A new systematic theory of describing the collective excitations in spherical odd-mass nuclei is developed. The theory can be regarded as a direct extension of the conventional quasi-particle-new-Tamm-Dancoff method (i.e. the quasi-particle-random phase approximation) for spherical even-mass nuclei into the case of spherical odd-mass nuclei. order to con struct properly the theory within the framework of the quasi-particle-new-Tamm-Dancoff method, it is shown to be decisive to introduce a new concept which precisely specifies the dressed three-quasi-particle modes. The new concept is recognized in connection with the space which has been introduced through the quasi-spin formalism for the pairing correlations. It is not the purpose of this paper, part I, to go into a clear-cut formulation of the theory and into detailed quantitative calculations, but rather to put an emphasis on the explanation of basic ideas. § I. Introduction Recent accumulation of the experimental data illuminating the structure of low-lying collective excited states in spherical odd-mass nuclei has stimulated the investigation of problems on particle-vibration coupling. An important effect of particle-vibration which has been neglected for a long time, has been emphasized by Bohr and Mottelson 1 ) in the Tokyo Conference in 1967: In the phenomenological coupling model, the lowest-order-perturbation effects which contribute to energies of the excited states composed of the odd quasi-particle and the one-phonon, are shown in Figs. lA and lB. The diagrams of type lA are nothing but the conventional ones which have so far been treated as phonon-quasi-particle coupling, while the diagrams of type lB have usually been neglected so far. The physical effect underlying the diagrams lB is that the phonon disassociates into a pair of quasi particle, one of which reassociates with the odd-quasi-particle while the remain ing quasi-particle is now the odd-quasi-particle. Thus this effect is essentially based on the Pauli principle between the quasi-particles composing the phonon and the extra quasi-particle outside the core. The extreme importance of the diagrams of type lB can be recognized as follows. The diagrams of type lA consist of the coupling with the factor (u!'u 2 - v 1v 2) which can be quite small,
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