Water evaporators are often used as heat sinks in spacecraft. The aim of this study is to investigate the heat transfer characteristics and the spatial and temporal characteristics of bubble formation in an airborne water evaporator at an absolute pressure of 7 KPa. In order to achieve this, a rectangular single-channel model based on the structure of the water evaporator is established. Since the temperature change of the glycol in the water evaporator is not obvious when it flows through the rectangular single-channel, the inner wall surface is set to be 333.15 K in order to reduce the computational cost in the simulation. In this paper, a VOF method is adopted to numerically investigate the heat transfer characteristics of the boiling in the upper pool of the rectangular channel under a low-pressure(7 kPa) environment. Good agreement was obtained by comparing the numerical results with the experimental data with the error within 6 %. The numerical results show that bubbles rise along the wall, combine with nearby small bubbles, grow and attach to the wall, and slide along the wall until they are discharged from the top of the wall. The perturbations generated by the bubbles cause the heat transfer coefficient and wall temperature to fluctuate, with the maximum fluctuation of the wall temperature being around 5 K. In addition, the effects of different rectangular channel structure sizes (0.5 mm, 1.5 mm, and 2.5 mm) on the boiling heat transfer and bubble characteristics were investigated. A channel size of 0.5 mm leads to severe bubble coalescence, which increases the wall temperature and deteriorates the heat transfer performance. When the channel spacing is increased, bubble coalescence is improved, but a channel spacing of 2.5 mm results in less bubble turbulence and weaker heat transfer performance.