Let $${\mathcal {L}}=\sum _{j=1}^{m}X_{j}^{2}$$ be a Hörmander sum of squares of vector fields in $${\mathbb {R}}^{n}$$ , where any $$X_{j}$$ is homogeneous of degree 1 with respect to a family of non-isotropic dilations in $${\mathbb {R}}^{n}$$ . Then, $${\mathcal {L}}$$ is known to admit a global fundamental solution $$\Gamma (x;y)$$ that can be represented as the integral of a fundamental solution of a sublaplacian operator on a lifting space $${\mathbb {R}}^{n}\times {\mathbb {R}}^{p}$$ , equipped with a Carnot group structure. The aim of this paper is to prove global pointwise (upper and lower) estimates of $$\Gamma$$ , in terms of the Carnot–Carathéodory distance induced by $$X=\{X_{1},\ldots ,X_{m}\}$$ on $${\mathbb {R}}^{n}$$ , as well as global pointwise (upper) estimates for the X-derivatives of any order of $$\Gamma$$ , together with suitable integral representations of these derivatives. The least dimensional case $$n=2$$ presents several peculiarities which are also investigated. Applications to the potential theory for $${\mathcal {L}}$$ and to singular-integral estimates for the kernel $$X_{i}X_{j}\Gamma$$ are also provided. Finally, most of the results about $$\Gamma$$ are extended to the case of Hörmander operators with drift $$\sum _{j=1}^{m}X_{j}^{2}+X_{0}$$ , where $$X_{0}$$ is 2-homogeneous and $$X_{1},\ldots ,X_{m}$$ are 1-homogeneous.
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