This study investigates particle dynamics impacting a charged spherical collector through experiments and simulations, revealing the influence of the collector’s non-uniform potential field. Electrostatic and drag forces govern trajectories, while gravity and dielectrophoretic forces play a minor role. Positive electrostatic and negative drag work are comparable, offering critical insights into particle energy budgets. Closer proximity to the collector center leads to a greater energy budget, causing uneven particle collection. Analysis of fractional energy loss indicates a critical point where electrostatic work dominates over viscous dissipation. This analysis is crucial for analyzing particle deposition behavior in non-uniform electric fields.