Airborne electromagnetic functional devices represented by frequency selective surface (FSS) are receiving increasing attention due to the ever-growing complication of electromagnetic environment in air space. Previous investigations have highlighted the capability of FSS to induce the distorted electric field encompassing an airborne radome. This phenomenon interferes with lightning attachment behavior and compromises the effectiveness of anti-lightning devices. A current challenge is how to reveal the physical mechanism behind this interference. In this paper, a lightning model is established for a honeycomb sandwich composite-FSS structure and a single FSS array, respectively, to investigate the interference effect of FSS on lightning attachment. Arc behavior is verified by structural damage characteristics in relevant experiments. An equivalent circuit representing the process of an FSS array suffering a lightning strike is proposed to reveal the interference mechanism of FSS. The results indicate that the electrical connectivity of FSS has a significant impact on lightning attachment behavior. Patch FSS can induce partial discharge and exacerbate interface damage to a radome while aperture FSS eases energy accumulation, although the latter is prone to induce lightning leaders without integration with composites. The obtained results provide potential guidance for the structural and anti-lightning design of an airborne radome.