Space Charge Distribution Research Articles

Revealing the flashover mechanism of EP/GF composite insulation under DC combined harmonic voltage

Abstract In ultra-high voltage converter stations, the phenomenon of flashover along the outer insulation of dry hollow reactors made of epoxy/glass fiber composites poses a potential threat to the stability of the power system. To enhance its flashover performance under varying complex conditions, it is necessary to conduct in-depth research on the flashover mechanism of this material under different voltage forms. This study conducted tests on the flashover voltage, surface space charge distribution, and partial discharge parameters under varying AC-DC ratios and AC frequencies, and exploring their relationships. The results show that the DC content in the AC-DC ratio decreases, the flashover voltage decreases, the apparent total discharge of partial discharges increases, and the maximum surface space charge density decreases. The main influencing factor is the increase in the number of seed charges involved in gas ionization. Increasing the AC frequency, the flashover voltage decreases, the apparent total discharge increases significantly, and the surface charge density remains basically unchanged. The main reason is that the change in the number of alternating cycles further increases the number of seed charges. This study reveals the flashover mechanism of epoxy/glass fiber composites under different voltage forms, which provides theoretical support for subsequent material modification.

OPTIMIZING THE INFLUENCE OF DOPING AND TEMPERATURE ON THE ELECTROPHYSICAL FEATURES OF P-N AND P-I-N JUNCTION STRUCTURES

In this paper, we investigate the effects of doping and temperature (at 300 K and 400 K) on the characteristics of Silicon (Si) and Gallium Arsenide (GaAs) p-n and p-i-n homojunction structures, utilizing doping concentrations of p+= n+=2∙1017 and p=n=1016 cm-3 through numerical calculation and modeling. Furthermore, we have analyzed three different cases: A) p-n, B) p+-n, and C) p-n+, to examine their influence on the distributions of space charge, potential, electric field, minority charge carriers, and the I-U curve at 300 K. It can be seen from the results that in case A, the recombination process is not observed at a lower voltage in the symmetrical p-n junction compared to than case B and C asymmetrical p-n junction. The voltage-temperature characteristics of the prepared samples were then measured at a temperature of 300K. I-U curve at 300 K. Calibration of the Si p-n homojunction structures is performed using experimental data to validate the proposed model. With the help of this constructed complex model, the influence of various geometrical changes, such as the radial p-n transition, on electrophysical properties will be examined in our next work.

Space charge effects in mixed ionic-electronic conducting electrodes for solid-state batteries.

Mixed ionic-electronic conductors are widely used as electroactive materials in energy applications. The contact of a mixed conductor with another phase plays a crucial role in charge storage and transport in energy devices. However, the interfacial chemistry at the heterojunctions comprising mixed conductors and its interplay with the bulk chemistry remains imperative yet inadequately understood. This study addresses the fundamentals of space charge effects by exploring the equilibrium situations for contacts consisting of mixed conductors. From the perspective of defect chemistry, and by unifying the bulk and interfacial conditions with the electrochemical potential, our treatment allows for predicting the built-in potential at heterojunctions, profiling the space charge distributions, and evaluating the resulting interfacial charge storage and transport. The treatment can be related to experimental characterization, including coulometric titration, conductivity, and capacitance measurements at electrochemical interfaces in all-solid-state batteries. Besides, our treatment also highlights the significance of size and doping effects in nanocrystalline electrodes. This work provides a comprehensive framework for understanding and engineering the heterojunctions in electrochemical devices.

Outstanding Superoxide Dismutase Catalytic Activity Of Simple Peptide‐Based Nickel(II) Complexes

AbstractWe present here the most active synthetic Ni superoxide dismutase (NiSOD) mimic reported to date. Reactive oxygen species are aggressive compounds, which concentrations are tightly regulated in vivo. Among them, the superoxide anion, O2⋅−, is controlled by superoxide dismutases. Capitalizing on the versatility of the Amino‐Terminal CuII‐ and NiII‐binding (ATCUN) peptide motif, we introduced positive charges around the NiII center to favor the interaction with the superoxide radical anion. At physiological pH, the pentapeptide H−Cys−His−Cys−Arg−Arg−NH2 coordinates NiII after the deprotonation of one thiol, two amides, and either the second thiol or the N‐terminal ammonium, leading to an equilibrium between the two N3S1 and N2S2 coordination modes. Under catalytic conditions, a kcat value of 8.6(4)×106 L.mol−1.s−1 was measured. Within the first second, the catalyst remained undegraded with quantitative consumption of O2⋅− (completed up to 37 catalytic cycles). An extra arginine (Arg) was introduced at the peptide C‐terminus to increase the global charge of the NiII complex from +1 to +2. This had no effect on the catalytic performance, highlighting the critical role of charge distribution in space as a determining factor influencing the reactivity.

Machine learning assisted mechanism modeling for gas phase electrohydrodynamic system

In this paper, a hybrid physics-data driven model for electrohydrodynamic gas system (EHDGS) was developed by combining artificial neural network (ANN) with mechanism modeling method. ANN was used to correlate the relationship between the variables (electrode distance, diameter of grounding cylinder, applied voltage, electric field gradient, etc.) in a needle-cylinder EHDGS and the initial space charge density. The results showed that the ANN model of nine neurons can well predict the initial space charge density. The coefficient of determination (R2) reaches 0.9874, and the mean absolute error is as low as 0.0067. Subsequently, a hybrid mechanism model where the initial space charge density was predicted from the ANN model was constructed to simulate the needle-cylinder EHDGS. The experiment with the needle-cylinder EHDGS was carried out. The simulation results were in good agreement with the experimental data, demonstrating the reliability of the proposed hybrid model. The electric field distribution, space charge distribution, and flow field distribution behavior of the EHDGS were then analyzed in detail. The effects of key parameters on the flow characteristics of EHDGS were systematically studied, showing that higher voltage and shorter distance give higher flow rate up to 2.5 m/s. The diameter of the cylinder also significantly influences the breakdown voltage. Three dimensionless groups were defined and their effects on spatial charge density distribution were investigated. This study provides both insights and an efficient tool for the design and optimization of EHDGS.

Investigation of Partial Discharge Transformation Characteristics in Polyimide (PI) Insulations under High-Frequency Electric Stress.

This research delves into the primary issue of polyimide (PI) insulation failures in high-frequency power transformers (HFPTs) by scrutinizing partial discharge development under high-frequency electrical stress. This study employs an experimental approach coupled with a plasma simulation model for a ball-sphere electrode structure. The simulation model integrates the particle transport equation, Poisson equation, and complex chemical reactions to ascertain microscopic parameters, including plasma distribution, electric field, electron density, electron temperature, surface, and space charge distribution. The effect of the voltage polarity and electrical energy on the PD process is also discussed. The contact point plays a pivotal role in triggering partial discharges and culminating in the breakdown of PI insulation. Asymmetry phenomena were found between positive and negative half-cycles by analyzing the PD data stage by stage. A significant number of PDs increased at every stage and the PD amplitude was higher during the negative cycle at the initial stage, but in later stages, the PD amplitude was found to be higher in the positive half-cycle, and scanning electron microscopy (SEM) revealed that the maximum damage occurred near the contact point junction. The simulation results show that the plasma initially accumulates the electron density near the contact point junction. Under the action of the electric field, plasma starts traveling at the PI surface outward from the contact point. Before the PD activity, all parameters have higher values in the plasma head. The microscopic parameters reveal maximum values near the contact point junction, during PD activities where significant damage takes place. These parameter distributions exhibit a decreasing trend over time as when the PD activity ends. The model's predictions are consistent with the experimental data. The paper lays the foundation for future research in polymer insulation design under high-frequency electrical stress.

Outstanding Superoxide Dismutase Catalytic Activity Of Simple Peptide-Based Nickel(II) Complexes.

We present here the most active synthetic Ni superoxide dismutase (NiSOD) mimic reported to date. Reactive oxygen species are aggressive compounds, which concentrations are tightly regulated in vivo. Among them, the superoxide anion, O2⋅-, is controlled by superoxide dismutases. Capitalizing on the versatility of the Amino-Terminal CuII- and NiII-binding (ATCUN) peptide motif, we introduced positive charges around the NiII center to favor the interaction with the superoxide radical anion. At physiological pH, the pentapeptide H-Cys-His-Cys-Arg-Arg-NH2 coordinates NiII after the deprotonation of one thiol, two amides, and either the second thiol or the N-terminal ammonium, leading to an equilibrium between the two N3S1 and N2S2 coordination modes. Under catalytic conditions, a kcat value of 8.6(4)×106 L.mol-1.s-1 was measured. Within the first second, the catalyst remained undegraded with quantitative consumption of O2⋅- (completed up to 37 catalytic cycles). An extra arginine (Arg) was introduced at the peptide C-terminus to increase the global charge of the NiII complex from +1 to +2. This had no effect on the catalytic performance, highlighting the critical role of charge distribution in space as a determining factor influencing the reactivity.

Interface charge accumulation in bi-layer dielectrics between cable and accessory insulation under temperature gradient

Bi-layer dielectrics are a feature of high-voltage direct-current cable and accessory systems, giving rise to the interfaces between the cable and accessory insulation. The interfaces act as preference sites for space charge build-up and are therefore regarded as potential breakdown initiation sites. A further complication is that during the operation of cable, a temperature gradient (TG) will be produced across the bi-layer insulation. In this paper, carbon black (CB) nanoparticles with 0, 0.5, 1, 1.5, 3.5 and 5.5 wt% are doped into silicon rubber (SR), space charge distributions in bi-layer dielectrics composed of cross-linked polyethylene (XLPE) and CB/SR nanocomposites under DC voltage and TG are measured using the pulsed electroacoustic method, and the effects of the doping proportion of CB nanoparticles and the TG on the bi-layer interface charge behavior are investigated. The experimental results show that under the TG, CB nanoparticles doped into SR can effectively suppress the interface charge accumulation, the amount of the interface charge decreases with the increase of the doping proportion from 0 to 1.5 wt% but increases with the increase of the doping proportion from 1.5 to 5.5 wt%, and the CB nanoparticle with 1.5 wt% shows relatively better suppression effect on the interface charge accumulation. With the increase of the TG, the amount of the interface charge increases initially and then decreases.

Detection of defect-induced luminescence in epoxy-based insulation materials via phase-resolved photon counting method

Electroluminescence (EL) has shown promise in detecting micro-defects in epoxy-based insulation materials. Understanding the various luminescence mechanisms caused by defects is crucial for improving the characterization and analysis of insulation defects. In light of this, this study proposes a photon counting-based approach to investigate the impact of defects on the entire evolutionary process of the luminescence mechanism. A phase-resolved photon counting (PRPC) method is proposed to examine the polarity and periodicity of photon counting results influenced by defects. Additionally, a simulation model based on the finite element method is established to analyze how defects modify the distribution of electric field and space charges. Observations suggest that the PRPC-based approach holds promise for advancing the defect analysis of epoxy insulation used in gas-insulated equipment.

Selection of antioxidants for capacitor grade polypropylene film: Insights into electrical performance of the oil-film system.

High voltage power capacitors employ the oil-impregnated polypropylene film as the insulation. The swelling phenomenon might drive the antioxidants and small molecules within the film to migrate into the oil. It is necessary to comprehensively investigate the physical migration mechanism of antioxidants and their impact on the electrical performance of the oil-film combination insulation system and, consequently, formulate the proper selective prescription of antioxidants. Theoretical elucidation of the competitive interaction mechanism between the film and the oil in attracting antioxidant molecules was achieved through the calculation of inter-molecular binding energy, and the migration coefficient ηm was introduced to quantify the migration characteristics of antioxidants. Experimentally, the effects of antioxidants on the space charge distribution of the film, the dielectric properties of the oil, and the breakdown characteristics of both the film and oil were investigated. The experimental conclusions are consistent with theoretical analysis. The lamellar structure antioxidant molecules with ηm > 1 tend to migrate from the film to the oil, which results in increased dielectric loss and decreased breakdown strength of the insulating oil. In addition, the presence of phosphorus atoms in phosphite antioxidants contributes to a reduction in the breakdown strength of the film. For capacitor grade polypropylene film, in addition to the synergistic effect between different types of antioxidants on the thermo-oxidative stability, the structure of the antioxidant molecules and its influence on the electrical performance of the oil-film systems should also be taken into account.

Hindered phenolic antioxidant grafting on tailoring the DC electrical characteristics of polypropylene cable insulation

AbstractThe authors focus on the impact of melt‐free radical grafting with hindered phenolic antioxidants (AO3052) on the electrical properties of polypropylene (PP) for DC cable insulation. The DC conductivity, space charge distribution and breakdown characteristic tests of grafting‐modified PP are performed by comparing unmodified PP. The results demonstrate that the grafting of antioxidants can effectively suppress space charge injection, owing to the deeper trap sites at the grafting molecule. The breakdown strength of the grafted PP is significantly enhanced from 30°C to 90°C and especially achieves a 5.3%–6.7% increase after the same DC‐prestressed time at 90°C. The surface electrostatic potential and molecular orbitals of the grafted PP are calculated. Simulation shows that the antioxidant introduces multi‐level local state traps that can effectively trap the injected space charge, thus decreasing the destruction of molecular chains by electrons and increasing the breakdown strength level. In conclusion, antioxidant grafting modification can improve the breakdown characteristics with or without DC prestress, and thus it appears to be promising in the application of PP‐insulated cables.

Influence of the Experimental Setup on Electromagnetic Pulses in the VHF Band at Relativistic High-Power Laser Facilities

We present experimental results for the controlled mitigation of the electromagnetic pulses (EMPs) produced in the interactions of a 1 PW high-power 30 fs Ti:Sa laser VEGA-3 with solid-density targets transparent to laser-forward-accelerated relativistic electrons. This study aims at the band of very high frequencies (VHFs), i.e., those in the hundreds of MHz, which comprise the fundamental cavity modes of the rectangular VEGA-3 vacuum chamber. We demonstrate mode suppression by a tailoring of the laser-produced space charge distribution.

Electronic properties of polyethylene naphthalate as derived from photo-stimulated discharge, luminescence experiments and quantum chemical calculation

The electronic properties of thin films of poly(ethylene 2,6-naphthalate)—PEN, are investigated based on their photo-physical (optical absorption, photoluminescence) and electrical (space charge distribution, photo-stimulated discharge) behavior. Photo-stimulated currents are associated with optical absorption of the material leading to space charge dissipation as demonstrated by space charge distribution measurement. Based on this set of experimental results and quantum chemical calculation performed on PEN macromolecular system, we propose a new scheme for the electronic levels of PEN. This scheme allows understanding the mechanisms at play in photo-stimulated discharge. One of the main conclusions of our work is that photo-stimulated current measurements do not probe the energy level of traps. Detrapping of charges results from a two-step process where the photon energy is absorbed by chromophores that restitute a part of this energy to trapped charges through various mechanisms. Moreover, the new scheme allows discussing the components of the luminescence excited under different stresses, being electric field, electronic and UV irradiation, charge recombination and thermal activation.

Space charge measurements for multilayer heterogeneous composite films by thermal pulse method

Multilayer composite films are suitable for high-temperature and high-electric-field insulation, but the accumulation of space charge may lead to the degradation of their insulating properties. However, few studies have been reported on space charge distribution in multilayer composite thin films due to the limitations of space charge measurement techniques. In this study, using Al2O3/PI and BOPP/PI composite structural samples as numerical examples, we proposed a method for calibrating electric fields in multilayer heterogeneous structures and combined it with the Tikhonov regularization algorithm, and successfully reconstructed the electric field distribution inside the samples. Based on this, the experimental results show that the reconstruction of the overall electric field in the BOPP/PI composite samples is consistent with the combined electric field reconstructed after the individual measurements of each layer, which further confirms the feasibility and validity of the use of thermal pulse to measure the charge distribution in multilayer heterogeneous composite films.

A method for calculating space charge distribution in ultra-high voltage direct current transmission lines based on the transport of diluted species theory

The occurrence of corona discharge in ultra-high-voltage direct current transmission lines results in the generation of space charge, which significantly affects the nearby electromagnetic environment. To investigate the micro-physical mechanisms of discharge and provide better guidance for the calculation of the ground ion current density and total electric field, a method based on the theory of the transport of diluted species is proposed. This method enables the visualization and analysis of the movement process of space charge in air medium, as well as the calculation of the total electric field below the transmission lines. To validate the effectiveness of this algorithm, experimental tests of the total electric field are conducted on actual transmission lines. The experimental results demonstrate that the algorithm not only highlights the evident differences in the transient microscopic processes between positive and negative corona discharges but also accurately calculates the total electric field below the transmission lines. In addition, considering the weather conditions in the Chongqing region, relevant recommendations are provided under the influence of wind speed, aiming to offer protection guidelines for individuals engaged in activities near transmission lines.

Effects of DC bias on evolutions of repetitively pulsed streamer discharge in humid air

Modulation efficiency and mechanisms of repetitively pulsed streamer discharge in humid air are ambiguous with dramatic variations in free electron availability, residual ion mobility, enhanced heat release, etc, caused by water molecules intentionally supplemented or existing in the surrounding environment. The inception and propagation patterns of repetitively pulsed streamer discharge modulated by superimposed DC bias are experimentally investigated in the needle-plane electrode configuration. The inception voltage decreases due to negative ion drift under positive DC bias. The secondary streamer with a bright glowing cloud prolongs towards the plane electrode and the diameter decreases under positive DC bias. The primary streamer tends to propagate along the off-axis direction under negative DC bias. The number of applied pulses before breakdown decreases with the increase in positive DC bias and illustrates an insignificant dependence on the negative DC bias. The effect of air humidity is more pronounced than the DC bias. The streamer inception, propagation, and morphological transition are explained by residual space charge distributions and drift velocity.

Effect of nanofillers with different energy levels on the electrical properties of epoxy‐based nanocomposites

AbstractThe authors investigate the effects of nanofillers with varying band‐gap energies on the space charge properties, breakdown field strength, and bulk resistivity of epoxy (EP)‐based composites. Additionally, the molecular orbital distribution of both the epoxy resin and nanofillers were examined through density functional theory. Experimental results indicate that the space charge accumulation within silicon dioxide/EP and germanium oxide/EP is reduced, leading to a more uniformly distributed electric field intensity within the specimen when compared to epoxy. As a result, both materials exhibit improved AC breakdown field strength and volume resistivity. Conversely, the amount of charge accumulated within tin dioxide/EP is higher, resulting in lower breakdown field strength than epoxy. The lowest unoccupied molecular orbital and the highest occupied molecular orbital energy level differences between epoxy and nanofillers introduce electron traps and hole traps at the interface, forming interfacial traps that affect the space charge distribution within the specimen, as well as the trap energy levels within the material. From the experimental results, shallow traps promote space charge accumulation and reduce the breakdown field strength, while deep traps have the opposite effect.

Vacancy pair induced surface chemistry reconstruction of Cs2AgBiBr6/Bi2WO6 heterojunction to enhance photocatalytic CO2 reduction

Cs2AgBiBr6/Bi-O vacancy pair Bi2WO6 (Cs2AgBiBr6/VBi-OBi2WO6) heterojunction was synthesised for photocatalytic CO2 reduction under visible light irradiation. The characterisation results show that the Bi-O vacancy pairs can reconstruct the surface electronic states of the heterojunction. The optimal 10%Cs2AgBiBr6/VBi-OBi2WO6 heterojunction exhibited a substantial CO yield of 48.5 μmol/g, approximately 22 times higher than that of Bi2WO6, exceeding the performance of most of the Bi-based photocatalysts reported to date. The enhanced activity of 10%Cs2AgBiBr6/VBi-OBi2WO6 was due to exposed Bi sites that facilitate the chemisorption and activation of CO2 and the lower reaction energy barrier for the protonation of CO2 to CO via the formation of COOH* intermediates with the cooperation of surface four-coordinated H2O molecules. Furthermore, charge migration from Cs2AgBiBr6 to VBi-OBi2WO6 and space-charge distribution in the heterojunction under visible light irradiation were demonstrated. This work reveals defective heterojunction catalysts that facilitate the transformation of reactive molecules in surface/interfacial reactions.

Modulating space charge of FeP/CoP p-n heterojunction for boosting oxygen evolution reaction

Surface reconstruction of electrocatalysts is an effective strategy to modulate the space charge distribution to enhance the electrocatalytic activity. The p-n heterostructured FeP/CoP-2D octagonal nanoplates were successfully constructed by cation-exchange method. The space charge effect caused by the p-n heterojunction accelerated the electron transfer, optimized the electronic structure, and improved the activity of the active sites during the oxygen evolution reaction process. As a result, FeP/CoP-2D required only 247 mV overpotential to achieve a current density of 10 mA cm−2 with a Tafel slope as low as 68 mV dec-1. Density-functional theory calculations confirmed that the construction of p-n heterojunctions can enhance the adsorption of *OH in the active centers and optimize the Gibbs free energy of the OER reaction. This study provides an effective and feasible strategy for constructing p-n heterojunctions to modulate the space charge state for optimizing the OER performance of electrocatalysts.

Anti-moisture, anti-bacterial cellulosic triboelectric materials enabled by hydroxyl coordination effect

Owing to their low cost, customizability, and environmental stability, cellulosic triboelectric materials have emerged among polymer materials. However, the rich hydrogen bonding network inherent in cellulose limits its polarity and electron-donating ability, and charge dissipation caused by the hygroscopicity of the hydroxyl-rich groups limits its application as a triboelectric material. In this study, a more convenient, economical, and environmentally friendly "stent surgery" strategy was adopted. The wetting and swelling of fiber molecules allowed Cu (II) coordination with hydroxyl groups in nanocellulose. The coordination effect of cellulose hydroxyl groups weakens the intermolecular hydrogen bonding network, leading to an increase in the molecular dipole moment and the formation of new polar regions to regulate its space charge distribution, which significantly improved the electron-supplying capacity of the nanocellulose materials, and the maximum output power density increased by a factor of 2.78 (from 45 to 125 μW cm−2). Notably, the CNF-Cu (II) triboelectric material demonstrated excellent antimicrobial (>99%) and UV transmittance (<8%) as well as resistance to humidity interference, exhibiting only 5.9% voltage output loss at high humidity (90% RH). The design of this study provides new approaches for cellulose polarity modulation and energy harvesting adapted to harsh environments.