We gauge the dynamics of macroeconomic and industry sector interactions between Mainland China and Taiwan in Greater China multivariate GARCH systems. Many studies have investigated the relations among the mainland Chinese, Hong Kong and Taiwan, some analysed the notion of cointegration among GCEA share markets (Cheung et al., 2003, Groenewold et al., 2004), others focused on economic integration (Wang and Schuh, 2000). Our paper contributes to the existing research on de facto or de jure integration among GCEA in deriving determinacy properties and version for these areas, especially from the point of vicious Cross-Strait macroeconomic relationship and sector effects. Since opening up to the outside world and transiting from a centrally planned to an increasingly market-based economy, Chinese economy is approaching to a so-called 'socialist market economy'. Which is different from the traditional centrally planned economy as well as the modern capitalist economy, to some extent, the patterns of structural change in the Chinese economy is difficult to detect. We apply sophisticated modeling techniques combined with an algorithm(iterated cumulative sums of squares algorithm, ICSS)to detect the economy and industrial sector structural changes under the increasingly opening of the Chinese economy. As the Mainland has gone through a period associated with a gradual opening of the economy, the dynamic interrelationships among Hong Kong, Taiwan and Mainland China has received considerable attention, especially during the period of regional or world financial crisis. By the way, we use a time-varying asymmetry conditional covariance multivariate GARCH systems combined with an algorithm (ICSS) which detects structural change during 1997 East Asian financial crisis and the nineteen terrorists on September 11, 2001, allowing for the asymmetric covariance effect due to simultaneously innovations between Mainland China, Taiwan and Mainland China, Hong Kong during the specific structural period. Owing to the different economic systems among the GCEA, VS (Volatility-switching) model generalizes the GJR model, provides a more flexible framework than any other ad hoc econometric model to scrutinize the disparate but identical market microstructure among these markets. Besides, this article provides an alternative explanation of dynamic interactions by application asymmetries conditional mean (ARAS) model to perform the Granger causality test. The causality relationship among GCEA, based on macroeconomic and industry sectors react to past positive and negative autoregressive process within and across broader would imply deindustrialization effect of Taiwan and the influence of increasing and persistent expansion in the Chinese economy over the last decade. The transmission of capital market and the embedded industrial structure thought-out primary, secondary and tertiary industries within the GCEA is examined for the period from 1996 through 2006. Long run equilibrium relationship among the Chinese Economic Zone is proved in this research. Our empirical result reveals two-way causality between Shenzhen A-stock markets and Taiwan stock markets. Different from previous studies investigating GCEA focus on the interaction of B-shares (instead of A-shares )with the other markets, A-shares are denominated in local currency which would not be affected by the variation of exchange rate as B-shares. A-share market seems to be driven by fundamental components. From the industry's clustering point of view, Taiwan's industries may follow a flying-geese style move to mainland China gathering on Shenzhen. Our evidence proves asymmetric covariance during the period nineteen terrorists between mainland China and Taiwan, the dummy variable of asymmetric covariance effect appear statistically significant thought-out primary, secondary and tertiary industries sectors. However, the inference of 1997 Asian financial crisis is limited.