Helmholtz decomposition of velocity perturbations is performed in conjunction with linear stability analysis to examine the effects of flow-thermodynamics interactions on the stability of high-speed boundary layers. A corresponding decomposition of the pressure field is also proposed. The contributions of perturbation solenoidal kinetic, dilatational kinetic and internal energy to the various instability modes are examined as a function of Mach number ( $M$ ). As expected, dilatational and pressure field effects play an insignificant part in the first-mode behaviour at all Mach numbers. The second (Mack) mode, however, is dominantly dilatational in nature, and perturbation internal energy is significant compared to perturbation kinetic energy. The observed behaviour is explicated by examining the key processes of production and pressure-dilatation. Production of the second-mode dilatational kinetic energy is mostly due to the solenoidal-dilatational covariance stress tensor interacting with the mean (background) velocity gradient. This cross production component also inhibits the first mode. The dilatational pressure facilitates energy transfer from the kinetic to the internal field in the near‐wall region, whereas the energy transfer away from the wall is mostly due to the solenoidal pressure work. The dilatational characters of the fast and slow modes are also examined. The fast mode is dominantly dilatational at both $M=4$ and $M=6$ , while the nature of the slow mode is dependent on $M$ . Finally, Helmholtz decomposition of the perturbation momentum vector is performed. Interestingly, both first and second modes are dominated by solenoidal components of momentum.
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