Stratigraphic Footwall Research Articles

Hydrothermal alteration and geochemical proximity indicators to ore at the Metsämonttu Zn–Pb–Cu–Au–Ag deposit, Uusimaa belt, southern Finland

The Paleoproterozoic Metsämonttu Zn–Pb–Cu–Ag–Au deposit (1.5 Mt at 3.5 wt% Zn, 0.8 wt% Pb, 0.3 wt% Cu, 13.2 wt% S, 25 g/t Ag, and 1.4 g/t Au, production 1952–1974) is the largest past-producing mine in the Aijala–Orijärvi area (Orijärvi formation, Aijala member) within the Uusimaa belt, southern Finland. The Aijala member is characterized by 1.9–1.88 Ga felsic-dominated volcanic-sedimentary supracrustal rocks with intercalated sedimentary carbonates and iron formations. The area is underexplored, and little deposit-scale research has been carried out, despite the lateral continuum to the world-class ore district of Bergslagen in south-central Sweden. To better understand the Metsämonttu VMS-related alteration system, we reassessed the previously described metamorphic mineral assemblages and their protolith rock compositions by using mobile and immobile element geochemistry. This resulted in the definition of four metamorphosed alteration mineral assemblages and eight chemostratigraphic rock units. The chemostratigraphic results suggest that the lithological and/or structural setting of the Metsämonttu succession is more complex than previously considered. The stratigraphic footwall is mainly characterized by an extensive cordierite + anthophyllite ± biotite ± phlogopite + pyrite ± pyrrhotite (Mg–Fe–S) assemblage dominated by mafic rocks, designated Mafic B1 and Mafic B2, and Andesite A1. The main sulfide mineralization is hosted by tremolite + diopside ± biotite ± phlogopite ± chlorite skarn (Ca–Mg–K). A sericite-bearing muscovite + quartz ± biotite ± phlogopite + pyrite (K–Si–S) assemblage is composed of felsic to mafic protoliths (Mafic B1–B2, Andesite A1, Dacite A1, Dacite B1, Dacite C1) and extends several tens of meters into the stratigraphic hanging-wall. A quartz + pyrite ± muscovite (Si–S) assemblage represents the immediate ore-proximal alteration and is derived from rocks with a rhyolitic composition (Rhyolite A1).Limited drill core samples near Metsämonttu mineralization, along with restricted surface alteration, pose challenges in studying geochemical variations from distal to ore proximal areas and limits the ability to model the shape and size of the alteration zone. Large mass changes suggest that the alteration was hydrothermal, and due to several protolith compositions, the alteration is interpreted to be predominantly discordant to stratigraphy. A 60-m-wide alteration halo surrounds the Metsämonttu deposit. Major and trace elements, namely MgO, Na2O, K2O, SiO2, Fe2O3, Cu, Zn, Pb, S, Ag, Tl, Hg, Se, Te, Sn, Sb, Rb, and Sr, and the indices modified alteration index (MAI), Ishikawa alteration index (AI), chlorite‑carbonate-pyrite index (CCPI), S/Na2O can be used for chemical vectoring, which can assist regional or near-mine exploration. Elements MnO, Ba, Cd, Bi, As, Ni, Co, W, Ga, Mo, and indices Hashigushi index and advance argillic alteration index (AAAI) were less useful as geochemical exploration indicators.

Age constraints on c. 1.9 Ga volcanism, basin evolution and mineralization at the world-class Zinkgruvan Zn-Pb-Ag(-Cu) deposit, Bergslagen, Sweden

We present improved age constraints for the world-class Zinkgruvan Zn-Pb-Ag and Cu deposit: one of the largest Zn deposits of the Fennoscandian shield, and one of the earliest large, basin-hosted Zn deposits that formed from oxidized saline brines. Secondary Ion Mass Spectrometry (SIMS) U-Pb dating on zircon is used to constrain at least two phases of c. 1.9 Ga volcanism in the Zinkgruvan area, separated by a period of fluvial sedimentation, all of which predated formation of the stratiform Zn-Pb-Ag mineralization. A 1908 ± 4 Ma age for a rhyolitic rock of the first volcanic phase is the oldest recorded U-Pb zircon age of a volcanic rock in the Bergslagen lithotectonic unit (BLU) where Zinkgruvan is located. Similarly, two identical ages of 1898 ± 5 Ma for volcanic rocks belonging to the second volcanic phase indicate that the local volcanic activity, which formed the stratigraphic footwall, ended earlier in the Zinkgruvan area than in other parts of the BLU, where intense explosive felsic volcanic and intrusive activity until c. 1891 Ma has been demonstrated. This, along with a hybrid siliciclastic-volcaniclastic (tuffitic) character of the Zinkgruvan ore host, confirms earlier interpretations that the Zinkgruvan deposit formed in an actively subsiding basin, distal to active volcanic centers in the BLU in the time range 1.90–1.89 Ga. Our results support models suggesting that basinal brine-driven hydrothermal systems in sedimentary basins distal to volcanic centers could form world-class Zn deposits as early as c. 1.90 Ga.

Volcanic reconstruction and geochemistry of the Powderhouse formation in the Paleoproterozoic VMS-hosting Chisel sequence, Snow Lake, Manitoba, Canada

The Powderhouse formation of the Paleoproterozoic Snow Lake arc assemblage comprises the stratigraphic footwall to six volcanogenic massive sulfide (VMS) deposits at Snow Lake, Manitoba, Canada. It is interpreted to be a product of voluminous pyroclastic eruptions and concomitant subsidence followed by a period of relative volcanic quiescence that was dominated by suspension sedimentation, the reworking of previously deposited pyroclastic units by debris flows and bottom currents, and localized emplacement of rhyolite domes. The rhyolite domes are spatially associated with the Chisel, Chisel North, Lost, Ghost, Photo, and Lalor deposits. The Chisel, Lalor, and Lost members compose the Powderhouse formation and are subdivided into 13 lithologically distinct lithofacies, which allows, for the first time, correlation of stratigraphy between the South Chisel basin and Lalor areas, critical in predicting the location of largely stratiform VMS deposits. The Chisel and Lalor members contain lithofacies and bedforms that are characteristic of emplacement by subaqueous pyroclastic mass flows and concomitant subsidence. The Chisel member also contains coarse volcaniclastic breccias emplaced by mass debris flows derived from movement along fault scarps following early pyroclastic eruptions, and during continued subsidence. The Lost member consists of lithofacies deposited by mass flows generated from faults scraps during continued subsidence, but also contains lithofacies reworked by bottom currents, those deposited by suspension sedimentation, and, locally, coherent rhyolite. The Lost member represents a time stratigraphic interval, the “ore interval”, that marks contemporaneous rhyolite dome emplacement, VMS formation, and a hiatus in explosive volcanism.

Fluid signature of the shear zone–controlled Veio de Quartzo ore body in the world-class BIF-hosted Cuiabá gold deposit, Archaean Rio das Velhas greenstone belt, Brazil: a fluid inclusion study

The world-class Cuiaba gold deposit of the Archaean Rio das Velhas greenstone belt in Brazil is hosted in banded iron formation containing carbonaceous matter and carbonate, within the reclined, isoclinal Cuiaba fold. Mineralised quartz veins are hosted in andesite in the stratigraphic footwall of the banded iron ores and form some of the more recently discovered ore bodies. Fluid inclusion data of the quartz vein–associated “Veio de Quartzo” ore body are obtained from four quartz types (Qz1, Qz2, Qz3, Qz5) in gold-mineralised V1 shear vein and V2 extensional veins, barren V3 extensional vein array, and V4 breccia-style veins, all developed during the Archaean D1 event. Three fluid types are distinguished: (i) aqueous fluids of low salinity (1.8–3.8 wt% NaCl equiv), homogenisation (into liquid) at 220 to 230 °C; (ii) aqueous fluids of moderate salinity (5.3–12.7 wt% NaCl equiv), and homogenisation at 250 to 290 °C; and (iii) aqueous-carbonic fluids of moderate salinity (6.0–15.1 wt% NaCl equiv), with 30–91 mol% CO2, 8–41 mol% CH4 and up to 28 mol% N2 and decrepitation (into vapour) at 280 to 310 °C. Based on an independent pressure estimate, a pressure correction was applied to aqueous fluid inclusions, resulting in minimum trapping temperatures at 360 °C for V1 veins, 330 °C for V2 veins, 300 °C for V3 veins and 270 °C for the late-stage V4 veins. Ion chromatography analyses reveal a Br/Cl ratio of 0.7 × 10−3 in Qz1-V1, from 1.4 to 1.5 × 10−3 in Qz2-V2, 0.3 to 0.4 × 10−3 in Qz3-V3 and 0.7 to 0.9 × 10−3in Qz5-V4 veins. Zinc, Pb and Cu are relatively enriched with ~ 100 to 1000 ppm in aqueous and aqueous-carbonic fluid inclusion assemblages in all vein and quartz types, which is similar to other orogenic gold deposits hosted in the Rio das Velhas greenstone belt. The fluid inclusion data are consistent with a model invoking a metamorphic origin for the mineralising fluid. A two-step model of hydrothermal fluid flow and gold enrichment is suggested to have developed during the Archaean D1 event, with an early, aqueous-carbonic fluid pulse of relatively high temperature (from V1 up to V3) and an evolved, aqueous-carbonic fluid pulse of lower temperature (V4, breccia-style veins). The Rio das Velhas greenstone belt is dominated by regionally metamorphosed metasedimentary rocks, resulting in a complex hydrothermal fluid evolution and related gold mineralisation such as the shear zone–controlled Veio de Quartzo ore body.

Dating hypogene iron mineralization events in Archean BIF at Weld Range, Western Australia: insights into the tectonomagmatic history of the northern margin of the Yilgarn Craton

This study is the first to constrain the absolute timing of hypogene iron mineralization in Archean BIF located in the Yilgarn Craton. In situ SHRIMP U–Th–Pb geochronology on xenotime and monazite grains has been used to constrain the age of hypogene magnetite replacement ores at the Beebyn deposit and hypogene magnetite vein ores at the Madoonga deposit in the Weld Range study area. The Beebyn magnetite replacement ores (c. 2627 Ma) are younger than the published maximum depositional age of the BIF hosts of the Wilgie Mia Formation (2792 ± 9 Ma) and partially overlaps crystallization ages of granitic rocks (2757–2606 Ma) that intrude supracrustal rocks throughout the study area. These plutons, and their probable subvolcanic expressions, are considered to be likely sources of energy and fluids responsible for magnetite replacement ores. In contrast, Madoonga magnetite veins record multiple dates: the first at 2857 ± 41 Ma, followed by events at c. 2775 Ma through 1812 Ma. The two oldest monazite dates of 2857 ± 41 and 2832 ± 51 Ma are interpreted to be mineralization ages for magnetite veins, possibly related to subseafloor volcanism and base metal VMS systems; whereas the younger dates (i.e. 2775–1812 Ma) probably represent multiple episodes of phosphate mineral precipitation related to reactivation of structures and overprinting by discrete pulses of hydrothermal fluids. The Madoonga BIFs are genetically distinct from the Beebyn BIFs and are the oldest dated BIFs at Weld Range, being older than c. 2857 Ma, but younger than the c. 2970 Ma felsic volcanic rocks in the stratigraphic footwall to the Madoonga BIFs. Hydrothermal events at the Madoonga deposit (2215–2120 Ma) coincide with published dates for rifting, mafic–ultramafic magmatism, and basin development along the northern margin of the Yilgarn Craton (2215–2145 Ma), whereas the younger phosphate mineral dates correspond with the Glenburgh (2002–1947 Ma) and Capricorn Orogenies (1817–1772 Ma). Tectonic activity along the northern margin of the Yilgarn Craton coincides with reported ages for hematite mineralization in BIF-hosted iron-ore deposits in the Hamersley Basin and Pilbara Craton, suggesting the far-reaching effects of tectonism along paleocratonic boundaries as drivers for iron mineralization in BIF.

Stratigraphic setting and timing of the Montagne d’Or deposit, a unique Rhyacian Au-rich VMS deposit of the Guiana Shield, French Guiana

In French Guiana, the Montagne d’Or gold deposit (5 Moz at 1.5 g/t Au) is located in the northern branch of the Rhyacian Paramaca Greenstone Belt. The sulphide deposit is hosted by a south-facing bimodal volcanic and volcaniclastic sequence that is highly strained and affected by a penetrative E-W striking and steeply south-dipping foliation.The volcanic sequence is composed of three members, (1) the Lower unit in the stratigraphic footwall, (2) a bimodal mafic-felsic formation hosting the orebody, and (3) the Upper sedimentary and volcanic rocks unit in the stratigraphic hanging-wall. The bimodal formation is dominated by calc-alkaline felsic volcanic rocks in the west, interbedded/interdigitated with tholeiitic mafic rocks in the east. Pillowed mafic flows and graded-bedded felsic volcaniclastic rocks collectively indicate effusive to explosive volcanic activity in a submarine environment. The mineralization consists of thick and laterally extensive sulphide zones forming (1) stratiform sulphide disseminations, (2) structurally-transposed stringer stockworks, and (3) thin layers of deformed semi-massive sulphides. The gold-rich sulphide mineralization consists mainly of pyrite, pyrrhotite and chalcopyrite with minor sphalerite, magnetite, galena and arsenopyrite, hosted by chlorite-sericite-rich alteration zones mainly developed in the felsic tuff facies.U-Pb zircon geochronology shows that most of the Montagne d’Or volcanic and intrusive sequence has crystallized during a multi-cycle magmatic event, from ca. 2152 Ma to ca. 2130 Ma. A porphyry intrusion crosscutting the ore yields a U-Pb zircon age of 2117.6 ± 5.1 Ma, hence constraining a minimum age for the auriferous sulphide mineralization. This also indicates that the sulphide mineralization was coeval with arc magmatism, demonstrating the volcanogenic nature of the Montagne d’Or gold deposit.

VHMS mineralisation at Erayinia in the Eastern Goldfields Superterrane: Geology and geochemistry of the metamorphosed King Zn deposit

Despite having been a target for volcanic-hosted massive sulfide (VHMS) deposits since the 1960s, few resources have been defined in the Archean Yilgarn Craton of Western Australia. Exploration challenges associated with regolith and deep cover exacerbate the already-difficult task of exploring for small, deformed deposits in stratigraphically complex, metamorphosed volcanic terranes. We present results of drill-core logging, petrography, whole-rock geochemistry and portable X-ray Fluorescence data from the King Zn deposit, to help refine mineralogical and geochemical halos associated with VHMS mineralisation in amphibolite-facies greenstone sequences of the Yilgarn Craton. The King Zn deposit (2.15 Mt at 3.47 wt% Zn) occurs as a 1–7 m-thick stratiform lens dominated by iron sulfides, in an overturned, metamorphosed volcanic rock-dominated sequence located ∼140 km east of Kalgoorlie. The local stratigraphy is characterised by garnet-amphibolite and strongly banded intermediate to felsic schists, with rare horizons of graphitic schist and talc schist. Massive sulfide mineralisation is characterised by stratiform pyrite–pyrrhotite–sphalerite at the contact between quartz–muscovite schists (‘the footwall dacite’), and banded quartz–biotite and amphibole ± garnet schists of the stratigraphic hanging-wall. A zone of pyrite–(sphalerite) and pyrrhotite–pyrite–(chalcopyrite) veining extends throughout the stratigraphic footwall. Footwall garnet-amphibolites are of sub-alkaline basaltic affinity, with a central zone dominated by chlorite ± magnetite interpreted to represent the Cu-bearing feeder zone. SiO2, CaO, Fe2O3T, MgO and Cu concentrations are highly variable, reflecting quartz–epidote ± chlorite ± magnetite ± sulfide alteration. Hydrothermal alteration in stratigraphically overlying intermediate to felsic rocks is characterised by a mineral assemblage of quartz–muscovite ± chlorite ± albite ± carbonate. Cordierite and anthophyllite are locally significant and indicative of zones of Mg-metasomatism prior to metamorphism. Increases in SiO2, Fe2O3T, pathfinder elements (e.g. As, Sb, Tl), and depletions of Na2O, CaO, Sr and MgO occur in quartz–muscovite schists approaching massive sulfide mineralisation. Within all strata (including the immediate hanging-wall), the following pathfinder elements are strongly correlated with Zn: Ag, As, Au, Bi, Cd, Eu/Eu*, Hg, In, Ni, Pb, Sb, Se and Tl. These geochemical halos resemble less metamorphosed VHMS deposits across the Yilgarn Craton and suggest that although metamorphism leads to element mobility and mineral segregation at the thin-section scale, assay samples of ∼20 cm length are sufficient to vector to mineralisation in amphibolite facies greenstone belts. Recognition of minerals such as Mg-chlorite, muscovite, cordierite, anthophyllite, biotite/phlogopite, and abundant garnet are significant, in addition to Al-rich phases (i.e. kyanite, sillimanite, andalusite and/or staurolite) not identified at King. Chemographic diagrams may be used to identify and distinguish different alteration trends, along with several alteration indices (e.g. Alteration Index, Carbonate–Chlorite–Pyrite Index, Silicification Index) and the abundance of normative corundum and quartz.

Geochemical vectors for stratiform Zn-Pb-Ag sulfide and associated dolomite-hosted Cu mineralization at Zinkgruvan, Bergslagen, Sweden

The Zinkgruvan deposit is the largest stratiform Zn-Pb-Ag mineralization in Sweden. The most recent genetic model attributes ore formation to the discharge of oxidized, near-neutral pH, metalliferous brines into a reduced basin, forming laterally extensive, stratiform sulfide mineralization on the seafloor. It has a known strike extent of 5 km and is underlain by a regionally extensive zone of K-altered metavolcanic rock and dolomitic marble, the latter hosting Cu-(Co-Ni) replacement mineralization near the inferred hydrothermal vent to the stratiform sulfides. The deposit is stratigraphically overlain by migmatized, pyrrhotite- and graphite-rich pelite that is in turn overlain by a banded almandine-biotite-quartz-ferrosilite-bearing unit at the base of a regionally extensive metasedimentary succession. These laterally continuous units are interpreted as metamorphosed organic-rich sulfidic mudstone and silicate-dominated Fe formation, respectively.The favorable stratigraphic interval contains anomalously high Zn, Pb, Ag, Cu, K2O/(K2O + Na2O), Mn, Co, Tl, Ba and B relative to adjacent metatuffite. However, only Zn, Pb, Ag, K2O/(K2O + Na2O) and Mn are significantly enriched relative to adjacent strata beyond the known lateral extent of the ore. Elevated copper, Co and Tl only occur in the vent-proximal part of the deposit, whereas anomalous enrichments of Ba and B are sporadic and occur mainly in the stratigraphic footwall. Many elements such as Si, Fe, Mg, Ca and Cs are of limited use in vectoring due to low enrichment factors relative to inferred background compositions and/or strong lithological controls on their distribution.Although ore metal (Zn, Pb and Ag) enrichments are the best quantitative and qualitative guides to ore, K, Mn and Co enrichments also provide corroborative support. The most useful elements for vectoring have been synthesized into exploration indices. The Modified Sedex Metal Index (MSMI; Zn + 3Pb + 100Ag) is a vector towards stratiform Zn-Pb-Ag mineralization, whereas MSMI2 [Zn + 3Pb + 10(Cu + Co)] also allows targeting of proximal Cu mineralization.The banded iron formation and the pyrrhotite- and graphite-rich pelite of the stratigraphic hanging wall are consistently enriched in base metals (e.g. 500–1000 ppm Zn), total S and Mn throughout the entire Zinkgruvan area. However, these units are not known to grade laterally along strata into economic base metal sulfide mineralization, and they are not obviously products of the same hydrothermal system which formed the stratiform Zn-Pb-Ag deposit.In a vent-distal setting, the somewhat spurious metal anomalies of the hanging wall units can be difficult to distinguish from those of the favorable interval. The favorable stratigraphic interval can, however, be recognized by also taking into account that positive Zn anomalies are mainly coincident with positive anomalies in both K and Mn only in the favorable interval. Furthermore, samples from the favorable interval generally have Co/Ni > 1 and display a positive Co/Ni vs. Zn trend, whereas samples of the pyrrhotite- and graphite-rich pelite have Co/Ni < 1 and define a negative Co/Ni vs. Zn trend. Thus, the index (Co/Ni)*Zn allows easy detection of weak Zn anomalies associated with the stratiform Zn-Pb-Ag mineralization.

Genesis of the Zinkgruvan stratiform Zn-Pb-Ag deposit and associated dolomite-hosted Cu ore, Bergslagen, Sweden

Zinkgruvan, a major stratiform Zn-Pb-Ag deposit in the Paleoproterozoic Bergslagen region, south-central Sweden, was overprinted by polyphase ductile deformation and high-grade metamorphism (including partial melting of the host succession) during the 1.9–1.8Ga Svecokarelian orogeny. This complex history of post-ore modification has made classification of the deposit difficult. General consensus exists on a syngenetic-exhalative origin, yet the deposit has been variably classified as a volcanogenic massive sulfide (VMS) deposit, a sediment-hosted Zn (SEDEX) deposit, and a Broken Hill-type (BHT) deposit. Since 2010, stratabound, cobaltiferous and nickeliferous Cu ore, comprising schlieren and impregnations of Cu, Co and Ni sulfide minerals in dolomitic marble, is mined from the stratigraphic footwall to the stratiform Zn-Pb-Ag ore. This ore type has not been fully integrated into any of the existing genetic models. Based on a combination of 1) widespread hematite-staining and oxidizing conditions (Fe2O3>FeO) in the stratigraphic footwall, 2) presence of graphite and reducing conditions (Fe2O3<FeO) in the ore horizon and hangingwall and 3) intense K-feldspar alteration and lack of feldspar-destructive alteration in the stratigraphic footwall, we suggest that both the stratiform Zn-Pb-Ag and the dolomite-hosted Cu ore can be attributed to the ascent and discharge of an oxidized, saline brine at near neutral pH. Interaction of this brine with organic matter below the seafloor, especially within limestone, formed stratabound, disseminated Cu ore, and exhalation of the brine into a reduced environment on the sea floor produced a brine pool from which the regionally extensive (>5km) Zn-Pb-Ag ore was precipitated.Both ore types are characterized by significant spread in δ34S, with the sulfur in the Cu ore and associate marble-hosted Zn mineralization on average being somewhat heavier (δ34S=−4.7 to +10.5‰, average 3.9‰) than that in the stratiform Zn-Pb-Ag ore (δ34S=−6 to +17‰, average 2.0‰). The ranges in δ34S are significantly larger than those observed in syn-volcanic massive sulfide deposits in Bergslagen, for which simple magmatic/volcanic sulfur sources have been invoked. Mixing of magmatic-volcanic sulfur leached from underlying volcanic rocks and sulfur sourced from abiotic or bacterial sulfate reduction in a mixing zone at the seafloor could explain the range observed at Zinkgruvan.A distinct discontinuity in the stratigraphy, at which key stratigraphic units stop abruptly, is interpreted as a syn-sedimentary fault. Metal zonation in the stratiform ore (decreasing Zn/Pb from distal to proximal) and the spatial distribution of Cu mineralization in underlying dolomitic marble suggest that this fault was a major feeder to the mineralization. Our interpretation of ore-forming fluid composition and a dominant redox trap rather than a pH and/or temperature trap differs from most VMS models, with Selwyn-type SEDEX models, and most BHT models. Zinkgruvan has similarities to both McArthur-type SEDEX deposits and sediment-hosted Cu deposits in terms of the inferred ore fluid chemistry, yet the basinal setting has more similarities to BHT and felsic-bimodal VMS districts. We speculate that besides an oxidized footwall stratigraphy, regionally extensive banded iron formations and limestone horizons in the Bergslagen stratigraphy may have aided in buffering ore-forming brines to oxidized, near-neutral conditions. In terms of fluid chemistry, Zinkgruvan could comprise one of the oldest known manifestations of Zn and Cu ore-forming systems involving oxidized near-neutral brines following oxygenation of the Earth’s atmosphere.

U–Pb zircon geochronology from the Alexander terrane, southeast Alaska: implications for the Greens Creek massive sulphide deposit

This paper presents results of a laser ablation – inductively coupled plasma – quadrapole mass spectrometer (LA–ICP–QMS) U–Pb dating study of small in situ zircon grains from samples collected in the vicinity of the Greens Creek massive sulphide deposit, on northern Admiralty Island, southeast Alaska. The Greens Creek mine is a volcanogenic massive sulphide deposit in the central portion of the Alexander Triassic metallogenic belt (ATMB) and is one of the top global silver producers despite having a dominantly mafic metavolcanic stratigraphic footwall. The stratigraphic footwall is a Mississippian mafic metavolcanic sequence with a protolith age of approximately 340–330 Ma. The first U–Pb zircon constrained chronostratigraphy for the area places the deposit near, or at, the base of the host Late Triassic stratigraphy just above an approximately 100 million year old unconformity and probably 10–15 million years older than mineralization at the Palmer and Windy Craggy deposits in the northern portion of the ATMB. The stratigraphic location of the Greens Creek deposit is atypical for a syngenetic massive sulphide deposit, and this may, at least partly, explain its unusual metal endowment. Pre-mineralization Permian U–Pb zircon metamorphic ages are consistent with published 273–260 Ma white mica ages related to the collision of the Admiralty and Craig subterranes, the basement to the ATMB. The much older age of the footwall rocks and their Permian pre-mineralization metamorphism demonstrates that though the mafic volcanic rocks are not genetically linked to the deposit, they likely influenced the style of alteration and mineralization.

Synsedimentary, Diagenetic, and Metamorphic Pyrite, Pyrrhotite, and Marcasite at the Homestake BIF-Hosted Gold Deposit, South Dakota, USA: Insights on Au-As Ore Genesis from Textural and LA-ICP-MS Trace Element Studies

The Paleoproterozoic Homestake deposit, northern Black Hills, South Dakota, is the largest banded iron-formation (BIF)-hosted gold deposit in the world and one of the largest single gold deposits globally (~1,300 t Au mined at an average grade of 8.4 g/t). The origin of the deposit has remained in dispute from its discovery, with views broadly falling into two groups: (1) the gold and associated elements were externally sourced and deposited in a suitable structural and/or chemical trap (e.g., iron formation), and (2) gold was indigenous to the host iron formation, from which it was remobilized into dilatant structural zones during deformation and metamorphism. In recent times, most workers have favored the former model, appealing to the broad synchroneity of Paleoproterozoic metamorphism, felsic magmatic activity, and gold event timing. LA-ICP-MS analysis of synsedimentary to early diagenetic sulfides at Homestake and surrounding area indicates that the Au in the orebodies may have originally had a significant syngenetic component. In particular, LA-ICP-MS mapping of multistage pyrites from carbonaceous shale in the upper Poorman Formation shows that Au and a suite of trace elements (Co, Ni, Cu, Zn, Se, Mo, Ag, Sb, Te, Au, Hg, Tl, Pb, and Bi), similar to those in diagenetic pyrite from around the globe, are contained in anhedral, sponge-textured cores and nodules surrounded by relatively trace element barren, Au-poor, euhedral pyrite rims. Furthermore, interelement ratios (e.g., Co/Ni, Ni/Ag) of the trace element-rich spongy and nodular pyrites are also similar to those of typical diagenetic pyrite. LA-ICP-MS imaging of pyrrhotite in the same rocks reveals multistage growth in this mineral as well, with the earlier generation having higher concentrations of Ag, Sb, Pb, Tl, and Bi than its presumed metamorphic counterpart. Imaging of marcasite in the shales of the upper Poorman Formation demonstrates this mineral’s high abundance of W and Tl relative to all generations of pyrite and pyrrhotite. Mass-balance calculations indicate that the volume of upper Poorman Formation in the mine area (approx. 12 km3) could potentially yield ~4,500 t of Au, a value greater than the total mined resource by more than a factor of three. These geochemical data and calculations suggest that a significant portion of the gold at Homestake may have been sourced from the relatively thick carbonaceous and sulfidic black shale facies in the stratigraphic footwall to the host iron formation, in a manner similar to other sediment-hosted gold districts.

Recognizing and quantifying metamorphosed alteration zones through amphibolite facies metamorphic overprint at the Key Anacon Zn–Pb–Cu–Ag deposits, Bathurst Mining Camp, New Brunswick, Canada

The Key Anacon deposits, Bathurst Mining Camp, New Brunswick, are hosted in upper greenschist- to amphibolite-facies felsic volcanic rocks. The occurrence of cordierite–biotite and garnet–biotite–muscovite assemblages parallel to the regional tectonic fabric in the metamorphosed hydrothermal alteration zones point to a pre-metamorphic mineralization event that was synchronous with sub-aqueous volcanism. Modeling the altered felsic volcanic rocks in the system K2O–Fe2O3–MgO–Al2O3–SiO2–H2O–TiO2 (KFMASHT) and comparing the observed peak metamorphic assemblages with those produced in a petrogenetic grid allows us to interpret the style of pre-metamorphic hydrothermal alteration related to deposit formation. The compositional change in the stratigraphic footwall (structural hanging wall) is characterized by mass gains of 0.1 to 4.0 wt.% Fe2O3 (Total), 0.7 to 22.2 wt.% MgO, and 0.5 to 55.2 wt.% CaO, and mass losses of 25.1 to 56.7 wt.% SiO2, 0.2 to 2.0 wt.% Na2O, and 0.3 to 3.8 wt.% K2O (the values of the mass changes cited here are in absolute terms).Variable gains and losses of Zn, Pb, and Cu are characteristic of the footwall alteration zones with Zn displaying gains proximal to the massive sulfide lens, and losses distal to the sulfide lens. The alteration indices (AI) values increase as the massive sulfide lens are approached from either the footwall or hanging wall, whereas the Ghandi index (GI) discriminates the intensely chlorite-altered rocks proximal to mineralization from the sericitic altered rock in more distal areas. Overall, there is an increase of the GI from the weakly to moderately altered zone (GI=1.3 to 6.0) to the more intensely altered zone (GI=6.1 to 60). These physical and geochemical observations are consistent with early feldspar-destructive alteration followed by chloritization proximal to the sulfide lens and accompanied by sericitization alteration distal prior to sulfidation and oxidation during prograde metamorphism.

U–Pb dating constraints on the felsic and intermediate volcanic sequence of the nickel-sulphide bearing Cosmos succession, Agnew-Wiluna greenstone belt, Yilgarn Craton, Western Australia

The Cosmos succession, within the Agnew-Wiluna greenstone belt of the Yilgarn Craton, consists of ultramafic, intermediate and felsic volcanic lithologies, and contains several komatiite-hosted nickel sulphide ore bodies. The volcanic succession that forms the stratigraphic footwall to the mineralised komatiite lavas consists of an intercalated sequence of fragmental and coherent extrusive lithologies, ranging from basaltic-andesites through to rhyolites. It also contains cross cutting felsic intrusions. The stratigraphic hangingwall consists largely of reworked volcanic-derived sedimentary rocks that include polymictic conglomerates containing granitic clasts. SIMS U–Pb dating was undertaken on zircons from nine felsic lithologies spanning the established stratigraphy. The footwall succession gives emplacement ages ranging from 2736±4 to 2724±3Ma. The overlying Cosmos Ultramafic sequence consists of two units; the basal ultramafic UMu1 package and the upper ultramafic UMu2 package, which are separated by a discontinuous felsic volcanic horizon that sits approximately 30–60m above the basal contact of the Cosmos Ultramafic sequence. This discontinuous felsic horizon is dated at 2685±8Ma and represents a break in accumulation of komatiite lavas and may be associated with a major hiatus. The succession also features two felsic intrusions emplaced at 2653±7Ma and 2670±6Ma, where the latter cross-cuts the upper contact of the UMu2 package. These results bracket the age of UMu1 package between 2724±3Ma and 2685±8Ma and that of UMu2 package between 2685±8Ma and 2670±6Ma. This stratigraphic division of the Cosmos ultramafic is further strengthened by the contrasting styles of mineralisation above and below the discontinuous felsic horizon and associated unconformity; UMu1 hosts several massive nickel sulphide deposits situated at the contact with the footwall volcanic succession, while UMu2 is typified by high-tenor disseminated nickel sulphide deposits situated just above the discontinuous felsic horizon. Our data indicates that the Cosmos volcanic succession was accumulated via punctuated volcanism spanning ∼50Ma that was followed by intrusive activity lasting for at least a further 32Ma. The results also imply that construction of this relatively small, mineralised greenstone succession lasted longer than anticipated on stratigraphic considerations alone, an outcome that may have implications for the timing of emplacement of other bi-modal volcanic successions in similar greenstone terranes.

Geology, mineralogy, and sulfur isotope geochemistry of the Sargaz Cu–Zn volcanogenic massive sulfide deposit, Sanandaj–Sirjan Zone, Iran

The Sargaz Cu–Zn massive sulfide deposit is situated in the southeastern part of Kerman Province, in the southern Sanandaj–Sirjan Zone of Iran. The stratigraphic footwall of the Sargaz deposit is Upper Triassic to Lower Jurassic (?) pillowed basalt, whereas the stratigraphic hanging wall is andesite. Mafic volcanic rocks are overlain by andesitic volcaniclastics and volcanic breccias and locally by heterogeneous debris flows. Rhyodacitic flows and volcaniclastics overlie the sequence of basaltic and andesitic rocks. Based on the bimodal nature of volcanism, the regional geologic setting and petrochemistry of the volcanic rocks, we suggest massive sulfide mineralization in the Sargaz formed in a nascent ensialic back-arc basin. The current reserves (after ancient mining) of the Sargaz deposit are 3 Mt at 1.34% Cu, 0.38% Zn, 0.08%Pb, 0.24 g/t Au, and 7 g/t Ag. The structurally dismembered massive sulfide lens is zoned from a pyrite-rich base, to a pyrite ± chalcopyrite-rich central part, and a sphalerite–chalcopyrite-rich upper part, with a sphalerite-rich zone lateral to the upper part. The main sulfide mineral is pyrite, with lesser chalcopyrite and sphalerite. The feeder zone, comprised of a vein stockwork consists of quartz–sulfide–sericite pesudobreccia and, in the deepest part, chlorite–quartz–pyrite pesudobreccia. Footwall hydrothermal alteration extends at least 70–80 m below the massive sulfide lens and more than a hundred meters along strike from the massive sulfide lens. Jasper and Fe–Mn bearing chert horizons lateral to the sulfide deposit represent low-temperature hydrothermal precipitates of the evolving hydrothermal system. Based on mineral textures and paragenetic relationships, the growth history of the Sargaz deposit is complex and includes: (1) early precipitation of sulfides (protore) on the seafloor as precipitation of fine-grained anhedral pyrite, sphalerite, quartz, and barite; (2) anhydrite precipitation in open spaces and mineral interstices within the sulfide mound followed by its subsequent dissolution, formation of breccia textures, and mound clasts and precipitation of coarse-grained pyrite, sphalerite, tetrahedrite–tennantite, galena and barite; (3) replacement of pre-existing sulfides by chalcopyrite precipitated at higher temperatures (zone refining); (4) continued “refining” led to the dissolution of stage 3 chalcopyrite and formation of a base-metal-depleted pyrite body in the lowermost part of the massive sulfide lens; (5) carbonate veins were emplaced into the sulfide lens, replacing stage 2 barite. The δ34S composition of the sulfides ranges from +2.8‰ to +8.5‰ (average, +5.6‰) with a general increase of δ34S ratios with depth within the massive sulfide lens and underlying stockwork zone. The heavier values indicate that some of the sulfur was derived from seawater sulfate that was ultimately thermochemically reduced in deep hydrothermal reaction zones.

U–Pb geochronology and Pb isotope characteristics of the Chahgaz volcanogenic massive sulphide deposit, southern Iran

The Chahgaz Zn–Pb–Cu volcanogenic massive sulphide (VMS) deposit occurs within a metamorphosed bimodal volcano–sedimentary sequence in the south Sanandaj–Sirjan Zone (SSZ) of southern Iran. This deposit is hosted by rhyodacitic volcaniclastics and is underlain and overlain by rhyodacitic flows, volcaniclastics, and pelites. Peperitic textures between rhyodacite flows and contact pelites indicate that emplacement of the rhyodacite occurred prior to the lithification of the pelites. The rhyodacitic flows are calc-alkaline, and show rare earth and trace elements features characteristic of arc magmatism. Zircons extracted from stratigraphic footwall and hanging-wall rhyodacitic flows of the Chahgaz deposit yield concordant U–Pb ages of 175.7 ± 1.7 and 172.9 ± 1.4 Ma, respectively, and a mean age of 174 ± 1.2 Ma. This time period is interpreted to represent the age of mineralization of the Chahgaz deposit. This Middle Jurassic age is suggested as a major time of VMS mineralization within pull-apart basins formed during Neo-Tethyan oblique subduction-related arc volcano-plutonism in the SSZ. Galena mineral separates from the layered massive sulphide have uniform lead isotope ratios of 206Pb/204Pb = 18.604–18.617, 207Pb/204Pb = 15.654–15.667, and 208Pb/204Pb = 38.736–38.769; they show a model age of 200 Ma, consistent with the derivation of Pb from a Late Triassic, homogeneous upper crustal source.

Towards a volcanic–structural balance: relative importance of volcanism, folding, and remobilisation of nickel sulphides at the Perseverance Ni–Cu–(PGE) deposit, Western Australia

Perseverance is a world-class, komatiite-hosted nickel sulphide deposit situated in the well-endowed Leinster nickel camp of the Agnew–Wiluna greenstone belt, Western Australia. The mine stratigraphy at Perseverance trends north-northwest (NNW), dips steeply to the west, and is overturned. Stratigraphic footwall units lie along the western margin of the Perseverance Ultramafic Complex (PUC). The PUC comprises a basal nickel sulphide-bearing orthocumulate- to mesocumulate-textured komatiite that is overlain by a thicker, nickel sulphide-poor, dunite lens. Hanging wall rocks include rhyodacite that is texturally and compositionally similar to footwall volcanic rocks. These rocks separate the PUC from a second sequence of nickeliferous, E-facing, spinifex-textured komatiite units (i.e. the East Perseverance komatiite). Past workers argue for a conformable stratigraphic contact between the PUC and the East Perseverance komatiite and conclude that the PUC is extrusive. This study, however, clearly demonstrates that these komatiite sequences are discordant, implying that the PUC may have intruded rhyodacite country rock as a sill with subsequent structural juxtaposition against the East Perseverance komatiite. Early N–S shortening associated with the regional DI deformation event (corresponding to the local DP1 to DP3 events at Perseverance) resulted in the heterogeneous partitioning of strain along the margins of the competent dunite. A mylonite developed in the more ductile footwall rocks along the footwall margin of the PUC, while isoclinal F3 folds, such as the Hanging wall limb and Felsic Nose folds, formed in low-mean stress domains along the fringes of the elongated dunite lens. Strata-bound massive and disseminated nickel sulphides were passively fold thickened in hinge areas of isoclinal folds, whereas basal massive sulphides lubricated fold limbs and promoted thrust movement along shallowly dipping lithological contacts. Massive sulphides were physically remobilised up to 20 m from their primary footwall position into deposit-scale fold hinges to form the 1A and Felsic Nose orebodies. First-order controls on the geometry of the Perseverance deposit include the thermomechanical erosion of footwall rocks and the channelling of the mineralised komatiitic magma. Second- or third-order controls are several postvolcanic deformation events, which resulted in the progressive folding and shearing of the footwall contact, as well as the passive fold thickening of massive and disseminated sulphide orebodies. Massive sulphides were physically remobilised into multiple generations of fold hinges and shear zones. Important implications for near-mine exploration in the Leinster camp include identifying nickeliferous komatiite units, defining their three-dimensional geometry, and targeting fold hinge areas. Fold plunge directions and stretching lineations are indicators of potential plunge directions of massive sulphide orebodies.

Geochemistry of Garnet-Rich Rocks in the Southern Curnamona Province, Australia, and Their Genetic Relationship to Broken Hill-Type Pb-Zn-Ag Mineralization

Garnet-rich rocks are locally associated with the giant Paleoproterozoic Broken Hill Pb-Zn-Ag deposit and hundreds of smaller Broken Hill-type occurrences in the southern Curnamona Province, Australia; however, others are present unrelated to sulfides. Mn-bearing garnet-rich rocks are conformable to bedding in metasedimentary rocks of the Paleoproterozoic Willyama Supergroup and, together with sulfide-bearing zones, are spatially related to amphibolite and/or felsic volcanic rocks or shallow granite intrusions. The stratiform garnet-rich rocks can be subdivided into two groups: Mn-rich varieties typical of the stratigraphic hanging wall of the Broken Hill deposit and Mn-poor and Fe-rich varieties that are typical of the footwall and are regionally widespread. These garnet-rich rocks formed on the floor of a rifted basin as a mixture of chemical precipitates and detrital sediments and were subsequently metamorphosed to the amphibolite or granulite facies during the Olarian orogeny. A plot of Fe/Ti versus Al/(Al + Fe + Mn) ratios of these rocks suggests equal proportions of hydrothermal and detrital components in the precursor phases. Low Co + Cu + Ni contents are consistent with the input of a small hydrogenous component. Quartz garnetite and garnet-gahnite rocks in the stratigraphic footwall of the Broken Hill deposit (Zn-rich, Cu-poor B and C lodes), and garnet-rich rocks elsewhere in the southern Curnamona Province that are Mn poor and Fe rich, exhibit chondrite-normalized rare earth element (REE) patterns with negative Eu anomalies, which indicate that the precursor minerals formed from hydrothermal fluids at <300°C and under relatively low f O2 conditions. Garnetite and hedenbergite-, bustamite-, and rhodonite-bearing garnet-rich rocks from the stratigraphic hanging wall of the Broken Hill deposit (Pb-rich 2 and 3 lenses and the A lode) are Mn and Ca rich, Fe poor, and have positive Eu anomalies. Precursors to these Mn-rich rocks formed from relatively cool hydrothermal fluids (~250°C) at f O2 conditions higher than those that formed Mn-poor, Fe-rich garnet- and gahnite-rich rocks at Broken Hill. Correlations among various elements show that the presence of positive or negative Eu anomalies in garnet-rich rocks depends on the composition of the precipitate (Fe, Mn, and trace metal content) as well as the chemical, crystallographic, or sorption control that the precursor Fe-Mn oxyhydroxides/oxides/carbonates had upon the incorporation of Eu. Garnet-rich rocks from the Broken Hill deposit have higher average Mn, K, Rb, Eu, Ga, Cs, Cu, Pb, Zn, As, Cd, Sb, Ag, W, and Au contents than those from other locations in the southern Curnamona Province, and these are more enriched in Fe, Mg, Ni, P, V, Co, Sc, Sr, Y, and U, which indicates a larger hydrogenetic component to their precursor minerals. Enrichments in Mn, S, Ga, Eu, Cu, Pb, Zn, As, Cd, Sb, Ag, and Au, and a positive Eu anomaly in garnetite can be used as exploration guides in the search for Broken Hill-type deposits by indicating close proximity to mineralization.

Lithogeochemical, mineralogical analyses and oxygen–hydrogen isotopes of the Hercynian Koudiat Aïcha massive sulphide deposit, Morocco

Koudiat Aïcha is a Visean stratiform, volcanogenic massive sulphide (VMS) zinc–copper–lead deposit, situated northwest of Marrakech, within the Central Domain of the Jebilet massif of the Western Moroccan Meseta. The Central Domain is formed mainly of sedimentary (argillite, siltstone, sandstone, carbonate) and magmatic (gabbro and rhyodacite) rocks that host numerous massive sulphide deposits (e.g., Koudiat Aïcha, Kettara and Draa Sfar) in a thick grayish argillite sequence (rhythmic metapelite). The deposit is stratabound and consists of highly deformed, sheet-like lenses of massive sulphide located structurally on the eastern flank of a large anticline. Prior to metamorphism, the country rocks were subjected to hydrothermal alteration which is particularly pronounced in the immediate vicinity of the sulphide deposits where chloritization and sericitization are prevalent. Hydrothermal alteration extends into both the stratigraphic footwall and the stratigraphic hanging wall. The footwall lacks an obvious pipe zone (sulphide stringers or vent complex) beneath the sulphide mineralization, but is characterized by an increase in the modal proportion of Mg-chlorite and by the breakdown of feldspar and sericite. Chloritization, the most extensive and readily recognizable alteration useful in mineral exploration, is evident for more than 60 m above the subcropping sulphide deposits. The hanging wall rocks show a pervasive sericitization (over 30 m wide) and a weak chlorite alteration accompanied by disseminated nodules of pyrrhotite stretched parallel to the S 1 foliation. Because chlorite and sericite are metamorphic minerals that also occur in unaltered rocks surrounding the sulphide deposits, abundant Mg-rich chlorite and the absence of feldspar in the footwall are used to distinguish hydrothermal alteration facies from metamorphic facies. The chlorite geothermometer reveals temperatures between 250 and 330 °C. Higher temperatures (up to 300 °C) are associated with chlorite located in and adjacent to sulphide mineralization, whereas lower temperatures correlate with distal chlorite in both the footwall and hanging wall rocks. Chemical trends in altered footwall rocks are shown by absolute mass gains for Fe 2O 3total, MnO and MgO, by absolute mass losses for CaO, K 2O and Na 2O, and by a moderate loss in SiO 2. Oxygen and hydrogen isotope compositions of Koudiat Aïcha lithofacies (6.2–12.4‰ for oxygen and −51‰ to −36‰ for hydrogen) have also been used to determine the temperature and origin of metalliferous fluids. The couple plagioclase–amphibole of gabbros provides equilibrium temperatures between 310 and 380 °C and suggests that the heat source for the ore-forming fluid system may have been igneous. On the other hand, oxygen and hydrogen isotope ratios cluster between normal values for sedimentary and magmatic rocks, suggesting a magmatic–metamorphic origin for the ore fluid.

Structural Modification of the Komatiite-Associated Harmony Nickel Sulfide Deposit, Leinster, Western Australia

The Harmony nickel sulfide deposit (3.2 Mt of ore) is situated along the eastern margin of the Agnew-Wiluna greenstone belt, Eastern Goldfields, Western Australia. The deposit occurs 2 km north of the larger Rocky’s Reward (15.9 Mt) and Perseverance (50.7 Mt) deposits. The mine stratigraphy trends north-northwest–south-southeast, dips moderately (30°–80°) to the west, is overturned, and metamorphosed to middle-amphibolite facies grades (about 550°C, 3 kbars). Stratigraphic footwall units to the west of the nickel-bearing komatiite include ca. 2720 to 2725 Ma (volcano-) sedimentary rocks and rhyodacite volcanic and volcaniclastic units. Hanging-wall units comprise mainly reworked sedimentary or volcaniclastic rocks interlayered with at least two barren spinifex-textured komatiite units exposed in the mine area. Exhalative pyrite-rich pelitic units and thin amphibolite units are locally present in the footwall and hanging wall. The nickeliferous komatiite is thickest in the center of the deposit and thins to the north, south, and at depth. Although massive sulfides and minor disseminated sulfides are mainly located along the sheared western footwall contact, minor massive sulfides occur throughout the komatiite and country rock in fold hinges, boudin neck areas, brittle-ductile shear zones, piercement cusps, piercement veins, and brittle faults. Footwall and hanging-wall units have a strong composite fabric defined by compositional layering and several subparallel axial planar foliations. East-west shortening resulted in the folding of the composite fabric to form abundant north-northwest–trending, tight, asymmetric, moderately (20°–40°) N- and S-plunging folds. The asymmetric folds thicken the komatiite and orebodies in the center of the pit and control deposit-scale orebody plunge directions. The attenuated north-northwest–trending komatiite fold limbs are boudinaged and concentrate pods of massive sulfides in boudin neck positions. Relaxation in horizontal shortening coincided with open recumbent folding of the steeply dipping limbs of earlier upright asymmetric folds. A resumption of east-west shortening in a brittle stress regime resulted in the remobilization of massive sulfides into east-west–trending brittle faults. The concentration of massive sulfides in brittle-ductile to brittle structures indicates that massive sulfide remobilization spanned a diverse range of deformation and metamorphic conditions. The present geometry and distribution of stratigraphy and orebodies at Harmony reflect a complex interplay of primary magmatic and secondary overprinting processes. Remobilized massive sulfide orebodies are an important exploration target in other deformed and metamorphosed terranes that host primary Ni-Cu-(PGE) deposits. Although footwall units are the preferential host to remobilized massive sulfide shoots, massive sulfides are commonly remobilized within shear zones and faults zones and hosted by hanging-wall units up to 50 m from their primary footwall position. In cases of folding, orebodies tend to be elongate parallel to the plunge direction of fold axes or mineral stretching lineation, and potential exploration targets occur along the trend of known folded ore shoots and more specifically along the plunge line of such shoots.

Lithogeochemistry and Hydrothermal Alteration at the Halfmile Lake South Deep Zone, a Volcanic-Hosted Massive Sulfide Deposit, Bathurst Mining Camp, New Brunswick

The Halfmile Lake South Deep zone, Bathurst Mining Camp, New Brunswick, was discovered by Noranda Inc. (Exploration) as a result of a 3-D seismic survey in 1998 and the subsequent drilling of ten diamond-drill cores. The deposit consists of massive, breccia, and stockwork Pb-Zn-Cu sulfide minerals, and is hosted by a volcano-sedimentary sequence belonging to the overturned Ordovician Tetagouche Group. Epiclastic rocks and interbedded fine-grained felsic pyroclastic rocks dominate the stratigraphic footwall. Locally, crystal-rich felsic tuffs and subordinate epiclastic rocks comprise the immediate stratigraphic hanging wall. The entire stratigraphic sequence was intruded by quartz-feldspar porphyritic intrusions, and cut by intermediate and basic dikes. The volcanic and sedimentary rocks can be discriminated geochemically using trace element ratios such as Zr/TiO2 and Nb/TiO2, despite intensive alteration and cleavage development. These ratios indicate that four protolith volcanic compositions exist: rhyolite, dacite, andesite, and basalt. The aphyric and feldspar- and quartzphyric volcanic rocks are dacitic and rhyolitic in composition; epiclastic rocks have trace element ratios consistent with dacitic compositions. Pearce element ratio diagrams, general element ratio diagrams, and petrographic observations demonstrate that the rhyolitic volcanic rocks exhibit evidence of albite, potassium feldspar, and quartz fractionation, dacitic volcanic rocks exhibit little evidence of any fractionation, and epiclastic sedimentary rocks exhibit evidence of quartz sorting only. Hydrothermal alteration is best represented by the presence of phengitic muscovite and daphnitic chlorite. Minor calcite occurs in the stratigraphic hanging wall, deep in the stratigraphic footwall, and in post-mineralization dikes, and thus is not interpreted to be part of the causative hydrothermal event. Element additions and losses during alteration have been used to determine net alteration reactions, and these have been used to identify alteration parameters that are independent of other forms of alteration and fractionation/sorting, and which can be used to guide exploration. These parameters include: a bulk hydrolysis measure, (2Ca+Na+K–2CO2)/Al; a muscovite alteration measure, K/Al; an albite destruction measure, Na/Al; a chlorite alteration measure, (Fe+Mg–S/2)/Al; a chlorite composition measure, (Fe–S/2)/Mg; a sulfidization measure, S/Ti; and a carbonatization measure, CO2/Ti. With the exception of the carbonatization measure, these alteration parameters define a distinct lateral and vertical zone of intense hydrothermal alteration in the stratigraphic footwall of the deposit, and demonstrate that the epiclastic rocks are predominantly chlorite altered, and the volcanic rocks are predominantly muscovite altered. Within the alteration halo, element additions of Fe and H, and element losses of Na are characteristic. Potassium was added to muscovite-altered rocks, but subsequently removed from chlorite-altered rocks. The results from this study demonstrate that metamorphism and deformation have not significantly obscured hydrothermal alteration signatures.