A new benchmark solution has been developed to aid in the development of neutron kinetics solvers for hexagonal geometries, such as those in water-water energetic reactors. This benchmark problem is based on the two-dimensional, two-group, International Atomic Energy Agency–Hex steady-state benchmark problem. Two transient problems are presented: a ramp and a step transient. To create a benchmark-quality solution to this transient problem, a basic neutron kinetics model was added to the computer program LUPINE (Liquid metal–cooled fast reactor Utility for Physics Informed Nuclear Engineering). LUPINE solves neutron kinetics equations in general unstructured mesh. First, the LUPINE kinetics solvers are verified using the TWIGL benchmark problems. Then the methods in LUPINE are used to perform a spatiotemporal convergence analysis to ensure that the solutions are sufficiently converged. Finally, Richardson extrapolation is performed to obtain the reference solutions for these new kinetics benchmark problems.