The quasi-potential approach is very famous in modern relativistic particles physics. This approach is based on the so-called covariant single-time formulation of quantum field theory in which the dynamics of fields and particles is described on a space-like three-dimensional hypersurface in the Minkowski space. Special attention in this approach is paid to methods for constructing various quasi-potentials. The quasipotentials allow to describe the characteristics of relativistic particles interactions in quark models such as amplitudes of hadron elastic scatterings, mass spectra, widths of meson decays and cross sections of deep inelastic scatterings of leptons on hadrons. In this paper SturmLiouville problems with periodic boundary conditions on a segment and a positive half-line for the 2m-order truncated relativistic finite-difference Schrdinger equation (LogunovTavkhelidzeKadyshevsky equation, LTKT-equation) with a small parameter are considered. A method for constructing of asymptotic eigenfunctions and eigenvalues in the form of asymptotic series for singularly perturbed SturmLiouville problems with periodic boundary conditions is proposed. It is assumed that eigenfunctions have regular and boundary-layer components. This method is a generalization of asymptotic methods that were proposed in the works of A. N. Tikhonov, A. B. Vasilyeva, and V. F Butuzov. We present proof of theorems that can be used to evaluate the asymptotic convergence for singularly perturbed problems solutions to solutions of degenerate problems when 0 and the asymptotic convergence of truncation equation solutions in the case m. In addition, the SturmLiouville problem on the positive half-line with a periodic boundary conditions for the quantum harmonic oscillator is considered. Eigenfunctions and eigenvalues
 are constructed for this problem as asymptotic solutions for 4-order LTKT-equation.