Stable Water Isotopes In Precipitation Research Articles

Below‐cloud evaporation effect on stable water isotopes in precipitation at the eastern margin of Qinghai‐Tibet Plateau

AbstractQuantitatively assessing the evaporation‐caused stable water isotope fractionation in precipitation below the cloud base is of great significance to understand the modern hydrological circulation especially in a plateau climate. Based on the hourly meteorological data at eight meteorological stations of the Gannan Plateau at the eastern margin of Qinghai‐Tibet Plateau in 2020, we examined the spatial and temporal variations of below‐cloud evaporation effect on precipitation isotopes, and then discussed the factors influencing the below‐cloud evaporation across the Gannan Plateau. The contemporary observation of precipitation isotopes at one site in the Gannan Plateau is also applied to understand the local meteoric water line associated with the below‐cloud evaporation. From 9:00 to 21:00 Beijing Time, the impact of below‐cloud evaporation is greater than that during the rest periods. Within the study region, the below‐cloud evaporation in the central area is usually stronger than that of the surrounding area. The diurnal and monthly variability of relative humidity is highly consistent with that of the remaining raindrop mass fraction after evaporation as well as the isotope variation in raindrop below the cloud base. When the relative humidity is greater than 95%, there is a linear relationship between the remaining raindrop mass fraction and the below‐cloud deuterium‐excess variation of approximate 1.1‰/%. Global warming will increase the below‐cloud evaporation effect across the Gannan Plateau. The findings are useful to understand the below‐cloud evaporation and isotope fractionation under a plateau climate.

Deuterium Excess in Precipitation Reveals Water Vapor Source in the Monsoon Margin Sites in Northwest China

The deuterium excess (d) in precipitation, determined by the stable hydrogen and oxygen isotopes (δ2H and δ18O), is a widely applied parameter in tracing the water vapor source. Based on the multiple-year observations of stable water isotopes in precipitation at four stations in the Lanzhou city, Northwest China, we analyzed the variations in deuterium excess in precipitation at the Asian monsoon margin region. The mean value of deuterium excess at the study region is 11.0‰ in the dry season and 8.0‰ in the wet season. The d value in precipitation negatively correlates with air temperature and vapor pressure. The low d value during the wet season reflects the monsoon moisture transported from long distances. During the dry season, the continental air masses correspond to the higher d value in precipitation. The moisture regimes based on reanalysis data are generally consistent with the findings using a stable isotopic approach, and the monsoon moisture is highlighted in summer precipitation at these monsoon margin sites.

Catchment storage and residence time in a periodically irrigated watershed

AbstractUnderstanding anthropogenic impacts on water storage and water flow pathways in catchments is an ongoing challenge in hydrology. Here, we study the dynamics of subsurface storage and residence time of water in a catchment in Berkeley, California, that is within a regional park but contains diverse land use within its perimeter, including a periodically irrigated golf course. Our study combines several isotopic tracers with water budget data to examine sources of water in a stream draining the site. Irrigation water, applied to a small area of the watershed, is a minor component of the water budget. However, geochemical tracers reveal that irrigation water is a significant fraction of stream flow downstream of the golf course during baseflow and during precipitation events. Isotopic tracers indicate that the watershed has a preference to release young water for stream flow generation, resulting in contrasting tritium ages for stream water and groundwater of 1.3 ± 0.5 year and 8.2 ± 1.7 year, respectively. We determined that the older water is a very small component (0.7%) of the stream water in the tail of an assumed exponential distribution. We used the seasonal variation of stable water isotopes in precipitation and stream water over two water years to explain the damping of the isotopic signature of stream water, which yields information about the catchment's response to the input signal. The methods described here may be applicable to other urban or suburban headwater catchments in areas with a component of non‐natural recharge from, for example, leaky infrastructure, storm water routing or dry season irrigation.

New water fractions and transit time distributions at Plynlimon, Wales, estimated from stable water isotopes in precipitation and streamflow

Abstract. Long-term, high-frequency time series of passive tracers in precipitation and streamflow are essential for quantifying catchment transport and storage processes, but few such data sets are publicly available. Here we describe, present, and make available to the public two extensive data sets of stable water isotopes in streamflow and precipitation at the Plynlimon experimental catchments in central Wales. Stable isotope data are available at 7-hourly intervals for 17 months, and at weekly intervals for 4.25 years. Precipitation isotope values were highly variable in both data sets, and the high temporal resolution of the 7-hourly streamwater samples revealed rich isotopic dynamics that were not captured by the weekly sampling. We used ensemble hydrograph separation to calculate new water fractions and transit time distributions from both data sets. Transit time distributions estimated by ensemble hydrograph separation were broadly consistent with those estimated by spectral fitting methods, suggesting that they can reliably quantify the contributions of recent precipitation to streamflow. We found that on average, roughly 3 % of streamwater was made up of precipitation that fell within the previous 7 h, and 13 %–15 % of streamwater was made up of precipitation that fell within the previous week. The contributions of recent precipitation to streamflow were highest during large events, as illustrated by comparing new water fractions for different discharges and precipitation rates. This dependence of new water fractions on water fluxes was also reflected in their seasonal variations, with lower new water fractions and more damped catchment transit time distributions in spring and summer compared to fall and winter. We also compared new water fractions obtained from stable water isotopes against those obtained from concentrations of chloride, a solute frequently used as a passive tracer of catchment transport processes. After filtering the chloride data for dry deposition effects, we found broadly similar new water fractions using chloride and stable water isotopes, indicating that these different tracers may yield similar inferences about catchment storage and transport, if potentially confounding factors are eliminated. These stable isotope time series comprise some of the longest and most detailed publicly available catchment isotope data sets. They complement extensive solute data sets that are already publicly available for Plynlimon, enabling a wide range of future analyses of catchment behavior.

Sensitivity of young water fractions to hydro-climatic forcing and landscape properties across 22 Swiss catchments

Abstract. The young water fraction Fyw, defined as the proportion of catchment outflow younger than approximately 2–3 months, can be estimated directly from the amplitudes of seasonal cycles of stable water isotopes in precipitation and streamflow. Thus, Fyw may be a useful metric in catchment inter-comparison studies that investigate landscape and hydro-climatic controls on streamflow generation. Here, we explore how Fyw varies with catchment characteristics and climatic forcing, using an extensive isotope data set from 22 small- to medium-sized (0.7–351 km2) Swiss catchments. We find that flow-weighting the tracer concentrations in streamwater resulted in roughly 26 % larger young water fractions compared to the corresponding unweighted values, reflecting the fact that young water fractions tend to be larger when catchments are wet and discharge is correspondingly higher. However, flow-weighted and unweighted young water fractions are strongly correlated with each other among the catchments. They also correlate with terrain, soil, and land-use indices, as well as with mean precipitation and measures of hydrologic response. Within individual catchments, young water fractions increase with discharge, indicating an increase in the proportional contribution of faster flow paths at higher flows. We present a new method to quantify the discharge sensitivity of Fyw, which we estimate as the linear slope of the relationship between the young water fraction and flow. Among the 22 catchments, discharge sensitivities of Fyw are highly variable and only weakly correlated with Fyw itself, implying that these two measures reflect catchment behaviour differently. Based on strong correlations between the discharge sensitivity of Fyw and several catchment characteristics, we suggest that low discharge sensitivities imply greater persistence in the proportions of fast and slow runoff flow paths as catchment wetness changes. In contrast, high discharge sensitivities imply the activation of different dominant flow paths during precipitation events, such as when subsurface water tables rise into more permeable layers and/or the river network expands further into the landscape.

The influence of the synoptic regime on stable water isotopes in precipitation at Dome C, East Antarctica

Abstract. The correct derivation of paleotemperatures from ice cores requires exact knowledge of all processes involved before and after the deposition of snow and the subsequent formation of ice. At the Antarctic deep ice core drilling site Dome C, a unique data set of daily precipitation amount, type, and stable water isotope ratios is available that enables us to study in detail atmospheric processes that influence the stable water isotope ratio of precipitation. Meteorological data from both automatic weather station and a mesoscale atmospheric model were used to investigate how different atmospheric flow patterns determine the precipitation parameters. A classification of synoptic situations that cause precipitation at Dome C was established and, together with back-trajectory calculations, was utilized to estimate moisture source areas. With the resulting source area conditions (wind speed, sea surface temperature, and relative humidity) as input, the precipitation stable isotopic composition was modeled using the so-called Mixed Cloud Isotope Model (MCIM). The model generally underestimates the depletion of 18O in precipitation, which was not improved by using condensation temperature rather than inversion temperature. Contrary to the assumption widely used in ice core studies, a more northern moisture source does not necessarily mean stronger isotopic fractionation. This is due to the fact that snowfall events at Dome C are often associated with warm air advection due to amplification of planetary waves, which considerably increases the site temperature and thus reduces the temperature difference between source area and deposition site. In addition, no correlation was found between relative humidity at the moisture source and the deuterium excess in precipitation. The significant difference in the isotopic signal of hoarfrost and diamond dust was shown to disappear after removal of seasonality. This study confirms the results of an earlier study carried out at Dome Fuji with a shorter data set using the same methods.

Factors controlling stable isotope composition of precipitation in arid conditions: an observation network in the Tianshan Mountains, central Asia

Approximately one-third of the Earth's arid areas are distributed across central Asia. The stable isotope composition of precipitation in this region is affected by its aridity, therefore subject to high evaporation and low precipitation amount. To investigate the factors controlling stable water isotopes in precipitation in arid central Asia, an observation network was established around the Tianshan Mountains in 2012. Based on the 1052 event-based precipitation samples collected at 23 stations during 2012–2013, the spatial distribution and seasonal variation of δD and δ18O in precipitation were investigated. The values of δD and δ18O are relatively more enriched in the rainfall dominant summer months (from April to October) and depleted in the drier winter months (from November to March) with low D-excess due to subcloud evaporation observed at many of the driest low elevation stations. The local meteoric water line (LMWL) was calculated to be δD=7.36δ18O – 0.50 (r2=0.97, p<0.01) based on the event-based samples, and δD=7.60δ18O+2.66 (r2=0.98, p<0.01) based on the monthly precipitation-weighted values. In winter, the data indicate an isotopic rain shadow effect whereby rainout leads to depletion of precipitation in the most arid region to the south of the Tianshan Mountains. The values of δ18O significantly correlate with air temperature for each station, and the best-fit equation is established as δ18O=0.78T – 16.01 (r2=0.73, p<0.01). Using daily air temperature and precipitation derived from a 0.5° (latitude)×0.5° (longitude) gridded data set, an isoscape of δ18O in precipitation was produced based on this observed temperature effect.

Analysis of long-term stable isotopic composition in German precipitation

Summary Stable water isotopes in precipitation ( 18 O and 2 H) have been frequently used as environmental tracers to understand processes and timescales in hydrology and climate research. Capturing changes of isotopic composition over time and investigating long-term processes requires long-term data set analysis. In Germany, we have one of the world’s densest national networks for long-term isotopic analysis of precipitation covering up to 36 years of time series at 28 locations. These data were used to identify the average as well as the temporal evolution of isotopic composition in German precipitation and how it is related to meteorological and geographical parameters. We found that individual Local Meteoric Water Lines (LMWL) and the long-term averages of δ 18 O and δ 2 H depend on latitude and elevation. More variable isotopic compositions and more enriched averages were found at the coast compared to more stable compositions and depleted averages in the South, South-East and at higher elevations. This continentality effect was strongly influenced by seasonal isotope-temperature dependencies. Removing the seasonality and looking at the changes over time compared to long-term averages indicate similar patterns for temperatures and 18 O at some locations. We concluded that temperature and isotopes are in equilibrium in inland air masses only. The trend in temperature evolution was consistent on the national level, and temperature increases were observed in almost all stations. In contrast, temporal patterns of 18 O revealed different patterns and increases were only observed in 20 out of 28 locations. Therefore, changes in isotopic composition in precipitation are not only influenced by large scale processes (i.e. temperature) but also by local factors which need to be further investigated.

High‐frequency storm event isotope sampling reveals time‐variant transit time distributions and influence of diurnal cycles

AbstractHigh‐frequency sampling of stable water isotopes in precipitation and stream water during winter and summer storm events was carried out in a 2·3 km2 lowland agricultural catchment. During peak flows of monitored events, the responses of δ2H and δ18O were comparable and inferred the dominance (ca 70%) of ‘old’ pre‐event water. Transit Time Distribution (TTD) inferred by a gamma function were fitted (Nash–Sutcliffe = 0·8) and were also similar for δ2H and δ18O. However, the shape (α) and scaling (β) parameters were markedly different for summer and winter events. Consequently, when antecedent wetness was high, mean transit times were in the order of days; when drier, they increased to months. Moreover, while the responses of δ2H and δ18O exhibited similar gradual recovery to pre‐event conditions during winter hydrograph recessions, they differed dramatically on summer recessions. Time series analysis showed that δ2H isotope content was correlated with the diurnal cycle of air temperature, suggesting an evaporative fractionation pattern which could be reproduced by a temperature‐based first‐order autoregressive model. The heavier δ18O isotope showed no evidence for such diurnal variability. The study highlights the utility of high‐frequency stable isotope sampling to explore the time‐variant nature of TTDs. Furthermore, it shows that the time of sampling in a diurnal cycle may have crucial significance for interpreting stream isotope signatures, particularly δ2H. Copyright © 2011 John Wiley &amp; Sons, Ltd.

Simulation of the Stable Water Isotopes in Precipitation over South America: Comparing Regional to Global Circulation Models

Abstract A simulation of the stable water isotope cycle over South America by the regional circulation model REMOiso is discussed. The performance of the regional model, with a resolution of 0.5° (∼55 km), is compared to simulations by the global circulation model ECHAMiso at two coarser resolutions and evaluated against observations of precipitation and δ18O. Here REMOiso is demonstrated to reproduce reasonably well climatic and isotopic features across South America. This paper explores further insights of δ18O as a climate proxy, based on REMOiso’s improvements as compared to ECHAMiso. In particular, the authors focus on the seasonal variation of the amount effect (δ18O decrease with precipitation amounts) and the anomalous δ18O continental gradient across the Amazon basin, as inferred from the REMOiso, ECHAMiso, and GNIP datasets. The finer resolution of topography in REMOiso enables a detailed analysis of the altitude effect: not only the first, but also the second derivative of δ18O with altitude is considered. It appears that high-altitude grid cells show an isotopic signature similar to Rayleigh distillation, in accordance with experimental studies. Finally, a Lagrangian reference frame is adopted to describe the evolution of δ18O in precipitation along its trajectory, in order to relate the simulation analysis to the fractionation mechanisms. This confirms that the amount effect, via Rayleigh distillation processes, is dominant during the wet season. During the dry season, the δ18O in precipitation is controlled by isotopic reequilibration of rain droplets with surrounding vapor, reflecting the impact of nonfractionating transpiration by the vegetation.