Stacking Sequence Of Layers Research Articles

Heterostructural interface engineering for ultrawide-gap nitrides from first principles: TaC / AlN and TaC / GaN rocksalt-wurtzite interfaces

Epitaxial lattice matching is an important condition for the formation of coherent interfaces with low defect densities. However, lattice-matched substrates with the same crystal structure as the active layer are often not available, suggesting opportunities for utilizing heterostructural interfaces. For example, at high Al contents that are interesting for ultrawide-gap applications in power electronics, AlxGa1−xN semiconductor alloys in the (0001) orientation of the wurtzite (wz) structure become lattice-matched to (111)-oriented rocksalt (rs) TaC substrates. To predict the expected interface atomic structures under different synthesis conditions, we perform high-throughput density-functional-theory calculations, using an algorithm for systematic sampling of the possible stacking sequences of the atomic layers on the in-plane hexagonal lattice. The approach considers octahedral, tetrahedral, and prismatic coordination motifs, and is generally applicable for the modeling of commensurate rs/wz heterostructural interfaces. Our results provide guidance for synthesis control of substrate-film bonding and the polarity of ultrawide-gap AlxGa1−xN alloys on TaC substrates. Published by the American Physical Society 2024

Multiple conformal-contact transfer of large-area crack-free transition metal dichalcogenide stacks

Abstract Atomically-thin two-dimensional (2D) transition metal dichalcogenides (TMDs) have emerged as an ideal platform for both physics investigation and device applications. By stacking different layers into homo- or hetero-structures, an extra degree of freedom is involved in further tuning their properties, thereby boosting scenarios in twistronics, moiré photonics and optoelectronics. However, interfacial imperfections such as contaminations and cracks, frequently occur during the layer stacking sequence and accumulate layer by layer, greatly degenerating the interface quality. In this study, we developed a multiple conformal-contact transfer method to construct TMD stacks with crack-free intrinsic interfaces. The design of a deformable buffer layer is crucial to guarantee the conformal contact and intact transfer of each layer, contributing to the successful construction of centimetre-scale TMD stacks up to 8 layers. Precise control over spatial location and interlayer twist angle is also feasibly achieved, evidenced by the stacking-dependent interlayer exciton (IE) effects in WS2-WSe2 heterostructures. This work provides a facile and precise approach for architecting 2D stacks with perfect interfaces, which will further accelerate the customized design for their device functionalization.

Impact of stacking sequence on burst pressure in glass/epoxy Type IV composite overwrapped pressure vessels for CNG storage

The shift from metallic to composite pressure vessels for storing compressed natural gas (CNG) is driven by the goal of reducing environmental impact by using lighter higher-performing structures. This work focuses on enhancing the internal pressure strength of a type IV composite overwrapped pressure vessel (COPV) by optimising the stacking sequence of the overwrapping composite layers. Parametric finite element (FE) models are developed to reveal symmetry effects. In these models, both the thickness build-up and fibre angle variation at the turnaround zones are accurately modelled. Subsequently, the stacking sequence is optimised with the objective function of maximising burst strength. The parametric modelling demonstrates that representing the COPV as an axisymmetric continuum reduces computational costs in 5400× while yielding results comparable to full 3D continuum models. Experimental burst tests are carried out to validate the numerical predictions, and the difference in pressure between them is 12.6 %.

Lego-like composite laminate construction and analysis on the fly

High-fidelity finite element (FE) analysis is computational demanding for parametric studies and design optimizations of composite laminates because it is time-consuming and inflexible in reconfiguration. Hence, we aim to develop rapid yet accurate 3-D FE analysis that can readily change (i) layer materials including fiber angles, (ii) the number of layers, and (iii) the stacking sequence of layers. To achieve these three features, we propose an offline-online framework hinging on static condensation (SC) integrated with port reduction (PR) and reduced basis element (RBE) methods, resulting in port-reduced static condensation (PR-SC) and port-reduced static condensation reduced basis element (PR-SCRBE) analyses. Thanks to the PR-SC and PR-SCRBE techniques, we may easily build a composite laminate using a variety of layer materials and any desired number of layers, akin to assembling Lego bricks, and swiftly analyze the constructed composite laminate. For demonstration, we assess both PR-SC and PR-SCRBE approximations using three different composite laminates with varying numbers of layers for each of three-point bending and tensile tests. Compared with FE analysis, PR-SC analysis exhibits insignificant accuracy loss in displacement and stress evaluation while obtaining meaningful computational speedup. In contrast, PR-SCRBE analysis shows moderate accuracy loss in displacement and stress evaluation while gaining considerable computational speedup. In conclusion, we recommend employing PR-SC for accuracy and PR-SCRBE for efficiency as per application requirements. The proposed two-stage framework may benefit many-query and real-time applications involving composite laminate analysis, including design optimization and virtual testing.

Bending behavior of multi-layer sandwich composites reinforced with weft-knitted spacer fabrics

In this study, the bending properties of multi-layer sandwich composites (MLSCs) were investigated. For this purpose, first, 1 × 1- and 5 × 5-Rib gaiting weft-knitted spacer fabrics were produced using E-glass yarns. Then, glass/epoxy sandwich composites were prepared using produced fabrics as reinforcement and epoxy resin as matrix. Considering both the pattern of reinforcements and the arrangement of layers, different types of MLSCs were fabricated by the implementation of different stacking sequences. The prepared samples were subjected to the three-point bending test. Generally, the orientation of samples, structures of each sandwich’s layer, and stacking sequence of layers, as three impressive parameters affected the bending behavior of MLSCs. The results showed that in all samples, the maximum bending force (MBF) of MLSCs in the longitudinal direction is generally higher than that in the transverse direction. The MBF of MLSCs included both 5 × 5-Rib gaiting layers and 1 × 1-Rib gaiting layers increased with increasing the number of 5 × 5-Rib gaiting layers to 1 × 1-Rib gaiting layers. The MBF of MLSCs included of same number of 5 × 5-Rib gaiting and 1 × 1-Rib gaiting structures increases by placing the 5 × 5-Rib gaiting fabrics in the bottom layers, which shows the influence of stacking sequence on the bending behavior of MLSCs. According to the generated geometrical models, two-layer MLSCs are numerically simulated using the FEM. FE simulation and the experimental results brought about the same bending behavior of MLSCs.

Interply hybridization of hollow glass fiber reinforced vascular composites

AbstractThe use of hybrid reinforcement in polymer composites has been getting attention due to its potential for weight and cost reduction while achieving improved design flexibility for mechanical and thermal properties. In this study, an interply hybridization of epoxy laminates was performed using layers of solid and hollow glass fibers. The structural and thermal performance of the resulting hybrid vascular composites was investigated. All composite parts were manufactured using vacuum‐assisted resin transfer molding (VARTM), following an interply hybridization plan for the stacking sequence of hollow and solid fiber layers. An expected decrease in flexural properties and thermal conductivity was observed for the laminates with completely hollow fibers. On the other hand, hybridization had a positive effect on the laminate properties. It was shown that hybrid vascular composites could be manufactured without a significant reduction in mechanical and thermal performance by a judicious hybridization plan. The optimum hybridization of the laminate achieved a 3.1% increase in the specific flexural strength and a 5.3% decrease in thermal conductivity while containing a vascular network that can be used for active thermal control.Highlights A vascular interply composite structure consisting of hollow and solid fibers was manufactured and characterized for the first time. The I4 composite, vascularized through the middle layers of the laminate, has almost as much flexural strength as solid composite and much more specific flexural strength. The thermal conductivity of the I4 composite is almost as much as that of the solid composite. Functional composites for thermal management and smart applications can be manufactured using hollow fibers without sacrificing flexural strength and thermal conductivity with interply vascularization.

Co-Free Heteroatom-Doped P2-Type Layered Oxide Cathodes: Advancing High Power Sodium-Ion Battery Technology

Sodium-ion battery technology has been blooming as an indigenous solution to stationary storage applications, triggering the cultivation of a cutting-edge alternative to the archaic lithium-ion (Li-ion) batteries due to high abundance, inexpensiveness, sustainability, safety and similar redox chemistry as of Li-ion technology 1. Although Na-ion batteries are propitious however, challenges such as long-term stability, high energy density, high specific capacity have impeded the practical application 2. The stepping stone for a successful Na-ion battery lies in the cathode, thus researchers have focused on development of layered oxide cathode. These are classified into P2, P3, O3 phases, depending on the environment of Na (prismatic or octahedral) and the stacking sequence of the anionic layers 3. P2-type Na0.67Ni0.33Mn0.65O2 (NMNO) cathodes offer high theoretical capacity, environmental friendliness, air-moisture stability, facile synthesis, and direct sodium-ion diffusion. However, there are still some setbacks, such as limited reversible capacity, rapid capacity decay, sluggish Na-ion kinetics, cracking and exfoliation in the crystallites 4. In order to overcome the challenges faced by sodium-ion batteries, researchers have employed several strategies such as inert or active cation substitution, limiting the cut-off voltage, surface modification, preparation of mixed-phase materials, sodium compensation additives, selection of binder, and choice of electrolyte 5. One of the most effective strategies is the doping of electrochemically inactive transition metals in layered transition metal oxide cathodes. However, a better understanding of the parameters that govern the stability of these cathodes are still necessary.By exploring the various factors that impact the stability of layered transition metal oxide cathodes, we propose a novel approach to synthesize a durable P2-type Na0.67Ni0.33Mn0.65Nb0.02O2 (NMNNbO) electrode with robust hexagonal crystallites through a quick, energy-efficient and cost-effective microwave-irradiated synthesis technique. Previous studies have utilized modified Pechini or conventional solid-state routes for inactive transition metal doping, which can be expensive, time-consuming and energy-intensive 6. This leads to an efficient cathode material with higher capacity and improved rate capability, which could be produced on a commercial scale at a lower cost due to the reduced synthesis time. A comprehensive investigation of the cathode material through X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), high resolution transmission electron microscopy (HR-TEM), X-ray photoelectron microscopy (XPS), reveals its superior electrochemical performance, stability, and durability. Through the use of advanced in-situ and ex-situ characterization techniques, the mechanism of Na-ion insertion and extraction, phase transition, and crack formation have been elucidated. Additionally, first-principle calculations using density functional theory (DFT) have been employed to gain a deeper understanding on the role of Nb in the cathode material. Electrochemical characterization was done against Na-metal in a half-cell format utilizing the electrolyte, 1 M NaPF6 in ethylene carbonate and propylene carbonate (1:1). The practicality of the material has also been validated through the evaluation of a full-cell performance against pre-sodiated hard carbon anode. A deeper understanding of the parameters affecting the electrochemical performance, can accelerate the development of high power and durable sodium-ion batteries, making them a more viable option for energy storage applications.

(Invited) Interlayer Excitons in Two-Dimensional Perovskite/Monolayer Transition Metal Dichalcogenide Heterostructures

The emergence of two-dimensional (2D) materials has intrigued a great deal of research on novel physical phenomena and various functional applications due to their particular crystal structures and reduced dimensionality. Unlike 3D materials, bulks of 2D materials can be easily thinned to atomic thickness by mechanical exfoliation and atomically thin 2D materials can be arbitrarily stacked to form vertical van der Waals (vdW) heterostructures, which could inherit the unique characteristics of the constituent layers and even exhibit new properties not possessed by them. Particularly, when type-Ⅱ vdW heterostructures are excited, the positive and the negative charges would reside in the different layers after the charge transfer but be limited within a short distance due to the strong quantum confinement effect of 2D materials, leading to strong Coulomb interaction and the formation of interlayer excitons (IXs). IXs are generally equipped with orientated dipole moment and long lifetime, making them ideal media for the future interconnects between optical transmission and electronic computation. Currently, studies on IXs are mainly focused on the vdW heterostructures formed by monolayers of transition-metal dichalcogenides (TMDs). Here, I will first talk about vdW heterostructures formed by 2D perovskites and TMDs for studying IXs. Stacking different kinds of 2D perovskites and TMDs, formation of IXs is confirmed by excitation-power-, temperature-, electric-field-dependent and time-resolved photoluminescence (PL) studies. Notably, robust IX emission can be observed regardless of the stacking sequence and geometric alignment of the constituent layers, showing great advantages over the TMD/TMD vdW heterostructures, which require special twist-angle and thermal annealing. Then, I would like to give a brief introduction on widely tuning the IX emission energy by changing the layer number of the 2D perovskite or the TMD, which shed light on the application of 2D perovskite/TMD vdW heterostructures in broad-spectrum optoelectronics. Furthermore, I would like to next talk about how the selection of organic chains in 2D perovskites influences the properties of the IXs. By using chiral 2D perovskites, the IX emission shows substantial circular polarization and the polarization direction is only related to the chirality of the molecules regardless of the excitation scheme or any other external field, which could open up new passages for controlling valley- or spin-polarization of IXs. By introducing molecules with different dielectric constants, the dielectric screening strength in the vdW heterostructure is changed and hence the binding energy of the IXs is also modified, which offers great opportunities for exploiting tunable excitonic devices and studying exciton condensation. Finally, I will also introduce IX as a non-destructive tool for probing the local phase transition at the surface of the 2D perovskite (BA)2PbI4 flakes. By spatially PL mapping of the (BA)2PbI4/WSe2 heterostructure, two different IX species can be observed to distinguish the low-temperature and the high-temperature phase respectively.

Verification of modulation mechanism of the interfacial dipole effect by changing the stacking sequence of monatomic layers in perovskite oxides

The magnitude of the dipole effect detected by the cutoff energy measurement was modulated for SrTiO3 (STO)/LaAlO3 (LAO)/SrRuO3 (SRO)/STO (001) subs. epitaxial stacks by ultrathin SrAlOx (SAO) insertion prior to LAO deposition. The difference in frictional forces on the LAO surfaces between the stacks with and without SAO insertion was clearly detected by lateral force microscopy (LFM), which indicated the change in dominating surface atomic layers. From the statistical analysis of LFM images, the SAO insertion was found to improve the lateral uniformity of the stacking sequence of charged monatomic layers in epitaxial LAO along the c-axis [(LaO)+ and (AlO2)−], taking account of the inevitable correlation between the surface-terminating atoms with the stacking sequence of the charged monatomic layers in epitaxial LAO. These results are consistently explainable with the proposed model that the interface dipole effect along the c-axis of the perovskite epitaxial stack is determined by the stacking sequence of charged monatomic layers of LAO.

Design, Fabrication, and Screening of Environmental‐Thermal Barrier Coatings Prepared by Ultrafast High‐Temperature Sintering

AbstractThe demand for more efficient gas turbines relies heavily on the development of new environmental‐thermal barrier coatings (ETBCs). However, there is still uncertainty about which alloys and composites will be used for the next generation of turbine blades, as well as the most promising coating materials. Herein, an ETBCs development strategy is presented by integrating the coating design, synthesis, and screening using an ultrafast high temperature sintering (UHS) technique to accelerate coating improvements. The initial basis for composition selection is their thermal expansion mismatch with the substrate alloys; for which a temperature‐dependent coefficient of thermal expansion database is created. By combining tape casting method with the UHS technique a high‐throughput synthesis of single and multi‐layer coatings are realized with different compositions, layer stacking sequences, and layer thicknesses. To evaluate the coatings, thermal cycling tests from room temperature to 1300 °C are conducted. The approach enabled coatings on objects with complex geometries, multi‐layer ETBCs, and porosity tailoring by using staged UHS that runs with different temperatures and durations. The fast iteration strategy is more cost‐effective for the screening of ETBCs compared to conventional methods and greater throughput which can be further extended for rapid optimization of other materials systems.

A novel three-layer woven fabric composite reinforced by (polyaniline + carbonyl iron) core-shell/carbonyl iron/polyaniline fillers for high-performance broadband radar absorbing structure

One of the most important applications of electromagnetic wave absorption is in stealth aircrafts and electromagnetic protection of avionic systems. The main limitations in the design of these structures are aerodynamics, thickness or weight, mechanical strength, manufacturing process, and reasonable cost. In this study, a novel three-layer woven fabric composite laminate (with a total thickness of about 3 mm) is proposed which each layer is reinforced by individual polyaniline, carbonyl iron, or (PANI + CI) core-shell fillers. The developed Non-dominated Sorting Genetic Algorithm II optimization algorithm suggests the stacking sequence of layers, the appropriate thickness of each layer, and the filler weight fraction in each layer to achieve a broadband absorption. Due to using both dielectric and magnetic absorbing fillers, this structure shows well-impedance matching and approximately absorbs 80% of the X-band (8-12 GHz) electromagnetic waves. The maximum reflection loss is about −14dB. Finally, the effect of the addition of absorbent particles on the mechanical properties has been investigated. Experimental results showed that the tensile modulus and strength decrease by about 21.5% and 20.6%, respectively, and the flexural modulus and strength reduce by 21.7% and 19.7%, respectively. However, the (PANI + CI) core-shell filler can be introduced as a high performance absorber filler because it suggests maximum reflection loss with low weight fraction compared to other fillers and consequently the minimum reduction in mechanical properties.

Energy-absorbing characteristics of hollow-cylindrical hierarchical honeycomb composite tubes under conditions of dynamic crushing

This paper presents an experimental and numerical study on the energy-absorbing characteristics of Biomimetic Multi-Cell Tubes (BMCTs), these being hollow-cylindrical-joint hierarchical honeycomb composite tubes inspired by the microstructural features of a beetle's forewing and geometrical features found in a spider's web. The BMCTs were fabricated using carbon fiber composites in optimized multi-tiered configurations. Low velocity crushing tests were conducted to characterize the load-displacement response, crashworthiness mechanisms, and energy absorption capacity of the BMCTs based on specific layer stacking sequences (LS). Additionally, the dynamic response of the BMCTs was modeled using the finite element analysis techniques.The predicted load-displacement relationships and failure modes show good agreement with the experimental results. Dynamic effects in the energy absorption characteristics of the tubes were evaluated. It is shown that the dynamic energy-absorbing capability of the BMCT-LS2 structure (Wall [±45/±30/±15]s Cylinder [±45/±30/±15/06]) is 6.5% higher than its quasi-static counterpart. In contrast, the SEA of BMCT-LS1 (Wall [+453/-453]s Cylinder [+453/-453/06]) is almost the same under both loading regimes. Finally, the quasi-static SEA of the plain circular tube is 13.8% lower than its dynamic counterpart. However, the SEA values of both BMCT-LS1 and BMCT-LS2 structures are 65% and 173% higher than the plain circular tubes, respectively.

Two-Dimensional Superconductivity in Air-Stable Single-Crystal Few-Layer Bi3O2S3.

The progress of unconventional superconductors at the two-dimensional (2D) limit has inspired much interest. Recently, a new superconducting system was discovered in the semimetallic ternary Bi-O-S family. However, pure-phase crystals are difficult to synthesize because of the complicated stacking sequence of multiple charged layers and similar formation kinetics among ternary polytypes, leaving several fundamental issues regarding the structure-superconductivity correlation unresolved. Herein, 2D single-crystal ultrathin Bi3O2S3 nanosheets are prepared by using low-pressure chemical vapor deposition, and their atomic arrangement is clarified. Magnetotransport measurements indicate a superconducting transition at ∼6.1 K that is thickness-independent. The transport results demonstrate 2D superconducting characteristics, such as the Berezinskii-Kosterlitz-Thouless transition, and strong anisotropy with magnetic field orientations following the 2D Tinkham formula. The difference from superconductivity of powder is demonstrated from the perspective of their corresponding microstructures. These results corroborate the superconducting behavior of Bi3O2S3, providing fresh insights into the search for other bismuth oxychalcogenides and derivative BiS2-based analogues at the 2D limit.

(Invited) Insights into the Effects of Doping on Structural Phase Evolution of Sodium Nickel Manganese Oxide Cathodes for High-Energy Sodium Ion Batteries

High-performance and low-cost transition metal (TM) layered oxides using earth abundant elements are promising cathodes for Na-ion batteries. However, it is challenging to obtain desired materials because the large Na size, different Na occupations and various layer stacking sequences multiply the complication in determining the structure of a given composition and exacerbate uncertainty to the structure-property correlation. In this work, we use the attainment of desired NaxMnyNizTM1−y-zO2-based cathode materials as model compound to demonstrate a general roadmap for batch development of sodium layered cathodes towards practical applications. Several cost-effective O3 and P2/O3 hybrid cathode materials have been obtained, all of which demonstrate excellent performance.Acknowledgement: This work is supported by the U.S. Department of Energy (DOE) Office of Electricity under contract No. 57558. PNNL is operated by Battelle Memorial Institute for the DOE under contract DE-AC05-76RL01830

Hybridization effects on ballistic impact behavior of carbon/ aramid fiber reinforced hybrid composite

Fiber reinforced polymer and its hybrid composites are widely used in bulletproof production. The ballistic limit, failure mode and energy absorption of a hybrid fiber reinforced polymer target (HFRPT) composed of carbon fiber reinforced polymer (CFRP) and aramid fiber composite (AF) were studied in this paper. A finite element model was formulated to investigate the hybridization effect of layer thickness and stacking sequence on the ballistic behavior. A theoretical method was proposed to predict the ballistic limits of HFRPT, demonstrating an error percentage of less than 10% in most of the hybridization. Four typical failure modes including compression failure, tensile failure, shear plugging failure and tension shear coupling failure were observed in HFRPT, and the influence of hybridization on the alternations of failure modes was observed. Additionally, the effect of stacking sequences and layer thickness on energy absorption of HFRPT was examined. For the HFRPTs with a total thickness of 10 mm, the AF/CFRP hybridization proves to offer better ballistic impact resistance performance than the CFRP/AF hybridization. The HFRPT with a stacking sequence of 9 mm AF and 1 mm CFRP achieves a maximum ballistic limit of 420 m/s and the highest impact energy areal density ratio of 323 J/(g/cm2).

The Zintl Concept Applied to Intergrowth Structures: Electron‐Hole Matching, Stacking Preferences, and Chemical Pressures in Pd5InAs

AbstractEnumerating the potential stacking sequences of layers is a fundamental way to account for the structure diversity of solid state compounds. In many cases, these stacking variations represent polymorphs with only small energetic differences. Here, we examine a compound for which the preferred stacking pattern instead reveals key aspects about its chemical bonding: Pd5InAs. Its structure is based on the intergrowth of slabs of the AuCu3 and PtHg2 (or alternatively, fluorite) structure types. Two basic stacking arrangements are available to this compound, represented by the Pd5TlAs and HoCoGa5 structure types. DFT total energy calculations reveal that the former outcompetes the latter by a staggering 0.65 eV/formula unit. Through a combination of DFT‐reversed approximation Molecular Orbital (DFT‐raMO) and DFT‐Chemical Pressure (DFT‐CP) analysis we trace this preference to two factors. First, with DFT‐raMO analysis, we derive a Zintl‐like bonding scheme of Pd5InAs. This scheme, along with the inspection of selected crystal orbitals, is then connected to preferred stacking through the coordination environments of the Pd atoms at the interface between the Pd−In and Pd−As layers. In the hypothetical HoCoGa5‐type and observed Pd5InAs‐type structures, different Pd coordination environments arise at the interfaces. The hypothetical structure features square planar PdIn2As2 units, in each of which the same 4d‐orbital serves in the Pd sublattice's role as both Lewis acid (for interactions with the As) and Lewis base (for interactions with the In). In the observed structure, tetrahedral PdIn2As2 units occur instead, so that these contradictory roles are distributed to separate 4d‐orbitals, leading to more effective bonding. DFT‐CP analysis illustrates that this driving force for the Pd5TlAs‐type arrangement is supplemented by a favorable alignment of the packing tensions in the parent structures. Altogether, the resulting picture demonstrates how the reaction of simple intermetallic structures to form intergrowths can be guided by recognizable chemical interactions.

Ballistic performance of integral body armor with closed-cell aluminum foam: A numerical study

This numerical study is dedicated to investigating the ballistic performance of three-component integral body armor comprising ceramic façade, layers of ultra-high molecular weight polyethylene fiber-based composite (Dyneema) and closed-cell aluminum foam against NIJ-Type IV armor-piercing bullets. A numerical model of integral armor with a ceramic façade and a fiber-reinforced composite backing plate was developed in IMPETUS Afea Solver and verified against experimental data. The verified model was used to design a "baseline configuration" of two-component integral armor that can stop the NIJ-Type IV projectiles. Three-component armor configurations were obtained by introducing layer(s) of closed-cell aluminum foam into the laminate. Laminates with different stacking sequences of composite and porous layers and different foam relative densities were studied and compared with the baseline two-component configuration. The study presents new insights into the mechanics of perforation of integral armor with closed-cell foam and provides design recommendations for such armor systems.

Sputter-grown c-axis-oriented PdCoO2 thin films

Metallic delafossites, ABO2 (A = Pd or Pt), are layered oxides that are as conductive as elemental metals. The high conductivity and surface polarity make metallic delafossites fascinating electrode materials for heterostructure devices. Here, we report the successful growth of c-axis-oriented PdCoO2 thin films on Al2O3 (001) substrates by magnetron sputtering that is widely used in industries. The observation of the PdCoO2 thin films through scanning transmission electron microscopy revealed layered crystal structures. A sharp interface exhibiting a layer stacking sequence of Pd/CoO2/Al2O3 was observed clearly, similar to the interfaces obtained with other growth methods such as pulsed laser deposition and molecular beam epitaxy. This layer stacking is particularly interesting because it can induce a high work function at the interface. The in-plane resistivity of the as-grown PdCoO2 thin film was 73 μΩ cm at room temperature, which decreased to 11 μΩ cm after post-annealing. The residual resistivity ratio of the annealed thin films was approximately 2.9. The impurity phases of PdOx were observed using x-ray diffraction and scanning transmission electron microscopy. The sputtering deposition of c-axis-oriented thin films could lead to the practical application of the polar surface of PdCoO2 in semiconductor devices.

Multi-layer modelling of masonry structures strengthened through textile-reinforced mortar.

Background Textile-reinforced mortar (TRM) is an innovative strategy for the reduction of the seismic vulnerability of existing masonry buildings consisting in the application on the masonry surface, of a mortar coating with fiber-based grids or textiles embedded. The paper presents the calibration and application of a simplified modelling approach, based on multi-layered elements, for the simulation of existing masonry elements and structures strengthened through TRM. Methods The strengthened masonry is modelled by using 20-nodes brick elements formed by a stacking sequence of layers representing the different material components (the masonry, the mortar coating and the embedded reinforcement). The nonlinear behavior of the materials is considered and calibrated on the basis of experimental characterization tests on individual components available in the literature. The simplified assumption of perfect bond among layers is considered. Results Non-linear static analyses are performed on samples of increasing complexity: elementary panels, structural elements (piers and spandrels) and a pilot building. The results of some tests on TRM strengthened masonry, available in the literature, are considered to assess the model reliability in terms of capacity curves and collapse mode. The model is capable of detecting the typical failure mechanism of both unstrengthened and TRM strengthened masonry, namely the diagonal cracking, the in-plane bending and the out-of-plane bending and is able to detect the activation also of mixed failure modes, that often occur in actual configurations. Conclusions Given the coarse mesh size and the smear plasticization assumption, the model is not suitable for the rigorous reproduction of individual cracks but represents a good compromise between the goal to grasp the structural performances at the wide scale, including failure modes, and the analysis optimization.

New designs of sandwich panels to mitigate high-frequency noise inside space vehicles

Radiation of noise to the interior of a space vehicle during liftoff and transonic climb is a long-standing problem. To attenuate noise inside the crew compartment during launch and in-space operation, sandwich panels have been employed in the pressurized outer shell to passively reduce the exterior noise transmission. However, the layouts and the sound transmission loss of the implemented sandwich panels have not been made available for public release. Against this idiosyncratic practice, this study envisioned disseminating the know-how on the sound attenuation ability of dissimilar sandwich panels. To efficiently absorb and dampen the acoustic energy, the sandwich panels were specifically configured using a honeycomb core, felts and a closed cell aluminum-foam in the material lay-up. The face sheets of the sandwich panels consisted of either glass fiber-reinforced epoxy or carbon fiber-reinforced epoxy composites. The sandwich panels were tested as acoustic barriers to a diffuse sound field in a sound transmission suite. As found, an increase in the panel thickness brought a decrease in the anti-symmetric coincidence frequency of sandwich panels. A rubber damping layer in the material lay-up added limp mass to a sandwich panel and reduced the panel vibration at excitation frequencies beyond 500 Hz. Multiple felts reinforced the sound transmission loss of a sandwich panel by dissipating the acoustic energy into thermal energy at the felt interstices in the frequency regime beyond 315 Hz. In conclusion, this study proposed optimized sandwich configurations considering the constitutive materials, number of material layers, material layer thickness and stacking sequence. The optimized sandwich configurations could fairly deliver the demanded sound transmission loss in the high-frequency regime.