Microalloyed Steel Research Articles

Insight into stress corrosion cracking in heat-affected zone of Nb micro-alloyed high-strength low-alloy steel in SO2-polluted seawater

Insight into stress corrosion cracking in heat-affected zone of Nb micro-alloyed high-strength low-alloy steel in SO2-polluted seawater

Effect of Initial Microstructure on Austenite Grain Size of Niobium Microalloyed Steels

Effect of Initial Microstructure on Austenite Grain Size of Niobium Microalloyed Steels

Reduced spheroidization in rail flash-butt welding by selective alloying

Thermal cycle (welding simulations) at the inter-critical region were performed on an Si and V micro-alloyed (not heat-treated) rail steel. The beginning of austenitization temperature (Ac1) in the micro-alloyed rail steel occurred significantly above that observed in an alternative heat-treated rail steel. Very little pearlite alteration was observed until austenitization at a temperatures above 750°C, where there was a reduction in hardness and onset of spheroidization. The maximum spheroidization together with the lowest observed hardness occurred at 760°C. It was also observed that there is a linear correlation between hardness and volume fraction of spheroidization of cementite. By the dilatometric variation, contraction due to austenitization was observed only from 760°C onwards in the 60 s isothermal period at the austenitization temperature. These results may lead to a new approach to weldability and reduction of the softened region concerning rail welding.

Continuous cooling transformation in micro-alloyed medium-carbon steel and optimization of the forging process for half-shaft production

Abstract Micro-alloyed medium-carbon steel is increasingly used as a cost-effective alternative to quenched and tempered steel in the production of half-shaft components. Current research emphasizes controlling the microstructure during thermomechanical processing to achieve the desired structural properties after cooling. This study investigated the effect of continuous cooling transformation on the microstructure and mechanical properties of micro-alloyed medium-carbon steel. At a cooling rate of 0.5 °C s−1, only pearlite transformation occurred. At rates between 1 °C s−1 and 8 °C s−1, both bainite and martensite transformations were observed, while only martensite formed at rates exceeding 12 °C s−1. Subsequently, a four-factor, three-level orthogonal experiment was designed based on the actual production process for half shafts. The optimal forging parameters were identified as a heating temperature of 1000 °C, a deformation temperature of 920 °C, a deformation extent of 15%, and a cooling rate of 0.5 °C s−1. The study offered solutions to enhance microstructural uniformity and effectively manage abnormal bainite and martensite formations, thereby establishing a foundation for the high-quality application of micro-alloyed medium-carbon steel in half-shaft components.

Simulating Study on the Shrinkage Cavity and Porosity of a Microalloyed Steel Ingot

Simulating Study on the Shrinkage Cavity and Porosity of a Microalloyed Steel Ingot

Mechanistic role of vanadium microalloying in improving corrosion resistance of low carbon bainitic steel

We here investigated the effect of vanadium microalloying on the microstructure, mechanical properties, especially corrosion performances of low carbon bainitic steels. The corrosion behaviors of the steels with different vanadium contents in 3.5 wt% NaCl solution were evaluated by electrochemical tests (including polarization curves and electrochemical impedance spectroscopic measurements) and alternating immersion test (including weight loss and rust layer observation). Results show that the mechanical properties and corrosion resistance of low carbon bainitic steels can be synergistically improved with vanadium microalloying. With help of the electron backscatter diffraction characterization and scanning Kelvin probe force microscopy, we first discovered that although the number of micro-galvanic couples increases because of grain refinement, the Volta potential gradient between the matrix and grain boundaries are decreased with vanadium microalloying, which can promote the formation of compact protective rust layers and improve the corrosion resistance of vanadium micro-alloyed low carbon bainitic steels.

The Influence of Thermomechanical Conditions on the Hot Ductility of Continuously Cast Microalloyed Steels.

Continuous casting is the most common method for producing steel into semi-finished shapes like billets or slabs. Throughout this process, steel experiences mechanical and thermal stresses, which influence its mechanical properties. During continuous casting, decreased formability in steel components leads to crack formation and failure. One reason for this phenomenon is the appearance of the soft ferrite phase during cooling. However, it is unclear under which conditions this ferrite is detrimental to the formability. In the present research, we investigated what microstructural changes decrease the formability of microalloyed steels during continuous casting. We studied the hot compression behaviour of microalloyed steel over temperatures ranging from 650 °C to 1100 °C and strain rates of 0.1 s-1 to 0.001 s-1 using a Gleeble 3800® (Dynamic Systems Inc, Poestenkill, NY, USA) device. We examined microstructural changes at various deformation conditions using microscopy. Furthermore, we implemented a physically-based model to describe the deformation of austenite and ferrite. The model describes the work hardening and dynamic restoration mechanisms, i.e., discontinuous dynamic recrystallisation in austenite and dynamic recovery in ferrite and austenite. The model considers the stress, strain, and strain rate distribution between phases by describing the dynamic phase transformation during the deformation in iso-work conditions. Increasing the strain rate below the transformation temperature improves hot ductility by reducing dynamic recovery and strain concentration in ferrite. Due to limited grain boundary sliding, the hot ductility improves at lower temperatures (<750 °C). In the single-phase domain, dynamic recrystallisation improves the hot ductility provided that fracture occurs at strains in which dynamic recrystallisation advances. However, at very low strain rates, the ductility decreases due to prolonged time for grain boundary sliding and crack propagation.

Revealing the Corrosion Resistance Mechanism of Plain Carbon Steel Micro-Alloyed by La in Simulated Industrial Atmosphere.

Plain carbon steel is the most widely applied steel in current engineering construction. With the increased application property needs, the service life of plain carbon steel has been severely tested. As one of the most destructive failure modes, corrosion resistance of carbon steel has attracted wide attention. Rare earth La, as the microalloying element, was employed in plain carbon steel, Q355, to improve its corrosion resistance. As the content of La increased, the microstructure was refined. The fraction of pearlite decreased, while the content of acicular increased. Within the La addition of 230 ppm, the tensile strength and impact energy were jointly improved. Furthermore, the microalloying element of La modified the inclusion types and refined the inclusion size. The modified microstructure and inclusions by La co-improved the corrosion resistance. The formula of effective La content was proposed to estimate the effect of La on corrosion. As the effective content of La increased, the relative corrosion rate decreased. La3+ promoted the protective rust layer to increase corrosion resistance.

Study on the control of transverse cracks at the corners of large square billets for continuous casting of marine 945 hypo-peritectic micro-alloyed steel

Hypo-peritectic micro-alloyed steel has strong crack sensitivity, and marine 945 steel, as a kind of sub-encapsulated crystalline micro-alloyed steel, has frequent corner cracks during production, which seriously affects the production rhythm and reduces the product quality. Through the study of the morphology and composition of the matrix near the crack, the study and analysis of the high-temperature mechanical properties of the steel itself, and combined with the actual production situation, the causes of the corner cracks were clarified and the process optimisation was carried out accordingly. The results of the study show that the generation of corner cracks is due to the improper deoxidation process, uneven heat transfer inside the crystallizer and inappropriate cooling water parameters in the steelmaking process. By changing the deoxygenation method, crystallizer protective slag performance, crystallizer cooling water volume, water volume in the second cooling zone and other measures, the occurrence of billet corner cracks was effectively reduced, and the frequency of billet corner cracks was reduced from 6.3 to 2/m.

Effects of rare earth on nitriding microstructure and properties of a La-Ce micro-alloyed Q235RE steel

Accelerating nitriding is an interesting topic in chemical heat treatment of ferrous parts. In order to have a deeper understanding of the catalysis principles of rare earth in nitriding, a Q235 carbon steel and a Q235RE steel micro-alloyed with rare earth elements La and Ce were nitrided respectively by plasma nitriding and gas nitriding. The microstructure, phase constitution, and composition of the nitrided specimens were analyzed. The hardness profile of nitriding layer and the brittleness of surface compound layer were measured. The results demonstrate that the Q235RE specimens obtained a higher hardness and deeper effective hardening layer than the Q235 specimens without rare earth microalloying. The rare earth catalysis effects were presented as the acceleration of nitrogen diffusion and the inhibition of nitride precipitation in the diffusion layer of the Q235RE specimens. In addition, the surface compound layer of the Q235RE specimens showed higher toughness and better adhesion to the matrix than that of the Q235 specimens, which is considered to be strongly related to the rare earth elements diffused into the compound and the enhanced residual compressive stress in the layer.

A prediction model of brittle crack arrest toughness in TMCP heavy plates

Micro-alloyed low carbon MnCrNiCuMo steels were proposed to produce heavy plates with a maximum thickness of 100 mm. An integrated industrial route including a thermo-mechanical control process (TMCP) based on a study on continuous cooling transformation was applied in industrial production. Comprehensive mechanical properties tests including the measurement on resistance against crack initiation using crack tip opening displacement (CTOD) approach were conducted. Large scale wide-plate temperature gradient double tension (DT) technique was employed to evaluate the crack arrest toughness Kca in the heavy plates under different conditions. Nil-ductility transition temperature (NDTT) was also tested across the entire thickness section of the plates. The results showed that heavy steel plates were qualified being brittle crack arrest (BCA) products at EH47 grade with yield strength high than 460 MPa. High crack initiation toughness was exhibited by both Charpy-V notch impact property and CTOD values. Crack arrest toughness at −10 °C greater than 253 MPa √m was achieved in a plate even with thickness of 100 mm. The mean value of crack arrest toughness at different temperature measured by the DT approach can be indexed by the highest NDTT in the interior section of the heavy plates leading to an empirical prediction model. Further, fracture mechanics based master curve approach was used to statistically predict crack arrest toughness distribution over a wide range of temperatures showing improved predictability over the empirical model and an existing model in the literature.

Experimental Study on Microalloyed Steel with Layers Subjected to Diesel

This work studies the mechanical behavior of microalloyed steels (API X60 and API X70) with boride layers using a boriding process and immersion in diesel. First, the microalloyed steels were borided using dehydrated boron paste at a temperature of 1273 K for 6 h, and then the borided microalloyed steels were immersed in diesel for one year. The characterization of the layers on the specimens subjected to diesel used scanning electron microscopy (SEM), energy dispersive spectroscopy, and X-ray diffraction (XRD). The evaluation of the mechanical properties was performed with tensile tests according to ASTM E8, and then the fracture surface was observed by SEM. This work contributes to the understanding of the changes in the mechanical properties of borided microalloyed steel immersed in diesel for possible potential applications in the storage of fuels, oils, hydrogen, and biofuels.

Austenite Growth Behavior and Prediction Modeling of Ti Microalloyed Steel.

Previous studies on the austenite grain growth were mostly based on a fixed temperature, and the relationship between the austenite grain and austenitizing parameters was fitted according to the results. However, there is a lack of quantitative research on the austenite grain growth during the heating process. In the present work, based on the diffusion principle of the controlled Ti microalloying element, the diffusion process of carbonitrides containing Ti during the heating process was analyzed. Combined with the precipitation model and the austenite growth model, the prediction model of austenite grain growth of Ti microalloyed steel during different heat treatment processes was established. The austenite grain size versus the temperature at four different heating rates of 0.5, 1, 10, 100 °C/s was calculated. The grain growth behavior of austenite during the heating process of Ti microalloyed steel was studied by optical microscope, scanning electron microscope and transmission electron microscope. The experimental data of the austenite grain size was in good agreement with the calculation by the proposed model, which provides a new idea for the prediction of austenite grain size in non-equilibrium state during the heating process. In addition, for Ti-containing microalloyed steels, the austenite grain size increased with the increasing heating temperature, while it changed little by further prolonging isothermal time after certain heating time, which was related to the equilibrium degree of the precipitation and the dissolution of Ti element. The austenite grain coarsening temperature of the tested Ti microalloyed steel was estimated within 1100~1200 °C.

Nucleation Stages Onset and Intra-granular Ferrite Morphologies in Titanium Free Micro-Alloyed Steel

The aim of this work is focused on nucleation stages with emphasis on the development of intra-granular ferrite morphologies during isothermal austenite transformation in titanium free micro-alloyed steel. Isothermal treatment was carried out in the temperature range 350 to 600οC. These treatments were interrupted at different times between 2 and 1800 s in order to analyze the evolution of the microstructure. Metallographic evaluation was done by using optical and scanning electron microscopy (SEM) enabled determination of the nucleation onset at all treatments and subsequent on the development of intra-granular ferrite of isothermally treated Ti free micro-alloyed steel. The results show that at high temperatures ( 500  C) polygonal intra-granularly nucleated ferrite idiomorphs, combined with grain boundary ferrite and pearlite were produced and followed by an incomplete transformation phenomenon, At intermediate temperatures (450 and 500  C) an interlocked acicular ferrite (AF) microstructure is produced, and at low temperatures (400 and 350  C) the sheave of parallel acicular ferrite plates, similar to bainitic sheaves but intra-granularly nucleated were observed. In addition to sheaf type acicular ferrite, the grain boundary nucleated bainitic sheaves are observed.

Nucleation Stages of Isothermal Transformation in Titanium and Titanium Free Micro-Alloyed Steels

This work is focused on nucleation stages during isothermal austenite transformation in two types ofVanadium micro-alloyed steels. Isothermal treatment wascarried out in the temperature range 350 to 600C.Metallographic evaluation using optical and scanningelectron microscopy (SEM) enabled determination of thenucleation curves of isothermally decomposed austenite.Three curves are found to be relevant to this initiation stageof transformation: first curve is related to grain boundarynucleated ferrite (GBF), second curve is related to intragranularly nucleated ferrite (IGF) and the third to pearlite(P) curve. GBF and IGF curves are divided into two regions,which represents the high temperature and the lowtemperature segments as consequence of either displacivenature of transformation or diffusion transformation.Addition of Ti to V – micro-alloyed steel in this work seemsto be balanced by a slightly higher C and Mn content,leading to limited effect on nucleation stage of austenitedecomposition.

The effects of quenching and partitioning on the microstructure and tensile properties of high strength suspension spring steel

The evolution of microstructure and mechanical properties were investigated by the quenching and partitioning heat treatment for a kind of micro-alloyed 51CrMnV spring steel. The results show that the microstructure of the test steel treated by quenching and partitioning heat treatment is mainly composed of martensite, retained austenite and carbides. Based on the quenching treatment, the optimal mechanical properties of test steel were obtained by the process of partitioning treatment at 350°C for 20 minutes. The tensile strength and elongation were 1812 MPa, 11.5 %, respectively. This is largely due to the microstructure of test steel having a good combination of martensite, filmy retained austenite, and fine carbides. As the partitioning temperature increases, the fraction of retained austenite decreases from 13.1 % at 250°C to 3.11 % at 350°C. Furthermore, the retained austenite almost disappears when the partitioning temperature increases to 400°C. In addition, as the partitioning temperature increases, the tensile strength remains above 1600 MPa, and the fracture behavior changes from brittle fracture to ductile fracture. At the same time, the grain size becomes larger, the proportion of large-angle grain boundaries increases, and the geometric dislocation densities become smaller.

Suppress Austenite Grain Coarsening by Nb Alloying in High-Temperature-Pseudo-Carburized Bearing Steel.

The effect of Nb alloying on the suppression of austenite grain coarsening behavior during pseudo-carburizing is investigated in high-temperature-carburized SAE4320 bearing steel. To explore the role of the Nb element in the pseudo-carburizing process, the morphology, composition, size, and distribution of NbC precipitates were analyzed. The results show that the fine austenite grain observed in Nb micro-alloyed steel is caused by the pinning effect of NbC precipitates, which hinders the coarsening of austenite grains and changes the growth dynamics of austenite grains. After the SAE4320 carburized bearing steel with the addition of 0.45 wt.% Nb element is kept at 1150 °C for 4 h, the PAG size is still below 20 μm, which indicates the Nb element has obvious advantages in limiting PAG growth at high temperatures and shows great potential for the development of high-temperature carburized bearing steel.

Cluster mediated high strength and large ductility in a strip casting micro-alloyed steel

Exhibiting exceptional mechanical properties and formability, high strength low alloy steels characterized by a single ferrite microstructure with finely dispersed nano-precipitates (ferritic HSLA steel) have garnered notable attention in the automotive industry. Nevertheless, to maximally utilize the precipitation hardening effect, these steels necessitate substantial additions of carbide-forming elements, unavoidably narrowing the process window and escalating the cost. Strip casting, featuring a streamlined process chain and high energy efficiency, has emerged as a promising technique for developing ferritic HSLA steels. In this work, leveraging the process characteristics of strip casting, we report that a novel single ferrite microstructure with multi-atomic layered clusters distributed in both interphase-precipitation and random fashions was engineered in a low Nb micro-alloyed ferritic HSLAs via raising the coiling temperature to 650 ℃. The multi-atomic layered clusters play a pivotal role in tailoring dislocation behaviors, facilitating local double cross-slips, contributing to dislocation multiplication and homogeneous distribution. These mechanisms collectively sustain mild work hardening to higher strains, leading to combined strength and ductility increments. In comparison to their cluster-free bainitic counterparts coiled at 480 ℃, the results demonstrate significant mechanical improvements with an increase in ultimate strength (630 MPa to 670 MPa) and a 90 % rise in plasticity (10.3 % to 19.1 %), signifying an alternative pathway for advancing the utilization of strip casting technology in designing and processing novel low-cost, high-performance HSLAs.

Carbonitride Precipitation Kinetics Model During Continuous Casting of Ti Microalloyed Steel

Carbonitride Precipitation Kinetics Model During Continuous Casting of Ti Microalloyed Steel

Correlative Electron Microscopy Analysis of Precipitates in a V–Nb–Mo Micro-alloyed Steel

Correlative Electron Microscopy Analysis of Precipitates in a V–Nb–Mo Micro-alloyed Steel