Stress-induced Martensitic Transformation Research Articles

Evolution of the Microstructure and Mechanical Properties of a Biomedical Ti-20Zr-40Ta Alloy during Aging Treatment

The research focus in the field of medical titanium alloys has recently shifted towards the development of low-modulus and high-strength titanium alloys. In this study, the influence of aging temperature on the microstructure and mechanical properties of a β-type Ti-20Zr-40Ta alloy (TZT) was investigated. It was found that the recovery and the recrystallization occurred in the as-rolled alloy depended on the aging temperature. The periodically distributed Ta-lean phase (β1) and Ta-rich phase (β2) were produced by the spinodal decomposition in all the samples aged at different temperatures. The spinodal decomposition significantly influenced the mechanical properties and deformation mechanisms of the TZT alloy. Upon aging at 650 °C and 750 °C, the as-rolled alloy exhibited a double-yield phenomenon during tensile testing, indicating a stress-induced martensitic transformation; however, its ductility was limited due to the presence of ω phases. Conversely, aging at 850 °C resulted in an alloy with high strength and good ductility, which was potentially attributed to the enhanced strength resulting from modulated structures introduced with spinodal decomposition.

Full-Field Deformation Study of Ti–25Nb, Ti–25Nb–0.3O and Ti–25Nb–0.7O Shape Memory Alloys During Tension Using Digital Image Correlation

AbstractA Ti–25Nb shape memory alloy (SMA) exhibits shape memory effect associated with stress-induced martensitic transformation from β to α″ phase. Addition of oxygen stabilizes the β phase and changes stress–strain response. Oxygen-added Ti–25Nb SMAs show a more distinct superelastic behavior. In this work, digital image correlation (DIC) was applied to investigate for the first time full-field deformation of Ti–25Nb, Ti–25Nb–0.3O and Ti–25Nb–0.7O (at. pct) SMAs. The specimens were subjected to loading–unloading tensile tests to study local and global mechanical characteristics related to activity of particular deformation mechanisms of the SMAs. Strain and strain rate fields were quantitatively compared at selected stages of each SMA’s deformation. It was found that the Ti–25Nb SMA exhibits a macroscopically localized Lüders-type deformation associated with the stress-induced phase transformation, whereas Ti–25Nb–0.3O and Ti–25Nb–0.7O SMAs show more discrete types of deformation related to activity of interstitial oxygen atoms. As a consequence, at particular stages of deformation, local values of strain rate of Ti–25Nb SMA were significantly higher than those of average strain rate. The results obtained in this paper provide a better understanding of the deformation mechanism in the oxygen-added Ti–25Nb based SMAs.

Damage accumulation and its effect during thermal- and stress-induced cycling martensite transformation of laser powder bed fused (LPBF) NiTi alloy

Nitinol (NiTi) alloys produced via laser powder bed fusion (LPBF) exhibit promising potential across diverse applications, yet their suitability for devices necessitating repetitive actuation confronts uncertainties regarding microstructural evolution and functional fatigue behavior during cyclic operation. Our investigation unveils that damage accumulation during thermal cycling stems from geometrically necessary dislocations formed through finite-scale incoherent interface motion, contrasting earlier hypotheses attributing LPBF-induced dislocation activity as the primary contributor. Damage accumulation during mechanical cycling is characterized by notable multiplication of cyclic dislocations via dislocation twinning interactions, rather than severe martensitic plasticity. These newborn cycling dislocations inherit martensite's crystallographic characteristics, exerting a distinct influence mechanism on martensite transformation and deformation behavior, diverging from conventional studies on function fatigue in traditional NiTi alloys. This study sheds light on the distinctive damage accumulation traits observed during thermal/mechanical cycling of LPBF-fabricated NiTi alloys, offering valuable insights for probing their functional fatigue mechanisms.

A three-dimensional phase-field model for studying the orientation-dependent interface evolution in stress-induced martensitic phase transformation

In this study, we address the challenging task of predicting the motion of interfaces in stress-driven martensitic phase transformations within shape memory alloys. The novelty of our approach lies in the introduction of a monolithically solved thermodynamic-based phase-field method, specifically tailored for large strain conditions at the nanoscale for three-dimensional problems. To achieve this, we have developed a custom finite element software seamlessly integrated into the FEniCS open-source framework, providing a sophisticated and efficient tool for the examination of nanostructure evolution. Our investigation delves into five distinct and complex scenarios under diverse loading conditions for two– and three-dimensional problems, each presenting unique challenges: (i) a straightforward uniaxial tension scenario featuring a square domain with a pre-existing martensitic nucleus; (ii) the evolution of interfaces in a square sample incorporating a circular central nanovoid under biaxial tensile stress; (iii) the analysis of a rectangular beam subjected to horizontal and vertical compressive loads; (iv) the assessment of an initially voided rectangular beam experiencing mixed loading conditions; and (v) the three-dimensional simulations of cubic-to-tetragonal phase transformation using various orientation of the habit plane. In contrast to prior studies, our analysis not only explores the standard factors of habit plane reorientation and strain transformation values but also delves into the impact of nanovoids on austenite–martensite interface evolution.

Reverse ε→γ transformations of temperature-induced and stress-induced martensites in Fe–Mn–Si alloys with shape memory effect

In this work we argue that the reverse martensitic transformation (MT) of the stress-induced martensite (SIM) of Fe–Mn–Si-based alloys for moderate prestrains occurs in essentially thermoelastic-like way, in contrast to non-thermoelastic MT of temperature-induced martensite (TIM). We compare, using a number of complementary experimental techniques, the temperatures and the kinetics of the reverse ε→γ martensitic transformation of SIM and TIM for commercial and model Fe–Mn–Si alloys after various thermomechanical treatments. We claim that two studied phenomena are generic in Fe–Mn–Si-based alloys of different compositions and microstructure: first, opposite to the conventional effect of stabilization of martensite by prestrain, the reverse MT during heating of alloys prestrained in bending and tension starts well below (up to 100 K) the start temperature of the reverse MT for the TIM of the same alloy. The difference between engineering temperatures of the start of the reverse transformation, As, for SIM and TIM reaches ca. 50 K, pointing to a need to consider different As for TIM and SIM, AsTIM and AsSIM. Second, the reverse transformations of TIM and SIM show very different kinetics. The reverse MT of SIM is diffuse over the temperature range exceeding 100 K. The reverse MT of TIM, on the contrary, is well localized within the temperature range of ca. 20 K. The experimental observations can be interpreted assuming that, due to the differences in the formation mechanisms of SIM and TIM, the latter shows non-thermoelastic behaviour, whereas the SIM shows similarities with the thermoelastic martensites stabilized by prestrain.

Grain refinement induced unusually large shape memory effect in lightweight titanium alloy

High-performance and lightweight shape memory alloys (SMAs) play a pivotal role in a variety of cutting-edge fields like aerospace, which however, are still quite difficult to be obtained until now. In the present work, we meticulously develop a novel lightweight Ti-12.5V-3.5Al-1Hf-0.8Fe-0.01B (at.%) SMA, which has a low mass density of ∼4.73 g/cm3. Prominently, distinct from the conventional wisdom in previous studies that is mainly based on eliminating grain boundaries or developing desired texture, we utilize the grain refinement strategy introduced by elaborate thermal-mechanical training, which effectively enables us to achieve exceptional shape memory response and strength-ductility combination simultaneously. It was revealed that a dominant β phase structure is achieved in this newly designed fine-grain SMA, accompanied by some α″ variants penetrating the grain boundaries. Compared to the coarse-grained counterpart, the deformation process becomes more intricate, involving stress-induced martensitic transformation and additional reorientations, which ultimately results in an unusually large recoverable strain up to 9.3 %. Furthermore, the fine-grain structure also contributes to an enhanced specific yield strength up to ∼159 MPa·m³/kg, while maintaining a large tensile ductility of ∼30 %. In light of its impressive structure-function integration and cost efficiency, this new-type SMA would emerge as a promising candidate for various advanced lightweight applications in a broad spectrum of fields.

Active operative heat storage application using thermoelastic martensitic transformation in TiNi-based alloy

We propose a new concept of heat-storage material that utilizes thermoelastic martensitic transformation in a TiNi-based alloy. In the material, the stored thermal energy is maintained over a wide temperature range between the thermal absorption and desorption temperatures, and the stored energy is released on demand by external stress on the ground of a latent heat of the stress-induced martensitic transformation. The heat-storage temperature range was effectively increased through a thermomechanical treatment without changing the amount of latent heat. The tensile force applied to the treated sample released to the environment more heat than the unbiased desorption temperature. The amount of heat released was in agreement with the values expected from the Clausius–Clapeyron equation and differential scanning calorimetry profiles. The amount of heat released was confirmed to remain unchanged up to the 9th cycle when the release process was repeated at 286 K by applying tension after heat absorption.

Achieving excellent strength-ductility-superelasticity combination in high-porosity NiTiNb scaffolds via high-temperature annealing

Metallic scaffolds with lightweight, low elastic modulus, and high energy-absorbing capacity are widely utilized in industrial applications but usually require post-heat treatment to enhance their comprehensive mechanical properties. However, it is unclear how to utilize the impact of β-Nb on the surrounding matrix for NiTiNb ternary alloys to achieve strength-ductility-superelasticity enhancement. Here, we prepared rhomboidal dodecahedral NiTiNb porous scaffolds with a porosity of 85.9% by additive manufacturing. Subsequently, annealing treatment was employed to drastically reduce the phase transformation temperatures and expand the thermal hysteresis. Interestingly, the 850°C annealed scaffold exhibited exceeding double compressive strength of the as-built sample, with a remarkable improvement in ductility and superelasticity. From the microstructure perspective, high-temperature annealing caused a further eutectic reaction of the unmelted Nb particles with the NiTi matrix and the transformation of mesh-like β-Nb into diffuse spherical β-Nb particles. The microstructure evolution after deformation indicated that stress-induced martensitic transformation occurred in the matrix away from the NiTi-Nb eutectic region whereas almost no martensite formed nearby β-Nb particles. Atom probe tomography characterization revealed an element diffuse zone in several nanometers surrounding the β-Nb particle, where the substitution of Nb with Ti led to a higher Ni: Ti atomic ratio, lowering transformation temperatures. Molecular dynamics simulations illustrated that β-Nb particles can not only entangle dislocations internally, acting as reinforcements but also hinder the twin growth, contributing to strain hardening. This work elucidates the influence of β-Nb particles on the deformation mechanism of the NiTi-Nb eutectic region through in-depth atomic-scale investigation, which can provide inspiration for the improvement of comprehensive mechanical properties of NiTiNb alloys.

Headed coupling behavior of large diameter Cu-Al-Mn shape memory alloy bars: Mechanical testing and microstructural analyses

Cu-Al-Mn (CAM) superelastic alloy bars (SEAs) have received increasing attention in bridge applications. To take full advantage of their strain recovery and energy dissipation capacity, CAM SEAs are usually only applied in the plastic hinge regions of columns as part of the longitudinal reinforcement and coupled with steel rebar through mechanical splices. In this study, the feasibility of using headed coupling to connect large diameter CAM SEAs with steel rebar was investigated. Five large diameter CAM SEAs with headed ends were prepared: one 30 mm diameter and four 20 mm diameter samples. First, mechanical tests were performed on the five headed samples where each sample was coupled with one steel rebar at each end. Monotonic, incremental and constant strain cyclic loading was applied to simulate earthquake loading. The key mechanical properties were extracted and discussed. Second, microstructural analyses including electron backscatter diffraction (EBSD), metallographic imaging, Vickers hardness testing and fractographic evaluation were performed. The crystal orientation, phase composition and fracture surfaces were investigated to understand the effect of heading process on the stress induced martensitic transformation (SIMT), phase composition and failure of the headed CAM SEAs. It was found that the heading process only affects the near end portion of the specimen and it has no influence in the middle portion of the bars. Therefore, the strain recovery capacity of the CAM SEAs after heading was not reduced. Heading process led to high density of bainite phase precipitation at the end portions, which strengthened the sample. In order to uniformly strengthen the headed end of large diameter CAM SEAs, the key is to ensure a consistent cooling rate in the central and peripheral regions of the headed end after the heading process.

Effect of heat treatment on the microstructure and superelasticity of NiTi alloy via selective laser melting

In this study, a Ni50.4Ti49.6 shape memory alloy (SMA) was fabricated by selective laser melting (SLM), and it is found that heat treatments were effective to change the phase transformation behavior, microstructure, and superelasticity under compression for SLM Ni50.4Ti49.6. Detailed results based on EBSD demonstrated that, for SLM Ni50.4Ti49.6 during solid solution and aging (450 °C) treatment, the ultrafine cellular and columnar grains (∼16.5 μm) in as-fabricated Ni50.4Ti49.6 became equiaxed grains (∼70.2 μm), and the frequency of low-angle grain boundaries (26.7%→13.5%) and kernel average misorientation (0.37 → 0.21) decreased. The SEM and TEM analyses show that Ti-rich Ti2Ni/Ti4Ni2Ox and Ni-rich Ni4Ti3 precipitate phases were formed in the matrix simultaneously. After solid solution treatment, the size and distribution of Ti2Ni/Ti4Ni2Ox almost unchanged with aging temperature increasing from 350 °C to 550 °C, however, the size of Ni4Ti3 in aging-treated NiTi samples increased with aging temperature obviously, and it is interesting to find that the distribution of Ni4Ti3 became uneven and dislocation networks were formed in the matrix when the aging treatment reached up to 550 °C, which originated from the internal stress generated by supersaturated Ni atoms. Furthermore, the results of superelasticity for aging-treated NiTi demonstrated that the characteristics of Ni4Ti3 precipitate phase were powerful to influence the process of superelasticity decay/fatigue instead of determining the ultimately recovery strain after 10 compressive cycles. The aging-treated NiTi with evenly-distributed, high-density, and relatively-small Ni4Ti3 precipitate phase shows minimum recovery strain at 1st cycle compression and best superelasticity stability among three aging-treated NiTi, which was attributed to strong obstruction effect of these Ni4Ti3 precipitate for the occurrence of stress-induced martensitic transformation process and formation of dislocations. In contrast, the aging-treated NiTi with unevenly-distributed and low-density Ni4Ti3 precipitate shows maximum recovery strain at 1st cycle compression and worst superelasticity stability. These results in this work can bring some meaningful insights into tailoring the microstructure and superelasticity of SLM NiTi SMAs.

Effect of burst-type martensitic transformation on superelastic and elastocaloric properties in a 〈116〉 oriented Cu70.5Al17.5Mn12 single crystal

We report the occurrence of stress-induced burst-type martensitic transformation in a 〈116〉A oriented Cu70.5Al17.5Mn12 single crystal. The burst-type transformation is observed in the reverse transformation of unloading from 250 K to 370 K in tension, showing strong coupling with plastic deformation in the temperature range between 310 K and 370 K. Such coupling greatly exacerbates the stress hysteresis and energy dissipation in association with the stress-induced transformation, resulting in a significant enhancement in the mechanical damping and degradation in the elastocaloric response. In particular, the merit index for damping exhibits a remarkably high value of 0.903 at 370 K, demonstrating the huge potential of coupled burst-type transformation and plastic deformation in manipulating damping properties. Moreover, it is evidenced that the microstructural evolution of burst-type transformation greatly deviates from that of the thermoelastic transformation.

Microstructure and Super-Elasticity of Fe-33Mn-17Al-8.5Ni (at. %) Alloy for Structural Applications

The control of the residually stressed γ’-FCC phase in the grain boundaries that affects super-elasticity in the promising Fe-Mn-Al-Ni shape memory alloy (SMA) and grain size enhancement was an epitome for research in the current study. New composition Fe-33Mn-17Al-8.5Ni (at. %) was designed with the help of thermocalc software TCFE 11 database, produced in an electric arc furnace under an argon atmosphere and systematically investigated in the as-cast and heat-treated conditions. Characterization was performed using optical microscopy, X-ray diffraction measurements (XRD), and compression tests. Controlling the cooling conditions after heat treatment (HT) with high flowrate air cooling helped to reduce on the formation of the detrimental phase, γ’ at the grain boundaries as well as observed some grain growth in the microstructure without necessarily causing cracking as reported previously with quenching in cold water. The yield strength depicting the stress-induced martensitic transformation was 925 MPa for as cast and 909 MPa upon heat treatment. From cyclic compression loading/deloading training, a recovery strain of 2.1% and 2.3% was attained at 800 MPa maximum stress in the as-cast and heat treated-conditions, respectively.

An Ultra-Low Modulus of Ductile TiZrHfTa Biomedical High-Entropy Alloys through Deformation Induced Martensitic Transformation/Twinning/Amorphization.

Biomedical alloys are paramount materials in biomedical applications, particularly in crafting biological artificial replacements. In traditional biomedical alloys, a significant challenge is simultaneously achieving an ultra-low Young's modulus, excellent biocompatibility, and acceptable ductility. A multi-component body-centered cubic (BCC) biomedical high-entropy alloy (Bio-HEA), which is composed of non-toxic elements, is noteworthy for its outstanding biocompatibility and compositional tuning capabilities. Nevertheless, the aforementioned challenges still remain. Here, a method to achieve a single phase with the lowest Young's modulus among the constituent phases by precisely tuning the stability of the BCC phase in the Bio-HEA, is proposed. The subtle tuning of the BCC phase stability also enables the induction of stress-induced martensite transformation with extremely low trigger stress. The transformation-induced plasticity and work hardening capacity are achieved via the stress-induced martensite transformation. Additionally, the hierarchical stress-induced martensite twin structure and crystalline-to-amorphous phase transformation provide robust toughening mechanisms in the Bio-HEA. The cytotoxicity test confirms that this Bio-HEA exhibits excellent biocompatibility without cytotoxicity. In conclusion, this study provides new insights into the development of biomedical alloys with a combination of ultra-low Young's modulus, excellent biocompatibility, and decent ductility.

Large Cyclability of Elastocaloric Effect in Highly Porous Ni-Fe-Ga Foams.

Solid-state refrigeration based on elastocaloric materials (eCMs) requires reversibility and repeatability. However, the intrinsic intergranular brittleness of ferromagnetic shape memory alloys (FMSMAs) limits fatigue life and, thus, is the crucial bottleneck for its industrial applications. Significant cyclic stability of elastocaloric effects (eCE) via 53% porosity in Ni-Fe-Ga FMSMA has already been proven. Here, Ni-Fe-Ga foams (single-/hierarchical pores) with high porosity of 64% and 73% via tailoring the material's architecture to optimize the eCE performances are studied. A completely reversible superelastic behavior at room temperature (297 K) is demonstrated in high porosity (64-73%) Ni-Fe-Ga foams with small stress hysteresis, which is greatly conducive to durable fatigue life. Consequentially, hierarchical pore foam with 64% porosity exhibits a maximum reversible ∆Tad of 2.0 K at much lower stress of 45 MPa with a large COPmat of 34. Moreover, it shows stable elastocaloric behavior (ΔTad = 2.0 K) over >300 superelastic cycles with no significant deterioration. The enhanced eCE cyclability can be attributed to the pore hierarchies, which remarkably reduce the grain boundary constraints and/or limit the propagation of cracks to induce multiple stress-induced martensitic transformations (MTs). Therefore, this work paves the way for designing durable fatigue life FMSMAs as promising eCMs by manipulating the material architectures.

Mechanical property enhancement in additively manufactured NiTi double-asymmetric honeycombs with bioinspired graded design

ABSTRACT The cuttlebone is known for its ability to possess high specific stiffness, progressive failure and lightweight from the porous chambered structure. Inspired by the microstructural characteristics of cuttlebone and incorporating the wall gradient design, a series of double-asymmetric honeycombs were designed and processed by LPBF. Results indicated that bionic structural units with the junction design can maintain the integrity of the residual parts after local buckling and failure, improving the load-bearing capacity. The double-asymmetric honeycomb with gradation parameter α = 2/3 achieved a maximum specific compressive strength of 70.64 MPa cm3/g. As α decreases, there is an increase in specific energy absorption and a narrowing of the hysteresis loop. The as-build honeycomb had undergone stress-induced martensite transformation during compression. The dissipated mechanical energy (ME) decreased with the increasing cycle number and the decreasing α. The results provide design guidelines and process strategies for developing high-performance honeycombs.

Cryogenic Tensile Behavior of Ferrous Medium-entropy Alloy Additively Manufactured by Laser Powder Bed Fusion

The emergence of ferrous-medium entropy alloys (FeMEAs) with excellent tensile properties represents a potential direction for designing alloys based on metastable engineering. In this study, an FeMEA is successfully fabricated using laser powder bed fusion (LPBF), a metal additive manufacturing technology. Tensile tests are conducted on the LPBF-processed FeMEA at room temperature and cryogenic temperatures (77 K). At 77 K, the LPBF-processed FeMEA exhibits high yield strength and excellent ultimate tensile strength through active deformation-induced martensitic transformation. Furthermore, due to the low stability of the face-centered cubic (FCC) phase of the LPBF-processed FeMEA based on nano-scale solute heterogeneity, stress-induced martensitic transformation occurs, accompanied by the appearance of a yield point phenomenon during cryogenic tensile deformation. This study elucidates the origin of the yield point phenomenon and deformation behavior of the FeMEA at 77 K.

Understanding the asymmetric orientations and stress states in polycrystalline NiTi SMA by in-situ synchrotron-based high-energy X-ray diffraction

The stress-induced martensite transformations (SIMTs) dramatically affect the recoverable strain and mechanical response of polycrystalline NiTi. An in-depth understanding of the propagation manner and orientation preference of SIMTs is therefore crucial. In this work, we present a unique asymmetric anisotropy of SIMTs and lattice strains induced by Lüders-type deformation in polycrystalline NiTi, achieved through a combination of in-situ synchrotron X-ray diffraction and uniaxial tensile loading and unloading experiments. Our experimental findings reveal that in polycrystalline NiTi under uniaxial deformation, the asymmetry of SIMTs is attributed to the inhomogeneous strain field caused by the Lüders-type mechanism. The asymmetrical SIMT starts with the forward Lüder band and disappears along with the backward Lüder band. The austenite with the favored orientation of ⟨110⟩A//loading direction (LD) transformed and recovered back at a higher rate compared to other orientations during both loading and unloading.

TEM and X-ray diffraction studies of structure of TiNi SMA treated by low-energy high-current electron beam

Advanced scientific and technological achievements in the surface engineering of TiNi shape memory alloys are closely related with their mechanical performance. Electron-beam treatments could be applied in order to modify surface properties of smart materials and promote stress-induced martensitic transformations. The fundamental issue of electron-beam processing is residual elastic stresses arising from the ultrafast quenching (∼108 K/s) of thin (∼2–4 μm) surface layers. We report the experimental results on phase composition, structure and residual elastic stresses formed in the binary TiNi SMA irradiated by a low-energy (< 25 keV) high-current (∼ 25 kA) electron beam. Microstructure, fracture mechanisms and phase analysis of the as-cast and deformed tensile specimens have been studied by X-ray diffraction and electron microscopy. After electron-beam treatment, both martensitic B19′ and R phases are found in the near surface layer. The X-ray diffraction studies indicate that compressive stresses in the B2 phase of the irradiated TiNi alloy reach –460 MPa. In the fractured specimen (after tensile test) the residual stresses decrease to –160 MPa and release through the B2→B19′→B2 martensitic transformation. In-depth gradient distribution of the defect substructures responsible for the mechanical behavior of TiNi alloys was revealed.

Abnormal superelastic cyclic behavior and stress-induced martensitic transformation mechanism of NiTi alloy with R phase

In this work, an abnormal phenomenon of the superelastic cycle in NiTi alloy with R phase is reported. The phase transformation of the 500°C-annealed-sample is B2-R-B19'. During the first superelastic cycle, the critical stress of stress-induced martensitic transformation (SIMT) is reduced to 305.5 MPa and the phase transition plateau is shortened. With the loading process, the transformation of R–B19′ and the elastic deformation of the B19′ occur. With the unloading process, martensite reversal transformation occurs and the high-density dislocation zone and residual martensite are formed. During the superelastic cycle, the R phase is consumed. The increase of irreversible residual martensite and crystal defects leads to the deterioration of superelasticity.

Effect of Surface Roughness and Chemical Composition of Metastable Austenitic Stainless Steels on Electrochemical Polishing-Induced Martensitic Transformation

Herein, we analyzed the martensitic transformation kinetics during electrochemical polishing (EP) for stainless steel specimens with varying surface roughness and austenite stability. Martensite fraction measurement demonstrated that specimens with higher surface roughness and lower austenite stability exhibited relatively higher levels of martensitic transformation. To understand these phase transformation characteristics, the amount of charge build-up on the specimen surface during EP was calculated using COMSOL Multiphysics simulations for specimens with different surface roughness. The effect of charge build-up-induced stress was analyzed using previously published first-principles calculations. We found that specimens with higher surface roughness accumulated more charge build-up, resulting in greater stress and a martensitic transformation driving force. Furthermore, the critical energy required for the martensitic transformation was calculated using Thermo-Calc for specimens with different austenite stabilities. We demonstrated that the martensitic transformation kinetics during EP could be explained in terms of austenite stability, similar to the stress-induced martensitic transformation.Graphical