Starch Dough Research Articles

Effect of salt and alkali on the viscoelastic behavior of noodle dough sheet with different wheat starch granule sizes

The underlying mechanisms of salt and alkali on the viscoelastic behaviors of noodle dough sheets with varied B/A-type starch ratios were investigated from water state, protein polymerization and conformation, and microstructure. The viscoelastic behaviors of dough sheets increased with increasing B/A-type starch ratio, regardless of the presence of salt and alkali, indicating the addition of salt and alkali did not change the effect law of starch granule size on dough viscoelasticity. The viscoelastic moduli of dough decreased in the presence of salt and alkali, and the effect was more obvious as the ratio of B/A-type starch decreased, which was mainly determined by the interactions of protein-protein, protein-starch, and starch-starch in dough systems. In the low ratio of B/A-type starch dough sheets, NaCl enhanced the non-covalent interactions and β-sheet structure, while alkali promoted the covalent cross-linking of protein. In the high ratio B/A-type starch dough samples, the big starch surface area provided by a high phase volume of starch granules led to the domination of starch-starch interactions over the protein phase, thus determining the viscoelastic behavior of dough. SEM images showed that NaCl caused the gluten to form a fibrous structure, while alkali induced a membrane-like and more closed structure. NaCl and alkali showed different influences on water distribution, molecular conformation, and network structure of dough sheets with varied B/A-type starch ratios and thus contributed to the different viscoelastic behaviors.

Enhanced B-type starch granules proportion modulates starch-gluten interactions during the thermal processing of reconstituted doughs

This work investigated structure-properties changes of reconstituted wheat A/B starch doughs under different ratios during dynamic thermal processing. Results indicated that a change in spatial conformation and aggregation structure of the starch-gluten system was induced with heating (30 °C–86 °C). Moderately increased B starch ratio can effectively fill the gluten network and improve starch-protein interactions, which promotes the free sulfhydryl group oxidation and results in the formation of more glutenin macropolymer; this contributes to a higher degree of cross-linking and stability to the gluten network matrix. This improvement is enhanced as the heating temperature is increased. Notably, the B starch ratio requires to be controlled within a suitable range (≤ 75%) to avoid aggregation and accumulation on the gluten matrix triggered by its excess. This work may provide insights and optimization for clarifying the on-demand regulation strategy of A/B starch in dough processing.

Liquid Chromatography with Tandem Mass Spectrometry Analysis of Carboxymethyl Lysine in Indonesian Foods.

There is little data on directly measured carboxymethyl lysine (CML) content in Indonesian foods. This study aimed to generate a database of CML values in foods commonly consumed in West Java and West Sumatra. The results were to be used to update our previous estimated CML values. CML values in food samples were measured using high-pressure liquid chromatography with tandem mass spectrometry (HPLC-MS/MS). Food protein content was analyzed by Kjeldahl's method or inferred from the nutrition facts' label. A total of 210 food samples were examined, with the food groups of meat and poultry (1.06 mg CML/100 g edible food), and starchy foods (0.21 mg/100 g edible food) having the highest and lowest mean CML levels, respectively. We found that the foods with the top three highest CML content were fried starch dough (cimol), fried fish crackers, and chicken gulai. The mean of the estimated values (0.80 mg CML/100 g edible food) was higher than the directly measured values (0.66 mg CML/100 g edible food), [p < 0.035]. Conclusion: This database provides information on CML values in Indonesian foods, and can be further used to make a guide policy for the selection of foods to reduce non-communicable diseases. Further measurements are needed on Indonesian dishes to complete the database.

Characterization of Beeswax and Rice Bran Wax Oleogels Based on Different Types of Vegetable Oils and Their Impact on Wheat Flour Dough Technological Behavior during Bun Making.

Five varieties of vegetable oil underwent oleogelation with two types of wax as follows: beeswax (BW) and rice bran wax (RW). The oleogels were analyzed for their physicochemical, thermal, and textural characteristics. The oleogels were used in the bun dough recipe at a percentage level of 5%, and the textural and rheological properties of the oleogel doughs were analyzed using dynamic and empirical rheology devices such as the Haake rheometer, the Rheofermentometer, and Mixolab. The thermal properties of beeswax oleogels showed a melting peak at a lower temperature for all the oils used compared with that of the oleogels containing rice bran wax. Texturally, for both waxes, as the percentage of wax increased, the firmness of the oleogels increased proportionally, which indicates better technological characteristics for the food industry. The effect of the addition of oleogels on the viscoelastic properties of the dough was measured as a function of temperature. All dough samples showed higher values for G' (storage modulus) than those of G″ (loss modulus) in the temperature range of 20-90 °C, suggesting a solid, elastic-like behavior of all dough samples with the addition of oleogels. The influence of the beeswax and rice bran oleogels based on different types of vegetable oils on the thermo-mechanical properties of wheat flour dough indicated that the addition of oleogels in dough recipes generally led to higher dough stability and lower values for the dough development time and those related to the dough's starch characteristics. Therefore, the addition of oleogels in dough recipes inhibits the starch gelatinization process and increases the shelf life of bakery products.

Mechanism of action of three different glycogen branching enzymes and their effect on bread quality

Bread staling adversely affects the quality of bread, but starch modification by enzymes can counteract this phenomenon. Glycogen branching enzymes (GBEs) used in this study were isolated from Deinococcus geothermalis (DgGBE), Escherichia coli (EcGBE), and Vibrio vulnificus (VvGBE). These enzymes were characterized and applied for starch dough modification to determine their role in improving bread quality. First, the branching patterns, activity on amylose and amylopectin, and thermostability of the GBEs were determined and compared. EcGBE and DgGBE exhibited better thermostable characteristics than VvGBE, and all GBEs exhibited preferential catalysis of amylopectin over amylose but different degrees. VvGBE and DgGBE produced a large number of short branches. Three GBEs degraded the starch granules and generated soluble polysaccharides. Moreover, the maltose was increased in the starch slurry but most significantly in the DgGBE treatment. Degradation of the starch granules by GBEs enhanced the maltose generation of internal amylases. When used in the bread-making process, DgGBE and VvGBE increased the dough and bread volume by 9 % and 17 %, respectively. The crumb firmness and retrogradation of the bread were decreased and delayed significantly more in the DgGBE bread. Consequently, this study can contribute to understanding the detailed roles of GBEs in the baking process.

Breaking the temperature limitation of zein-rice starch dough by microwave pre-gelatinization: Morphological, structural and rheological properties of the dough

Zein has gluten-like viscoelasticity, but its use is limited due to high glass transition temperature (Tg). To break the temperature limitation of zein-starch dough, microwave heating was used to pre-gelatinize a partial of the starch with zein, and then the remaining was added and kneaded to form a dough. Pre-gelatinized doughs formed by rice starch (PRS), zein-starch (PUZS), and extruded zein-starch (PEZS) were included in this study. The thermal, morphological, rheological, and secondary structural properties of the dough were investigated. The results showed that zein and starch formed a composite gel network and firmly bound starch granules, which improved the dough properties with a smooth surface and compact internal structure, increased strain tolerance, and decreased stiffness. Unextruded zein was distributed uniformly and had strong interactions with the starch. Extruded zein tended to form large particles and had limited interaction with starch but improved dough extensibility. Microwave pre-gelatinization increased the stability of the secondary structure of zein and maintained the viscoelasticity of dough below zein’s Tg, which provided a safe and effective way to break the temperature limitation of zein as a structural protein used in foods.

Thermo-mechanical and baking properties of the gluten free zein - starch doughs

Thermo-mechanical properties of doughs based on zein and different types of starch (native corn starch, modified corn starch and tapioca) were investigated in this study. The physical properties of the gluten free breads, prepared using the model zein – starch mixtures, were additionally determined. The Mixolab parameters measured while running the Chopin+ protocol indicated that the dough exhibited viscoelastic properties at 39°C, and not at 30°C as in the case of gluten system dough. The type of starch used in admixture with zein to prepare the dough significantly influenced the viscoelastic properties of the samples. The lowest starch retrogradation was obtained for the zein-modified corn starch mixture (C5-C4 of 0.55 Nm), while in case of the samples with native corn starch and tapioca the C5-C4 values were close to 0.74-0.79 Nm. The zein-tapioca sample had the lowest breakdown (C3-C4) of 0.22 Nm, followed by the zein-native corn starch sample, with C5-C4 of 0.53 Nm. Bread samples prepared with zein and native or modified corn starch at high water absorption levels (77% and 85%, respectively) had the highest specific volume values of 3.18 cm3/g and 2.22 cm3/g, respectively. These results indicate that zein can be successfully combined with starch from various sources for obtaining gluten free products.

Milling of buckwheat hull to cell-scale: Influences on the behaviors of protein and starch in dough and noodles

Superfine grinding of insoluble dietary fiber (IDF) is a promising method to improve the product quality by regulating the interaction between protein and starch. In this study, the effects of buckwheat-hull IDF powder, at cell-scale (50–10 μm) and tissue-scale (500–100 μm), on the dough rheology and noodle quality were investigated. Results showed that cell-scale IDF with higher exposure of active groups increased the viscoelasticity and deformation resistance of the dough, due to the aggregation of protein–protein and protein-IDF. Compared with the control sample, the addition of tissue-scale or cell-scale IDF significantly increased the starch gelatinization rate (β, C3-C2) and decreased the starch hot-gel stability. Cell-scale IDF increased the rigid structure (β-sheet) of protein, thus improving the noodle texture. The decreased cooking quality of cell-scale IDF-fortified noodles was related to the poor stability of rigid gluten matrix and the weakened interaction between water and macromolecules (starch and protein) during cooking.

Enhancing zein-starch dough and bread properties by addition of hydrocolloids

Similar to gluten, zein can form a viscoelastic network upon hydration and shear. This makes zein a promising protein to develop gluten-free bakery products. In this study, the effect of addition of different hydrocolloids (hydroxypropyl methylcellulose (HPMC), guar and xanthan gum), and the inclusion of pregelatinized starch (PG starch) and lactic acid (LA) on zein-corn starch dough and bread properties was examined. The addition of HPMC, and to a lesser extent guar gum, significantly changed the viscoelastic zein dough properties and resulted in bread samples with improved loaf volume and sensory properties. Scanning electron microscopy revealed the formation of a continuous fine foam-like structure in the zein-starch dough when HPMC and guar gum were added. This finer structure translated in a lower dough stiffness and resistance to deformation, and a higher degree of deformation characterized by lower complex moduli and increased creep compliance values. Xanthan gum addition, conversely, had an adverse effect on zein bread loaf volume which was attributed to potential weak repulsion between xanthan and zein molecules. In addition, the amount of α-helix and β-sheet secondary structures in bread samples was altered upon hydrocolloid and PG starch addition and played a role in bread crumb hardness. Overall, the zein bread with HPMC showed textural properties most similar to gluten bread. This research sheds light on different structure levels of zein-based gluten-free recipes as affected by inclusion of hydrocolloids, PG starch and LA, and provides a sound basis for the rational development of zein-based gluten-free breads.

Molecular structure and linear-non linear rheology relation of rice starch during milky, dough, and mature stages

Immature rice has potential to be used as healthy food. The relation between molecular structure and rheological properties was investigated. The lamellar repeating distance (8.42–8.63 nm) and crystalline thickness (4.60–4.72 nm) were not different among stages indicating a complete lamellar structure even at early stage. The relative crystallinity was higher in dough (39.62 %) than milky (36.69 %) and mature starch (35.22 %) caused by molecular structure, amylose, and amylose-lipid complex. The short amylopectin branched chains (A and B1) in dough starch were easily entangled resulted in higher Payne effect and elastic dominant. Dough starch paste exhibited higher G′Max (738 Pa) than milky (685 Pa) and mature (645 Pa) starch. In a non-linear viscoelastic regime, small strain hardening was found in milky and dough starch. Mature starch showed the highest plasticity and shear thinning at high-shear strains as the long-branched chains (B3) microstructure was disrupted, disentangled, followed by chain orientation along shear.

Retrogradation behavior of starch dough prepared from damaged cassava starch and its application in functional gluten-free noodles

A novel starch-based model dough used to exploit staple foods was demonstrated to be feasible, which was based on damaged cassava starch (DCS) obtained by mechanical activation (MA). This study focused on the retrogradation behavior of starch dough and the feasibility of its application in functional gluten-free noodles. Starch retrogradation behavior was investigated by low field-nuclear magnetic resonance (LF-NMR), X-ray diffraction (XRD), scanning electron microscope (SEM), texture profile and resistant starch (RS) content analysis. During starch retrogradation, water migration, starch recrystallization and microstructure changes were observed. Short-term retrogradation could significantly alter the texture properties of starch dough, and long-term retrogradation promoted the formation of RS. The damage level influenced starch retrogradation, and damaged starch with the increasing damage level was beneficial to facilitate the starch retrogradation. Gluten-free noodles made from the retrograded starch had acceptable sensory quality, with darker color and better viscoelasticity than Udon noodles. This work provides a novel strategy for the proper utilization of starch retrogradation for the development of functional foods.

Impact of wheat starch granule size on viscoelastic behaviors of noodle dough sheet and the underlying mechanism

The contribution of starch to dough behaviors has been largely overshadowed by the role of gluten, receiving much less attention in comparison. The impact of wheat starch granule size on the viscoelastic behaviors of low-moisture noodle dough and its underlying mechanism were investigated. Dough with a high ratio of B-type starch granules (BS) had higher viscoelastic moduli (G″ and G′), percent stress relaxation (SR%), and smaller creep compliance (J max ), indicating higher viscoelasticity and strength. This might be related to the higher filling ability and water-binding capacity of B-type starch. Compared to large A-type starch granules (AS), small B-type granules would easily embed to form a more closely packed and uniform network structure. In addition, the differences in water distribution and hydration properties could affect the hydrophobicity of starch and the surface environments of the protein, thus influencing the polymer interactions in the doughs. The hydrogen bonds were the main con-covalent bonds in the low-moisture noodle dough. With increasing B-/A-type starch ratios, β-sheet and hydrogen bond contents significantly increased, while the GMP content showed a decrease, suggesting the enhanced hydrogen bond interaction in a high ratio of B-type starch dough could cooperate with intermolecular disulfide bonds to stabilize the network structure of gluten, improving the dough strength. These results demonstrated that the viscoelastic behaviors of dough sheets were related to the granule size distribution of wheat starch. Finally, a schematic model describing the mechanism of the influence of starch granule size on dough behaviors was built. • B-type wheat starch granules promoted uniform and compact gluten network formation. • Small B-type granules led to stronger hydrogen bond interaction in the noodle dough. • The enhanced interaction by hydrogen bonding could improve the dough strength. • Viscoelasticity of dough sheet increased with increasing B- to A-type starch ratios.

Dough rheological properties, texture, and structure of high-moisture starch hydrogels with different potassium-, and calcium-based compounds

The effects of four kinds of potassium- (potassium alginate, PA; potassium dihydrogen phosphate, KDP) and calcium-based (calcium carbonate, CC; calcium silicate, CSi) compounds on the pasting behavior, rheological properties, microstructure, water mobility, and textural characteristics of pastes, dough, and high-moisture starch hydrogels from potato starch were evaluated. The results showed that the addition of 0.5% CSi, 0.5% CC, 0.4% PA and 0.4% KDP (w/w, total starch basis) significantly improved the tensile strength of high-moisture starch hydrogels compared to that of pure potato starch. Further discussion about the mechanism revealed that the addition of these components could reduce the swelling capacity and peak viscosity of potato starch during heating, further enhance the network structure of the starch dough, and reduce the water mobility thereof, thus contributing to a compact stacking of starch and smaller and denser pore structure of the high-moisture starch hydrogels. This study provides a theoretical basis for the formulation design of alum-free hydrogel derived products.

Structural, gelatinization, and rheological properties of heat-moisture treated potato starch with added salt and its application in potato starch noodles

Gluten-free noodles, e.g. potato starch noodles, are getting popular due to the increasing population with gluten sensitivity and celiac disease. However, due to the lack of gluten network, the solid loss of potato starch noodles during cooking leads to lower textural and sensory attributes. The starch modification provides the opportunity to address these shortcomings. Here, we report the application of heat-moisture treated (HMT) potato starch with added salt as a binder to improve the cooking and textural properties of potato starch noodles. In the presence of sodium tripolyphosphate (STPP) and sodium chloride (SC), starch granules exhibited irregular shapes and deformed crystalline growth rings, agglomerated due to partial gelatinization, and lost double-helical structures and the perfection of crystallites after being subjected to HMT. As affected by the starch-ions interactions and changed water structure, HMT-modified starch with added SC and STPP had higher pasting temperatures, less amylose leaching, and lower gelatinization enthalpies and pasting viscosities than HMT starch without salts. Meanwhile, higher cross-over temperatures and lower G’ values were found in HMT starch with added STPP and SC compared to HMT starch. Iodine-staining micrographs also confirmed the delay in the disintegrating process of starch granules in HMT-modified starch with added SC and STPP. Furthermore, when HMT-modified starch with added SC was applied as binder paste, starch dough owned higher hardness and starch noodles exhibited less solid loss and broken noodles, firmer texture, and better elasticity. The results thus provide the opportunity to improve the textural attributes of potato starch noodles with the application of HMT potato starch and salt as the binder. • Structural changes of starch before and after HMT as affected by salts are studied. • Adding sodium chloride induces the losses of ordered structure of starch during HMT. • Adding salts delays the disintegrating of starch granules during gelatinization. • HMT starch with added sodium chloride (HPS-SC) has better heat and shear stability. • HPS-SC as a binder improves cooking performance and texture of starch noodles.

PELATIHAN LABELING DAN PACKAGING BAGI PELAKU UMKM DI DESA CIHERANG KECAMATAN GUNUNG SARI, KABUPATEN SERANG

The community of Ciherang village, Gunung Sari sub-district, several housewives to improve their family's economy carry out entrepreneurial activities. There are various kinds of entrepreneurial activities depending on the expertise/ability of each individual. One of the UMKM in Ciherang Village is Baso aci or commonly called boci. These aci meatballs are pure meatballs made from starch dough without being mixed with ground beef. From the main ingredient of starch, or Sundanese people call it aci, it looks similar to the cilok sauce that we often encounter. The problem that was encountered after we conducted the survey was the lack of handling of packaging or packaging on the baso aci, therefore the solution we gave was to increase UMKM in Ciherang village. as well as additional menus to complement these UMKM products to make them more attractive and in demand by consumers by holding labeling and packaging training for UMKM baso aci players in Ciherang Village

Effects of different storage temperatures on the structure and physicochemical properties of starch in frozen non-fermented dough

This study investigated the effects of different storage temperatures on the structure and physicochemical properties of starch in frozen nonfermented dough. The results showed that the water activity and water loss rate of dough samples decreased with decreasing storage temperature. The density of hydrogen protons in the dough sample decreased as well. The freezable water content in dough increased with decreasing freezing temperature. The results showed that with decreasing freezing temperature, the formation and recrystallization of ice crystals in the process of freezing storage resulted in an increase in depressions and holes in wheat starch grains, internal and external damage to starch, and a gradual decrease in the relative crystallinity. The porous surface of starch particles and their loose molecular order structure promote the infiltration of water molecules into the interior of the starch particles. The combination of starch chain and water molecules makes the peak viscosity of starch in the dough gradually rise, but diminishes its stability when heated. Compared with the control group, the starch recovery value increased, and the starch enthalpy value increased gradually. The structure and physicochemical properties of starch in nonfermented dough stored at -12 °C and -18 °C were similar.

Influence of wheat starch on rheological, structural and physico‐chemical properties gluten–starch dough during mixing

SummaryThis study mainly explored that the influence of wheat starch source on the rheology behaviours and structural properties of gluten–starch dough, and then the model doughs were prepared by the AK58 wheat gluten and three types of starches from strong (ZM366S), medium (AK58S) and weak gluten wheat (ZM103S) during mixing were studied. The damaged starch content of wheat starch was positively correlated with the wheat gluten strength, while the granule size was negatively. The G', G" and the extension resistance of ZM366S dough were higher than those of other doughs, which implied the source of starch also had a significant influence on the rheological properties. CLSM also observed that ZM366S was more closely bound to the gluten protein network. The glutenin macropolymer (GMP) content of ZM366S model dough was the highest, while the SH content was the lowest. Decreases in elasticity, extension and GMP, and small increase in SH content were displayed during dough mixing. Molecular forces were varied with different wheat starch and mixing time. The covalent bond was the main force between ZM103S and gluten, whereas the hydrogen and covalent bonds were the main force between ZM366S or AK58S and gluten. The interactions between ZM366 starch and gluten were stronger than others starch.

Phase separation affects the rheological properties of starch dough fortified with fish actomyosin.

Starch and protein are common polymers in food, and their phase separation often occurs during food processing. Protein-fortified starch dough can be considered as a triple phase separation system, and the effect of phase separation on dough rheology warrants further research. In this study, starch doughs fortified with fish actomyosin were used, and their rheological properties were researched and explained with respect to phase separation. The results suggested that the phase separation of actomyosin-binder-starch granules in the raw dough affected the quality of dough. The addition of actomyosin significantly decreased stiffness and shear sensitivity but increased the fluidity of the blended dough. Moreover, it was found that the interaction between mung bean starch and actomyosin was very weak. The polymer molecules were connected by physical links. Owing to phase separation, it was presumed that “wall slip” occurred between the binder, starch granule, and actomyosin. The blended dough containing 30% of the added actomyosin (R3) showed the best recovery ability and the weakest molecular interaction (interaction type Z′ = 0.40 for storage modulus G′ and 0.31 for loss modulus G′′). Additionally, the phase structure of the model doughs was investigated. It was found that the starch network played a dominant role when 10% (R1) actomyosin was added. With the addition of actomyosin, the protein network formed gradually. A bicontinuous phase structure with interpenetrating network was observed in R3 (actomyosin = 30%). In summary, our findings demonstrate the feasibility to make blended doughs by mixing fish actomyosin and mung bean starch. Moreover, in terms of use in traditional noodle making, the blended R3 dough was found to be the best in terms of recovery ability and flow characteristics.

Comparative study of rheology and steamed bread quality of wheat dough and gluten: Starch doughs

To explore the interaction between wheat starch and gluten, the thermomechanical, rheological properties, steamed bread quality of wheat flour, and gluten–starch doughs from different varieties were compared. Thermomechanical analysis showed that the stable time and gelatinization viscosity of model dough were higher than that of wheat dough. The results showed that R model dough (the ratio of starch/gluten is consistent with the original flour) had a higher stable time, strength, viscosity, stability, and extension properties than that of C model dough (the protein content is consistent with the original flour). Steamed bread prepared by model doughs exhibited higher hardness, gumminess, and chewiness. The internal structure of R dough steamed bread exhibited more tightly than that of C model dough steamed bread. Optimization of the starch/gluten ratios in wheat flour will be important for wheat breeding and controlling wheat processing aiming to better control the quality of steamed bread. Practical applications Wheat starch and protein are the two main components of wheat flour. Dough is a complex material with a high degree of elasticity and rheological properties of dough play an important role in end-product quality. The processing of dough is the result of the interaction between starch and gluten, and the interaction affects the rheological properties of dough and ultimately the quality of products. In this study, two models of starch–gluten dough were established. First, starch–gluten ratio of dough was consistent with original wheat flour dough; second, the gluten content was consistent with the original dough. The rheological properties and the quality of steamed bread were compared between the original wheat flour dough and the model dough. The information obtained is expected to be important for wheat breeding and wheat dough processing aiming to broaden the application of wheat and wheat flour.

Physicochemical properties of starch-wheat germ oil complex and its effects on water distribution and hardness of noodles

The physicochemical properties of starch-wheat germ oil complex (SWGOC) and its influences on the water distribution and hardness of noodles were investigated. The results showed that SWGOC retarded the retrogradation, lowered the breakdown value and solubility, and increased the swelling power of starch compared to the control. The T21 (immobilized water) of starch dough made by SWGOC was lower than that of the control, however, the T21 of raw noodles increased slightly from 0.12 ms to the maximum 0.13 ms and then decreased to 0.10 ms with the increase of SWGOC. The pasting profile of SWGOC during the holding phase (95 °C) suggested the dissociation of starch-lipid complexes during cooking. The released amylose predominantly induced double-helix at 0 h, resulting in the higher initial hardness of noodles, while the combination of liberated lipids and amylose occurred concomitantly but in a slower rate, reducing the firming rate during the first 2 h. Interestingly, the anti-firming effect was not proportion to the content of starch-lipid complexes, and noodles with less starch complexes seemed to be more effective in reducing firming rate. This study provides insight into the importance of starch-wheat endogenous lipids on noodle quality.