We report a high growth rate (37 μm/min) synthesis of vertically aligned carbon nanotube (VACNT) forest, achieving remarkable height exceeding a millimetre with good crystallinity. VACNTs with few numbers of walls have been grown over Fe–Co/Al2O3/SiO2 coated Si wafer using the water assisted atmospheric pressure chemical vapour deposition (WACVD) method. The key to this success lies in the synergistic combination of a bimetallic catalyst (Fe-Co) with buffer Al2O3 layer and the WACVD method. Notably, the VACNT forest, synthesised at optimized conditions can be directly used without the need for additional post-growth purification processes, eliminating the risk of potential damage to the CNTs. Finally, the VACNT forest exhibits excellent areal capacitance of 133.33 mF/cm2 at a current density of 1 mA/cm2 with outstanding cyclic stability of 130 % @ 3000 cycles.