AbstractEvasion of carbon dioxide (CO2) from headwater streams is a dominant process controlling the fate of terrestrially derived carbon in inland waters. However, limitations of sampling techniques inhibit efforts to accurately characterize CO2 evasion from streams, and particularly headwater streams with steep gradients, complex morphologies, and challenging terrain. CO2 source dynamics coupled with turbulence conditions control gas transfer velocities of CO2 ( ) and therefore drive CO2 evasion. We present estimates of and CO2 evasion from a steep, turbulent headwater stream in southwestern British Columbia, Canada, collected using an automated in situ CO2 tracer technique. Gas transfer velocities scaled positively with discharge, with a median of 36.8 m/day and a range of 13.5 to 169 m/day. Gas transfer velocities were highest during high‐flow events, with 84% of all CO2 emissions occurring when discharge was higher than Q50, the median discharge (92.6 L/s). Widely used models overestimated gas transfer velocities with a mean relative error of 24% but underestimated k600 values above 165 m/day. Our determinations of gas transfer velocities for a range of streamflow suggest that CO2 evasion may be higher than previously estimated from direct measurements or models, particularly during high‐flow events. These findings illustrate the need for direct, frequent, in situ determinations of to accurately characterize CO2 evasion dynamics in steep headwater streams.
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