Stable Isotope Variations Research Articles

Effects of different surface water flow frequencies on water use characteristics of Tamarix ramosissima in the hinterland of the Taklamakan Desert

Tamarix ramosissima is a dominant species in desert ecosystems and an ecological barrier species in arid areas, playing a crucial role in stabilizing dunes and preventing desertification. In this study, river water, groundwater, soil water, and T. ramosissima individual samples were collected from three sites in July and October 2023 at the Daliyaboyi Oasis located at the tail of the Kriya River in the hinterland of the Taklamakan Desert. The three sites are referred to as the center (SE), west (SW), and north (SN) sites within the Daliyaboyi Oasis, and each experienced different flood frequencies. The SE site experienced flooding in July and October, the SW site experienced flooding only in July, and the SN site experienced no flooding in July or October. The spatial and temporal variation in hydrogen and oxygen stable isotopes and line-conditional excess (lc-excess) in water and plant samples were analyzed, and the potential changes in water use of T. ramosissima were analyzed by the hydrogen and oxygen stable isotope and MixSIAR model. The findings indicated that the slope of SWL at the SE, SW, and SN sites was higher in July (6.77, 6.42, and 3.05, respectively) than in October (7.37, 3.30, and 2.14, respectively). The lc-excess value of the SE site did not exhibit seasonal changes; only the lc-excess values of soil water in SW and SN sites showed seasonal changes. MixSIAR results indicated frequent flood events at the SE site, with relatively constant proportions of water source utilization by T. ramosissima in July and October. In addition, shallow soil water (0–60 cm) and deeper soil water (60–80 cm) were the main water sources of T. ramosissima at SE. The SN site was slightly influenced by surface water, resulting in statistically non-significant changes in the water source utilization by T. ramosissima. Indeed, deep soil water (60–200 cm) and groundwater were the sources of water for T. ramosissima at this site. In contrast with October, the SW site experienced flood events in July, resulting in the utilization of water by T. ramosissima from the shallow soil (0–60 cm) and deep soil (60–280 cm) in July and October, respectively. Different surface water flow patterns led to different water use characteristics of T. ramosissima, which further demonstrated that T. ramosissima has high resilience and ecological plasticity. This work provides a useful reference for the implementation of effective ecological water transport measures in the Daliyaboyi Oasis and similar arid habitats.

Stable-isotope variability in daily precipitation: insights from a low-cost collector in SE England

ABSTRACT Precipitation stable-isotope data are often used in hydroclimatic, hydrological and hydrogeological investigations, with measurements typically undertaken on integrated monthly samples. However, daily sampling reveals overlooked aspects of controls on precipitation isotope values, including synoptic meteorological conditions. We present a one-year record of stable isotopes in daily precipitation during 2021, from a site in SE England close to Greater London. We find marked daily variability over the course of the year (–15.62 to +0.92 ‰ for δ18O, –108.7 to +2.9 ‰ for δ2H and –6.5 to +23.1 ‰ for deuterium excess). Correlations with individual meteorological variables including precipitation amount, temperature and weather type are moderate to weak suggesting complex controls on the daily rainfall isotope values. The daily data are compared with three other daily datasets from England and, by conversion to monthly values, directly with data from three long-term collection stations across Britain and Ireland. The scale of variability in the daily data from our site is consistent with that seen in other English records despite them all coming from different time periods. The monthly data show broad consistency, although there are differences that also highlight geographical variability in precipitation values across the British Isles.

Variation and fractionation of δ2H, δ18O, and δ17O stable isotopes from irrigation water to soil, grapes, and wine for the traceability of geographical origins

To investigate the variation and fractionation of stable isotopes from irrigation water to soil, grapes, and wine, δ2H, δ18O, and δ17O in different samples from 10 regions in China were determined using a water isotope analyser. The values were significantly different among regions according to the chemometric analysis. All isotopes were significantly and positively correlated with irrigation water–soil and grape–wine. A significant water isotopic fractionation effect was observed from the irrigation water to the soil, grapes, and wine. Stable isotope distribution characteristics correlated with longitude, latitude, altitude, temperature, precipitation, station pressure and wind speed. The linear discriminant analysis (LDA), random forest (RF), support vector machine (SVM), and feed-forward neural network (FNN) models 58.33–100 %, 80–100 %, 53.33–100 %, and 73.33–100 % accurate for distinguishing the geographical origins of all samples from training and test data, respectively. These findings provide a theoretical basis for authenticating the geographic origin of Chinese wines using stable isotope analysis.

High‐Frequency Isotope Compositions Reveal Different Cloud‐Top and Vertical Stratiform Rainfall Structures in the Inland Tropics of Brazil

AbstractUnderstanding the key drivers controlling rainfall stable isotope variations in inland tropical regions remains a global challenge. We present novel high‐frequency isotope data (5–30 min intervals) to disentangle the evolution of six stratiform rainfall events (N = 112) during the passage of convective systems in inland Brazil (September 2019–June 2020). These systems produced stratiform rainfall of variable cloud features. Depleted stratiform events (δ18Oinitial ≤ −4.2‰ and δ18Omean ≤ −6.1‰) were characterized by cooler cloud‐top temperatures (≤−38°C), larger areas (≥48 km2), higher liquid‐ice ratios (≥3.1), and higher melting layer heights (≥3.8 km), compared to enriched stratiform events (δ18Oinitial ≥ −3.8‰ and δ18Omean ≥ −5.1‰). Cloud vertical structure variability was reflected in a wide range of δ18O temporal patterns and abrupt shifts in d‐excess. Our findings provide a new perspective to the ongoing debate about isotopic variability and the partitioning of rainfall types across the tropics.

Stable isotope and fatty acid variation of a planktivorous fish among and within large lakes.

Aquatic food webs are spatially complex, potentially contributing to intraspecific variability in production pathway reliance of intermediate trophic level consumers. Variation in trophic reliance may be described by well-established trophic indicators, like stable isotope ratios (δ13C, δ15N), along with emerging trophic indicators, such as fatty acid composition. We evaluated stable isotope ratios and fatty acid profiles of European smelt (Osmerus eperlanus) among and within distinct regions of three large Swedish lakes (Hjälmaren, Mälaren, Vättern) which differed in trophic status. We expected that smelts in more oligotrophic lakes and regions would be characterized by distinct stable isotope signatures and fatty acid profiles, with particularly high polyunsaturated fatty acid (PUFA) relative levels. However, we acknowledge that frequent movement of smelts among regions may serve to spatially integrate their diet and lead to limited within-lake variation in stable isotope ratios and fatty acid composition. As expected, in comparison with more productive lakes (i.e., Hjälmaren and Mälaren), smelts from ultra-oligotrophic Vättern were characterized by low δ15N, high δ13C and high percent of a dominant PUFA, docosahexaenoic acid (DHA). Smelts from different regions of the morphometrically complex Mälaren displayed differential stable isotope ratios and fatty acid relative concentrations, which were consistent with within-lake differences in productivity and water residence times, suggesting that smelts in this lake forage locally within distinct regions. Finally, at the individual smelt level there were particularly strong and consistent associations between a well-established trophic indicator (δ13C) and percent DHA, suggesting that the relative concentration of this fatty acid may be a useful additional trophic indicator for smelt.

Skill of isotope-enabled climate models for daily surface water vapour in East Asia

The isotope-enabled general circulation models (GCM) have been widely applied to simulate the variability of stable isotopes in meteoric water at various time scales. The in-situ observations of water vapour isotopes are an important basis for assessing the performance of isotope-enabled GCMs, although they are still limited. Here we compiled the observations of near-surface water vapour isotopes on a daily scale at 17 stations in East Asia, and assessed the skill and the association between isotope error and meteorological errors on a daily scale. Generally, the spatial pattern and seasonal variability can be well simulated in the isotope-enabled GCMs. The models show better skill for warm and humid backgrounds, which also corresponds to the monsoonal regions with lower latitudes in East Asia. As spatial resolution is finer, the skill of models is better, which can be seen from the two GCMs. According to the correlation coefficient, the improvement of resolution is more obvious in summer than in winter, especially for IsoGSM. In addition, the correlation coefficient in winter is usually larger than that in summer. The daily modelling has good potential to investigate the daily or synoptic climate information in water isotopes. The findings are useful for understanding the applicability of isotope-enabled models in East Asia and the climate factors influencing the skill of isotope-enabled models on a daily basis.

Stable Isotope Variation in East and Southeast Asian Marine Ecosystems and its Relevance for Archaeological Analysis

ABSTRACT This paper delves into the utilisation of stable isotope analysis as a tool for understanding ancient human adaptations to diverse marine environments, with a specific geographical focus on Southeast Asia and the Pacific. It analyzes stable isotope data from modern fish bones and tooth enamel, focusing on δ13C, δ15N, and δ18O values. The data confirm the reliability of δ13C as a proxy for marine consumption in archaeological contexts and emphasises the potential of combining δ13C and δ15N measurements to reconstruct marine food consumption and trophic level. This, in turn, helps us gain insights into ancient marine consumption and ecosystems in Southeast Asia. While distinctions between marine niches are not clear, δ15N shows potential for distinguishing feeding behaviours among fish species. The data also suggests geographical and ecological variations in stable isotope values, highlighting the need for locally-based baseline datasets in archaeological studies of marine subsistence strategies.

The influence of moisture transport processes on the stable isotopic compositions in precipitation on the South slope of the Himalayas

Understanding spatiotemporal variations in stable isotopes in precipitation (ẟ18O and ẟD) on the south slope of the Himalayas is crucial for comprehending moisture variations reaching the Tibetan Plateau (TP). Here, we analyze these variations at seven stations in Nepal spanning altitudes from 102 m to 5050 m above sea level in 2017. Our findings show no significant temperature or precipitation amount effect on isotopes, with synoptic precipitation exerting a strong influence. Non-monsoon precipitation primarily originates from the vicinity of the Koshi River basin and the Ganges River, while during the monsoon, the Bay of Bengal, the Koshi River basin, and the Ganges River contribute, with minimal input from the Arabian Sea. Convective activities significantly regulate inner-seasonal precipitation δ18O, with strong convection associated with low isotopic values. Increasing altitude leads to substantial differences in δ18O values, indicating modulation by higher condensation levels and lower temperatures. These findings underscore the impact of regional moisture transport on precipitation isotopic variability and offer insights into interpreting paleo-isotope records in the Indian Summer Monsoon region.

Understanding arsenic behavior in alluvial aquifers: Evidence from sediment geochemistry, solute chemistry and environmental isotopes

The hydro-geochemistry and isotopic variations in groundwater, coupled with sediment geochemistry, were investigated in the Middle Gangetic Plain, India, to better understand the aquifer dynamics that influence the arsenic (As) evolution and mobilization. Eighty-four groundwater samples, thirteen River water samples, and two sediment cores (33 mbgl) were studied. The samples were analyzed for major ions and trace metals, including As and stable isotopic variability (δ2H, δ18O, and δ13C). The study area was categorized into older and younger alluvium based on existing geomorphological differences. Younger alluvium exhibits higher As enrichment in sediment and groundwater, ranging of 2.59–31.52 mg/kg and bdl to 0.62 mg/L. Groundwater samples were thermodynamically more stable with As(OH)3 species ranging from 88.5% to 91.4% and FeOOH from 69% to 81%, respectively. PHREEQC and mineralogical analysis suggested goethite and siderite act as a source and sink for As. However, statistical analysis suggested reductive dissolution as the primary mechanism for As mobilization in the study area. Spatio-temporal analysis revealed elevated concentrations of As in the central and northeastern regions of the study area. Stable isotope (δ2H and δ18O) analysis inferred active recharge conditions primarily driven by precipitation. The depleted d-excess value and enriched δ18O in the groundwater of younger alluvium indicate the effect of groundwater recharge with significant evaporation enrichment. Groundwater recharge potentially decreased the quantity of arsenic in groundwater, whereas evaporation enrichment increased it. Rainwater infiltration during recharge introduces oxygenated water into the aquifer, leading to changes in the redox conditions and facilitating biogeochemical reactions. The carbon isotope (δ13C) results suggest that high microbial activity in younger alluvium promotes As leaching from sediment into the groundwater.

Application of process-based modelling for interpretation of stable isotope variations in tree rings

Application of process-based modelling for interpretation of stable isotope variations in tree rings

The Effect of Convective/Advective Precipitation Partitions on the Precipitation Isotopes in the Monsoon Regions of China: A Case Study of Changsha

Abstract Convective/advective precipitation partitions refer to the divisions of precipitation that are either convective or advective in nature, relative to the total precipitation amount. These distinct partitions can have a significant influence on the stable isotope composition of precipitation. This study analyzed and compared the effect of precipitation partitions on δ18O in precipitation (δ18Op) by using daily precipitation stable isotope data from Changsha station and monthly precipitation stable isotope data from the Global Network of Isotopes in Precipitation (GNIP), under different time scales, time intervals (i.e., annual, warm season, and cold season), and precipitation intensities. The results showed that the correlation between the convective precipitation fraction (CPF) and total precipitation amount was influenced by the intensity of convection in different time intervals. On both the daily and monthly scales, the CPF decreased as the precipitation amount increased in the warm season, while it increased with increasing precipitation amount in the cold season. Regardless of the season, daily δ18Op at Changsha station consistently increased with an increase in daily CPF. On a daily scale, the effect of convective activity on δ18Op was stronger than that of the “precipitation amount effect” in the cold season, as compared to the situation in the warm season. As a result, the regression line slope between δ18Op and CPF increased with increasing precipitation intensity in the warm season, meaning that as the CPF increased, the δ18Op increased at a faster rate under higher precipitation intensity. Similarly, the slope increased with increasing precipitation intensity in the cold season. This suggests that precipitation intensity and convection intensity can affect the relationship between δ18Op and CPF. Our findings shed light on how different precipitation partitions affect stable isotope composition of precipitation, thus enhancing our understanding of the variability of precipitation stable isotopes in the monsoon regions of China. Significance Statement This study aims to better elucidate the influence of different precipitation partitions on precipitation stable isotopes. In the eastern monsoon region of China, stable isotopes in precipitation showed a robust positive relationship with convective precipitation faction. On a daily scale, the convective activity enhanced the influences of the “precipitation amount effect” on precipitation stable isotopes in the warm season and reduced such influences in the cold season. These results improve our understanding of stable isotopic variability of precipitation in the eastern monsoon region, China.

Consumer isoscapes reveal heterogeneous food webs in deep-sea submarine canyons and adjacent slopes

The deep sea is the largest biome on earth, but one of the least studied despite its critical role in global carbon cycling and climate buffering. Deep-sea organisms largely rely on particulate organic matter from the surface ocean for energy – these organisms in turn play critical roles in energy transport, transformation, storage, and sequestration of carbon. Within the deep sea, submarine canyons are amongst the most complex and dynamic environments in our oceans, where varied morphology, powerful currents, and variable nutrient conditions influence the distribution of species and transport of organic material throughout the water column and the seafloor. Significant habitat heterogeneity provides ideal substrates for cold-water corals, making submarine canyons of interest to conservation and management. However, how these and other topographic features in the deep ocean influence energy flow and trophic pathways is poorly known. Thus, submarine canyons serve as model systems to track variability in organic material flux and consequential utilization and assimilation by the benthos. In this study, we used an extensive stable isotope dataset to examine food-web structure in Baltimore and Norfolk submarine canyons and compared them to their adjacent slopes located along the U.S. Atlantic margin. Linear models were used to construct geospatially-explicit consumer isoscapes that predicted variation in carbon and nitrogen isotopes across the canyon-slope seascape, providing a predictive map from which to test hypotheses on the distribution and flow of energy resources, relevant to understanding whole community function. Communities were composed of isotopically diverse feeding groups with photosynthetically-derived organic carbon providing the basal food resource. Canyon communities were distinct from the slope, with canyon consumers significantly 13C-depleted, indicating a greater supply and/or utilization of fresh organic matter compared to the slope. Isoscapes for benthic and suspension feeders were distinct, possibly due to the consumption of different quality organic matter sources (fresh = suspension feeders, old = benthic feeders), each with distinct isotope composition. To our knowledge, our modeled isoscapes represent the first spatially extensive isotopic maps of deep-sea consumers, providing insights into regional-scale variation in stable carbon and nitrogen isotopes for different consumer groups. They provide a baseline for tracking climate-change induced fluctuations in the quality and availability of surface primary production and the consequential impact to benthic communities, which play critical roles in carbon cycling in our world’s oceans.

Pushing the limits of C3 intrinsic water use efficiency in Mediterranean semiarid steppes: Responses of a drought‐avoider perennial grass to climate aridification

Abstract Intrinsic water use efficiency (WUEi) reflects the trade‐off between photosynthetic carbon gain and water loss through stomatal conductance and is key for understanding dryland plant responses to climate change. Stipa tenacissima is a perennial tussock C3 grass with an opportunistic, drought‐avoiding water use strategy that dominates arid and semiarid steppes across the western Mediterranean region. However, its ecophysiological responses to aridification and woody shrub encroachment, a major land‐use change in drylands worldwide, are not well‐understood. We investigated the variations in leaf stable isotopes (δ18O, δ13C, δ15N), nutrient concentrations (N, P, K), and culm water content and isotopic composition (δ18O, δ2H) of paired pure‐grass and shrub‐encroached S. tenacissima steppes along a 350 km aridity gradient in Spain (10 sites, 160 individuals). Culm water isotopes revealed that S. tenacissima is a shallow‐rooted grass that depends heavily on recent rainwater for water uptake, which may render it vulnerable to increasingly irregular rainfall combined with faster topsoil drying under climate warming and aridification. With increasing aridity, S. tenacissima enhanced leaf‐level WUEi through more stringent stomatal regulation of plant water flux and carbon assimilation (higher δ13C and δ18O), reaching exceptionally high δ13C values (−23‰ to −21‰) at the most arid steppes. Foliar N concentration was remarkably low across sites regardless of woody shrub encroachment, evidencing severe water and N co‐limitation of photosynthesis and productivity. Shrub encroachment decreased leaf P and K but did not affect S. tenacissima water status. Perennial grass cover decreased markedly with both declining winter rainfall and shrub encroachment suggesting population‐level rather than individual‐level responses of S. tenacissima to these changes. The fundamental physiological constraints of photosynthetic C3 metabolism combined with low foliar N content may hamper the ability of S. tenacissima and other drought‐avoider species with shallow roots to achieve further adaptive improvements in WUEi under increasing climatic stress. A drought‐avoiding water use strategy based on early stomatal closure and photosynthesis suppression during prolonged rainless periods may thus compromise the capacity of semiarid S. tenacissima steppes to maintain perennial grass cover, sustain productivity and cope with ongoing climate aridification at the drier parts of their current distribution. Read the free Plain Language Summary for this article on the Journal blog.

Spatial variability in stable isotopes from Lesotho surface waters: insights into regional moisture transport

Precipitation in Lesotho is highly spatially variable, a feature of the high altitude and rugged topography. The hydroclimate dynamics, despite being critical to the water security of Lesotho and adjacent South Africa, are poorly understood. Ratios of oxygen and hydrogen isotopes in meteoric water are excellent tracers of hydroclimatic processes. This study presents the first analysis of stable isotopes from surface waters in Lesotho, and an investigation into the moisture sources. Our results demonstrate considerable variability in isotope values. There are statistically significant relationships between both oxygen and hydrogen isotopes and the altitude of the site and source of rivers sampled, and with hydrogen isotopes and longitude. The meteoric water line for the Lesotho samples is most closely aligned with that of the Global Network of Isotopes in Precipitation (GNIP) station at Harare, in Zimbabwe. The meteoric water line for Windhoek is more closely aligned to the Lesotho samples than the more proximate Cape Town or Pretoria meteoric water lines, which would more closely represent the South African winter- and summer-rainfall zones respectively. HYSPLIT back-trajectory air parcel analysis supports these findings, demonstrating a frequent continental anticyclonic track through southern Zimbabwe. Deuterium excess values vary widely, although are most likely related to processes during moisture transport rather than differences in moisture source. These findings are of particular importance in the context of the future water security of both Lesotho and South Africa, especially as the poleward displacement of the westerly moisture corridor has raised concerns for winter precipitation in the region.

Role of stable isotopes in revealing moisture sources and rainfall variability in India

Precipitation is a crucial component of the water cycle and is essential for the livelihood of people and ecosystems; therefore, understanding precipitation parameters is vital. Stable isotopes in precipitation can provide important information on precipitation sources, atmospheric circulation patterns, and hydrological processes. In this study, stable isotopes in precipitation for four cities in India were analyzed, namely New Delhi, Hyderabad, Shillong, and Calicut, using data from the International Atomic Energy Agency (IAEA) Global Network for Isotopes in Precipitation (GNIP). The GNIP data were supplemented with in-situ measurements. Results showed the correlations between climate-related factors such as surface air temperature and precipitation levels with the stable isotope composition of precipitation. The relationships critically explore interannual variations in the isotope data over the last three decades. The Local Meteoric Water Line (LMWL) for New Delhi and Hyderabad had intercepts less than 10‰, implying a higher evaporation effect over precipitation, consistent with arid and semi-arid regions with increased altitude. The weighted average value of d-excess for southern and Himalayan points were 10.7 and 12.7, respectively, and the average value of δ¹⁸O were − 3.65 and − 5.84, and δ²H were − 16.8 and − 35.8. The d-excess value was significantly lower in the Northern part (New Delhi), with an average weighted value of 6.6. The key values include the isotopic composition of rainfall in different regions of India, the LMWL for different stations, the d-excess value, and the consistency of meteoric water lines with regional and global values. The results of this study provide valuable information on the variability of stable isotopes in precipitation in India. The study's outcomes can be compared with the isotopic composition of surface water and groundwater. This discovery offers more understanding of the isotopic differences that occur on a smaller scale during organized convection and the factors that affect them. As a result, it enhances our ability to decipher the paleoclimate data in arid, semi-arid, and subtropical monsoon regions.

Bonneville basin critical zones

Playa margin wetlands in the Bonneville basin are sustained by groundwater-fed brackish springs, which transport salts and other solutes into the playa basin. These wetlands are sensitive to changing water availability and quality, which are impacted by changing climate and land use, and whose sediments also provide important records of changing environmental conditions. Gastropods building their shells in these springs provide important recorders of water chemistry and may reflect changing aqueous conditions. In this paper, we analyze spring water chemistry, gastropod ecology and gastropod shell chemistry of Blue Lake (BL) and Horseshoe Springs (HRS), two groundwater-fed wetlands in the Great Salt Lake watershed. We report the physical parameters including pH, temperature, and specific conductivity across the spring pond at Horseshoe springs. There was a slight but statistically significant variation in these physical characteristics between the deeper and shallower parts of the pool, providing evidence that there are different subsite microclimates, which may impact the populations and the isotopic composition of gastropod shells. We measured gastropod population diversity amongst nearly 12,000 shells sampled at Horseshoe springs, finding low population diversity (Shannon’s Diversity Index of 0.432), although the populations of shallow and deep snails are slightly different. The dominant snail at HRS is the Pyrgulopsis which is imperiled, and we also note that we did not find living snails here. We evaluated the bulk shell variation of stable carbonate isotopes (δ13C, and δ18O) across sites and genera. We show that there were no significant subsite-level differences in gastropod δ13C compositions, suggesting that water depth and productivity were not impacting the isotopic signal. We found subsite- and genera-specific differences in snail δ18O compositions, which we interpret to be more dependent on the geography and microclimate of where the snail lived rather than the genera’s physiology (pulmonate versus gil-breathing). We report concentrations of alkali metals (Li, Na, K, Rb, Cs), alkali earth metals (Be, Mg, Ca, Sr, Ba), and metals and metalloids (Al, Sc, Mn, Fe, Cu, Ni, Zn, As) at spring site waters and in bulk shells as potential baseline data for interpreting future or past environmental changes as recorded in shell material. We found trace element concentration and certain elemental ratio differences between genera at the same site (particularly of note were Li, Zn, Mn and Al) that will be important to constrain if these shells are to be applied as a paleoenvironmental proxy and are sometimes attributed to land use change.

Morphology of the Buluus, Ulakhan-Taryn aufeis, conditions of its occurrence and stable oxygen and hydrogen isotope variations in the lower part

Aufeis is one of the most dangerous natural phenomena. The negative impact of aufeis is determined by the unexpected flooding of the territory and subsequent freezing of water, the formation of ice barriers, the icing of underground structures and communications (mines, tunnels, culverts, and sewer wells), as well as the icing of roads and railways, coastal hydraulic structures, etc. There are cases when explosions of aufeis mounds produce catastrophic disturbances within a few seconds. The aufeis that forms annually in the valley of the Buluus Creek is one of the most famous and studied aufeis of Central Yakutia. The aufeis was sampled from a vertical section. The aufeis is layered, and the thickness of the layers is 3-10 cm. In the upper part of the aufeis, the ice layers are thicker than in the lower. Sampling from the aufeis ice was carried out using a 5.1-cm-diameter steel crown driven by a Bosch electric drill. Measurements of the isotopic composition of oxygen and hydrogen in ice were performed using a Picarro L 2130-i laser isotope analyzer. The isotopic composition of the Buluus ice varies in a narrow range: δ18O values vary from −20.2 to −21.9‰, δ2H values vary from −159.5 to −173.7‰. Generally, the ice is isotopically slightly enriched compared to the surface water of the Ulakhan-Taryn creek, where the δ18O value is −22.18‰ and the δ2H value is −175.1%. Groundwater is isotopically close to the creek water; its isotope composition is also isotopically enriched compared to the ice of the aufeis, with δ18O values varying from −22.17 to −22.25‰ and δ2H values varying from −173.7 to −175.1‰.

Atmospheric process factors affecting the stable isotope variations in precipitation in Guiyang, Southwest China

Atmospheric process factors affecting the stable isotope variations in precipitation in Guiyang, Southwest China

Assessing spatial impacts of historical pulp mill effluent on trophic dynamics in a coastal marine ecosystem using stable isotope (δ13C and δ15N) analysis

Boat Harbour, Nova Scotia was a tidal estuary that was converted into a wastewater treatment facility for pulp mill effluent in 1967. Treated effluent from Boat Harbour was discharged into the coastal Northumberland Strait, contributing significant nutrient and freshwater inputs into the coastal environment, potentially impacting local biogeochemistry and ecosystem structure. This study used stable isotope analysis of carbon (δ13C) and nitrogen (δ15N) of representative taxa to assess spatial variability in nutrient sources and trophic dynamics. Results identified stable isotope variation with depleted δ13C and δ15N values in taxa near Boat Harbour. Blue mussel (Mytilus edulis) and mummichog (Fundulus heteroclitus) were the most suitable bioindicators for identifying variation in nutrient sources. Stable isotope signatures in this study may be reflective of residual pulp mill effluent-derived nutrients, differences in marine versus terrestrial nutrient sources, and a pronounced coastal salinity gradient. The present study defined the baseline nutrient conditions of the Northumberland Strait and will be useful in assessing the effectiveness of remediation activities.

Changes in geochemical and isotopic contents in groundwater before seismic events in Ischia Island (Italy)

We analysed the hydrogeochemical and isotopic contents in groundwater for the period 2002–2020, in the Ischia Island, a volcanic island in Southern Italy, and compared them with seismic events that occurred in the same period. The study is based on a large hydrochemical database, which includes chemical (major and minor compounds, metals and trace elements) and isotopic analyses (δ18O and δ2H). For each of the 34 seismic events occurred in the studied period, we considered coordinates, date, time, depth and magnitude. To exclude the influence of meteorological variability on the hydrochemistry, we examined rainfall time series measured in four stations located in the island. Results show hydrogeochemical anomalies for some chemical elements observed months before the seismic events. Arsenic, electrical conductivity, chromium and vanadium have been identified as potentially affected by hydrogeochemical anomalies related to the earthquakes. The variations in stable isotopes (δ2H and δ18O) in groundwater also seem associated with the earthquakes.This study aims to contribute to the individuation of components in groundwater prone to register sudden changes related to seismic events and it highlights the need of a continuous and long-term hydrogeochemical monitoring in seismic areas. Indeed, the conclusions of this study must be further confirmed by a future continuous monitoring of major compounds, trace elements and isotopes in groundwater to evaluate the effective temporal coincidence/lag with the seismic events.