Effective capturing of anionic pollutants from wastewater under industrial operating conditions, which requires high processing flux and fast adsorption rate remains a challenge. Here, a commercially available melamine sponge (MS) with reticulated 3D macroporous structures was covalently modified with positively charged moieties using a single step functionalization under mild conditions. The developed novel polycationic melamine sponge (MS+) was formed by a nucleophilic addition reaction between glycidyltrimethylammonium chloride (GMTA) and MS, followed by a self-propagation of GMTA. The produced MS+ possessed strong electrostatic interactions with different anions such as Rose Bengal (RB) and phosphates (P) under a wide pH range (3–11). The MS+ exhibited promoted static adsorption efficiencies of 400 mg g−1 (P) and 600 mg g−1 (RB), within 5 min and 60 s, respectively. Furthermore, the MS+ showed high stability and recyclability for up to 15 cycles of uses, and the recycling process was environmentally friendly by using 1 M NaCl as a releasing solution. Benefiting from fast flow through the macroporous MS+ and highly positive charged skeleton, the MS+ was applied for rapid dynamic enrichment process of P from real manure wastewater with an enrichment factor of 4.4. Utilization of the MS+ as the substrate brings additional advantages such as low cost, availability, and flexibility to fit into existing filtration devices. The developed MS+ could be expanded for enrichments of other anionic species from various polluted water sources.
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