New whole-rock geochemical and detrital zircon U–Pb and Lu–Hf data of metasedimentary sequences of the Silvretta Nappe, Orobic Alps, Strona-Ceneri Zone, Gotthard Massif and Venediger Nappe are presented. These units seem to share a common early to middle Paleozoic geological record, which has alternatively been interpreted as the result of intraplate or orogenic processes. Detrital zircon data mainly indicate late Ediacaran to early Ordovician maximum sedimentation ages for the studied sequences, suggesting that they were intimately related to Cadomian and Cenerian orogenic processes along the northwestern Gondwana margin. The common presence of late Ediacaran to Cambrian Cadomian ages associated with variable subchondritic to suprachondritic Lu–Hf compositions points to recycling processes of Cadomian sequences, further supported by geochemical data indicating a relatively low to moderate maturity of sedimentary protoliths. The occurrence of Cenerian arc-related intrusions in Austroalpine and South Alpine basement unit points to an arc/back-arc position in the early Paleozoic Cenerian orogen, except for the Strona-Ceneri Zone, which was likely located closer to the forearc region, as indicated by the presence of high-pressure metamorphism. Younger sequences, such as the Landeck Quartz-phyllite, document post-Cenerian sedimentation, whereas those of the Venediger Nappe more likely record the early stages of Variscan subduction, as indicated by Devonian maximum deposition ages.
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