Urban transportation significantly contributes to global carbon emissions, thus emphasizing the importance of green and efficient alternatives like public transportation. Enhancing the appeal of public transport through the strategic placement of bus stops can mitigate carbon emissions concurrently. This research proposes a Quantum Entangled Self-Attention Neural Networks (QESANN) model that considers both the passengers and stops characteristics to optimize bus stop locations. The QESANN model integrates the complexity of the relationship between passengers and bus stops characteristics, thereby fostering a more holistic approach to bus stop placement. It uses a Conditional Random Field (CRF) to initialize and process the attributes of both commuters and bus stops through quantum entanglement. The Vehicle Specific Power (VSP) model is employed to gage the variation in bus carbon emissions pre and post bus stop location optimization. Simulation tests, conducted via the Anylogic software and the IBM Quantum platform, demonstrated promising results. Over a yearly travel cycle for 1,000 individuals, the number of bus commuters rose from 322 to 651, concurrently reducing urban traffic carbon emissions by 430,243.70 kg annually. These findings affirm the effectiveness of the proposed QESANN model in enhancing the appeal of bus stops, reducing carbon emissions from urban transportation, and fostering a more sustainable urban environment.