Structural Perspective Research Articles

The study on the splicing seam of mini‐light‐emitting‐diode display screen

AbstractWhen viewing the mini‐LED display screen from a large angle, the seam appearing at the edge of the module can disrupt the uniformity of the entire screen's bright state. This paper studies the formation mechanism of bright and dark seam and color seam from the perspectives of spatial frequency and packaging structure, derives the formula for spatial frequency, analyzes the optical path at the splicing position, and designs a reasonable packaging film structure to solve the color seam.

Understanding the keyword adoption behavior patterns of researchers from a functional structure perspective

Understanding the keyword adoption behavior patterns of researchers from a functional structure perspective

Milk fat globule membrane (MFGM) phospholipid - Whey protein interaction characterization and its effect on physicochemical, interfacial properties and evaluation of in vitro digestion of emulsions - Inspired by the MFGM

The interfacial composition of fat globules can change the interfacial structure and further affect the digestive characteristics. In this study, the interaction between whey protein (WP), which is the main protein added in infant formula (IF), and milk fat globule membrane phospholipid (MPL) was investigated from the perspective of simulated fat globule structure, we further characterized the physicochemical properties and the in vitro digestive performance of the emulsions. The results showed that the interaction between MPL and WP changed the secondary and tertiary structures of WP, and formed a dense protective layer at the interface of the fat globule with strong interaction, which improved the emulsification property and physical stability of the emulsion. When MPL: WP was 5:10, the emulsions showed smaller particle size, higher absolute value of zeta-potential and more uniform and stable emulsion state. In addition, during the simulated in vitro digestion of infants, the degree of lipolysis and free fatty acid release content were significantly increased, which improved the fat digestion.

The Influence of the Spatial Structure of Urban Agglomeration on the Digital Economy and Its Impact Mechanism: Evidence From China

The urban agglomeration (UA), as the carrier of regional economic transformation, is an important impetus for the development of the digital economy (DE) in the future. Based on the perspective of the spatial structure of UA, this paper first attempts to clarify the theoretical aspects of the influence of the spatial structure on DE, its heterogeneous characteristics, and inner impact mechanism, and then empirically test the corresponding hypotheses by utilizing the data on China’s 18 UAs from 2011 to 2019. Our findings are as follows: (1) The monocentric structure has an inverted “U-shaped” impact on DE, namely, first promotion and then inhibition effects. (2) Heterogeneity analysis reveals that the inverted “U-shaped” relationship between the monocentric structure and DE is not observed in UAs lacking megacities and is insignificant during the early and middle development phases of UAs. However, this non-linear relationship becomes significant in UAs with megacities and UAs in mature and later development stages. (3) More deeply, this study uncovers that innovation serves as a mediating factor in the influence of the monocentric structure on DE. This article not only enriches the existing body of research on UAs and DE but also provides valuable theoretical insights for the development of DE within UAs.

Institutional investor network and idiosyncratic volatility of stocks

AbstractThis paper constructs an institutional investor network based on the heavy holdings of the same stock in China and conducts a social network analysis to investigate the influence of this network on stock price volatility from the perspectives of network structure (density) and location (centrality). The study demonstrates that institutional investor network density is negatively related to stock price volatility, while network centrality is positively related to it. Mechanism analyses further reveal that network density reduces stock price volatility by mitigating private information arbitrage behavior among institutional investors, whereas network centrality increases stock price volatility by creating private information arbitrage opportunities within the network. Additionally, the paper finds that information asymmetry enhances the positive effect of network centrality on stock price volatility. These findings are generally consistent across subsample analyses for different market states, reactions to good and bad news, and types of equity ownership, as well as in other robustness tests. The practical implications of these findings are significant for market stability regulation.

The key role of methylenediammonium and tetrahydrotriazinium in the phase stability of FAPbI3

Formamidinium lead triiodide (FAPbI3) is the prime candidate for single-junction perovskite solar cells, despite the metastability of the phase. To improve its ambient-phase stability and produce world-record photoelectric conversion efficiencies, methylenediammonium (MDA) has been used as an additive in FAPbI3. However, the exact function and role of MDA are still uncertain. The MDA doping may exist in the perovskite lattice in either the original structure or the THTZ-H (tetrahydrotriazinium) structure. In this research, the effects of the MDA and THTZ-H doping FAPbI3 perovskite on its stability are explored by first-principles calculations. Both MDA and THTZ-H doping can improve the stability of FAPbI3 perovskite from a structural perspective due to lattice strain and stronger H–I bonds. However, the doping mechanisms differ significantly in terms of electronic properties. The MDA doping acts by the traditional passivation mechanism. It can eliminate the iodine interstitial defect states that trap charge carriers and inhibit iodine interstitial defect migration. The THTZ-H cation can directly contribute to the band edge construction in the FAPbI3 bulk. Electron delocalization in the π-conjugated ring structure lowered the frontier orbital separation of the THTZ-H organic molecule and enabled orbital overlap with the inorganic moiety. The in-depth understanding of the mechanism of improving stability in this study would facilitate the application of FAPbI3 perovskite optoelectronic devices.

The complex regulation of Slo1 potassium channels from a structural perspective.

Fast and regulated potassium efflux by Slo1 channels is crucial in many tissues in animals including neurons, the kidney and smooth muscle. During the last decade, structures have revealed many details about the gating mechanism and regulation of these large and complex molecular machines. This review summarizes these findings and the current knowledge about the intricate regulation of these important channels. Slo1 integrates sensing of the membrane potential via a voltage-sensor domain that undergoes subtle but significant structural rearrangements with a calcium-induced expansion of parts of the intracellular gating ring. Together, these two signals synergistically lead to changes in the conformation and chemical nature of the pore domain, allowing potassium ions to be translocated. In many native tissues, Slo1 channels are assembled with at least three classes of auxiliary subunits that change the gating kinetics or allow the channel to open also in absence of one of the two signals. Finally, Slo1 is inhibited, activated or deregulated by natural toxins and synthetic compounds, underlining the importance of the channel for the organism and as a potential target for drugs and other molecules.

Characterising the Hierarchy of Multi-time Quantum Processes with Classical Memory

Memory is the fundamental form of temporal complexity: when present but uncontrollable, it manifests as non-Markovian noise; conversely, if controllable, memory can be a powerful resource for information processing. Memory effects arise from/are transmitted via interactions between a system and its environment; as such, they can be either classical or quantum. From a practical standpoint, quantum processes with classical memory promise near-term applicability: they are more powerful than their memoryless counterpart, yet at the same time can be controlled over significant timeframes without being spoiled by decoherence. However, despite practical and foundational value, apart from simple two-time scenarios, the distinction between quantum and classical memory remains unexplored. Here, we analyse multi-time quantum processes with memory mechanisms that transmit only classical information forward in time. Complementing this analysis, we also study two related – but simpler to characterise – sets of processes that could also be considered to have classical memory from a structural perspective, and demonstrate that these lead to remarkably distinct phenomena in the multi-time setting. Subsequently, we systematically stratify the full hierarchy of memory effects in quantum mechanics, many levels of which collapse in the two-time setting, making our results genuinely multi-time phenomena.

Femtosecond Laser 3D Nano‐Printing for Functionalization of Optical Fiber Tips

AbstractFunctionalized optical fiber tips featuring miniature sizes and diverse functions have broken the limitations of traditional optical fiber with fixed shapes and single materials, significantly enriching the application scenarios in communication, sensing, imaging, and other fields. However, the unconventional shape presents challenges in manufacturing arbitrarily sophisticated 3D micro/nano structures on optical fiber tips. Femtosecond laser 3D nano‐printing (FL‐3DNp) technology injects new vitality into the functionalization of fiber tips due to its high‐precision, customizable structure, and real 3D processing abilities, as well as advantages of non‐vacuum, maskless, and plentiful materials. This paper extensively compares the key performance parameters of various micro‐nano manufacturing technologies for functionalizing optical fiber probes and focuses on the FL‐3DNp technology. In addition, the latest research progresses are systematically presented from the perspective of structure and application. Finally, the current research challenges and future development directions in this emerging field are discussed, aiming at providing scientific and industrial guidance for FL‐3DNp in functionalizing optical fibers.

The hemostatic performance and mechanism of palygorskite with structural regulate by oxalic acid gradient leaching

Palygorskite (Pal) is a naturally available one-dimensional clay mineral, featuring rod-shaped morphology, nanoporous structure, permanent negative charges as well as abundant surface hydroxyl groups, exhibiting promising potential as a natural hemostatic material. In this study, the hemostatic performance and mechanisms of Pal were systematically investigated based on the structural regulate induced by oxalic acid (OA) gradient leaching from perspectives of structure, surface attributes and ion release. In vitro and in vivo hemostasis evaluation showed that Pal with OA leaching for 1 h exhibited a superior blood procoagulant effect compared with the raw Pal as well as the others leached for prolonging time. This phenomenon might be ascribed to the synergistic effect of the intact nanorod-like morphology, the increase in the surface negative charge, the release of metal ions (Fe3+ and Mg2+), and the improved blood affinity, which promoted the intrinsic coagulation pathway, the fibrinogenesis and the adhesion of blood cells, thereby accelerating the formation of robust blood clots. This work is expected to provide experimental and theoretical basis for the construction of hemostatic biomaterials based on clay minerals.

Synthesis, crystallization behavior and mechanical property of biodegradable Poly(butylene succinate-co-2-methyl succinate) copolyesters

In this research, a series of biodegradable poly(butylene succinate-co-2-methyl succinate) (PBSMS) random copolyesters with butylene 2-methyl succinate (BMS) unit content from about 10 to 90 mol% were successfully synthesized. Both the homopolymers poly(butylene succinate) (PBS), poly(butylene 2-methyl succinate) (PBMS), and PBSMS copolyesters showed relatively high intrinsic viscosity values of over 0.8 dL/g. The basic thermal parameters, crystallization behavior, crystal structure, spherulitic morphology and growth rate, and mechanical properties of PBSMS copolyesters were extensively studied and compared with those of PBS. The incorporation of methyl group not only effectively increased the toughness of PBSMS copolyesters but also significantly restrained the crystallizability of these copolyesters, showing that PBSMS copolyesters with the BMS unit content higher than 50 mol% were amorphous. Among these copolyesters, PBSMS30 (BMS unit content = 30 mol%) exhibited the most outstanding mechanical properties, with a Young's modulus of 188.0 ± 19.1 MPa, a tensile strength of 19.1 ± 1.8 MPa, and an elongation at break of 714.5 ± 23.2 %. By randomly introducing methyl as a side group into the PBS main chain, the mechanical properties of PBSMS copolyesters have been significantly improved. From the perspective of structure and properties, this study should be interesting and crucial for the development and research of biodegradable polymers.

A Review of the Current State and Future Directions for Management of Scalp and Facial Vascular Malformations.

Vascular malformations are structural abnormalities that are thought to result from errors in vasculogenesis and angiogenesis during embryogenesis. Vascular malformations of the scalp present unique management challenges due to aesthetic and functional implications. This review examines the pathophysiology, clinical presentation, and management techniques for six common types of vascular malformations of the face and scalp : infantile hemangioma, capillary malformations, venous malformations, lymphatic malformations, arteriovenous malformations, and arteriovenous fistulas. These lesions range from common to rare, and have very different natural histories and management paradigms. There has been increasing understanding of the molecular pathways that are altered in association with these vascular lesions and these molecular targets may represent novel strategies of treating lesions that have historically been approached from a structural perspective only.

A structural perspective on the interaction between glucocerebrosidase and the positive allosteric modulator BIA 28-6156

A structural perspective on the interaction between glucocerebrosidase and the positive allosteric modulator BIA 28-6156

On the prediction of the induced damage by the start-up sequence of Francis turbines: On operational resilience framework

The number of transient operations in hydraulic machinery connected to power grid, notably start-ups and shut-downs, has observed a substantial increase in recent decades, primarily driven by the global shift toward intermittent renewable energy sources. Simultaneously, advancements in MW power converter technology and its cost-effectiveness have altered the operational paradigms of hydropower plants. These transformations offer novel opportunities for asset management within the industry. This study introduces a new method aimed at forecasting stress during start-up procedures, leveraging steady-state measurements acquired from a reduced scale model of the hydraulic turbine. Through a dedicated modular telemetry measurement system and the integration of strain gauges onto the reduced-scale runner blades, a tool is devised to predict dynamic loads characteristic of these transient operations. Utilizing steady-state measurements and a Voronoi cell tessellation, the transient predicted stress signal is constructed by concatenating the information from each encountered cell, thus providing an estimated projection of the stress likely to occur during the sequence. The proposed methodology demonstrates a robust forecast of the stresses on the runner blades during steady-state and transient operations of Francis turbines. Its immediate value lies in the ability to correctly estimate the lifetime of the runner as well as the possible integration into an optimization framework for stress reduction, thereby potentially extending the operational lifespan of the unit, from the runner structure perspectives.

Structural evolution and rheology of continuous shear-induced dense granular flow in unsteady state

The structural properties of particulate matter can significantly affect the rheology of the system. We report the structural evolution and flow properties of dense granular flows induced by Couette shear and try to reveal the relationship between them. In unidirectional shear, monodisperse particles undergo a transformation from disorder to order. Throughout this continuous process, both the velocity and shear strain rate of the particles experience alterations. By filling with particles of varying polydispersity, the structural potential of the system can be controlled, thereby influencing the extent of structural transformations. The results indicate that the transition in flow characteristics is suppressed as the initial filling in the system approaches from high to low structural potential. The results based on the local volume fraction and relative positions of particles suggest that it is due to the weakening of the structural thinning effect caused by order. We found that both fixed shear paths and more rotatable local structures caused a significant reduction in the contact force to transfer energy. Inertia number and apparent viscosity vary with volume fraction, indicating a transition in dense granular flow after volume fraction φ≳ 0.62, with the onset of significant structural thinning effects. We have revealed the physical mechanisms influencing fluidity from a local structural perspective and established the relationship between fluidity g and φ in the continuous process of unsteady flow.

Implementasi Kebijakan Program Badan Usaha Milik Desa (BUMDES) di Desa Hulawa Kecamatan Paguyaman Kabupaten Boalemo

Based on the study, implementing the Village-Owned Enterprise Program (BUMDes) Policy in Hulawa Village, Paguyaman Sub-district, Boalemo regency, has followed Hulawa Village Regulation number 3 of 2017. These are viewed from the perspective of communication, resources, implementing attitude/disposition, and bureaucratic structure. In its implementation, several problems were still found, namely the lack of ability of policy implementers to carry out existing programs, lack of communication and ccordination between policy makers and policy implementers, and the absence of a clear and structured organizational structure. It can be concluded that the implementation of the Village-Owned Enterprises (BUMDes) Program Policy in Hulawa Village, Paguyaman Sub-district, Boalemo Regency, has not been implemented optimally following existing regulations. Several things still need to be improved, such as aspects of communication, resources,implementing attitude/disposition, and bureaucratic structure.

A Comparative Study on the Trade Structure between China and Major Spanish American Countries

As one of the largest emerging economies in the world, the Latin American region is also a region with high global strategic value. The trade between 19 Spanish American countries and China has a significant impact on economic and trade cooperation between China and Latin America. This article is based on the perspective of trade commodity structure, analyzing trade data between China and Spanish American countries in recent years, comparing and studying the import and export commodity structure between China and three major Spanish American countries: Mexico, Chile, and Peru, and analyzing the changes. Finally, in response to the issues identified in the study, some suggestions are proposed for trade exchanges between China and Spanish American countries, with the hope of providing reference for optimizing the trade commodity structure between China and Spanish American countries and for enterprises to further develop the Latin American market.

Resilience of interdependent supply chain networks design and protection under the ripple effect

Firms painstakingly assemble vast supply networks of cyber and physical interdependence. Wars, pandemics, and cyber-attacks have disrupted and rippled recently through these networks. The ripple effect in interdependent networks can be caused by functional and structural failures simultaneously, known as mixed ripple effects, which have been studied less in the past. To help managers enhance network resilience against mixed ripple effects, we propose a design and protection strategy from a network structure perspective. This paper is the first to propose a growth-maturity-decline (GMD) model for designing an interdependent network structure. Then, a protection strategy based on node collaboration and redundancy is proposed. Considering that a single resilience metric makes it difficult to distinguish the performance of different strategies, we develop a three-dimensional quantitative framework to evaluate network resilience by conducting case studies on synthetic and real-life supply chain networks. The simulation results indicate that (i) the GMD model enhances network resilience at different phases; (ii) the threshold of the upper capacity limit parameter for cyber-supply networks is 2.7; and (iii) the more uniform the role distribution of firms, the more resilient the network is. This study can provide more informed management decision support for improving network resilience.

Systemic Importance and Risk Characteristics of Banks Based on a Multi-Layer Financial Network Analysis

Domestic and international risk shocks have greatly increased the demand for systemic risk management in China. This paper estimates China’s multi-layer financial network based on multiple financial relationships among banks, assets, and firms, using China’s banking system data in 2021. An improved PageRank algorithm is proposed to identify systemically important banks and other economic sectors, and a stress test is conducted. This study finds that China’s multi-layer financial network is sparse, and the distribution of transactions across financial markets is uneven. Regulatory authorities should support economic recovery and adjust the money supply, while banks should differentiate competition and manage risks better. Based on the PageRank index, this paper assesses the systemic importance of large commercial banks from the perspective of network structure, emphasizing the role of banks’ transaction behavior and market participation. Different industries and asset classes are also assessed, suggesting that increased attention should be paid to industry risks and regulatory oversight of bank investments. Finally, stress tests confirm that the improved PageRank algorithm is applicable within the multi-layer financial network, reinforcing the need for prudential supervision of the banking system and revealing that the degree of transaction concentration will affect the systemic importance of financial institutions.

Fragility crossover mediated by covalent-like electronic interactions in metallic liquids

Abstract Fragility is one of the central concepts in glass and liquid sciences, as it characterizes the extent of deviation of viscosity from Arrhenius behavior and is linked to a range of glass properties. However, the intervention of crystallization often prevents the assessment of fragility in poor glass-formers, such as supercooled metallic liquids. Hence experimental data on their compositional dependence are scarce, let alone fundamentally understood. In this work, we use fast scanning calorimetry to overcome this obstacle and systematically study the fragility in a ternary La-Ni-Al system, over previously inaccessible composition space. We observe fragility dropped in a small range with the Al alloying, indicating an alloying-induced fragility crossover. We use x-ray photoelectron spectroscopy, resistance measurements, electronic structure calculations, and DFT-based deep-learning atomic simulations to investigate the cause of this fragility drop. These results show that the fragility crossover can be fundamentally ascribed to the electronic covalency associated with the unique Al-Al interactions. Our findings provide insight into the origin of fragility in metallic liquids from an electronic structure perspective and pave a new way for the design of metallic glasses.