Abstract In ultra-high voltage converter stations, the phenomenon of flashover along the outer insulation of dry hollow reactors made of epoxy/glass fiber composites poses a potential threat to the stability of the power system. To enhance its flashover performance under varying complex conditions, it is necessary to conduct in-depth research on the flashover mechanism of this material under different voltage forms. This study conducted tests on the flashover voltage, surface space charge distribution, and partial discharge parameters under varying AC-DC ratios and AC frequencies, and exploring their relationships. The results show that the DC content in the AC-DC ratio decreases, the flashover voltage decreases, the apparent total discharge of partial discharges increases, and the maximum surface space charge density decreases. The main influencing factor is the increase in the number of seed charges involved in gas ionization. Increasing the AC frequency, the flashover voltage decreases, the apparent total discharge increases significantly, and the surface charge density remains basically unchanged. The main reason is that the change in the number of alternating cycles further increases the number of seed charges. This study reveals the flashover mechanism of epoxy/glass fiber composites under different voltage forms, which provides theoretical support for subsequent material modification.