical compatibility.

The artificial anal sphincter is a device used to treat patients with fecal incontinence who are unable to control their bowel movements on their own. Long-term morphological changes in the tissue surrounding the artificial anal sphincter can cause biomechanical compatibility problems, which seriously affect the clinical application of the artificial anal sphincter. In this paper, the superelasticity of shape memory alloys was utilized to design and fabricate a biomechanically compatible constant force clamping artificial anal sphincter. An invitro simulation system was constructed to verify the effectiveness, safety, and constant force characteristics of the artificial anal sphincter. The experimental results demonstrated that the artificial anal sphincter could be effectively closed with no leakage of the liquid-like intestinal contents, which are most likely to leak. The pressure of the artificial anal sphincter on the intestinal tube gradually increased and eventually became constant during closure, and the pressure value was always less than the intestinal blood supply pressure threshold. In this paper, we designed an artificial anal sphincter based on biomechanical compatibility and the corresponding invitro simulation experimental program and preliminarily verified the effectiveness, safety, and constant force characteristics of the artificial anal sphincter.

Development of Lightweight 6 m Deployable Mesh Reflector Antenna Mechanisms Based on a Superelastic Shape Memory Alloy

This paper describes the design and experimental verification of a 6 m parabolic deployable mesh reflector antenna mechanism based on a superelastic shape memory alloy. This antenna mainly consists of a deployable primary reflector with a superelastic shape memory alloy-based hinge mechanism and a fixed-type secondary reflector mast, where a rotary-type holding and release mechanism and deployment speed control system are installed. The main feature of this antenna is the application of a superelastic shape memory alloy to the mechanism, which has the advantages of plastic deformation resistance, high damping, and fatigue resistance. A shape memory alloy is applied to the hinge mechanism of each primary reflector rib and to the rotary-type holding and release mechanism as a deployment mechanism. In addition, a superelastic shape memory alloy wire is applied to the antenna in the circumferential direction to maintain the curvature of the primary reflector. The effectiveness of the proposed mechanism design was verified through repeated deployment tests on models of the superelastic shape memory alloy-based hinge mechanism and the antenna system.

Hysteretic Behavior of Self-Centering Shear Wall Incorporating Superelastic Shape Memory Alloy Bars and Engineered Cementitious Composites Subjected to Cyclic Loading

Hysteretic Behavior of Self-Centering Shear Wall Incorporating Superelastic Shape Memory Alloy Bars and Engineered Cementitious Composites Subjected to Cyclic Loading

Cyclic tensile response and crack closure performance of novel superelastic Ni-Ti SMA cable grid-reinforced engineered cementitious composites

To further improve the tensile and self-healing properties of engineered cementitious composites (ECCs) for their special uses such as harsh environments, plastic hinge regions, and old members strengthening, an innovative high-performance superelastic Ni-Ti shape memory alloy (SMA) cable grid-reinforced ECC (SMACG-ECC) was first proposed and tested in this study. The effects of water-binder ratio, cable grid material, and reinforcement ratio on the cyclic tensile properties and crack closure performance of the proposed SMACG-ECC were systematically examined. Test results revealed that the tensile strength, initial crack strength, ultimate tensile strain, dense crack, crack closure, and self-healing properties of the traditional ECC were obviously improved by being reinforced with the SMACG. Compared with the ordinary steel cable grid-reinforced ECC (SCG-ECC), the proposed SMACG-ECC exhibited approximately 50 % lower first crack strength, similar tensile strength and deformation ductility, but a 53.7 %-75.1 % greater energy dissipation, 75.8 %-80.2 % lower residual strain, and 80.4 %-83.4 % smaller maximum residual crack width. The tensile properties, cracking performance, and self-healing ability improved with the incorporation of SMACG as well as the increase in reinforcement ratio. Notably, most specimens showed satisfactory composite operation with no cable ends slipping during the entire cyclic loading process, with a maximum tensile strain amplitude of 8 %.

Cyclic response and stability of shape memory alloy cables considering training, displacement history, and prestrain effects

Superelastic shape memory alloy (SMA) cables have been considered in the development of various seismic protection technologies. The cyclic nature of seismic loads necessitates a comprehensive understanding of the mechanical behavior of SMA cables under repeated loading conditions. As SMAs undergo repeated phase transformation cycles, alterations in their properties occur due to defects generated and modified during the transformation. When utilizing superelasticity, this response can be stabilized after numerous transformation cycles. In various applications, components made of SMAs undergo a stabilization process referred to as training to enhance the predictability of the alloy’s response. Despite the widespread acceptance of training cycles to achieve stable cyclic response, a well-defined protocol is lacking. This study investigates the effects of various factors, including training strain amplitude, repeated loading, low-cycle fatigue loading, loading at high strain amplitudes, displacement loading history, and prestrain on the cyclic response of a large-diameter SMA cable. A total of 14 SMA cable specimens are tested under various tensile loading conditions. The experimental results, including stress-strain curves and various response parameters such as peak stress, residual strains, energy dissipation capacity, and equivalent viscous damping are examined in detail. The results indicate that training SMA cables at a strain amplitude near the end of phase transformation plateau leads to a highly stable cyclic response. However, it is worth noting that, in comparison to untrained cables, training induces a softening effect in the cable response.

Strength optimization of transverse retrofitting device for seismic isolated bridge based on seismic repair cost ratio

At present, the application of seismically isolated bridges is widespread. However, the elongation of the period of isolated bridges often leads to large displacements in the superstructure and significant residual displacements after earthquakes, which results in high repair costs or even bridge collapse. Therefore, various retrofitting measures for laminated rubber-bearing isolated bridges have emerged. The selection and design of these retrofitting measures are crucial to the response of bridges. In this study, three types of retrofitting devices are considered: concrete shear key, steel cable, and superelastic shape memory alloy (SMA) cable. The performance of different retrofitting devices is compared using the annualized seismic repair cost ratio (ASRCR) analysis and incremental dynamic analysis (IDA). Then the ASRCR analysis based on probability is used to optimize the strength of the retrofitting device. The results demonstrate that SMA cables and steel cables demonstrate similar effectiveness in reducing the fragility of bearings, but the superior self-centering ability of SMA cable significantly reduces the residual displacements of bearings. Furthermore, a mathematical model is developed to evaluate the economic benefits of seismic isolated bridges equipped with SMA cables and the strength of SMA cables can be designed rapidly by this model.

Recoverable and plastic strains generated by forward and reverse martensitic transformations under external stress in NiTi SMA wires

Although superelastic NiTi shape memory alloy wire displays very high resistance to plastic deformation in austenite and martensite phases, incremental plastic strains are recorded whenever the cubic to monoclinic martensitic transformation (MT) proceeds under external stress leading to functional fatigue degradation. Therefore, special closed-loop thermomechanical loading tests were performed to shed light on the mechanism by which the incremental plastic strain are generated. These tests revealed that both forward and reverse MTs occurring above certain stress thresholds generate plastic strains specific for the [temperature, stress] conditions under which the MTs occurred. While the forward MT upon cooling does not produce plastic strain or permanent lattice defects up to 500 MPa stress, the reverse MT upon heating starts to generate them from 100 MPa. While plastic strain generated by the forward MT merely elongates the wire, plastic strain generated by the reverse MT also reduces the recoverable strain. Since the reverse MT upon heating generates plastic strains at lower external stresses than the forward MT upon cooling, it is largely responsible for cyclic instability of NiTi actuators. The characteristic thresholds and magnitudes of plastic strains generated by the forward and reverse MTs define the functional fatigue limits for specific NiTi wires.

Superelasticity with narrow stress hysteresis and high cyclic stability in Co–V–Al polycrystalline alloy

Superelasticity of shape memory alloy associated with the martensitic transformation is extremely attractive for applications in sensors and biomedical. This application requires narrow stress hysteresis to reduce energy dissipation and a stable superelasticity cycle is an important factor in their practical applications. Co–V–Al alloys have inimitable advantages due to their narrow stress hysteresis, low-cost, and corrosion resistance, but the low number of superelasticity cycles restricts its development. Here, we report an intrinsic Co58V29Al13 polycrystalline alloy with a superelasticity stress hysteresis of 30 MPa at room temperature, the lowest among the alloys in this system, and a superelasticity strain of 3.6%. In addition, the sample shows no significant decay trend after 500 loading and unloading cycles. The high number of superelasticity cycles is mainly due to the elastic stress field generated around the dislocation during the cycle, which provides internal stress for martensite nucleation and reduces energy dissipation during martensitic transformation. This work provides essential guiding significance for the design of high-performance superelasticity alloys.

Shake table tests of steel moment resisting frame with self‐centering SMA‐based isolators

AbstractThis paper investigates a steel moment resisting frame (MRF) with a novel type of self‐centering (SC) base isolators, wherein superelastic shape memory alloy (SMA) U‐shaped dampers (SMAUDs) work as core components. A two‐story steel MRF model equipped with two SMAUD‐based isolators was designed and built in the laboratory, and a series of shake table tests were conducted to examine the dynamic behavior and seismic performance of the frame. Throughout all the tests, no interventions, such as repair or replacement of frame or isolator members, were done. Shake table test results demonstrated that the SMAUD‐based isolators could withstand multiple strong earthquakes with stable SC behavior. The utilization of SMAUD‐based isolators provided effective protection for the frame, enabling it to restore its original position with minimal structural damage. A numerical model of the tested steel MRF with SMAUD‐based isolators was also built. The results obtained from the numerical analyses agreed with those of the shake table tests satisfactorily. A comparative study of the seismic performance between the MRF with SMAUD‐based isolators and the MRF with traditional steel U‐shaped damper‐based isolators was also conducted in the shake table tests. The results showed that SMAUD‐based isolators not only inherit the isolation function of conventional isolators to protect the frame but also possess an SC ability to eliminate residual isolator deformation effectively. Moreover, SMAUD‐based isolators demonstrate remarkable resilience to withstand multiple strong seismic events without any need for repair or replacement.

Study on the working mechanism of self-resetting performance of superelastic SMA fiber-reinforced ECC beams

Study on the working mechanism of self-resetting performance of superelastic SMA fiber-reinforced ECC beams

Superelastic Cu68.5Al17.5Mn14 single crystal with an ultra-wide working temperature range for elastocaloric cooling

Superelastic shape memory alloys with elastocaloric cooling ability suitable for working at a broad temperature range are crucially lacking in facing various scenarios of cooling applications. Low-cost Cu-Al-Mn shape memory alloys are very promising candidates because of their low temperature dependence of critical driving stress of martensitic transformation. Here, a <105>A oriented Cu68.5Al17.5Mn14 single crystal is developed based on cyclic heat treatments, showing large superelastic response and elastocaloric cooling ability covering an ultra-wide temperature range spanning from 77 K to 450 K. Such enhanced temperature span also contributes to an exceptional refrigeration capacity of 5012 J kg–1, well surpassing those in the elastocaloric materials reported so far.