Subduction Of Oceanic Plate Research Articles

Targeting deeply-sourced seeps along the Central Volcanic Zone

At convergent margins, plates collide producing a subduction process. When an oceanic plate collides with a continental plate, the denser (i.e., oceanic) plate subducts beneath the less dense (continental) plate. This process results in the transportation of carbon and other volatiles into Earth’s deep interior and is counterbalanced by volcanic outgassing. Sampling deeply-sourced seeps and fumaroles throughout a convergent margin allows us to assess the processes that control the inventory of volatiles and their interaction with the deep subsurface microbial communities. The Andean Convergent Margin is volcanically active in four distinct zones: the Northern Volcanic Zone, the Central Volcanic Zone, the Southern Volcanic Zone and the Austral Volcanic Zone, which are each characterised by significantly different subduction parameters like crustal thickness, age of subduction and subduction angle. These differences can change subduction dynamics along the convergent margin, possibly influencing the recycling efficiency of carbon and volatiles and its interaction with the subsurface microbial communities. We carried out a scientific expedition, sampling along a ~800 km convergent margin segment of the Andean Convergent Margin in the Central Volcanic Zone of northern Chile, between 17 °S and 24 °S, sampling fluids, gases and sediments, in an effort to understand interactions between microbiology, deeply-sourced fluids, the crust, and tectonic parameters. We collected samples from 38 different sites, representing a wide diversity of seep types in different geologic contexts. Here we report the field protocols and the descriptions of the sites and samples collected.

Late Eocene tectonic-geomorphic transition and its dynamic mechanism: Case study of the Beibuwan Basin, northern South China Sea

The continuous sedimentary records of the Beibuwan Basin preserve vital information on the interaction between Tethys and Pacific tectonic domains. The elusive interaction between the lithosphere and mantle significantly impacts the differential evolution of basins. However, the understanding of surface-mantle dynamic coupling beneath the Beibuwan Basin remains unclear. In this study, we analyze Cenozoic tectonic deformation, sedimentation, and mantle dynamic processes in the Beibuwan Basin in the northern South China Sea to clarify the nature of the tectonic-geomorphic transition during the late Eocene. Results show that the basin underwent late Eocene stratigraphic flexural folding, syn-rift transition from NE to EW orientated, and depocenter migration. The orientation of the primary controlling fault system during this period changed from NE-SW to NEE-SWW, the number of syn-depositional faults decreased from 368 to 172. The thickness of depocenters decreased from 5000 m to 1800 m, and the lacustrine Beibuwan Basin became shallower and wider. A comparison of the tectonic-structural history of the Beibuwan Basin with the history of plate subduction reconstructed from global geodynamic models shows that the late Eocene tectonic transition was closely related to changes in the stress field and the mantle wind related to oceanic plate subduction. We conclude that this enduring surface-mantle interaction associated with subduction of the Izanagi-Pacific mid-ocean ridge resulted in the late Eocene tectonic transition and geomorphic changes in the Beibuwan Basin.

Petrogenesis and tectonic implication of the Triassic monzogranite from the central segment of the East Kunlun Orogen, NW China

The Triassic granitoids in the East Kunlun Orogenic Belt (EKOB) are crucial for understanding the tectonic evolution of the Paleo-Tethys Ocean. This study presents zircon U–Pb ages, Lu–Hf isotopes, whole-rock major and trace elements, and Sr–Nd isotope compositions from monzogranite plutons in the central segment of EKOB to constrain their petrogenesis and tectonic evolution. These monzogranites are dominant composed of mineral assemblages of K-feldspars, plagioclase, minor biotite and accessory minerals. U–Pb dating of zircons from the Xinle South (XLS), Nanshankou (NSK) and Changgou South (CGS) plutons yield ages of 251 Ma, 232 Ma and 221 Ma, respectively. The studied monzogranites have relatively high SiO2 and Al2O3, but have low contents of TiO2, Fe2O3T, MgO relative to the coeval granodiorites. These monzogranites are classified as fractionated I-type granites, ranging from calc-alkaline to high-K calc-alkaline compositions. Their negative εNd(t) values (−4.2 to −6.3) and zircon εHf(t) values (−6.1 to −9.3) suggest that magma generation occurred through partial melting of ancient lower crust, followed by extensive fractional crystallization. Integrating our new data with regional geological evidence, we propose that the Early Triassic XLS monzogranite emplaced in a localized extensional environment linked to the northward subduction of the Paleo-Tethys oceanic plate. In contrast, during the post-collisional extensional phase of the Late Triassic, the formation of the NSK and CGS monzogranite plutons was directly influenced by asthenospheric upwelling, lower crust delamination, and subsequent continental rifting.

Effects of the Sedimentary Environment on Organic-Rich Shale in the Intracratonic Sag of the Sichuan Basin, China

The enrichment of organic matter in high-quality marine shale is generally controlled by factors such as the redox conditions of sedimentary environments, productivity levels, terrigenous input, and ancient productivity. However, the controlling effect of the sedimentary environment on organic matter enrichment in intracratonic sag is still unclear. This study takes samples from the Qiongzhusi formation shale in southern Sichuan Basin as the research object, focusing on trace elements as well as rare earth elements in different stratigraphic intervals. The provenance of the Qiongzhusi formation shale is mainly terrigenous, with sediment sources mainly consisting of sedimentary rocks and granites. The primary sedimentary environment transitions from a continental margin setting, influenced by rift-related tectonic activity and sediment influx from adjacent landmasses, to an open oceanic environment characterized by mid-ocean ridge processes and oceanic plate subduction zones. During sedimentation, saline water was present, with predominant sedimentary environments ranging from shallow water to deep water continental shelves. The shale in the study area is characterized by a higher content of silicates and a lower content of carbonate minerals. Its siliceous sources are mainly influenced by biogenic and terrigenous debris, indicating higher ancient primary productivity and representing a favorable target for shale gas exploration.

Tectonic evolution of the Early Paleozoic proto-East Asian continental margin: Inference from Paleozoic metamorphic rocks in the South Kitakami belt, northeast Japan

To constrain the incipient Pacific-type orogeny and tectonic processes in the Early Paleozoic proto-East Asian continental margin, the Motai–Matsugadaira–Yamagami (MMY) metamorphic rocks in the South Kitakami belt, northeast Japan were investigated. They are divided into two different types: amphibolite-facies rocks associated with serpentinite and blueschist-facies rocks associated with pelitic and psammitic schists. Three geochemical groups are identified from the MMY metamorphic rocks. Groups 1 and 2 resemble geochemical characteristics of mid-ocean ridge basalt and continental arc rocks, respectively. Group 3 exhibits considerable depletion of highly incompatible elements, which is caused by the high degree of partial melting of a hot mantle plume. The zircon U–Pb ages of Group 1 indicate that the protoliths experienced amphibolite-facies metamorphism soon after their formation in the Early Ordovician. Group 2 exhibits a coeval zircon U–Pb age with Group 1. The age distribution of detrital zircons in the MMY psammitic schists shows a peak of 500–400 Ma, the presence of Archean to Neoproterozoic zircons, and the youngest Late Devonian zircon. The following model is proposed for the tectonic evolution of the proto-East Asian continental margin: (1) the formation of an arc in the eastern margin of the South China craton in the Cambrian to Ordovician; (2) the subduction of a spreading axis and an oceanic plateau at the same time as the continental arc formation; (3) the consumption and subduction of arc materials by tectonic erosion; and (4) the formation of the Carboniferous accretionary complex and high-pressure metamorphic rocks under steady oceanic plate subduction. The proposed tectonic evolution model may also be applicable to equivalent Early Paleozoic rocks in southwest Japan.

Mercury isotope evidence for the importance of recycled fluids in collisional ore systems.

The sources of fluids and metals in porphyry systems of continental-collision settings are poorly constrained. Mercury isotopes display unique mass-independent fractionation (expressed as Δ199Hg) and may provide important constraints on metal and volatile sources given that Hg is a highly volatile metal. Here, we report Hg isotope data on ore-forming porphyries, barren magmatic rocks, and mantle-derived mafic magmas from southern Tibet. The fertile porphyries and coeval mafic magmas display mainly positive Δ199Hg values (up to +0.25 per mil), while Δ199Hg values in barren magmatic rocks and mafic magmas are largely negative (-0.54 to 0.00 per mil). The positive Δ199Hg values observed here are consistent with seawater and marine sediments, suggesting that the ultimate source of fluids involved in the genesis of post-subduction porphyry copper deposits was the mantle lithosphere metasomatized by previous oceanic plate subduction. Our Hg isotope data provide an alternative view to current metallogenetic models on collisional porphyry systems that focus on melting of the lower continental crust.

Successful subduction of oceanic plate after failed attempts in the Late Archean: Petrological and geochemical constraints

When and how plate tectonics started and evolved to the style as we know it today is a fundamental yet highly controversial question. Numerical geodynamic modelling predicts that the transition into plate tectonics in the Archean was episodic with possible alternation between success and failure of subduction. However, direct geological evidence for failed subduction is scarce. While this possibility has been suggested by numerical modelling, it is still lack of geological evidence. Here we present a combined study of zircon U-Pb ages and Hf-O isotopes, as well as whole-rock major and trace elements, for meta-igneous rocks from the Alxa Block in the westmost North China Craton (NCC). Two periods of Late Archean magmatism ca. 2.75 Ga and 2.5 Ga are identified to occur surrounding a pre-3.0 Ga continental nucleus. Geochemical analyses of the ca. 2.75 Ga meta-mafic and meta-felsic igneous rocks show two different modes of tectonic regime. The felsic rocks resemble typical Archean TTG (tonalite-trondhjemite-granodiorite) in composition, with variable εHf(t) values from -2.8 to 11.0 and δ18O values from 4.3 ‰ to 7.9 ‰. Petrogenetic modelling suggests that their magmatic source was the ca. 3.1–2.75 Ga oceanic crust that was hydrothermally altered at different temperatures and then mixed with the older continental crust and partially melted in lower crust in the garnet stability field. This requires tectonic accretion of the oceanic crust to the continental nucleus, signifying an attempted or failed subduction. On the contrary, the meta-mafic rocks exhibit arc-like trace element patterns and calc-alkaline evolution trend, indicating a metasomatic mantle source due to successful subduction of the oceanic slab to subarc depths. Taken together, the present results provide robust constraints on the behavior of oceanic slab at the Archean convergent margin, where successful oceanic subduction would be achieved after several failed attempts. Such failure-success processes of oceanic subduction may be applicable to the whole NCC and other cratons elsewhere in the world, reflecting the gradual maturation of plate tectonics in the Archean, consistent with predictions of numerical modelling.

Geology and genesis of the Aqishan Pb-Zn deposit, NW China: Insights from mineralogy, geochemistry, and in situ U-Pb geochronology

The unique ore-forming processes and the key factors responsible for formation of skarn deposits are still obscure, and challenges exist in the determination of timing of Pb-Zn skarns owing to lacking suitable mineral chronometers. Here we present detailed paragenesis, bulk geochemistry, in situ U-Pb dating of zircon and garnet, and garnet oxygen isotopes together with in situ zircon Hf-O isotopes from the newly discovered Aqishan Pb-Zn deposit in the southern Central Asian Orogenic Belt (CAOB), northwest China. This comprehensive data set revealed a Late Carboniferous subduction-related distal Pb-Zn skarn system associated with the granitic magmatism. Pre-ore stage garnets are generally subhedral to euhedral with oscillatory zoning and show slightly fractionated rare earth element patterns with positive Eu anomalies that point to an infiltration metasomatism origin under high water/rock ratios. The syn-ore stage sphalerite is typically enriched in Mn and Cd and has moderate Zn/Cd ratios (337–482), with a formation temperature of 265 °C to 383 °C, which indicate magmatic-hydrothermal signatures. The isocons defined by P2O5 decipher that the principal factors for skarn formation were elevated activities of Fe, Ca, and Si species, where remobilization of Pb metals, meanwhile, contributed to ore-forming budgets to mineralizing fluids. SIMS U-Pb dating of zircons from granite porphyry that occurs distal to the skarns and Pb-Zn orebodies shows that these intrusions emplaced at ca. 311.3–310.6 Ma, recording the subduction of the Paleo-Tianshan oceanic plate. Hydrothermal garnets in close textural association with Pb-Zn sulfides yield indistinguishable in situ LA-ICP-MS U-Pb ages of 310.5 ± 4.1 Ma. Whole-rock geochemistry and in situ zircon Hf-O isotopes (δ18O = 4.6‰–6.0‰) indicate that the granite porphyry was derived from partial melting of juvenile crust and influenced by subducted oceanic crust. Oxygen isotope compositions of garnets (δ18O = 8.0‰–9.0‰) demonstrate that the equilibrated ore fluids were inherited from fluid-rock interactions between a primary magmatic water and host tuff rocks. Our study highlights the application of garnets as a potential robust U-Pb geochronometer and isotopic tracer of ore fluids in skarn mineralizing systems in subduction-related arc environments.

A high-resolution seismic velocity model for East Asia using full-waveform tomography: Constraints on India-Asia collisional tectonics

East Asia's complex tectonic history makes it a unique place for plate-tectonic studies. While the crust and mantle structures beneath this region have been extensively investigated by receiver function and many different kinds of tomography studies, discrepancies among seismic velocity models have complicated our understanding of East Asia's tectonic evolution. Here, we use full-waveform adjoint tomography to study the seismic P- and S-wave velocity structures of the crust and mantle beneath East Asia. We use a large waveform dataset from 141 earthquakes recorded by 4640 broadband seismic stations. Our inversion optimizes the normalized correlation coefficient between synthetic and observed seismograms within individual time windows of different seismic phases, from P arrivals to the slowest surface waves. This approach allows us to fit regional multipathed waveforms and provides very well-resolved seismic P- and S-wave velocity structures from the crust to depths of about 800 km. Furthermore, we are able to obtain this resolution over most of East Asia allowing us to compare the amplitude and shapes of anomalies across the entire region. The observed structures in our new full-waveform tomography model (FWEA23) correlate well with tectonic units, revealing sharp contrasts across tectonic boundaries. Our model reveals narrow and strong linear fast anomalies associated with subduction zones in the western Pacific and Southeast Asia. Compared to these oceanic slabs, we observe different and more complicated mantle structures beneath the India-Asia continental collision zone. While our model spans a wide region in East Asia, we focus our interpretations on the seismic velocity anomalies beneath Tibet and surrounding regions, as our model provides significant implications for India-Asia continental collision tectonics. Our analysis suggests that cratonic Indian lithosphere collided with Eurasian plate around 25–20 Ma, subsequently underthrusting beneath Tibet horizontally with little deformation. This resulted in thickening, destabilization, and delamination of the rheologically weaker and less buoyant mantle lithosphere beneath north-central Tibet. Moreover, our model reveals isolated lithospheric fragments within the mantle transition zone and lower mantle beneath southern Tibet and northern India, suggesting that non-cratonic Greater India continental lithosphere has broken off and sunk into the deeper mantle. The lack of continuity among these lithospheric fragments suggests a convective destabilization process, distinct from typical oceanic plate subduction. Our results emphasize the important role of rheological properties of continental lithospheres in shaping the dynamics of continental collision.

Early cretaceous multi-stage extension in the North Dabie complex in the eastern central China: insights from structural and geochronological data

A dominantly NW-SE directed extensional tectonics in the Early Cretaceous significantly reworked the Late Permian-Triassic orogenic framework of the Dabie orogenic belt. The North Dabie complex (NDC) is the principal domain recording this tectonic event. However, the precise structure-kinematic architectures, particularly those observed in the ductile regime, along with the respective time scales for different extensional stages, have not been adequately established. This significantly impedes our comprehensive understanding of the extensional style and deformation history in the North Dabie complex. To better address these issues, we conducted a systematic structural study and LA-ICP-MS zircon U-Pb dating of the pre-, syn-, and post-kinematic intrusions and syn-kinematically metamorphosed high-grade gneisses/migmatites of the NDC. Our results demonstrate that the extensional deformation in the NDC may initiate at ca. 144 Ma, which is characterized by a pervasive NW-SE oriented coaxial plastic flow in the ductile regime of the middle-lower crust. A large-scale detachment processing zone subsequently started activating at ca. 140 Ma at the upper-middle level of the middle crust, and concentratedly accommodated the extensional strain by top-to-NW ductile shearing. Locally, there was uprising of sub-magmatic flow in the atatexite-diatexite from the deeper lower crust taking place in the manner of top-to-outward shearing as early as ca. 137 Ma. This composite process of extension manifests vertical strain partitioning across the ductile middle-lower crusts and progressive strain localization during the lithospheric thinning. The NW-SE orientation dominated extensional tectonics was strongly driven by the westward subduction of the Paleo-Pacific oceanic plate during the Late Mesozoic.

The Ordovician Arc–Basin System in the Northern Great Xing’an Range (Northeast China): Constraints from Provenance Analysis of the Luohe Formation

The Northeast China Block is a major component of the Central Asian Orogenic Belt, and its tectonic evolution has attracted much research attention. Ordovician strata are important in reconstructing the tectonic evolution of the Northeast China Block. This paper presents the results of sedimentological, zircon U–Pb, and geochemical analyses of sandstones of the Luohe Formation in the Wunuer area, Northern Great Xing’an Range, Northeast China. Lithological data, sedimentary structures, and grain-size analysis indicate that the Luohe Formation was deposited in a shallow marine environment. Detrital zircon U–Pb dating yields age peaks of 463, 504, 783, 826, 973, and 1882 Ma for sandstones from the Luohe Formation. The youngest zircon grain age of 451 ± 6 Ma represents the maximum depositional age of the Luohe Formation. The peak age at 463 Ma is consistent with the timing of post-collisional magmatism and the formation of the Duobaoshan island arc, while the peak at 504 Ma is consistent with the timing of magmatic activity related to the collision between the Erguna and Xing’an blocks. The peaks at 788, 826, 973, and 1882 Ma correspond to magmatism in the Erguna block, these ages indicate that the sandstones of the Luohe Formation were derived mainly from the Erguna block. Sandstone modal compositional analysis indicates that the provenance of the Luohe Formation was mainly a magmatic arc. The geochemical compositions of the sandstones suggest that the source rocks have continental island arc signatures. Based on the depositional age, sedimentary environment, provenance, and regional geology, it is concluded that the Luohe Formation was deposited in a back-arc basin setting during the formation of the Duobaoshan island arc–basin system in response to subduction of the Paleo-Asian oceanic plate.

Thermogenic methane and hydrogen generation in subducted sediments of the Nankai Trough

Active and widespread CH4 accumulations and emissions in the Nankai Trough subduction zone are attested by numerous mud volcanoes, gas plumes, and gas hydrates containing biogenic and thermogenic CH4. However, the source rocks of the thermogenic CH4 and the geological source of H2 for microbial CH4 production by methanogens remain uncertain. Here, we reveal the timing and rate of thermogenic CH4 and H2 generation from shales and metapelites associated with oceanic plate subduction in the Nankai Trough by gas and geochemical analyses. The results show that the thermogenic CH4 and H2 are generated mainly in the underthrust sediments below the décollement. The sustainable H2 supply from the underthrust sediments can potentially contribute to microbial CH4 production. The findings enhance our understanding of the active CH4 emission, large-scale gas hydrate formation, and subseafloor biosphere in the oceanic plate subduction zone.

Positive Δ199Hg anomalies in Mesozoic porphyry Mo deposits of Northeastern China and their implications to the metallogeny of arc-related hydrothermal systems at convergent margins

Mercury (Hg) isotopes display unique mass-independent isotope fractionation (MIF, reported as Δ199Hg), which is primarily generated via Hg photochemical processes in the land-ocean-atmosphere system. Magmatic and hydrothermal processes do not trigger MIF of Hg isotopes, therefore, Hg-MIF signals detected in deep reservoirs (mantle and crust) are theoretically sourced from recycled surface materials. Here, we observed positive Δ199Hg signals (0.10 ± 0.07‰, SD) in Mesozoic porphyry Mo deposits of NE China. These values correspond to the recently reported Δ199Hg signature of Mesozoic epithermal AuAg systems in NE China (Δ199Hg: 0.11 ± 0.07‰, SD), suggesting that both mineral systems receive large amounts of Hg from subducted marine materials, given that marine Hg has positive Δ199Hg composition. Our study thus provides novel geochemical evidence on the linkage between oceanic plate subduction and metallogeny of various hydrothermal systems at convergent margins. Subduction contributes large amounts of volatiles to arc magmas, which then release metal-rich magmatic-hydrothermal fluids of the porphyry to epithermal ore deposit spectrum.

Subduction and retreat of Permian oceanic plates in the East Kunlun Orogenic Belt: evidence from mafic-ultramafic intrusive rocks

ABSTRACT The East Kunlun Orogenic Belt, an important part of the Central Orogenic Belt in China, preserved wealthy geological information for the tectonic evolution of the Proto- and Paleo-Tethys Ocean. Several Permian mafic-ultramafic rocks were identified in the Qimantagh area, EKOB, and zircon U-Pb dating, zircon Hf isotope, geochemistry and whole-rock Sr-Nd isotopes were studied in this paper. The results suggest that the formation age of the Xiyingzhaogou intrusion is 280 ± 4 Ma. The rocks show the characteristics of continental-arc calc-alkaline basalt. The whole-rock εNd(t) value of gabbro in Xiyingzhaogou intrusion is −4.2~-2.6 and the εHf(t) value of zircon is 2.77 ~ 5.82, indicating the characteristics of enriched or weakly depleted mantle; The formation age of Yingzhaogou intrusion is 263 ± 4 Ma. The geochemical characteristics of the Yinzhaogou rocks are consistent with those of continental-arc tholeiite. The whole-rock εNd(t) value of gabbro in Yingzhaogou intrusion is 0.73 ~ 0.92, and the εHf(t) value of zircon is 8.33 ~ 13.50, indicating the characteristics of depleted mantle. We believe that the Xiyingzhaogou intrusion was formed in the Early Permian and originated from the mantle wedge metasomatized by subduction fluid. The Yingzhaogou intrusion was formed in an extensional continental-arc environment caused by the retreat of the subduction plate. Asthenospheric mantle and fluid metasomatic lithospheric mantle were jointly involved in the mantle source. This study confirmed that the subduction of the Paleo-Tethys oceanic slab should had started before the Early Permian and a wide magma arc formed due to flat subduction. The retreat of the subduction plate led to the extension of the East Kunlun region, resulting in the significant enhancement of magmatism in the Middle Permian.

Petrogenesis and metallogenic potential of granodiorite porphyry in the Kalatag district, East Tianshan, NW China: Constraints from geochronology, mineral geochemistry, Sr–Nd–Hf–O–S isotopes and sulfide trace elements

The Hongshi epithermal Cu deposit is located in the northern margin of the Dananhu arc in the East Tianshan Orogenic Belt, NW China. The Hongshi deposit is hosted by andesite and is famous for its lode type sulfide ores. Recently, the deep drill hole exploration shows a porphyry Cu mineralization and is predominantly hosted in granodiorite porphyry in the Hongshi. As for porphyry mineralization, the metallic minerals mainly include chalcopyrite, magnetite, and pyrite, with minor amounts of molybdenite. Ore minerals occur as dense dissemination and veins. Laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) U–Pb dating of zircons showed that the ore-bearing granodiorite porphyry was emplaced at ca. 434 Ma, recording the early subduction of the Paleo-Tianshan oceanic plate. Major element geochemical characteristics show that granodiorite porphyry samples have A/CNK values of 1.04–1.10 and moderate Mg# values of 45–49, indicating an I-type granitoid attribute. Trace element geochemical analysis indicates that ore-bearing granodiorite porphyry samples exhibit obvious large ion lithophile elements (LILEs) enrichment, high field strength elements (HFSEs) depletion, together with mantle-like bulk Sr–Nd ((87Sr/86Sr)i = 0.706417–0.708601; εNd(t) = 6.3–7.0) and zircon Hf–O isotope signatures (εHf(t) = 15.5–21.7, δ18O = 3.8 ‰–4.7 ‰), indicating that they were generated from partial melting of metasomatized mantle by the subducted slab fluids. In situ S isotope results of pyrite (1.46 ‰–2.07 ‰) and chalcopyrite (0.79 ‰–1.93 ‰) imply that granodiorite porphyry magmas and volcanic rocks provided ore-forming components (S and metals) for porphyry Cu mineralization in the deep drill hole ZK7501. The ore-bearing granodiorite porphyry samples have high logfO2 values ranging from − 12.4 to − 10.7, corresponding to ΔFMQ values of 0.6–5.2 (FMQ is the fayalite-magnetite-quartz buffer). Zircons from granodiorite porphyry have high Ce4+/Ce3+ ratios ranging from 74 to 187 and high Ti-in-zircon temperatures (764 to 869 °C). Electron microprobe analyses (EPMA) composition results of plagioclase, apatite and amphibole reveal that granodiorite porphyry magma had systematically high oxygen fugacity, high water contents (7.6–8.4 wt%), and low Cl contents (0.08–0.27 wt%), further demonstrating that granodiorite porphyry may be beneficial to the porphyry Cu mineralization in the deep drill hole ZK7501. Pyrite in the deep drill hole ZK7501 is enriched in Co, Ni, Ag, Cu, As, and Pb, but poor in Mn, Ga, Ge, Cd, In, Sn. Mn, As, Tl, Pb and Sb in pyrite substituted Fe2+ by coupled mechanisms, while Ag and Cu can enter the mineral lattice in the form of solid solution or micro-inclusions, which was also demonstrated by LA–ICP–MS mapping and textural studies. Pyrite shows variable Co/Ni ratios ranging from 10 and 455, indicating that ore-forming fluid originated from a magmatic source. The involvement of highly oxidized magmas is fundamental for the formation of porphyry Cu mineralization in an arc tectonic setting. Additionally, water concentrations also play an important factor that controlled metal fertility of the Early Paleozoic porphyry Cu mineralization in the Kalatag district.

Structural patterns and ages of Permian-Triassic multistage strike-slip faulting in the Chifeng area, southeastern Inner Mongolia, China: Implications for the final closure of the Paleo-Asian Ocean

The closure of the Paleo-Asian Ocean (PAO) to the north of the North China Craton (NCC) holds significance in comprehending the Phanerozoic continental evolution of East Asia. However, the timing of the final closure of the PAO, tectono-magmatic records of this process in the northern margin of the NCC, and related geodynamics remain to be resolved. Here we undertaken detailed macro- and micro-structural investigations on the E-W-striking and NNE-striking fault system in the Chifeng area, northern edge of the NCC. Combined with new zircon U-Pb and muscovite 40Ar/39Ar dating, we delineated three phases of strike-slip faulting in the research region during the Permian-Triassic, including WNW-ESE-striking and NE-SW-striking ductile sinistral shearing at ∼ 270–258 Ma and 258–246 Ma, respectively, and subsequent ∼ E-W-oriented ductile–brittle dextral shearing at ∼ 230–209 Ma. Based on analysis of paleotectonic stress fields, we propose that the first two-stage deformation shared a regional unified N-NNE contractional setting, while the late ∼ E-W-striking dextral shearing reflected a distinct regional NNW-SSE shortening event. The regional magmatism reveals three age peaks of ∼ 270 Ma, ∼250 Ma and ∼ 230 Ma, corresponding well to the above three-phase deformation. Further, zircon Hf isotopic data imply that the composition of juvenile material in regional deep-seated crust gradually increased from Permian to Triassic. The N-NNE contraction may be controlled by the eastward scissor-like final closure of the PAO during the Middle Permian-Early Triassic. The middle-late Late Triassic NNW-SSE contraction is likely influenced by the remote effect of the low-angle southward subduction of the Mongol-Okhotsk oceanic plate.

Early Triassic S-Type Granitoids in the Qinzhou Bay Area, South China: Petrogenesis and Tectonic Implications

The influence of the paleo-Tethys or paleo-Pacific oceanic plate subduction on Early Triassic South China has long been debated. We have studied the zircon U-Th-Hf isotopes, trace elements, and whole-rock geochemistry of Early Triassic peraluminous granitoids in the Qinzhou Bay area, South China Block. LA–ICP–MS zircon U–Pb dating has revealed the Jiuzhou granodiorites and Dasi-Taima granite porphyries formed between 248.32 ± 0.98 and 246.6 ± 1.1 Ma. These rocks are characterized by high K2O and Al2O3, and low MgO, CaO, and P2O5 contents with A/CNK = 1.06–1.17, showing high-K calc-alkaline S-type affinities. The Early Triassic intrusive rocks and adjacent silicic volcanic rocks in the Qinzhou Bay area were found to be comagmatic and derived from a common magma pool, detached in an undifferentiated melt instead of indicating remarkable crystal—melt separation. Although the analyzed granitoids have highly enriched zircon Hf isotopic compositions (εHf(t) = −23.9 to −7.8), they cannot originate solely from metasedimentary protoliths. Source discrimination indicators have revealed enriched lithospheric mantle-derived magma was also an endmember component of the S-type silicic magma, which provided a heat source for the crustal anatectic melting as well. We inferred the studied Early Triassic granitoids formed under the paleo-Tethys tectonic regime before the collision of South China and Indochina blocks, as the oceanic plate subduction would have created an extensional setting which further caused the mantle-derived upwelling and volcanic eruption.

Mid-Neoproterozoic (ca. 845 Ma) metamorphism of the southwestern Yangtze Block and its tectonic implications

The evolutionary history of the Yangtze Block plays an increasingly important part in reconstructing Proterozoic paleogeography and associated supercontinent cycles. We document mid-Neoproterozoic amphibolite facies metamorphism related to crustal thickening and possible terrane accretion within an accretionary orogen along the southwestern margin of the Yangtze Block. Kyanite-staurolite bearing schists in the Dahongshan Group record a main deformation stage and a peak metamorphic assemblage Grt rim + Ky + St + Bt + Ms + Rt + Pl ± Ilm. Petrography and phase equilibrium calculations suggest a clockwise P-T path under medium-pressure facies condition. Monazite U-Th-Pb ages from the Dahongshan Group constrain the timing of peak metamorphism to 845 ± 6 Ma (n = 33, MSWD = 1.01), which overlaps the metamorphic climax in the northern segment of the southwestern Yangtze Block. Based on the comprehensive analysis of geochemical, metamorphic and sedimentary data from the Yangtze Block, we consider that the outboard domain occupied by the Dahongshan Group along with the Hekou, Huili, Julin (Yuanmou) groups constitutes a terrane(s) that was separated from the rest of the Yangtze Block by a marginal sea formed at the end of the Mesoproterozoic. Mid-Neoproterozoic re-accretion to the inner Yangtze Block during ongoing convergent plate margin activity resulted in the deformation and metamorphism of these rock units. Similarities in the Neoproterozoic evolution of the Yangtze Block, the Seychelles, and the western margin of Greater India suggest a protracted history of oceanic plate subduction periodically interrupted by coupling across the plate margin driving deformation and metamorphism.

Seismotectonics of the Querétaro Region (Central Mexico) and the 1934 MI 4.8 Earthquake North of Celaya

AbstractThe Querétaro region (central Mexico) is located in the trans-Mexican volcanic belt, an active volcanic arc related to the subduction of oceanic plates along the Pacific margin of Mexico. It is characterized by north–south-striking normal faults of the southern Basin and Range Province, up to 40 km long and with morphologically pronounced scarps, such as the San Miguel de Allende fault and the faults forming the Querétaro graben. These faults are located directly north of a major regional-scale system of east–west striking, seismically active intra-arc normal faults that are oriented parallel to the axis of the volcanic arc. Where the two orthogonal normal fault systems interfere, the outcrop-scale observations show that the east–west intra-arc fault system overprints the Basin and Range Province structures. Here we document a 1934 earthquake in a region previously not known for seismic activity. Our study is mostly based on an unpublished contemporary dossier preserved at Archivo Histórico del Instituto de Geología de la Universidad Nacional Autónoma de México, a recently inventoried archive that also preserves several unpublished macroseismic and instrumental studies of major Mexican subduction zone earthquakes between 1911 and 1954. A mainshock–aftershock sequence that initiated 14 July 1934 is documented by instrumental recordings at the Tacubaya observatory and by macroseismic observations at ten population centers, ranging in intensity between five and seven on the modified Mercalli scale. Based on the size of the damage area, the intensity magnitude of the mainshock is estimated at 4.8 ± 0.5. Based on the intensity distribution, the epicenter was located in the Laja River valley north-northeast of the town of Celaya, in the south-southwestern extrapolated continuation of the San Miguel de Allende normal fault scarp, which suggests that this fault extends to the epicentral region of the 1934 earthquake and is characterized by recurrent Quaternary tectonic activity.

A late Neoarchean continental arc system in the northeastern North China Craton: constrain from the Guanghua mélange in the Tonghua area, southern Jilin Province

ABSTRACT The late Neoarchean tonalite – trondhjemite – granodiorite (TTG) and mafic rocks record essential information regarding the early tectonic evolution of the North China Craton, which is crucial for understanding the onset and development of the plate tectonic regime. In this study, we present a comprehensive analysis of petrography, geochronology, and geochemistry of the Guanghua Mélange from the Tonghua area in NE China. The mélange comprises basalt, gabbro, pyroxene diorite, and trondhjemite, and is classified into three groups: basaltic – gabbroic rocks (Group #1), dioritic rocks (Group #2), and trondhjemites (Group #3). Zircon U-Pb analyses indicate that they formed at 2596–2550 Ma, 2531–2515 Ma, and 2502 Ma, respectively, with metamorphism occurring during ~ 2500–2450 Ma. Meanwhile, geochemical data indicate that the calc – alkaline basaltic rocks (Group #1) exhibit slight depletion of Nb or Ta with weakly negative Eu anomalies, suggesting derivation from the lithospheric mantle and formation within a continental arc environment. The pyroxene diorites (Group #2) display similar geochemical characteristics to Group #1, likely formed by partial melting of depleted mantle that underwent sgignificant metasomatism due to variable amounts of slab-derived fluids or melts. The tholeiitic granitoids (Group #3) exhibit strongly fractionated chondrite-normalized REE patterns with high (La/Yb)N and Sr contents, low Y contents, and depletion of Nb, Ta or Ti, resembling adakites generated in arc setting, indicating likely formation through partial melting of subducted oceanic crust. This process was controlled by the initial plate tectonics under a higher geothermal gradient. Consequently, when combined with previous findings, we conclude that an initial subduction of oceanic plate operated in the northeastern North China Craton during the late Neoarchean (>2.55 Ga). Subsequently, it transformed into modern-type plate tectonics during ~ 2.55–2.53 Ga, eventually followed by the continent-continent collision at ~ 2.50–2.45 Ga, resulting in the formation of the Ji – Liao – Ji (Jilin – Liaoning – Hebei) Collision Orogenic Belt.