Formation Of Spin Domains Research Articles

Synthesis and Properties of La14TME6CuS24O4, Exhibiting Multivalent Spin Chains (TME = Cr, Fe).

Two homologues in a series of quinary oxysulfides, La14TME6CuS24O4 (TME = Cr or Fe), have been synthesized by solid-state synthesis in sealed ampules, and their structures are homologue to assume a novel crystal structure. X-ray diffraction analyses of single crystal and powder samples give a monoclinic lattice, described in the C2/m (No. 12) space group, with lattice parameters a = 15.3853(5) Å, b = 13.9729(5) Å, c = 10.5074(4) Å, and β = 116.227(3)° for the Cr analogue and a = 15.4303(2) Å, b = 14.0033(2) Å, c = 10.4909(2) Å, and β = 116.261(2)° for Fe. The crystal structure contains one-dimensional (1D) chains consisting of interconnected transition metal element (TME) trimers, which are further arranged into two-dimensional (2D) layers. These spin-chain planes are interspaced with 1D chains of lanthanum-oxygen coordinations and an apparent disordered occupation of copper sites. Alternating current (AC) and direct current (DC) magnetic susceptibility measurements show that the Cr and Fe analogues exhibit what is best described as spin-domain formation. Density functional theory (DFT) calculations suggest the formal oxidation state of the species is best represented in the form La14TME52+TME3+Cu+S24O4.

Anomalous Pressure Response of Temperature-Induced Spin Transition and a Pressure-Induced Spin Transition in Two-Dimensional Hofmann Coordination Polymers.

Spin transition (ST) compounds have been extensively studied because of the changes in rich physicochemical properties accompanying the ST process. The study of ST mainly focuses on the temperature-induced spin transition (TIST). To further understand the ST, we explore the pressure response behavior of TIST and pressure-induced spin transition (PIST) of the 2D Hofmann-type ST compounds [Fe(Isoq)2M(CN)4] (Isoq-M) (M = Pt, Pd, Isoq = isoquinoline). The TISTs of both Isoq-Pt and Isoq-Pd compounds exhibit anomalous pressure response, where the transition temperature (T1/2) exhibits a nonlinear pressure dependence and the hysteresis width (ΔT1/2) exhibits a nonmonotonic behavior with pressure, by the synergistic influence of the intermolecular interaction and the distortion of the octahedral coordination environment. And the distortion of the octahedra under critical pressures may be the common behavior of 2D Hofmann-type ST compounds. Moreover, ΔT1/2 is increased compared with that before compression because of the partial irreversibility of structural distortion after decompression. At room temperature, both compounds exhibit completely reversible PIST. Because of the greater change in mechanical properties before and after ST, Isoq-Pt exhibits a more abrupt ST than Isoq-Pd. In addition, it is found that the hydrostatic properties of the pressure transfer medium (PTM) significantly affect the PIST due to their influence on spin-domain formation.

Local symmetry breaking drives picosecond spin domain formation in polycrystalline halide perovskite films.

Photoinduced spin-charge interconversion in semiconductors with spin-orbit coupling could provide a route to optically addressable spintronics without the use of external magnetic fields. However, in structurally disordered polycrystalline semiconductors, which are being widely explored for device applications, the presence and role of spin-associated charge currents remains unclear. Here, using femtosecond circular-polarization-resolved pump-probe microscopy on polycrystalline halide perovskite thin films, we observe the photoinduced ultrafast formation of spin domains on the micrometre scale formed through lateral spin currents. Micrometre-scale variations in the intensity of optical second-harmonic generation and vertical piezoresponse suggest that the spin-domain formation is driven by the presence of strong local inversion symmetry breaking via structural disorder. We propose that this leads to spatially varying Rashba-like spin textures that drive spin-momentum-locked currents, leading to local spin accumulation. Ultrafast spin-domain formation in polycrystalline halide perovskite films provides an optically addressable platform for nanoscale spin-device physics.

Plasma-Assisted Chemical Vapor Deposition of F-Doped MnO2 Nanostructures on Single Crystal Substrates.

MnO2 nanostructures were fabricated by plasma assisted-chemical vapor deposition (PA-CVD) using a fluorinated diketonate diamine manganese complex, acting as single-source precursor for both Mn and F. The syntheses were performed from Ar/O2 plasmas on MgAl2O4(100), YAlO3(010), and Y3Al5O12(100) single crystals at a growth temperature of 300 °C, in order to investigate the substrate influence on material chemico-physical properties. A detailed characterization through complementary analytical techniques highlighted the formation of highly pure and oriented F-doped systems, comprising the sole β-MnO2 polymorph and exhibiting an inherent oxygen deficiency. Optical absorption spectroscopy revealed the presence of an appreciable Vis-light harvesting, of interest in view of possible photocatalytic applications in pollutant degradation and hydrogen production. The used substrates directly affected the system structural features, as well as the resulting magnetic characteristics. In particular, magnetic force microscopy (MFM) measurements, sensitive to the out-of-plane magnetization component, highlighted the formation of spin domains and long-range magnetic ordering in the developed materials, with features dependent on the system morphology. These results open the door to future engineering of the present nanostructures as possible magnetic media for integration in data storage devices.

Structure and properties of Mn3O4 thin films grown on single crystal substrates by chemical vapor deposition

Mn3O4 thin films were fabricated on SrTiO3(111) and Y3Al5O12(100) substrates by chemical vapor deposition (CVD) under O2 atmospheres, starting from a fluorinated Mn(II) diketonate-diamine adduct. The obtained systems were investigated by a multi-technique characterization in order to elucidate the interplay between preparation conditions and their chemico-physical properties. The results highlighted the formation of phase-pure and homogeneous α-Mn3O4 (haussmannite) films, characterized by a smooth morphology, an appreciable Vis light absorption and structural features directly dependent on the used substrate. The target systems were uniformly doped with fluorine, due to the used Mn compound acting as a single-source precursor for both Mn and F. In addition, magnetic force microscopy measurements revealed the formation of spin domains and long-range magnetic order in the target materials, paving the way to their future implementation as magnetic media toward device integration for data storage.

Insights into the Plasma-Assisted Fabrication and Nanoscopic Investigation of Tailored MnO2 Nanomaterials.

Among transition metal oxides, MnO2 is of considerable importance for various technological end-uses, from heterogeneous catalysis to gas sensing, owing to its structural flexibility and unique properties at the nanoscale. In this work, we demonstrate the successful fabrication of supported MnO2 nanomaterials by a catalyst-free, plasma-assisted process starting from a fluorinated manganese(II) molecular source in Ar/O2 plasmas. A thorough multitechnique characterization aimed at the systematic investigation of material structure, chemical composition, and morphology revealed the formation of F-doped, oxygen-deficient, MnO2-based nanomaterials, with a fluorine content tunable as a function of growth temperature ( TG). Whereas phase-pure β-MnO2 was obtained for 100 °C ≤ TG ≤ 300 °C, the formation of mixed phase MnO2 + Mn2O3 nanosystems took place at 400 °C. In addition, the system nano-organization could be finely tailored, resulting in a controllable evolution from wheat-ear columnar arrays to high aspect ratio pointed-tip nanorod assemblies. Concomitantly, magnetic force microscopy analyses suggested the formation of spin domains with features dependent on material morphology. Preliminary tests in Vis-light activated photocatalytic degradation of rhodamine B aqueous solutions pave the way to possible applications of the target materials in wastewater purification.

Large-scale Ising spin network based on degenerate optical parametric oscillators

Simulating a network of Ising spins with physical systems is now emerging as a promising approach for solving mathematically intractable problems. Here we report a large-scale network of artificial spins based on degenerate optical parametric oscillators (DOPO), paving the way towards a photonic Ising machine capable of solving difficult combinatorial optimization problems. We generated >10,000 time-division-multiplexed DOPOs using dual-pump four-wave mixing (FWM) in a highly nonlinear fibre (HNLF) placed in a fibre cavity. Using those DOPOs, a one-dimensional (1D) Ising model was simulated by introducing nearest-neighbour optical coupling. We observed the formation of spin domains and found that the domain size diverged near the DOPO threshold, which suggests that the DOPO network can simulate the behavior of low-temperature Ising spins.

Quenched binary Bose-Einstein condensates: Spin-domain formation and coarsening

We explore the time evolution of quasi-1D two component Bose-Einstein condensates (BEC's) following a quench from one component BEC's with a ${\rm U}(1)$ order parameter into two component condensates with a ${\rm U}(1)\shorttimes{\rm Z}_2$ order parameter. In our case, these two spin components have a propensity to phase separate, i.e., they are immiscible. Remarkably, these spin degrees of freedom can equivalently be described as a single component attractive BEC. A spatially uniform mixture of these spins is dynamically unstable, rapidly amplifing any quantum or pre-existing classical spin fluctuations. This coherent growth process drives the formation of numerous spin polarized domains, which are far from the system's ground state. At much longer times these domains grow in size, coarsening, as the system approaches equilibrium. The experimentally observed time evolution is fully consistent with our stochastic-projected Gross-Pitaevskii calculation.

Skyrmion formation and optical spin-Hall effect in an expanding coherent cloud of indirect excitons.

We provide a theoretical description of the polarization pattern and phase singularities experimentally evidenced recently in a condensate of indirect excitons [H. High et al., Nature 483, 584 (2012)]. We show that the averaging of the electron and hole orbital motion leads to a comparable spin-orbit interaction for both types of carriers. We demonstrate that the interplay between a radial coherent flux of bright indirect excitons and the Dresselhaus spin-orbit interaction results in the formation of spin domains and of topological defects similar to Skyrmions. We reproduce qualitatively all the features of the experimental data and obtain a polarization pattern as in the optical spin-Hall effect despite the different symmetry of the spin-orbit interactions.

Magnetic domains in spinor Bose-Einstein condensates

We discuss the structure of spin-1 Bose-Einstein condensates in the presence of a homogenous magnetic field. We demonstrate that phase separation can occur in the ground state of antiferromagnetic (polar) condensates, while the spin components of ferromagnetic condensates are always miscible, so that no phase separation occurs in them. Our analysis predicts that this phenomenon takes place when the energy of the lowest homogenous state is a concave function of the magnetization. We propose a method for creating spin domains by adiabatic switching-on of a magnetic field. We also discuss the phenomena of dynamical instability and spin domain formation.

Spin dynamics and domain formation of a spinor Bose-Einstein condensate in an optical cavity

We consider a ferromagnetic spin-1 Bose-Einstein condensate (BEC) dispersively coupled to a unidirectional ring cavity. We show that the ability of the cavity to modify, in a highly nonlinear fashion, matter-wave phase shifts adds an additional dimension to the study of spinor condensates. In addition to demonstrating strong matter-wave bistability as in our earlier publication [L. Zhou et al., Phys. Rev. Lett. 103, 160403 (2009)], we show that the interplay between atomic and cavity fields can greatly enrich both the physics of critical slowing down in spin-mixing dynamics and the physics of spin-domain formation in spinor condensates.

Localization of spin mixing dynamics in a spin-1 Bose-Einstein condensate

We propose to localize spin mixing dynamics in a spin-1 Bose-Einstein condensate by a temporal modulation of spin exchange interaction, which is tunable with optical Feshbach resonance. Adopting techniques from coherent control, we demonstrate the localization and freezing of spin mixing dynamics, and the suppression of the intrinsic dynamic instability and spontaneous spin domain formation in a ferromagnetically interacting condensate of $^{87}\mathrm{Rb}$ atoms. This work points to a promising scheme for investigating the weak magnetic spin dipole interaction, which is usually masked by the more dominant spin exchange interaction.

Excited spin states and phase separation in spinor Bose-Einstein condensates

We analyze the structure of spin-one Bose-Einstein condensates in the presence of a homogeneous magnetic field. We classify the homogeneous stationary states and study their existence, bifurcations, and energy spectra. We reveal that phase separation can occur in the ground state of antiferromagnetic (polar) condensates while the spin components of the ferromagnetic condensates are always miscible and no phase separation occurs. Our theoretical model, confirmed by numerical simulations, explains that this phenomenon takes place when the energy of the lowest homogeneous state is a concave function of the magnetization. In particular, we predict that phase separation can be observed in a $^{23}\text{N}\text{a}$ condensate confined in a highly elongated harmonic trap. Finally, we discuss the phenomena of dynamical instability and spin domain formation.

MAGNETO-OPTICAL ABSORPTION AND PHOTOMAGNETISM IN EUROPIUM CHALCOGENIDES

The absorption threshold in EuTe and EuSe was investigated as a function of applied magnetic field in the Faraday geometry. A well-resolved doublet of sharp dichroic lines was observed when the magnetic field induced ferromagnetic alignment of the spins in the crystal lattice. In contrast, at zero magnetic field only a broad and featureless absorption onset is seen. These results are fully explained in terms of a model of electronic transitions between localized states at the Eu lattice site and a tight-binding conduction band, which incorporates the formation of spin domains. Based on this model, predictions are made concerning the possibility of inducing magnetization of the spin lattices by illuminating the material with circularly polarized light.

Spin-domain formation in antiferromagnetic condensates

Antiferromagnetic condensates are generally believed not to display modulational instability and subsequent spin-domain formation. Here we demonstrate that in the presence of a homogeneous magnetic field antiferromagnetic spin-1 Bose-Einstein condensates can undergo spatial modulational instability followed by the subsequent generation of spin domains. Employing numerical simulations for realistic conditions, we show how this effect can be observed in sodium condensates confined in an optical trap. Finally, we link this instability and spin-domain formation with stationary modes of the condensate.

Normal-superfluid interaction dynamics in a spinor bose gas.

Coherent behavior of spinor Bose-Einstein condensates is studied in the presence of a significant uncondensed (normal) component. Normal-superfluid exchange scattering leads to near-perfect local alignment between the spin fields of the two components. We observe that, through this spin locking, spin-domain formation in the condensate is vastly accelerated as the spin populations in the condensate are entrained by large-amplitude spin waves in the normal component.

Spin domains in ground-state Bose–Einstein condensates

Bose-Einstein condensates of dilute atomic gases, characterized by a macroscopic population of the quantum mechanical ground state, are a new, weakly interacting quantum fluid. In most experiments condensates in a single weak field seeking state are magnetically trapped. These condensates can be described by a scalar order parameter similar to the spinless superfluid 4He. Even though alkali atoms have angular momentum, the spin orientation is not a degree of freedom because spin flips lead to untrapped states and are therefore a loss process. In contrast, the recently realized optical trap for sodium condensates confines atoms independently of their spin orientation. This opens the possibility to study spinor condensates which represent a system with a vector order parameter instead of a scalar. Here we report a study of the equilibrium state of spinor condensates in an optical trap. The freedom of spin orientation leads to the formation of spin domains in an external magnetic field. The structure of these domains are illustrated in spin domain diagrams. Combinations of both miscible and immiscible spin components were realized.

Spin relaxation of Mn ions in (CdMn)Te/(CdMg)Te quantum wells under picosecond optical pumping

Spin relaxation of Mn ions in a Cd0.97Mn0.03Te/Cd0.75Mg0.25Te quantum well with photogenerated quasi-two-dimensional electron-hole plasma at liquid helium temperatures in an external magnetic field has been investigated. Heating of Mn ions by photogenerated carriers due to spin and energy exchange between the hot electron-hole plasma and Mn ions through direct sd-interaction between electron and Mn spins has been detected. This process has a short characteristic time of about 4 ns, which leads to appreciable heating of the Mn spin subsystem in about 0.5 ns. Even under uniform excitation of a dense electron-hole plasma, the Mn heating is spatially nonuniform, and leads to formation of spin domains in the quantum well magnetic subsystem. The relaxation time of spin domains after pulsed excitation is measured to be about 70 ns. Energy relaxation of excitons in the random exchange potential due to spin domains results from exciton diffusion in magnetic field B=14 T with a characteristic time of 1 to 4 ns. The relaxation time decreases with decreasing optical pump power, which indicates smaller dimensions of spin domains. In weak magnetic fields (B=2 T) a slow down in the exciton diffusion to 15 ns has been detected. This slow down is due to exciton binding to neutral donors (formation of bound excitons) and smaller spin domain amplitudes in low magnetic fields. The optically determined spin-lattice relaxation time of Mn ions in a magnetic field of 14 T is 270±10 and 16±7 ns for Mn concentrations of 3% and 12%, respectively.