South Portuguese Research Articles

Heterogeneous deformation in fold and thrust belts induced by anisotropies in the ocean topography; the South Portuguese Variscan Zone example (SW Portugal)

The Variscan fold and thrust belt related with the South Portuguese Zone presents a SW forward propagation and the coeval development of synthetic folds and thrusts pervasive at all scales. Although several models have been proposed for their formation, the estimated strain pattern is more compatible with a push from the rear induced by the north-eastern subduction zone. Although there is a strong consistence concerning the kinematics of these Variscan structures, there is an important contrast of their geometries between the inner and the external sectors, where the very low dips prevails. Although, there are some previous models suggesting that the behaviour of the more external domains could be related with the interference between the undeformed sedimentary sequence of the upper plate with the active margin of the fold and thrust belt, independent evidence of this process is lacking. The realization of scaled analogue experiments concerning the Carboniferous evolution of SW Iberia Variscides, not only show that they could induced the flat lying major thrust of the external domains, but also emphasize their important role in the structural evolution of much of the fold and thrust belt.

BivalveNet: A hybrid deep neural network for common cockle (Cerastoderma edule) geographical traceability based on shell image analysis

Bivalve traceability is a major concern. It is of utmost importance to develop tools that allow providing important information to the consumer, not only on the origin of the product but also on its sustainability and safety, due to the harvest restrictions imposed by regulatory entities. This study evaluated the application of computer vision machine learning technologies for efficiently discriminating cockle harvesting origin based on shell geometric and morphometric analysis, improving the traceability methodologies in these organisms, and highlighting the potential of these low-cost techniques as a reliable traceability tool. Thirty Cerastoderma edule samples were collected along the five locations in Atlantic West and South Portuguese coast with individual images processed using lazysnapping segmentation, spectro-textural-morphological phenotype extraction, and feature selection through hybrid Principal Component Analysis and Neighborhood Component Analysis which resulted in R, a*, b*, entropy, and diameter. Three approaches of traceability models were developed and tested: pre-trained networks (EfficientNet-Bo, ResNet101, MobileNetV2, InceptionV3) with numerical inputs (Approach 1), image-based pre-trained networks (Approach 2), and hybrid deep neural networks of Long Short-Term Memory (LSTM), Gated Recurrent Unit (GRU), and Bidirectional LSTM (BiLSTM) (Approach 3). Based on the test results, Approach 3 with GRU-LSTM-BiLSTM sequence exhibited the highest accuracy (96.91%) and sensitivity (96%) among the other thirteen machine learning models, hence, named as BivalveNet. Comparing the attained accuracy from the BivalveNet to other mollusc traceability studies, it was observed that an efficiency close to the attained using standard destructive, time-consuming, and expensive techniques, making BivalveNet a highly advantageous approach for common cockle geographical traceability studies, available for application to other bivalve species.

Crustal Imaging of Portugal Mainland Using Magnetotelluric Data

AbstractThe comprehensive mapping of resistivities in depth and its interpretation is of great importance to unravel the electrical properties of deep‐seated rocks, providing significant insights into the structure of the crust. The first 3D resistivity model for Portugal mainland is here reported using data from 31 broadband MT soundings spaced 50 × 50 km apart. The model shows large crustal volumes with contrasting resistivity values. The central and northern regions are characterized by a high resistivity crustal domain spreading in‐depth (103–105 Ω.m) that correlates well with voluminous granitoid bodies and high‐grade metamorphic rocks. To the west and the south, roughly corresponding to the Portuguese Western Shore and the South Portuguese Zone (SPZ) respectively, the crustal resistivity tends to decrease unevenly to values between 1 and 103 Ω.m. Interconnected graphite in structural discontinuities, possibly forming a regional mid‐crustal décollement at ≈13–15 km depth, are highlighted by multiple low resistivity crustal domains (1–100 Ω.m). Similarly, the model reveals a very large E‐W low resistivity crustal domain in SPZ possibly representing a deep‐seated major décollement. The present study aims to contribute to a better understanding of the physical properties characterizing the concealed crust in Portugal mainland, providing also indirect information on its composition and structure.

Time-space evolution of Iberian Pyrite Belt igneous activity: Volcanic and plutonic lineaments, geochronology, ore horizons and stratigraphic constraints

The volcanism in the Iberian Pyrite Belt migrated from the present day west/southwest to the east/northeast during Devonian/Carboniferous times. Evidence is here discussed based in U-Pb zircon ages of felsic volcanic and plutonic rocks, bounded by enclosed sediments and their biostratigraphic ages, together with hosted massive sulphides deposits and associated plutonic counterparts.Volcano-Sedimentary Complex rocks define several volcanic axes, or lineaments, with the general NW-SE to WNW-ESE belt trending orientation. The usage of all the available data from high-resolution stratigraphy, geology and geophysics lead to establishment of eleven main volcanic axes, nine with zircon U-Pb radiometric ages (166 samples).In this research, we reinforce a previous inter-axes volcanic evolutionary trend, but we also suggest an intra-axis evolutionary trend of the IPB igneous activity with time. This means the basin igneous activity also evolved along most of the volcanic and plutonic lineaments, from west/northwest to east/southeast.Successive weighted average ages for each axis (SW to NE) and opposite end-point sample ages for each axis (NW/W to SE/E) are presented. Similar trends are found with felsic volcanic rocks, subvolcanic and plutonic rocks and even massive sulphide ages correspond to the regional trend corroborating the proposed geological framework.Siliciclastic sediments and lower VSC sequences (sediments, felsic volcanic rocks and massive sulphides) show a comparable age trending evolution although upper VSC sediments seem to be contemporaneous across the province. Older ages, from zircon U-Pb and from associated reworked palynomorph in the sediments, show a long-lasting age distribution along most Devonian times, suggesting the IPB evolved since Lochkovian times (Lower Devonian). Therefore, we propose the IPB inter-axes evolution could be related with a NE-direction plate motion (present-day location) over a heat source, while intra-axes are probably due to the collisional/compressive tectonic interaction of South Portuguese – Ossa-Morena zones tectonic setting.

Palinspastic restoration of Variscan oroclines – implications for dextral transpression and terrane affinities

Abstract The Paleozoic Variscan orogen in Europe has a markedly circuitous trace for which several different origins have been postulated, including deformation around promontories on the colliding continental margins, extrusion within the collision zone, folding of a ribbon continent and collision with a substantial dextral component. Adopting the latter assumption, unfolding of the large, steeply plunging folds (‘oroclines’) of Iberia and the Moroccan Meseta requires more than 4000 km of dextral lateral translation of Laurussia with respect to Gondwana. Constraints on the age of the folding require that this lateral translation occurred in mid-late Carboniferous time. Significant dextral translation of Laurussia with respect to Gondwana late in the Variscan collision is supported by palaeomagnetic data for the two supercontinents, although the exact timing of this relative motion is not well constrained due to large uncertainties in the palaeomagnetic pole positions. Our palinspastic reconstruction of the major Variscan folds of Iberia places the rocks of the South Portuguese Zone of western Iberia adjacent to the Rhenish Massif; for instance, as part of Avalonia. By the same token, the Sehoul Block in the Moroccan Meseta probably originated at the western end of Cadomia, although nothing in our analysis precludes it also being derived from Avalonia.

Detrital zircon similarities and dissimilarities between the Iberian Pyrite Belt, Ossa-Morena Zone and Meguma

Despite the so-called exotic nature of the South Portuguese Zone relatively to the other major domains of the Iberian Massif of peri-Gondwanan affinity, Devonian detrital rocks of the oldest strata in the Iberian Pyrite Belt have a remarkable resemblance with the Ossa-Morena Zone’s Neoproterozoic-Cambrian rocks and the West Meguma’s Cambrian-Ordovician rocks, presenting the so-called “West African signature”.

New Insights about Upwelling Trends off the Portuguese Coast: An ERA5 Dataset Analysis

In recent decades, several studies have highlighted the importance of the temporal and spatial structure of upwelling in defining the high levels of productivity of coastal upwelling systems. This work intends to assess the temporal and spatial trends of upwelling along the west and south Portuguese coasts from 1979 to 2020, comparing the patterns between these regions. Two different methodologies to calculate the upwelling indexes (UI), based on wind and sea surface temperature (SST) data, were applied to relate the wind-induced upwelling-favourable conditions (UIET) with the expected response on superficial waters, as indicated by the SST patterns (UISST). The upwelling-favourable conditions are quite consistent and more frequent and intense on the west coast than on the south coast. Spatially, it was verified from the UIET that upwelling-favourable conditions are more intense in association with the main west coast capes and that there is an intensification of favourable winds towards Cape São Vicente, both on the west and south coasts. Seasonally, upwelling-favourable UIET was found to be more consistent in the summer on both coasts. However, it also exists in the winter months. In terms of interannual variations, it should be highlighted that between 1992 and 2005 more intense favourable conditions and an apparent change in the seasonality after 2015 were found. Although some of the results derived from the UIET are corroborated by the UISST (namely, the main spatial trends and interannual variations in the upwelling intensity), several uncertainties are associated with the last index that interfere with its interpretation. For future works, it is advisable to develop a more robust SST-based index that can circumvent the uncertainties pointed out in the present study.

The Carboniferous shoshonitic (s.l.) gabbro–monzonitic stocks of Veiros and Vale de Maceira, Ossa-Morena Zone (SW Iberian Massif): Evidence for diverse subduction-related lithospheric metasomatism

Post-collisional potassium-rich rocks are a critical petrogenetic and geodynamic marker across the European Variscan Belt. We present a detailed characterization of the only potassium-rich mafic intrusions identified so far in the Ossa-Morena Zone (Iberian Massif). Using new major, trace and SmNd isotopic whole-rock analyses, as well as mineral chemistry analyses, we discussed the petrogenesis of the early Carboniferous potassium-rich Veiros and Vale de Maceira (Portugal) stocks in the geotectonic framework of the southern Iberia, marked by the collision of the Ossa-Morena Zone, a Gondwanan terrane, with the South Portuguese Zone, a Laurussian terrane. The Veiros and Vale de Maceira shoshonites (s.l.) range from gabbros to syenites, with a predominance of monzonites and monzogabbros, characterized by different proportions of olivine, clinopyroxene, orthopyroxene, plagioclase, alkali feldspar, phlogopite and brown hornblende. The Veiros stock is mainly composed of fine-grained ultrapotassic rocks, and the Vale de Maceira stock is composed chiefly of medium-grained shoshonite rocks. A small group of hornblende-bearing medium-grained calk-alkaline rocks was also identified. The stocks have high contents of K2O, MgO, total alkalis, Th and other LILE, high ratios of LREE/HREE and LREE /HFSE, and show a Nb-Ta-Ti negative anomaly, typical of orogenic settings. Sr and Nd isotopes yielded moderate radiogenic Sr and unradiogenic Nd, that might suggest the involvement of a crustal component. However, the combined use of isotopic and elemental compositions rules out significant contamination by crustal materials upon ascent and emplacement. Instead, a source metasomatised by subduction-related fluids and hydrous melts from the slab is proposed. This diversely metasomatised source was a phlogopite-amphibole-bearing and (phlogopite-free) amphibole-bearing lherzolite at the upper part of the garnet stability field in the sub-continental lithospheric mantle. The Devonian mafic volcanic rocks point to a northward dipping (present coordinates) subduction of the Rheic oceanic plate underneath the Ossa-Morena Zone during the Variscan Orogeny. However, the Veiros and Vale de Maceira magmas originated during the post-collisional stage from the partial melting of the supra-subduction metasomatized lithosphere. The melting occurred during a period of enhanced heat due to asthenospheric upwelling related to the slab break-off of the Rheic's slab. The stocks are concomitant with the profusion of granitoid intrusions, which is compatible with a post-collisional tectonic setting. They are also coeval with the opening of the Beja-Acebuches back-arc, likely related to slab roll-back of a segment of the Rheic oceanic crust, implying polyphasic subduction and a complex geodynamic setting for the late stages of oceanic closure in southern Iberia.

Does Ocean Sunfish Mola spp. (Tetraodontiformes: Molidae) Represent a Risk for Tetrodotoxin Poisoning in the Portuguese Coast?

Tetrodotoxin (TTX) is a potent neurotoxin naturally occurring in terrestrial and marine organisms such as pufferfish. Due to the risk of TTX poisoning, fish of Tetraodontidae family and other puffer-related species must not be placed in the EU markets. This restriction applies to fish of the family Molidae even though no data on toxins’ occurrence is available. In this study, the presence of TTX and its analogues was investigated in the main edible tissue (the white muscle) and the main xenobiotics storage organ (the liver) of ocean sunfish Mola spp. (n = 13) from the South Portuguese coast. HILIC-MS/MS analyses did not reveal TTX in the analyzed samples, suggesting an inexistent or very limited risk of TTX poisoning.

A new approach to palynostratigraphy of the middle–late Famennian Gafo Formation, southern sector of the Pulo do Lobo Domain, SW Iberia (Portugal and Spain)

AbstractNew palynological results from the Gafo Formation (southern sector of the Pulo do Lobo Domain, South Portuguese Zone) are integrated with recently studied sections and drillholes from the Portuguese and Spanish sectors. A total of 44 samples were studied, 27 of which were positive for palynomorph taxonomy. This research revealed well preserved palynological assemblages, including 73 spore species allocated to 28 genera, four acritarch genera, three prasinophyte algae genera plus common chitinozoan remains. Some additional forms were retained under open nomenclature. From this, the first complete age determination for the Gafo Formation in Portugal and Spain was achieved, indicating a middle Famennian (Grandispora gracilis–Grandispora famenensis, GF Biozone) to a late Famennian (Grandispora echinata, VH Biozone) age. A greywacke sample from the same Gafo Formation was dated by U–Pb zircon geochronology and a maximum depositional age of 369 ± 2.5 Ma was obtained. A correlation between these palynological and U–Pb zircon data and the palynoflora assemblages of previous authors was made, as well as with the ages of felsic volcanic rocks found intercalated in the Gafo Formation, confirming the complex stratigraphy of Pulo do Lobo Domain. The results are consistent with stratigraphic mapping and structural interpretations, allowing a middle–late Famennian age (GF and VH Biozone) to be assigned to the Gafo Formation sedimentary rocks. This work has also contributed to a reinterpretation of Gafo Formation depositional facies correlatives (e.g. the Santa Barbara Group in Spain) as being the same lithological unit.

The Deep South Portuguese Margin: An Attempt to Account for Heat Flow Density Variation in this Region

Heat flow data measured in a region characterized by a very high and non-uniform thickness (accretionary prism) of sediments, traversed by strike-slip faults in the E-W direction and thrust faults in the N-S direction, were analyzed. Mud volcanoes have been discovered in the region during the last 20 years. The region includes parts of the borders between the Eurasian and the African plates, at SW of the Iberian Peninsula. Sediment porosity and vertical fluid movements were inferred from thermal conductivity and thermal gradient data. Fault location and boundary of the sediment prism were used to test the results inferred and to explain the scatter in the published heat flow values. Special attention was given to values obtained in regions separating different geologic settings (Gorringe Bank – Horseshoe Plain and Marquês de Pombal fault region). Geoid height values were used to obtain information related with heat flow values from deep parts of the Horseshoe plain and in the Gorringe Bank located in the western part of the region studied outside the accretionary prism of sediments. Information related with the evolution of some transient properties in the region were obtained from geoid height variations using three models made for three different years. Information about the thermal disturbance caused by fluid movements in the region and the heat flow values without them were obtained at the end of the work.

Geochemical Considerations from the Carboniferous Unconventional Petroleum System of SW Iberia

The Baixo Alentejo Flysch Group (BAFG) is an important stratigraphic unit that covers over half of the South Portuguese Zone (SPZ) depositional area, and it is composed by three main tectono-stratigraphic units: the Mértola, Mira, and Brejeira formations. All of these formations contain significant thicknesses of black shales and have several wide areas with 0.81 wt.%, 0.91 wt.%, and 0.72 wt.% average total organic carbon (TOC) (respectively) and thermal maturation values within gas zones (overmature). This paper is considering new data from classical methods of organic geochemistry characterization, such as TOC, Rock–Eval pyrolysis, and organic petrography, to evaluate the unconventional petroleum system from the SPZ. A total of 53 samples were collected. From the stratigraphical point of view, TOC values seem to have a random distribution. The Rock–Eval parameters point out high thermal maturation compatible with gas window (overmature zone). The samples are dominated by gas-prone extremely hydrogen-depleted type III/IV kerogen, which no longer has the potential to generate and expel hydrocarbons. The petrographic analyses positioned the thermal evolution of these samples into the end of catagenesis to metagenesis (wet to dry gas zone), with values predominantly higher than 2 %Ro (dry gas zone). The presence of thermogenic hydrocarbon fluids characterized by previous papers indicate that the BAFG from SPZ represents a senile unconventional petroleum system, working nowadays basically as a gas reservoir.

Mobility of potentially toxic elements in family garden soils of the Riotinto mining area

Agricultural soils in mining areas usually accumulate potentially toxic elements (PTEs) that can become a health risk to humans by entering the trophic chain. In this study, five small agricultural plots close to Riotinto mines (SW Spain) were studied, with the aims of comparing the concentration of PTEs with respect to the regional (South Portuguese Zone) baseline and conducting availability studies in order to determine the contamination of soils. Chemical composition, total and clay mineralogy, and edaphic parameters were determined in topsoil and subsoil samples to characterize the soils, and single extractions were conducted to assess the mobility. The mineralogy of the soils was composed of quartz and phyllosilicates, with small amounts of feldspars and occasionally containing hematite and calcite. The texture ranged from sandy to silty loam, the pH was slightly acidic, and high contents of organic matter were found. Total concentrations of trace elements correlated with the texture, the content in iron oxy-hydroxides and the pH. The values of As, Pb, Cu, and Zn exceeded the regional baseline even in sites unaffected by mining. The results suggest that a widespread sampling is necessary to determine the local background. The most water-soluble element was As, due to the competition of organic matter for sorption sites. The content of Cu, Cr and Zn extracted with different methods were higher in sandy soils with low iron oxy-hydroxides content. Monoammonium phosphate and EDTA extractions seemed to remove elements from organic matter and iron oxy-hydroxides. The extracted fractions of As and metals reached up to 10–30 wt%. Despite the high total concentrations of the element in soils, they generally showed low available proportions, especially with water and ammonium acetate extractants. The results suggest that the soils are not necessarily a risk to humans and higher investigation efforts are necessary to assess the availability of PTEs and their transfer to plants.

Whole-rock and Sm–Nd isotopic geochemistry of Triassic SW Iberia sandstones: implications for provenance

Whole-rock and Sm–Nd isotopic geochemistry data were used to characterise the probable sources of the Triassic Alentejo and Algarve sandstones. These rocks were deposited in a rift setting, plot within the recycled field in the QFL and discrimination function diagrams for sandstones, thus supporting derivation from a recycled orogenic terrane. They all show negative Eu anomalies, enrichment of LREE, and nearly flat HREE patterns, typical of upper-continental crustal sources. Their Nd TDM model ages and detrital zircon populations are significantly coincident with those of the Late Devonian-Early Carboniferous Phyllite-Quartzite and Tercenas formations and Early Carboniferous Mira turbidites of the South Portuguese Zone (SPZ), indicating that these may have been their dominant sources, with a minor contribution from the Visean Mertola turbidites. In particular, the Mira turbidites may also be regarded as the dominant source of the eastern Algarve Triassic sandstones. Furthermore, the Nd TDM model ages and the detrital zircon populations of the central Algarve Triassic sandstones as compared with those of the SPZ Late Carboniferous Brejeira and Late Devonian Ronquillo formations suggest a strong source to sink relationship. Finally, some of the western Algarve Triassic sandstones show older Nd TDM model ages which have not been recognized in the SPZ basement rocks, and, hence, suggest that these sediments may derive directly from primary remote sources. We advance the suggestion that beyond remote potential sources from the Meguma Terrane, others from the Moroccan Variscan Belt have been reproduced in the Devonian-Carboniferous SPZ basement as the result of sediment recycling. These SPZ would represent intermediate sediment repositories and would be later on reworked and incorporated into the Triassic Algarve Basin, thus indicating multi-cycle sedimentation.

Age of the basement beneath the Mesozoic Lusitanian Basin revealed by granitic xenoliths from the Papôa volcanic breccia (West Iberia)

The dyke of the Papôa volcanic breccia cross-cutting the Lower Jurassic sequence of the Lusitanian Basin (West Iberia) contains granitic xenoliths. In this study, for the first time, U-Th-Pb zircon analysis of two xenoliths yielded 298±4Ma for biotite granite and of 292±2Ma for two-mica granite, indicating that the pre-Mesozoic basement of the Lusitanian Basin includes Permian intrusions. These ages are close within the margin of error of the age of the Late Carboniferous granites of the Berlengas isle that with the Late Devonian high-grade metamorphic rocks of the Farilhões isles, located northwest of the study area, which form the pre-Mesozoic basement of the Lusitanian Basin. These new geochronological findings enable it to be established that Permo-Carboniferous magmatism lasted at least 13Ma, in this region of the Appalachian-Variscan belt. Furthermore, a comparison with available data from Paleozoic tectonic units of the Appalachian-Variscan belt located both in the Iberian Massif and outside it enables the suggestion to be made that the Lusitanian Basin (Peniche) most probably rests on the South Portuguese Zone, which may also be correlated with the Rhenohercynian Zone present in southwest England, and the Meguma terrane of Nova Scotia.

Hydrocarbon anomalies using airborne gamma radiation over the unconventional petroleum system of the South Portuguese Zone, Portugal

The use of airborne gamma radiation in hydrocarbon exploration is widely known to define possible areas of microseepage. At this paper, the radiometric survey was applied to identify hydrocarbon anomalies over the South Portuguese Zone (SPZ) unconventional petroleum system. Spectral gamma-ray data were processed to thorium normalization method. Obtained results show positive anomalies mainly on the southwest sector of the SPZ, corroborating the data obtained through fluid geochemical analysis, revealing other several surface sweet spots for hydrocarbons emanations.

A first appraisal on copper sources for Chalcolithic settlements in southern Portugal using Pb isotope analysis

This work presents the first provenance study on copper in use by 3rd millennium BC communities in southern Portugal. Copper ores from small mines and copper artefacts from Chalcolithic settlements were subjected to Pb isotope analysis. Some of Pb isotope ratios obtained in ores from the Ossa-Morena Zone, but also from the South Portuguese Zone, evince the existence of deposits with highly radiogenic Pb, which was previously considered rare in the Iberian Peninsula. Pb isotope ratios of artefacts were compared with Pb isotope fields of closer geological/tectonostratigraphic zones, namely the South Portuguese Zone, Ossa-Morena Zone and Central Iberian Zone. The assessment suggests that most artefacts were produced with copper from the Ossa-Morena Zone. Nevertheless, a flat axe of the Três Moinhos settlement is a remarkable exception due to its highly radiogenic Pb signature, which only has parallels in the Iberian Peninsula on copper ores of the Chalcolithic mines of La Profunda and El Milagro (northern Spain). Consequently, this flat axe constitutes the first indication of a possible long-distance trade of copper between the Cantabrian region and southwestern Iberian Peninsula during the 3rd millennium BC.

Physico-Chemical Characterization of Two Portuguese Coastal Systems: Ria de Alvor and Mira Estuary

The present study aims to research the physico-chemical processes in two under-researched coastal systems located on the west and south Portuguese coast—Mira Estuary and Ria de Alvor—through the development and exploitation of dedicated coupled physical and water quality models. Both systems are highly dynamic, supporting a wide range of biological diversity; however, they are characterized by distinct environmental and oceanographic conditions, enhancing the importance of a comparative approach. In this context, the Delft3D modeling suite was implemented and successfully calibrated and validated for both systems, accurately reproducing their hydrodynamic, hydrographic, and chemical features. A broad characterization of Mira Estuary and Ria de Alvor was carried out. Results show that the tidal wave interacts differently with the different geomorphology of each estuary. The tidal wave amplitude decreases as it propagates upstream for both estuaries; however, the magnitude for Ria de Alvor is higher. A flood tidal dominance was found for Mira Estuary, allowing the transport of well-oxygenated water into the estuary, contributing to high residence times in the middle estuary and therefore to poor dissolved oxygen (DO) replenishment. Ria de Alvor shifts from ebb dominance at the central area to flood dominance upstream with low residence times, allowing an effective exchange of water properties. Results also reveal that the water temperature is the dominant driver of seasonal dissolved oxygen variations in both estuaries, with the lowest levels occurring during the late summer months when the water temperature is highest. In addition, pH is influenced by biological activity and freshwater inflow.

Chronostratigraphic framework and provenance of the Ossa-Morena Zone Carboniferous basins (southwest Iberia)

Abstract. Carboniferous siliciclastic and silicic magmatic rocks from the Santa Susana–São Cristovão and Cabrela regions contain valuable information regarding the timing of synorogenic processes in SW Iberia. In this region of the Ossa-Morena Zone (OMZ), late Carboniferous terrigenous strata (i.e., the Santa Susana Formation) unconformably overlie early Carboniferous marine siliciclastic deposits alternating with volcanic rocks (i.e., the Toca da Moura volcano-sedimentary complex). Lying below this intra-Carboniferous unconformity, the Toca da Moura volcano-sedimentary complex is intruded and overlain by the Baleizão porphyry. Original sensitive high-resolution ion microprobe (SHRIMP) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U–Pb zircon are presented in this paper, providing chronostratigraphic and provenance constraints since available geochronological information is scarce and only biostratigraphic ages are currently available for the Santa Susana–São Cristovão region. Our findings and the currently available detrital zircon ages from Paleozoic terranes of SW Iberia (Pulo do Lobo Zone – PLZ – South Portuguese Zone – SPZ – and OMZ) were jointly analyzed using the K–S test and multidimensional scaling (MDS) diagrams to investigate provenance. The marine deposition is constrained to the age range of ca. 335–331 Ma (Visean) by new U–Pb data for silicic tuffs from the Toca da Moura and Cabrela volcano-sedimentary complexes. The Baleizão porphyry, intrusive in the Toca da Moura volcano-sedimentary complex, yielded a crystallization age of ca. 318 Ma (Bashkirian), providing the minimum age for the overlying intra-Carboniferous unconformity. A comparison of detrital zircon populations from siliciclastic rocks of the Cabrela and Toca de Moura volcano-sedimentary complexes of the OMZ suggests that they are derived from distinct sources more closely associated with the SPZ and PLZ than the OMZ. Above the intra-Carboniferous unconformity, the Santa Susana Formation is the result of the recycling of distinct sources located either on the Laurussian side (SPZ and PLZ) or Gondwanan side (OMZ) of the Rheic suture zone. The best estimate of the crystallization age of a granite cobble which was found in a conglomerate from the Santa Susana Formation yielded ca. 303 Ma (Kasimovian–Gzhelian), representing the maximum depositional age for the terrestrial strata. The intra-Carboniferous unconformity seems to represent a stratigraphic gap of approximately 12–14 Myr, providing evidence of the rapid post-accretion and collision uplift of the Variscan orogenic belt in SW Iberia (i.e., the OMZ, PLZ, and SPZ).

Isotope geochemistry evidence for Laurussian-type sources of South Portuguese Zone Carboniferous turbidites (Variscan Orogeny)

Abstract New Rb–Sr isotopic data from South Portuguese Zone (SPZ) turbidites show that the 87 Sr/ 86 Sr( t ) ratio increases from the basal Mértola Formation (Visean–Serpukhovian: 0.706–0.707), through the Mira Formation (Serpukhovian–Bashkirian: 0.706–0.712) to the uppermost Brejeira Formation (Bashkirian–Moscovian: 0.713–0.715). In addition, estimated Nd T DM model ages for the Mértola (1.29–1.09 Ga), Mira (1.58–1.1 Ga) and Brejeira (1.73–1.37 Ga) formations indicate inverted stratigraphy for their isotopic sources. The isotope geochemical data indicate significant changes in the sources from which the SPZ Carboniferous turbidites are derived, consistent with the progressive denudation of a continental magmatic arc built on the Laurussian margin. Mértola turbidites inherited their geochemical and isotopic characteristics from an adjacent dissected Middle–Late Devonian continental magmatic arc with an intermediate–felsic composition: that is a Laurussian (Rheic magmatic arc)-type source. The progressive erosion of its plutonic roots and older host continental basement rocks are indicated in the Mira and Brejeira formations by the increasing contribution of recycled ancient continental crust. The pronounced similarity between the Nd T DM model ages and the detrital zircon populations of the Mira and Brejeira formations (SW Iberia) suggest that they share a common Laurussian (West Avalonia/Meguma terrane)-type source but a contribution from Gondwanan (Ossa-Morena)-type sources cannot be discarded.