To improve the output characteristics of seawater desalination-solar chimney power plants, enrich the theoretical research basis and promote its commercial application, this paper introduces the concept of multilayer flow channel, establishes four new types of multilayer collector flow channel, and constructs the corresponding heat and mass transfer mathematical models, revealing the mechanism of the influence of different flow channel and structural parameters on the system performance. The results showed that the surround-flow system extended the heat absorption time of the airflow, had two thermal storage layers, and had the best performance. The daily average power generation was 43.3 kW, and the average water production rate was 87.2 g/(h·m2), which was 132.8 % and 91.2 % higher than the traditional type’s, respectively, but had the longest start-up time. For the surround-flow system, the main reason for the flow loss increasing is swirling regions below the inlet and the transition section caused by the structure itself. Both the inlet width increasing and the roof’s inclination angle decreasing can increase power generation, with little impact on water production. Corner width increasing results in a significant decrease in water production, with little impact on power generation. The determination of structural parameters should also consider operational costs.
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