Soft Materials Research Articles

Ionic Liquid Enabled Transparent Heterogeneous Elastomers for Soft Electronics

AbstractDielectric elastomer (DE), as an electrically active soft material, has enabled stretchable electronics, electronic skins, artificial muscles, biomimetic soft robots, and non‐magnetic motors. High permittivity is urgently desired for increasing the sensitivity of DE sensors and lowering the driving voltage of DE actuators. However, existing efforts for significantly enhanced permittivity is usually achieved at the expense of transparency of the DE by compositing external fillers, which limits the applications in optoelectronics, such as displays, touch screens, artificial eyes, etc. Here, by utilizing of transparent functional filler, ionic liquid micro‐droplet, and precise matching the refractive index with polydimethylsiloxane (PDMS) elastomer matrix, heterogeneous composites with high transparency and high permittivity are obtained simultaneously. The composites are transparent in the visible range (transmittance, 80%–95%). The permittivity reaches up to 22, which is more than seven times higher than the original value of the elastomer matrix. Moreover, the arbitrary deformability of ionic liquid filler endows the composites with better stretchability (300%) and much lower elastic modulus (0.5 MPa, about a quarter the value of PDMS), which is beneficial for soft electronics. Based on the as‐prepared high‐performance composites, high sensitivity and transparent soft sensors and touch panels have been realized, as well as wireless transmission of sensing signals.

Recent advances in 4D printing of hydrogels

Abstract 4D printing, the fabrication of dynamic 3D objects, has emerged as a frontier in additive manufacturing, benefiting from rapid advancements in 3D printing technologies and the development of new stimuli-responsive materials. Among the diverse materials explored for 4D printing, the hydrogel, renowned for its exceptional flexibility, biocompatibility, and tunable mechanical properties, is a class of soft materials well-suited for 4D printing. In addition to selecting and developing appropriate stimuli-responsive materials, it is important to devise suitable printing strategies to enable the fabrication of hydrogel-based structures that can perform complex shape-changing under external stimuli in various applications, such as soft robotics and biomedical areas. In view of this, various printing strategies, including structural design, printing scheme, and stimuli control are systematically summarized. This review aims to provide an up-to-date evolution of 4D-printed hydrogels and insights into the utilization of these printing strategies and printing techniques, such as direct ink writing, stereolithography, and two-photon polymerization, in the 4D printing of hydrogel structures for specific functions and applications.

The development of direct 3-dimensional printing of patient-specific mitral valve in soft material for simulation and procedural planning

ObjectivesReplicating 3-dimensional prints of patient-specific mitral valves in soft materials is a cumbersome and time-consuming process. The aim of this study was to develop a method for a direct 3-dimensional printing of patient-specific mitral valves in soft material for simulation-based training and procedural planning. MethodsA process was developed based on data acquisition using 3-dimensional transesophageal echocardiography Cartesian Digital Imaging and Communication of Medicine format, image processing using software (Vesalius3D, Blender, Meshlab, Atum3D Operation Station), and 3-dimensional printing using digital light processing, an additive manufacturing process based on photopolymer resins. Experiments involved adjustment of 3 variables: curing times, model thinness, and lattice structuring during the printing process. Printed models were evaluated for suitability in physical simulation by an experienced mitral valve surgeon. ResultsDirect 3-dimensional printing of a patient's mitral valve in soft material was completed within a range of 1.5 to 4.5 hours. Prints with postcuring times of 5, 7, 10, and 15 minutes resulted in increased stiffness. The mitral valves with 2.0-mm and 2.4-mm thinner leaflets felt more flexible without tear of the sutures through the material. The addition of lattice structures made the prints more compliant and better supported suturing. ConclusionsDirect 3-dimensional printing of a realistic and flexible patient-specific mitral valve was achieved within a few hours. A combination of thinner leaflets, reduced curing time, and lattice structures enabled the creation of a realistic patient-specific mitral valve in soft material for physical simulation.

One-step laser preparation of unidirectional liquid spontaneous transport structures

The Tilted Wedge Microcavity Array (TWMA) structure of the Nepenthes alata peristome allows for unidirectional fluid transport without any surface energy gradient. However, current methods of creating bionic Nepenthes alata peristome structures have significant improvement room in terms of structural shape, machining efficiency, and cost-effectiveness. To address these issues, in this paper, bionic Nepenthes alata peristome TWMA structures on 7075 aluminium alloy was built via a nanosecond laser with highly efficiency, low cost and flexible processing pattern. A unilateral tilted microcavity structure was fabricated by designing the laser processing path, and at the same time, the samples were tilted to change the angle at which the laser beam hit the working surface. This ensures that the microcavity is machined without destroying the microcavity structure underneath. The variation law of aluminum alloy ablation threshold under the influence of laser incidence angle was studied. The dimensional parameters of the TWMA structure were analysed in relation to laser incidence angle θ, laser processing power P, number of laser scans n, and laser scanning speed V. Additionally, liquid spreading tests were carried out on different surfaces of bionic structures, and the influence of surface wettability on the spreading results was investigated. The results indicate that the ablation threshold decreases initially and then increases with an increase in the laser incidence angle. This reflects the trend of the aluminium alloy absorption rate, which initially increases and then decreases with an increase in the incidence angle. For the prepared TWMA structure, the optimum speed of achieving the unidirectional spreading effect was found to be 2.41 mm s−1 with a surface contact angle (CA) of 35°. This study presents a low-cost and rapid preparation method for creating liquid unidirectional transport structures without any energy input.

Formation of Natural Melanin/TiO2 Nanostructure Hybrids with Enhanced Optical, Thermal and Magnetic Properties as a Soft Material

Formation of Natural Melanin/TiO2 Nanostructure Hybrids with Enhanced Optical, Thermal and Magnetic Properties as a Soft Material

Geometrically exact 3D arbitrarily curved rod theory for dynamic analysis: Application to predicting the motion of hard-magnetic soft robotic arm

Magnetorheological elastomers are active materials which can be actuated by the applied magnetic field. Hard magnetic soft (HMS) materials, a type of magnetorheological elastomers, show great potential in the fields of biomedical engineering and soft robotics, due to their short response time, remote operation, and shape programmability. To exploit its potential, a series of theoretical frameworks of HMS rods have been developed, but they are mainly limited to the static rod models or classical curved rod models that fail to consider the effect of the “initial curvature” on the distribution of the stress. In this work, we develop a curved rod theory to predict the 3D dynamic motion of the rod-like HMS robotics under large deformation. Based on the geometrically exact rod theory, we include the heterogeneous initial length of the longitudinal fiber caused by “initial curvature” into our model and obtain the reduced balance equations of the HMS robotics. As a result, the “tension-bending” and “shear-torsion” coupling effects of curved rods emerge in the present model. A numerical implementation of our model based on the classical Newmark algorithm is presented. To validate our model, three numerical examples, including the dynamic snap-through behavior of a bistable arch, are performed and compared with the simulation or experiment results reported in literatures, which show a good agreement. Finally, we experimentally study the 2D and 3D static and dynamic motion of a quarter arc HMS robotic arm under an applied magnetic field of 10 mT, and our model gives a satisfactory prediction, especially for static deformation.

Simulation of ultrasonic shear effect on the viscoelastic soft scale of heat exchangers

The shear effect on the viscoelastic soft scale of heat exchangers is simulated in this study, focusing on a chemical company’s heat exchanger and the associated fouling on its inner tube shell wall. The finite element software ABAQUS simulates the ultrasonic descaling process, incorporating viscoelastic soft scale materials into the calculations through software fitting functions. Based on ABAQUS data transfer technology, the model was first subjected to implicit static analysis, followed by explicit kinetic analysis containing pre-stress. The vibration propagation of ultrasonic waves on the heat exchanger model was simulated under different working conditions. Distribution of shear stresses of the fouling on different paths of the pipeline wall was obtained, and the results revealed the influence of different parameters of the ultrasonic waves on the shear descaling effect, which provides a reference for selecting appropriate parameters to improve the efficiency of ultrasonic descaling.

Impact of Cerium Oxide Nanoparticles Incorporation on Water Sorption and Solubility of Acrylic-Based Denture Soft Lining Material

Denture soft liners are specifically engineered to enhance patient performance by altering the surfaces of prosthetics that come into touch with the soft tissues within the oral cavity. Acrylic resin Polymethyl methacrylate (PMMA) based and silicone elastomer-based are the two main types of denture soft liners. Nanotechnology was employed as a means to enhance the mechanical qualities of dentures. The primary objective of this investigation was to examine the impact of cerium oxide (CeO2) nanoparticles (NPs) on the water sorption and solubility characteristics of acrylic-based soft liners. The data was subjected to analysis of variance (ANOVA). The surface characteristics were determined using scanning electron microscopy (SEM). This in vitro study demonstrates that including CeO2 NPs at 2% and 3% concentrations does not impact acrylic-based soft lining materials' water sorption and solubility. The solubility of CeO2 is well-recognized to be very low. The results indicated that there were no statistically significant differences between the groups.

Comparative analysis of two types of mechanical grippers for gripping flexible packaging materials

Abstract To study the different structure types of flexible packaging material gripping mechanical grippers and their application to the working environment, two types of cylinder-type soft packaging material gripping mechanical grippers are designed in this paper. According to the structural characteristics of the mechanical gripper, mathematical analysis is carried out to determine the coordinate relationship of each joint of the mechanical gripper. The plot function in MATLAB is used to plan and simulate the path curves of the two types of mechanical grippers and to determine the working environment of the two types of mechanical grippers applied respectively; the movement of the mechanical gripper is analyzed by using the fifth-degree polynomial, and MATLAB Robotics toolbox is used for simulation, which results in the displacement, velocity, and speed of the end of the two mechanical grippers. The fifth-degree polynomial is used to analyze the motion of the mechanical gripper, and the MATLAB Robotics toolbox is adopted for simulation, as well as the displacement, velocity, and acceleration curves of the end of the two mechanical grippers. The aim is to understand the motion characteristics of the two kinds of mechanical grippers, master the two kinds of mechanical grippers’ working state, and provide a reference for subsequent research on flexible packaging material gripping mechanical grippers.

Magnetic characterisation of ferromagnetic material

In magnetic and electromagnetic non-destructive testing, the physical properties of the material are often not well known or completely unknown. The design of the non-destructive testing systems that provide the magnetisation is often oversized in order to get enough magnetic saturation (e.g. in magnetic flux leakage method or in magnetoscopy method). An improvement of the device performances, expressed usually by the signal to noise ratio, can be obtained only when the designer of the device well knows the material characteristic in terms of magnetic curve, the curve that links the magnetic field strengths to the magnetic flux density. A good device must be able to saturate the material sample under test but not to overcame determinate values. In fact, when the magnetisation is low, the leakage of the flux is negligible, while when the magnetisation is too strong the material tends to be like air and the leakage flux is negligible too. The experimental characterisation is derived from the technique adopted for the testing of soft magnetic material adopted in electrical machines or electromechanical actuators. In the present paper will be presented some material characterisation useful for the non-destructive testing of railway track, metallic ropes or reinforcement iron.

Space-resolved dynamic light scattering within a millimeter-sized drop: From Brownian diffusion to the swelling of hydrogel beads.

We present a dynamic light scattering setup to probe, with time and space resolution, the microscopic dynamics of soft matter systems confined within millimeter-sized spherical drops. By using an ad hoc optical layout, we tackle the challenges raised by refraction effects due to the unconventional shape of the samples. We first validate the setup by investigating the dynamics of a suspension of Brownian particles. The dynamics measured at different positions in the drop, and hence different scattering angles, are found to be in excellent agreement with those obtained for the same sample in a conventional light scattering setup. We then demonstrate the setup capabilities by investigating a bead made of a polymer hydrogel undergoing swelling. The gel microscopic dynamics exhibit a space dependence that strongly varies with time elapsed since the beginning of swelling. Initially, the dynamics in the periphery of the bead are much faster than in the core, indicative of nonuniform swelling. As the swelling proceeds, the dynamics slow down and become more spatially homogeneous. By comparing the experimental results to numerical and analytical calculations for the dynamics of a homogeneous, purely elastic sphere undergoing swelling, we establish that the mean square displacement of the gel strands deviates from the affine motion inferred from the macroscopic deformation, evolving from fast diffusivelike dynamics at the onset of swelling to slower, yet supradiffusive, rearrangements at later stages.

Simulating dynamics of ellipsoidal particles using lattice Boltzmann method.

Anisotropic particles are often encountered in different fields of soft matter and complex fluids. In this work, we present an implementation of the coupled hydrodynamics of solid ellipsoidal particles and the surrounding fluid using the lattice Boltzmann method. A standard link-based mechanism is used to implement the solid-fluid boundary conditions. We develop an implicit method to update the position and orientation of the ellipsoid. This exploits the relations between the quaternion which describes the ellipsoid's orientation and the ellipsoid's angular velocity to obtain a stable and robust dynamic update. The proposed algorithm is validated by looking at four scenarios: (i) the steady translational velocity of a spheroid subject to an external force in different orientations, (ii) the drift of an inclined spheroid subject to an imposed force, (iii) three-dimensional rotational motions in a simple shear flow (Jeffrey's orbits), and (iv) developed fluid flows and self-propulsion exhibited by a spheroidal microswimmer. In all cases the comparison of numerical results shows good agreement with known analytical solutions, irrespective of the choice of the fluid properties, geometrical parameters, and lattice Boltzmann model, thus demonstrating the robustness of the proposed algorithm.

A finite-strain plate model for the magneto-mechanical behaviors of hard-magnetic soft material plates

In this paper, we propose a plate model, within the framework of finite-strain elasticity, to study the magneto-mechanical behaviors of hard-magnetic soft material plates. The 2D vector plate equation is derived from the 3D governing equations through a series expansion and truncation approach. The displacement and traction boundary conditions on the edges of plate samples are also proposed. Compared with the other plate or shell theories, the current plate model naturally incorporates the elastic incompressibility and the magneto-mechanical coupling effect of the material, which doesn't involve any a priori hypotheses on the geometry and deformation of the plates. Thus, it is applicable for modeling the large deformations of hard-magnetic soft material plates. To show the efficiency of the plate model, we study a benchmark problem, i.e., the plane-strain bending deformations of plate samples induced by magnetic and mechanical loads. Some analytical solutions of the plate equation system are derived, which provide accurate predictions on the magneto-mechanical response of the plate samples with different thickness-length ratios and magnetization directions. To promote applications of the plate model, we further derive a simplified plate equation system and write out its weak form, which is then implemented into the finite element software COMSOL Multiphysics. The efficiency of the simplified plate equation system is also verified through some typical examples. It is found that the numerical results obtained from the 2D plate model show good consistency with those of the 3D volume model, while the plate model exhibits obvious advantages in the aspects of numerical efficiency.

Composite strengthening via stress-concentration regions softening: the proof of concept with Schwarzites and Schwarzynes inspired multi-material additive manufacturing

Inspired by nature, porous graded topological structures based on carbon, like Schwarzites and Schwartzynes, exhibit a distinctive radial-gradient distribution of pores. The pores are strategically arranged in two patterns: small pores at the centre and larger pores in the outer region (ψ), and larger pores at the centre with smaller pores in the outer region (Ω). This type of topological engineering, with its unique deformation behaviour, makes these structures highly suitable for engineering applications requiring high energy absorption. However, the existence of stress-concentration regions within the porous graded structures leads to premature structural failure during uni-axial compression. To enhance the mechanical properties of such porous graded structures, this study proposes a strategy of tailoring their pores' deformation characteristics by replacing the stress concentration regions with soft/flexible materials. The selective reinforcing two (ψ2) and three layers (Ω3) soft material enhances the specific yield strength of the multi-material composite and by 187.27% and 230.22%, respectively compared to the respective porous soft structures. Specific resilience is heightened by 289.93% and 323.82% for multi-material composite ψ2 and Ω3, w.r.t the respective porous hard structure(ψ0′ and Ω0,). Our results present a unique strategy for improving the structural performance of the porous graded structures by tailoring the deformation characteristics. Engineered multi-material-based advanced composites, resulting from this approach, exhibit significant potential for applications requiring energy absorption without failure.

Emerging Aspects of Triazole in Organic Synthesis: Exploring its Potential as a Gelator.

Cu(I)-catalyzed azide-alkyne 1,3-dipolar cycloaddition (CuAAC) - commonly known as the "click reaction" - serves as the most effective and highly reliable tool for facile construction of simple to complex designs at the molecular level. It relates to the formation of carbon heteroatomic systems by joining or clicking small molecular pieces together with the help of various organic reactions such as cycloaddition, conjugate addition, ring-opening, etc. Such dynamic strategy results in the generation of triazole and its derivatives from azides and alkynes with three nitrogen atoms in the five-membered aromatic azole ring that often forms gel-assembled structures having gelating properties. These scaffolds have led to prominent applications in designing advanced soft materials, 3D printing, ion sensing, drug delivery, photonics, separation, and purification. In this review, we mainly emphasize the different mechanistic aspects of triazole formation, which includes the synthesis of sugar-based and non-sugar-based triazoles, and their gel applications reported in the literature for the past ten years, as well as the upcoming scope in different branches of applied sciences.

Manipulation of encapsulated artificial phospholipid membranes using sub-micellar lysolipid concentrations

Droplet Interface Bilayers (DIBs) constitute a commonly used model of artificial membranes for synthetic biology research applications. However, their practical use is often limited by their requirement to be surrounded by oil. Here we demonstrate in-situ bilayer manipulation of submillimeter, hydrogel-encapsulated droplet interface bilayers (eDIBs). Monolithic, Cyclic Olefin Copolymer/Nylon 3D-printed microfluidic devices facilitated the eDIB formation through high-order emulsification. By exposing the eDIB capsules to varying lysophosphatidylcholine (LPC) concentrations, we investigated the interaction of lysolipids with three-dimensional DIB networks. Micellar LPC concentrations triggered the bursting of encapsulated droplet networks, while at lower concentrations the droplet network endured structural changes, precisely affecting the membrane dimensions. This chemically-mediated manipulation of enclosed, 3D-orchestrated membrane mimics, facilitates the exploration of readily accessible compartmentalized artificial cellular machinery. Collectively, the droplet-based construct can pose as a chemically responsive soft material for studying membrane mechanics, and drug delivery, by controlling the cargo release from artificial cell chassis.

The comprehensive study on texture evolution and recrystallization behavior of twin-roll strip casting Fe-50 %Co alloy

The iron-cobalt soft magnetic alloy exhibits excellent properties such as high saturation magnetic induction, high magnetic permeability, and high Curie temperature, making it widely used in areas like aviation generators and electric motors. However, traditional iron-cobalt alloy strip materials often suffer from a high magnetic anisotropy constant, which hinders their performance in practical applications. In this study, twin-roll strip casting was employed to produce Fe-50Co soft magnetic alloy cold-rolled strip materials. The research findings reveal that the initial microstructure of the Fe-50Co alloy strip prepared through twin-roll strip casting is primarily composed of coarse columnar grains and equiaxed grains, with a strong {001} orientation for the columnar grains. Notably, a significant number of Σ3 grain boundaries are present within the cast strip. These grain boundaries effectively reduce dislocation accumulation during the cold rolling process and subsequently minimize the nucleation sites for γ-texture during subsequent annealing. Furthermore, a strong {001}<uv0> texture is formed in the finished strip material after cold rolling and annealing, resulting in superior magnetic properties. The alloy exhibited excellent magnetic properties after annealing at 900 ℃ for 5 h followed by furnace cooling to 750 ℃ with the cooling rate of 50 ℃/h and then to 300 ℃ with the cooling rate of 180 ℃/h, the B5000 was ∼ 2.417 T, P1.5/400 was ∼22.651 W/kg and P2/1000 was 183.51 W/kg. These findings provide valuable insights for the development of Fe-50Co alloys with excellent magnetic properties.

Pf bacteriophages hinder sputum antibiotic diffusion via electrostatic binding.

Despite great progress in the field, chronic Pseudomonas aeruginosa (Pa) infections remain a major cause of mortality in patients with cystic fibrosis (pwCF), necessitating treatment with antibiotics. Pf is a filamentous bacteriophage produced by Pa and acts as a structural element in Pa biofilms. Pf presence has been associated with antibiotic resistance and poor outcomes in pwCF, although the underlying mechanisms are unclear. We have investigated how Pf and sputum biopolymers impede antibiotic diffusion using pwCF sputum and fluorescent recovery after photobleaching. We demonstrate that tobramycin interacts with Pf and sputum polymers through electrostatic interactions. We also developed a set of mathematical models to analyze the complex observations. Our analysis suggests that Pf in sputum reduces the diffusion of charged antibiotics due to a greater binding constant associated with organized liquid crystalline structures formed between Pf and sputum polymers. This study provides insights into antibiotic tolerance mechanisms in chronic Pa infections and may offer potential strategies for novel therapeutic approaches.

Analytical model of friction at low shear rates for soft materials in 3D printing.

The biological properties of silicone elastomers such as polydimethylsiloxane (PDMS) have widespread use in biomedicine for soft tissue implants, contact lenses, soft robots, and many other small medical devices, due to its exceptional biocompatibility. Additive manufacturing of soft materials still has significant challenges even with major advancements that have occurred in development of these technologies for customized medical devices and tissue engineering. The aim of this study was to develop a mathematical model of tangential stress in relation to shear stress, shear rate, 3D printing pressure and velocity, for non-Newtonian gels and fluids that are used as materials for 3D printing. This study used FENE (finitely extensible nonlinear elastic model) model, for non-Newtonian gels and fluids to define the dependences between tangential stress, velocity, and pressure, considering viscosity, shear stress and shear rates as governing factors in soft materials friction and adhesion. Experimental samples were fabricated as showcases, by SLA and FDM 3D printing technologies: elastic polymer samples with properties resembling elastic properties of PDMS and thermoplastic polyurethane (TPU) samples. Experimental 3D printing parameters were used in the developed analytical solution to analyse the relationships between governing influential factors (tangential stress, printing pressure, printing speed, shear rate and friction coefficient). Maple software was used for numerical modelling. Analytical model applied on a printed elastic polymer, at low shear rates, exhibited numerical values of tangential stress of 0.208-0.216 N m - 2 at printing velocities of 0.9 to 1.2 mm s - 1, while the coefficient of friction was as low as 0.09-0.16. These values were in accordance with experimental data in literature. Printing pressure did not significantly influence tangential stress, whereas it was slightly influenced by shear rate changes. Friction coefficient linearly increased with tangential stress. Simple analytical model of friction for elastic polymer in SLA 3D printing showed good correspondence with experimental literature data for low shear rates, thus indicating possibility to use it for prediction of printing parameters towards desired dimensional accuracy of printed objects. Further development of this analytical model should enable other shear rate regimes, as well as additional soft materials and printing parameters.

Biodegradable and Flexible Wood-Gelatin Composites for Soft Actuating Systems.

Compliant materials are indispensable for many emerging soft robotics applications. Hence, concerns regarding sustainability and end-of-life options for these materials are growing, given that they are predominantly petroleum-based and non-recyclable. Despite efforts to explore alternative bio-derived soft materials like gelatin, they frequently fall short in delivering the mechanical performance required for soft actuating systems. To address this issue, we reinforced a compliant and transparent gelatin-glycerol matrix with structure-retained delignified wood, resulting in a flexible and entirely biobased composite (DW-flex). This DW-flex composite exhibits highly anisotropic mechanical behavior, possessing higher strength and stiffness in the fiber direction and high deformability perpendicular to it. Implementing a distinct anisotropy in otherwise isotropic soft materials unlocks new possibilities for more complex movement patterns. To demonstrate the capability and potential of DW-flex, we built and modeled a fin ray-inspired gripper finger, which deforms based on a twist-bending-coupled motion that is tailorable by adjusting the fiber direction. Moreover, we designed a demonstrator for a proof-of-concept suitable for gripping a soft object with a complex shape, i.e., a strawberry. We show that this composite is entirely biodegradable in soil, enabling more sustainable approaches for soft actuators in robotics applications.