Hydrogen Ion Source Research Articles

Cancer radiotherapy with mini neutron/gamma-ray generators

Recent advancements in negative hydrogen (H-) or negative deuterium (D-) ion source technology as well as the commercial availability of high-frequency AC high-voltage power supplies have enabled the development of mini neutron/gamma-ray generators using low-energy nuclear reactions. These generators can provide a useful flux of high-energy neutrons or gamma photons in either pulsed or continuous operations. With the new mini generator, intraoperative radiotherapy as well as treatment of tumors in the brain, skin, breast, salivary gland, pancreas, liver, and kidney can be performed using external or internal neutron/gamma-ray beams. The new radiotherapy system is very compact and requires very low power for operation, enabling its location inside an operation room of a hospital or clinical facility.

Polymer and micellar catalysis in d-fructose oxidation by imidazolium fluorochromate: A kinetic and mechanistic study

This work investigated the oxidation of d-fructose using imidazolium fluorochromate (IFC) as an oxidant and analyzed how sodium dodecyl sulfate (SDS) and polyethylene glycol (PEG-400) affected the reaction kinetics. The process exhibited a unit-order dependence on IFC, d-fructose, and perchloric acid concentration. Perchloric acid was the primary source of hydrogen ions in the reaction mixture. The stoichiometry of the reaction indicated that 3 mol of d-fructose requires 4 mol of IFC. Acrylonitrile, a radical-generating species, did not impact the reaction rate, indicating the absence of a free radical intermediate. The reaction rate decreases as the Mn (II) ions concentration increases, suggesting the involvement of Cr (IV) species in the reaction. The dielectric value of the reaction medium (D) had an inverse effect on the rate, and the outcomes were consistent with the Amis (log k1 and 1/D) and Kirkwood plots (log k1 and (D-1/2D+1)), indicating the presence of dipole-dipole interactions in the process. SDS and PEG-400 catalyzed the reaction. The reaction showed significant catalysis before reaching the critical micelle concentration (CMC). However, the observed rate constants stabilized at higher SDS concentrations exceeding the CMC. Piszkiewicz's cooperativity model was employed to describe the surfactant catalysis, while the Benesi-Hildebrand equation was utilized to explain polymer catalysis. The activation parameters are ΔH† = 44.3 ± 1.3 kJ mol−1, and ΔS† = −133.4 ± 4.3 J K−1 mol−1. The products of the reaction have been identified by spectral analysis as d-arabinoniclactone and formic acid. The formation of an ester complex followed by its decomposition was proposed as the rate-limiting step in the proposed mechanistic reaction pathway.

Towards ITER-Relevant CW Extraction at Negative Ion Sources for Fusion

Negative hydrogen or deuterium ion sources for neutral beam injection (NBI) systems used at fusion devices are based on the surface production process at a caesiated low work function converter surface. While producing a stable and globally homogeneous negative ion beam is not an issue, during long pulses typically a pronounced increase in the co-extracted electrons is observed, limiting the pulse length or the achievable performance. This effect is particularly pronounced in deuterium and it is attributed to an increasing work function of the converter surface. In the last years the negative ion source test facilities at IPP Garching, BATMAN Upgrade (using the small prototype source) and ELISE (using a source of the same width but only half the height of the ITER NBI source) have been converted into CW machines, making possible investigating at ITER conditions counter-measures for the increase in the co-extracted electrons. Investigations are performed, mainly at ELISE, on homogenizing and stabilizing the co-extracted electrons by affecting the ion source plasma close to the converter surface by means of biasing (additional) surfaces in the plasma.

Simple 3D PIC Analysis for Beam Phase Space Oscillation in RF Driven Negative Hydrogen Ion Source

Temporal oscillation of the negative hydrogen ion (H−) beam in the Radio Frequency (RF) ion source is investigated by a simple 3D3V Particle-In-Cell (PIC) model. The model solves electron, proton, and H− transport processes in the extraction region. The calculation domain is from the vicinity of the beam aperture to the ground electrode. To understand the relation between the plasma density oscillation and the extracted H− beam characteristics, the input electron and proton fluxes from the driver region are varied parametrically with the fundamental J-PARC RF frequency (2 MHz). The numerical results give an idea of the main physical processes between the oscillations of the plasma parameters and the extracted H− ion trajectories depending on the plasma meniscus shape in the different RF phases.

Determining absolute VUV fluxes for assessing the relevance of photon-surface interaction in ion sources

A portable device was developed to quantify VUV fluxes flexibly at ion source setups. It consists of a VUV sensitive photodiode and optical filters for wavelength selection and is calibrated against a VUV spectrometer down to 46 nm for a variety of discharge gases, including Ar, N2, O2 and H2. It was applied to the negative hydrogen ion source at BATMAN Upgrade to quantify the VUV radiation emitted by the driver as well as in front of the extraction surface (plasma grid, PG). The combined VUV fluxes impinging on the PG with photon energies larger than 6.6 eV has a comparable magnitude as the ion flux. It could be shown that the recently confirmed influence of the ion source plasma on the surface work function of the PG can at least partly be ascribed to the VUV radiation from the driver and that photo-emitted electrons from the PG should not play a role in the sheath physics.

Work function of the caesiated converter surface at the BATMAN Upgrade H− ion source at different operational scenarios

Since negative hydrogen ion sources for neutral beam injection (NBI) systems rely on the surface production of negative hydrogen ions, Cs is injected to lower the work function of the extraction electrode surface. The adsorbed Cs layers are affected by residual gases from the given non-UHV conditions as well as by reactive hydrogen species during plasma phases, which leads to a complex surface chemistry and the occurrence of temporal changes of the work function. To control the work function and get insight into its temporal dynamics, an absolute work function diagnostic has been developed for ion sources with which measurements can be performed in vacuum phases between pulses. The diagnostic is applied at the BATMAN Upgrade test facility, which is equipped with the prototype RF ion source for the ITER NBI. It is shown that the Cs conditioning of the ion source leads to a dramatic decrease in the work function to ultra-low values < 1.5 eV. First measurements after the application of 1000 s pulses indicate that the ultra-low work function layer is not stable upon long-term plasma exposure and it is revealed that high dynamics of the Cs surface properties are given right after the pulse.

Beam divergence of RF negative hydrogen ion sources for fusion

Neutral beam injectors (NBI) for fusion facilities have strict requirements on the beam divergence (7 mrad for the ITER NBI at 1 MeV). Measurements of the single beamlet divergence of RF negative ion sources (at lower beam energy < 100 keV) show significantly higher values (9–15 mrad), also larger than filament arc sources at similar beam energies. This opened up questions whether the higher divergence is caused by different measurement or evaluation techniques, whether it is a direct cause of the RF source, e.g. due to a higher temperature of negative ions or an oscillating extraction meniscus, and whether it is a problem at all after full acceleration. In a joint effort between the labs modeling and diagnostic capabilities at the NNBI test facilities have been strongly extended and evaluation methods benchmarked. Particularly challenging is the strong increase in beamlet divergence at a lower filling pressure, seen both in filament arc and RF sources.Beside the source and beam investigations carried out in SPIDER (with selected, isolated apertures rather than the total of 1280 apertures) at Consorzio RFX, the IPP test facilities ELISE (640 apertures) and BATMAN Upgrade (70 apertures) contribute to the physics understanding of the beam optics in RF sources. The determination of the beam divergence is not straight-forward because effects originating from measuring the divergence of multiple beamlets (Beam Emission Spectroscopy) and/or constraints from the individual diagnostic (lateral heat conductance in CFC tiles) lead to difficulties. Still, the divergence requirement is not met at the limited total beam energy available at ELISE and BATMAN Upgrade (< 60kV). However, variation of the beam energy show a decrease of the divergence for higher energies and beam simulation for the ITER NBI accelerator predict that the divergence requirement will be met after full acceleration of the negative ion beam.

Discharge characterization of two-region arc plasma (TRAP) ion source

The Korea Atomic Energy Research Institute (KAERI) is developing a novel Two-Region Arc Plasma Ion Source (TRAP) as a negative hydrogen (deuterium) ion source for a Neutral Beam Injection (NBI) system in a fusion tokamak. The TRAP ion source is based on a two-region configuration, comprising a high energy electron region that creates highly vibrationally excited molecules and a low electron temperature region that generates negative ions by attaching electrons to molecules. This configuration can be achieved by optimizing the filament position and magnetic cusp field. In order to optimize the TRAP configuration, the plasma parameters are investigated under various operating conditions, such as filament position, gas pressure, and arc power. Electron density and temperature are determined using Langmuir probe measurements. In this paper, the detailed experimental results are described and discussed.

Influence of surface work function and neutral gas temperature on mechanism of H− production in negative hydrogen ion sources

Negative hydrogen ion sources (NHISs) based on surface production with cesium (Cs) seeded can fulfill the demanded parameters for neutral beam injection systems for ITER. In this study, the Global Model for Negative Hydrogen Ion Source based on volume-produced H− ions is developed to include surface-produced H− ions and is validated against experimental data obtained in a planar inductively coupled plasma discharge used for study of Cs effect on H− production. The H− density predicted by the model decreases three times with surface work function from 2.1 to 4.5 eV, achieving good agreement with the experimental results, as surface conversion yield of particles to H− ions shows exponential decline with surface work function. The model predicts the rise in neutral gas temperature remarkably enhances surface production but reduces volume production of H− ions, because of increase in surface conversion yield of H atoms to H− ions and in electron temperature, respectively. The dependences of H− production on surface work function and neutral gas temperature are analyzed by evaluating creation rates of the H− ions from different reaction pathways. The developed model can be applied for prediction of H− production in NHISs and ultimate parameter optimization of negative ion beams for fusion reactors.

3D modeling of a double-driver ion source considering ion magnetization: an investigation of plasma symmetry modulation methods

A three-dimensional fluid model of a double-driver negative hydrogen ion source for China Fusion Engineering Test Reactor (CFETR) neutral beam injection is developed. In this model, the magnetic filter field is generated by 16 permanent magnets, which are surrounded by a soft iron. In order to accurately describe the transportation of charged species in the presence of strong magnetic field, both the electron magnetization and ion magnetization are taken into account, and the accuracy of the model has been proved by comparison with experimental data. By employing this model, the spatial distributions of the plasma parameters have been investigated, and three methods are proposed to optimize the symmetry at the bottom of the expansion region of a double-driver source. The results indicate that by adjusting the power of Driver I while keeping the power of Driver II constant, the symmetry of the electron density and negative hydrogen ion density could be improved. Furthermore, the inclusion of partition improves the symmetry of the electron temperature and density but has no impact on the regulation of the negative hydrogen ion density distribution. Finally, the application of magnetic shield can not only improve the symmetry of the electron density and negative hydrogen ion density, but also increase their densities at the bottom of the expansion region.

Energy distribution of fragments from H2 and H2 + dissociation by electron impact for the use in numerical models applied to negative ion sources

In negative hydrogen ion sources, the kinetic energy of the atoms is directly related to the negative ion yield at the caesiated converter, with a larger contribution from hot atoms. The energy distribution of hydrogen atoms is related to the formation process: either the kinetic energy release, resulting from dissociation of the hydrogen molecules or molecular ions, or the proton neutralization either in the volume or during reflection at walls. The interpretation of recent experimental measurements related to the translational energy distribution of atoms or positive ions could profit from accurate inclusion of the initial energy distribution in numerical models. In this work, we focus on the calculation of the kinetic energy release for the various dissociation channels due to electron impact on H2 and H2 +, in the Franck-Condon and delta approximation. Since in negative ion sources non-equilibrium vibrational distributions of H2 are found, the energy distribution of fragments is calculated for all vibrational levels. The inverse cumulative distribution functions related to the main dissociation processes are given, as well as the cumulative distributions for all dissociation channels by electron impact, for simple implementation in Monte Carlo numerical simulations. Finally, the application of the method to few cases of interest for negative ion sources is discussed.

Reaction of Partially Methylated Polygalacturonic Acid with Iron(III) Chloride and Characterization of a New Mixed Chloride-Polygalacturonate Complex.

We have described a new route for the preparation of partially methylated polygalacturonic acid containing hydrolyzed (acidic) and unhydrolyzed (methyl esterified) carboxylate groups in a ratio of 1:1 (PGA, compound 1), and one of its basic FeIII-salts (compound 2) with a ~1:2 FeIII:GA stoichiometry (GA means galacturonic acid and methylated galacturonic acid units). The partially hydrolyzed pectin was transformed into compound 1 with the use of double ion exchange with a strongly acidic macroreticular sulfonated styrene-divinylbenzene copolymer as a hydrogen ion source. The reaction of compound 1 with FeCl3 resulted in compound 2. Compound 2 has a polymeric nature and contains binuclear FeIII(µ-O)(µ-OH)FeIII core units with two kinds of distorted octahedral iron geometries. The salt-forming acidic and methylated GA units of compound 1 are coordinated to FeIII centers in asymmetric bidentate-chelating and -bridging (via C=O group and glycosidic oxygen) modes, respectively. Two kinds of outer-sphere chloride anions were also detected by XPS in various chemical environments fixed by different sets of hydrogen bonds. We also observed a partial reduction of FeIII into FeII due to the ring-opening of the chain-end GA units of compound 1. This reaction provides a new route to determine the number of chain-ends in compound 2, and with the use of the number of GA units calculated from charge neutrality, the average length of these chains and the average molecular weight were also determined. The average molecular weight of the partially methylated polygalacturonic acid used in the industrial-scale production of commercial anti-anemic iron-polygalacturonate agents was ~50,000 g/mol. Compound 2 was also characterized by IR, Mössbauer, and X-ray photoelectron spectroscopy, and magnetic susceptibility measurements. These results on the structure and average molecular weight of basic iron(III) polygalacturonate provide a tool to design Fe-PGA complexes with tuned iron-releasing properties.

Effect due to Cs injection upon current oscillation of the beam extracted from the J-PARC negative hydrogen ion source

A high-speed emittance measurement system installed at the J-PARC RF negative hydrogen (H-) ion source test stand can construct emittance diagrams of the beam of a specific frequency component. The driving 2 MHz RF power produces small amplitude oscillating components at 2 MHz and at higher harmonic frequencies in the total H- ion beam detected by a Faraday installed downstream of the emittance measurement system. Magnitudes of oscillating component at 2 MHz and 4 MHz frequencies become appreciable as the slits of the emittance measurement system separate the H- ion beam into the position/angle resolved phase space elements. The reconstructed emittance diagrams of H- ion beams for the operation condition with continuous supply of Cs realizing large H- ion current to total extraction current ratios indicate that 2 MHz and 4 MHz frequency oscillating beam components propagate surrounding the center DC beam. Both 2 MHz and 4 MHz oscillating beam components comprise two to three beam particle groups in the phase space. The DC component of the H- ion beam exhibit a single peak in the angular distribution. Meanwhile, oscillating components often take the minima where the DC H- ion beam takes the maximum in the angular distribution diagram. Thus, the regions that produce large amplitude oscillations of the H- ion beam are considered located at the circumference of the beam extraction aperture. One possible explanation for observing larger amplitude beam oscillation can be the enhanced H- ion surface production at the plasma facing the wall of the beam extraction aperture. The operation without the Cs delivery to the source increased electron current coextracted with H- ions and changed the structure of the beam emittance diagram. In the direction perpendicular to the magnetic fields created by a magnetic filter and electron suppression magnets, the peak of the 4 MHz oscillating beam components appeared at the center of the DC beam. This observation suggests the extraction of H- ions formed in the central region by the volume production process near the internal RF antenna. Mechanisms that can excite and diminish the beam fluctuation amplitudes of the extracted H- ion beam are discussed.

Discoloration of RF antenna coil surface after long-term operation of J-PARC ion source

In J-PARC (Japan Proton Accelerator Research Complex) center, the continuous operation period of the Radio Frequency (RF) negative hydrogen ion (H−) source equipped with the internal RF antenna coil is extended step by step in these 6–7 years for the goal to supply stable beam during the entire period of J-PARC user operation each year. In 2022, the continuous ion source operation for 4,001 hours (5.5 months) was achieved with 60 mA H− beam current at the ion source exit, 25 Hz repetition, mainly 500 μs beam pulse width, and 25 kW RF power injection. As the lifetime of the RF ion source is mainly limited by the deterioration of the enamel coating on the RF antenna coil, a detailed evaluation of the antenna surface is required to ensure the feasibility of the further extension of the operation period. In the present study, surface discoloration on the RF antenna coil observed after 5 months of operation is investigated by the application of a digital microscope and SEM/EDS analyses. The EDS analyses show that depositions of the sputtered stainless steel elements and the injected cesium are the most possible candidates for impurities on the enamel coating. The dimension measurements of the RF antenna thickness before and after the long-term operation also support the assumption that the discoloration is due to the deposited elements and hence insulation of the RF antenna coil by enamel coating is maintained. Possible mechanisms leading to antenna deterioration starting from element depositions on the antenna coating are also discussed in the summary part of this manuscript.

Development and commissioning of a hydrogen ion source for the CERN ALPHA experiment

The CERN ALPHA experiment makes precision measurements of antihydrogen atoms held in a superconducting magnetic minimum trap. Recent studies of the antihydrogen spectrum have provided unique tests of fundamental physics, and to improve on these studies ALPHA is now proposing upgrades to directly compare hydrogen and antihydrogen within their existing atom trap. One route towards producing cold, neutral hydrogen atoms is the integration of a hydrogen ion source into the experiment. Ideally, this should provide both positive (H+, H2 +, H3 +) and negative (H-) ions to facilitate different schemes for producing and trapping hydrogen atoms. For compatibility with ALPHA's existing beamlines, the source must produce modest (∼ 10 μA) beam currents at very low final energies (<100 eV). PELLIS, previously developed at JYFL, is a filament-driven ion source that generates 5–10 keV H- beams with small emittances and tens of microamps of beam current. Here, we present a modified PELLIS design to provide both positive and negative hydrogen ions for ALPHA. The use of an electromagnet filter field in PELLIS allows for the optimisation of H- volume production, and also tuning of the positive ion species fraction. We present simulations of H- (and similarly H+) transport through the initial extraction optics, which have been configured for a lower beam energy of 5 keV and designed to match a proposed beamline to interface with ALPHA. We present the results of detailed vacuum simulations that were used to guide the optics design, allowing the source (at 10-2 mbar) to interface with a transport beamline ∼ 0.5 m downstream that has strict vacuum requirements of < 10-9 mbar. We present experimental results from commissioning of the source, and show that it broadly performs as designed for both positive and negative hydrogen ions.

Ultra-low work function of caesiated surfaces and impact of selected gas species

Modern high-power negative hydrogen ion sources rely predominantly on the surface production of negative hydrogen ions. Hence, low work function converter surfaces are mandatory, for which the alkali metal Cs is commonly evaporated into the ion source to lower the work function of refractory metals by surface adsorption. To study the work function behaviour upon caesiation under the typically given non-ultra-high vacuum conditions, investigations are performed at a dedicated laboratory experiment. In a vacuum environment dominated by water vapour, the work function evolution is found to be dependent on the flux ratio of Cs to H2O onto the surface. For sufficiently high flux ratios, ultra-low work functions in the range of 1.25±0.10 eV are generated with excellent reproducibility. In the absence of Cs evaporation, the work function gradually increases under the influence of the residual gases, and re-caesiation processes lead to lower quantum efficiencies and higher work functions of typically 1.9–2.1 eV. While the addition of hydrogen and deuterium gas at several Pa as well as the leakage of inert gases (argon and nitrogen) into the vacuum system have a negligible influence on the caesiation process, small amounts of oxygen with partial pressures of ∼10-2–10-1 Pa lead to an instant reduction of the Cs density in the gas phase by several orders of magnitude and to an increase in the work function of the order of 1 eV. After the oxygen exposure is terminated, however, the Cs density and work function fully recover within several minutes.

Development and Testing of a High-Frequency Driver for a Charge-Exchange Source of Negative Hydrogen Ions

A source of negative hydrogen ions based on the recharging of a beam of positive ions in a gas target is being developed at the Institute of Nuclear Physics. G.I. Budker SB RAS. The charge exchange source can be used to inject into the tandem accelerator a neutron source intended for boron neutron capture therapy. One of the important elements of the source is the plasma emitter, which creates positive ions for primary acceleration. As an emitter, a high-frequency driver based on an induction discharge and designed for a multi-second operating mode was chosen. In this work, we measured the emission characteristics of a high-frequency driver using a moving grid probe. As a result, the parameters necessary for the use of the driver in a rechargeable source of negative ions have been achieved. The analysis of experimentally measured thermal loads in the multisecond mode is carried out.

Effect of H atoms and O impurities on the adsorption stability and work function of the cesiated Mo(0 0 1) surface: A study about negative hydrogen ion sources for neutral beam injection systems

The impact of H atoms and O impurities on the adsorption stability and work function of cesiated Mo (001) surface are investigated in this paper through DFT calculations. The 53 surface structures with different surface coverages are constructed in this work. Two types of co-deposition structures are considered: Cs-O (or Cs-H) bonds (1) leaning towards and (2) perpendicular to the surface. Our results demonstrate that the minimum work function corresponds to a 0.5 ML coverage of Cs for any surface coverage of H (or O) when the bonds are tilted. Compared to pure Cs deposition, the work function of Cs and H (or O) co-deposition surface increases at low or saturated Cs coverage, while decreases at 0.5 ML. Analysis of the surface dipole moment revealed that the work function changed inversely with the surface dipole moment density. Comparing charge transfer and polarization, it is evident that charge polarization has a significant impact on dipole moment changes. The presence of O impurities significantly enhances the adsorption stability of Cs, with higher coverage of O impurities leading to greater adsorption stability. The average adsorption energy of Cs atoms increases by ∼0.36 eV when co-deposits with O (0.5 θ). The effect of the H atoms on the adsorption stability of Cs atoms is limited. We also find that the vertical co-deposition case did not offer an advantage in terms of adsorption stability and low work function.

Experimental and simulation study on the backstreaming positive ions on the quarter-size negative ion source for CRAFT NNBI test facility

As an effective methods of plasma heating, neutral beam injection (NBI) systems based on negative hydrogen ion sources will be utilized in future magnetic-confinement nuclear fusion experiments. Because of the collisions between the fast negative ions and the neutral background gas, the positive ions are inevitable created in the acceleration region in the negative NBI system. These positive ions are accelerated back into the ion source and become high energy backstreaming ions. In order to explore the characters of backstreaming ions, the track and power deposition of backstreaming H+ beam is estimated using the experimental and simulation methods at NNBI test facility. Results show that the flux of backstreaming positive ions is 1.93 % of that of negative ion extraction from ion source, and the magnet filed in the beam source has an effect on the backstreaming positive ions propagation.

Constant current pulsed power supply for long pulse arc discharge positive hydrogen ion source.

The simplest way to produce high density hydrogen plasmas is to form an arc between the arcing electrode and the plasma chamber (cathode). For arc-based hydrogen plasma generation, a pulsed power supply that delivers 2 ms-long constant current pulse has been developed. This pulsed power supply employs a high frequency buck converter topology with a nonlinear filter inductor. This paper describes the development and testing of a constant current pulsed power supply that operates at 50A and 550V with a pulse width of 2ms and a pulse repetition rate of 2Hz. By changing the arc current, the arc impedance and the positive hydrogen ion current were also measured. The extraction of positive hydrogen ions was carried out using a three-electrode extraction design, which results in a current of 80 mA of positive hydrogen ions at an energy of 50keV.